Basic Information

Faculty

• 理学部

Academic Degree

• 修士（理学）(九州大学)
• 博士（理学）(九州大学)

ID,URL

• J-Global ID

  201401097040279620

Website(s) (URL(s))

• https://scholar.google.co.jp/citations?user=eDI39pQAAAAJ&hl=ja

researchmap URL

• https://researchmap.jp/7000008974

Research

Research Topics, Overview of the research

• Research Topics

  1. Syntheses and electronic properties of novel mixed-valence ladder complexes
  2. Fabrications and functionalities of crystalline metal-organic framework nanofilms

Research Areas

• Nanotechnology/Materials, Inorganic and coordination chemistry

Papers

• Strain-Controlled Spin Transition in Heterostructured Metal-Organic Framework Thin Film

  Tomoyuki Haraguchi; Kazuya Otsubo; Osami Sakata; Akihiko Fujiwara; Hiroshi Kitagawa

  Journal of the American Chemical Society, 06 Oct. 2021

  
• Ni@onion-like carbon and Co@amorphous carbon: control of carbon structures by metal ion species in MOFs

  Megumi Mukoyoshi; Hirokazu Kobayashi; Kohei Kusada; Kazuya Otsubo; Mitsuhiko Maesato; Yoshiki Kubota; Tomokazu Yamamoto; Syo Matsumura; Hiroshi Kitagawa

  CHEMICAL COMMUNICATIONS, May 2021

  
• Surface morphology-induced spin-crossover-inactive high-spin state in a coordination framework

  Shun Sakaida; Kazuya Otsubo; Ken Ichi Otake; Shogo Kawaguchi; Mitsuhiko Maesato; Susumu Kitagawa; Hiroshi Kitagawa

  Chemical Communications, 11 Feb. 2021

  
• A mixed-valent metal-organic ladder linked by pyrazine

  Ken-ichi Otake; Kazuya Otsubo; Hiroshi Kitagawa

  JOURNAL OF PHYSICS-CONDENSED MATTER, Jan. 2021

  
• Crystal Size Effect on the Spin-Crossover Behavior of {Fe(py)2[Pt(CN)4]} (py = Pyridine) Monitored by Raman Spectroscopy.

  Shun Sakaida; Kazuya Otsubo; Mitsuhiko Maesato; Hiroshi Kitagawa

  Inorganic chemistry, 07 Dec. 2020

  
• Remarkably enhanced proton conduction of {NBu2(CH2COOH)2}[MnCr(ox)3] by multiplication of carboxyl carrier in the cation.

  Hisashi Ōkawa; Kazuya Otsubo; Yukihiro Yoshida; Hiroshi Kitagawa

  Chemical communications (Cambridge, England), 07 Jun. 2020, Peer-reviewed

  
• A Phosphate-Based Silver-Bipyridine 1D Coordination Polymer with Crystallized Phosphoric Acid as Superprotonic Conductor.

  Arun Pal; Shyam Chand Pal; Kazuya Otsubo; Dae-Woon Lim; Santanu Chand; Hiroshi Kitagawa; Madhab C Das

  Chemistry (Weinheim an der Bergstrasse, Germany), 06 Apr. 2020, Peer-reviewed

  
• Confined water-mediated high proton conduction in hydrophobic channel of a synthetic nanotube

  Ken-ichi Otake; Kazuya Otsubo; Tokutaro Komatsu; Shun Dekura; Jared M. Taylor; Ryuichi Ikeda; Kunihisa Sugimoto; Akihiko Fujiwara; Chien-Pin Chou; Aditya Wibawa Sakti; Yoshifumi Nishimura; Hiromi Nakai; Hiroshi Kitagawa

  Nature Communications, Feb. 2020, Peer-reviewed

  
• Network-Selectivity, Magnetism, and Proton Conduction of 2-D and 3-D Metal-Organic Frameworks of the Constituents {P(CH2OH)4}+/MII (MnII, FeII, or CoII)/[CrIII(ox)3]3.

  Hisashi O Kawa; Yukihiro Yoshida; Kazuya Otsubo; Hiroshi Kitagawa

  Inorganic chemistry, 06 Jan. 2020, Peer-reviewed

  
• A Novel Platinum(III)-Platinum(III) Neutral Dimer Complex, Pt-2(cdtb)(4)I-2 (cdtb: 4-Cyanodithiobenzoate)

  Moriyama Hayato; Otsubo Kazuya; Aoki Kentaro; Maesato Mitsuhiko; Sugimoto Kunihisa; Kitagawa Hiroshi

  CHEMISTRY LETTERS, Sep. 2019, Peer-reviewed

  
• Modular Cavities: Induced Fit of Polar and Apolar Guests into Halogen-Based Receptors

  Kentaro Aoki; Kazuya Otsubo; Garry S. Hanan; Kunihisa Sugimoto; Hiroshi Kitagawa

  Inorganic Chemistry, 04 Jun. 2018, Peer-reviewed

  
• Compression of a Flapping Mechanophore Accompanied by Thermal Void Collapse in a Crystalline Phase

  Takuya Yamakado; Kazuya Otsubo; Atsuhiro Osuka; Shohei Saito

  Journal of the American Chemical Society, 23 May 2018, Peer-reviewed

  
• Emergence of Surface- and Interface-Induced Structures and Properties in Metal–Organic Framework Thin Films

  Tomoyuki Haraguchi; Kazuya Otsubo; Hiroshi Kitagawa

  European Journal of Inorganic Chemistry, 30 Apr. 2018, Peer-reviewed

  
• Superprotonic Phase Change to a Robust Phosphonate Metal-Organic Framework

  Zohreh Hassanzadeh Fard; Norman E. Wong; Christos D. Malliakas; Padmini Ramaswamy; Jared M. Taylor; Kazuya Otsubo; George K. H. Shimizu

  Chemistry of Materials, 23 Jan. 2018, Peer-reviewed

  
• A highly crystalline oriented metal-organic framework thin film with an inorganic pillar

  Yuki Watanabe; Tomoyuki Haraguchi; Kazuya Otsubo; Osami Sakata; Akihiko Fujiwara; Hiroshi Kitagawa

  CHEMICAL COMMUNICATIONS, Sep. 2017, Peer-reviewed

  
• Nanoscale crystalline architectures of Hofmann-type metal-organic frameworks

  Kazuya Otsubo; Tomoyuki Haraguchi; Hiroshi Kitagawa

  COORDINATION CHEMISTRY REVIEWS, Sep. 2017, Peer-reviewed

  
• Fabrication and Structural Characterization of an Ultrathin. Film of a Two-Dimensional-Layered Metal-Organic Framework, {Fe(py)(2)[Ni(CN)(4)]} (py = pyridine)

  Shun Sakaida; Tomoyuki Haraguchi; Kazuya Otsubo; Osami Sakata; Akihiko Fujiwara; Hiroshi Kitagawa

  INORGANIC CHEMISTRY, Jul. 2017, Peer-reviewed

  
• Mixed-Valence Nickel Bis(azamacrocycle) Compounds with Ghost-Leg-type Sheets

  Ryota Hashiguchi; Kazuya Otsubo; Mitsuhiko Maesato; Kunihisa Sugimoto; Akihiko Fujiwara; Hiroshi Kitagawa

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Mar. 2017, Peer-reviewed

  
• An Electrically Conductive Single-Component Donor-Acceptor-Donor Aggregate with Hydrogen-Bonding Lattice.

  Hayashi M; Otsubo K; Maesato M; Komatsu T; Sugimoto K; Fujiwara A; Kitagawa H

  Inorganic chemistry, 19 Dec. 2016, Peer-reviewed

  
• Guest-Induced Two-Way Structural Transformation in a Layered Metal-Organic Framework Thin Film

  Tomoyuki Haraguchi; Kazuya Otsubo; Osami Sokota; Akihiko Fujiwara; Hiroshi Kitagawa

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2016, Peer-reviewed

  
• Conducting Behavior and Valence Ordering of a One-Dimensional MMX-Type Coordination Polymer under High Pressure

  Kazuya Otsubo; Tomohiko Suto; Atsushi Kobayashi; Ryuichi Ikeda; Masato Hedo; Yoshiya Uwatoko; Hiroshi Kitagawa

  EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Sep. 2016, Peer-reviewed

  
• Crystalline coordination framework endowed with dynamic gate-opening behaviour by being downsized to a thin film

  Shun Sakaida; Kazuya Otsubo; Osami Sakata; Chulho Song; Akihiko Fujiwara; Masaki Takata; Hiroshi Kitagawa

  NATURE CHEMISTRY, Apr. 2016, Peer-reviewed

  
• Ultrafine metal-organic right square prism shaped nanowires

  Otake, K.-I.; Otsubo, K.; Sugimoto, K.; Fujiwara, A.; Kitagawa, H.

  Angewandte Chemie - International Edition, 2016, Peer-reviewed

  
• Neutral-Type One-Dimensional Mixed-Valence Halogen-Bridged Platinum Chain Complexes with Large Charge-Transfer Band Gaps

  Otake, K.-I.; Otsubo, K.; Sugimoto, K.; Fujiwara, A.; Kitagawa, H.

  Inorganic Chemistry, 2016, Peer-reviewed

  
• A three-dimensional accordion-like metal organic framework: synthesis and unconventional oriented growth on a surface

  Tomoyuki Haraguchi; Kazuya Otsubo; Osami Sakata; Shogo Kawaguchi; Akihiko Fujiwara; Hiroshi Kitagawa

  CHEMICAL COMMUNICATIONS, 2016, Peer-reviewed

  
• Remarkable Lattice Shrinkage in Highly Oriented Crystalline Three-Dimensional Metal-Organic Framework Thin Films

  Tomoyuki Haraguchi; Kazuya Otsubo; Osami Sakata; Akihiko Fujiwara; Hiroshi Kitagawa

  INORGANIC CHEMISTRY, Dec. 2015, Peer-reviewed

  
• Lithium Ion Diffusion in a Metal–Organic Framework Mediated by an Ionic Liquid

  Fujie, Kazuyuki; Ikeda, Ryuichi; Otsubo, Kazuya; Yamada, Teppei; Kitagawa, Hiroshi

  Chemistry of Materials, Nov. 2015, Peer-reviewed

  
• Proton Conduction Study on Water Confined in Channel or Layer Networks of La^IIIM^III(ox)<inf>3</inf>·10H<inf>2</inf>O (M = Cr, Co, Ru, La)

  Hisashi Okawa; Masaaki Sadakiyo; Kazuya Otsubo; Ko Yoneda; Teppei Yamada; Masaaki Ohba; Hiroshi Kitagawa

  Inorganic Chemistry, 08 Sep. 2015, Peer-reviewed

  
• Proton Conduction Study on Water Confined in Channel or Layer Networks of (LaMIII)-M-III(ox)(3)center dot 10H(2)O (M = Cr, Co, Ru, La)

  Hisashi Okawa; Masaaki Sadakiyo; Kazuya Otsubo; Ko Yoneda; Teppei Yamada; Masaaki Ohba; Hiroshi Kitagawa

  INORGANIC CHEMISTRY, Sep. 2015, Peer-reviewed

  
• The Role of a Three Dimensionally Ordered Defect Sublattice on the Acidity of a Sulfonated Metal-Organic Framework

  Jared M. Taylor; Tokutaro Komatsu; Shun Dekura; Kazuya Otsubo; Masaki Takata; Hiroshi Kitagawa

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 2015, Peer-reviewed

  
• Low temperature ionic conductor: ionic liquid incorporated within a metal-organic framework

  Kazuyuki Fujie; Kazuya Otsubo; Ryuichi Ikeda; Teppei Yamada; Hiroshi Kitagawa

  CHEMICAL SCIENCE, 2015, Peer-reviewed

  
• Homochiral metal phosphonate nanotubes

  Xun-Gao Liu; Song-Song Bao; Jian Huang; Kazuya Otsubo; Jian-Shen Feng; Min Ren; Feng-Chun Hu; Zhihu Sun; Li-Min Zheng; Shiqiang Wei; Hiroshi Kitagawa

  CHEMICAL COMMUNICATIONS, 2015, Peer-reviewed

  
• A compact planar low-energy-gap molecule with a donor-acceptor-donor nature based on a bimetal dithiolene complex

  Mikihiro Hayashi; Kazuya Otsubo; Tatsuhisa Kato; Kunihisa Sugimoto; Akihiko Fujiwara; Hiroshi Kitagawa

  CHEMICAL COMMUNICATIONS, 2015, Peer-reviewed

  
• Metal-organic framework thin films with well-controlled growth directions confirmed by x-ray study

  Kazuya Otsubo; Hiroshi Kitagawa

  APL MATERIALS, Dec. 2014, Peer-reviewed

  
• Influence of Confined Polymer Structure on Proton Transport Property in Sulfonated Polyimide Thin Films

  Karthik Krishnan; Tomoaki Yamada; Hiroko Iwatsuki; Mitsuo Hara; Shusaku Nagano; Kazuya Otsubo; Osami Sakata; Akihiko Fujiwara; Hiroshi Kitagawa; Yuki Nagao

  ELECTROCHEMISTRY, Oct. 2014, Peer-reviewed

  
• Enhancing Proton Conduction in 2D Co-La Coordination Frameworks by Solid-State Phase Transition

  Song-Song Bao; Kazuya Otsubo; Jared M. Taylor; Zheng Jiang; Li-Min Zheng; Hiroshi Kitagawa

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2014, Peer-reviewed

  
• Hierarchical structural fabrications based on transition-metal complexes in the nanometer scale

  大坪 主弥; 北川 宏

  京都大学低温物質科学研究センター誌 : LTMセンター誌, Jun. 2014

  
• Structural design and electronic properties of halogen-bridged mixed-valence ladder systems with even numbers of legs

  Kazuya Otsubo; Hiroshi Kitagawa

  CRYSTENGCOMM, 2014, Peer-reviewed

  
• Structural design and electronic properties of halogen-bridged mixed-valence ladder systems with even numbers of legs

  Kazuya Otsubo; Hiroshi Kitagawa

  CRYSTENGCOMM, 2014, Peer-reviewed

  
• Variable-Rung Design for a Mixed-Valence Two-Legged Ladder System Situated in a Dimensional Crossover Region

  Kazuya Otsubo; Atsushi Kobayashi; Kunihisa Sugimoto; Akihiko Fujiwara; Hiroshi Kitagawa

  INORGANIC CHEMISTRY, Jan. 2014, Peer-reviewed

  
• Superprotonic Conductivity in a Highly Oriented Crystalline Metal-Organic Framework Nanofilm

  Gang Xu; Kazuya Otsubo; Teppei Yamada; Shun Sakaida; Hiroshi Kitagawa

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2013, Peer-reviewed

  
• A Novel Triangular Macrocyclic Compound, [(tmeda)Pt(azpy)](3)(PF6)(6)center dot 13H(2)O (tmeda: Tetramethylethylenediamine, azpy: 4,4 '-Azopyridine)

  Ryota Hashiguchi; Kazuya Otsubo; Hodeki Ohtsu; Hiroshi Kitagawa

  CHEMISTRY LETTERS, Apr. 2013, Peer-reviewed

  
• Designer coordination polymers: dimensional crossover architectures and proton conduction

  Teppei Yamada; Kazuya Otsubo; Rie Makiura; Hiroshi Kitagawa

  CHEMICAL SOCIETY REVIEWS, 2013, Peer-reviewed

  
• Facile "Modular Assembly" for Fast Construction of a Highly Oriented Crystalline MOF Nanofilm

  Gang Xu; Teppei Yamada; Kazuya Otsubo; Shun Sakaida; Hiroshi Kitagawa

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Oct. 2012, Peer-reviewed

  
• Step-by-Step Fabrication of a Highly Oriented Crystalline Three-Dimensional Pillared-Layer-Type Metal-Organic Framework Thin Film Confirmed by Synchrotron X-ray Diffraction

  Kazuya Otsubo; Tomoyuki Haraguchi; Osami Sakata; Akihiko Fujiwara; Hiroshi Kitagawa

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jun. 2012, Peer-reviewed

  
• Bottom-up realization of a porous metal-organic nanotubular assembly

  Kazuya Otsubo; Yusuke Wakabayashi; Jun Ohara; Shoji Yamamoto; Hiroyuki Matsuzaki; Hiroshi Okamoto; Kiyofumi Nitta; Tomoya Uruga; Hiroshi Kitagawa

  NATURE MATERIALS, Apr. 2011, Peer-reviewed

  
• Magnetic Properties of Segregated Layers Containing M(II)3(mu(3)-OH)(2) (M = Co or Ni) Diamond Chains Bridged by cis,cis,cis-1,2,4,5-Cyclohexanetetracarboxylate

  Mohamedally Kurmoo; Kazuya Otsubo; Hiroshi Kitagawa; Marc Henry; Masaaki Ohba; Seishi Takagi

  INORGANIC CHEMISTRY, Oct. 2010, Peer-reviewed

  
• Pressure-Induced Consecutive Phase Transitions of a Metallic MMX-Chain Complex, Pt-2(dtp)(4)I (dtp: C2H5CS2-)

  Kazuya Otsubo; Atsushi Kobayashi; Masato Hedo; Yoshiya Uwatoko; Hiroshi Kitagawa

  CHEMISTRY-AN ASIAN JOURNAL, 2009, Peer-reviewed

  
• Most stable metallic phase of the mixed-valence MMX-chain, Pt-2(dtp)(4)I (dtp=C2H5CS2-), in purely d-electronic conductors based on the transition-metal complex

  K Otsubo; A Kobayashi; H Kitagawa; M Hedo; Y Uwatoko; H Sagayama; Y Wakabayashi; H Sawa

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jun. 2006, Peer-reviewed

  

Misc.

• 25aZB-2 Physical property and structural control of MX-Ladder complex

  Kobayashi Atsushi; Otsubo Kazuya; Kitagawa Hiroshi; Wakabayashi Yusuke; Sawa Hiroshi

  Meeting abstracts of the Physical Society of Japan, 18 Aug. 2006

  
• 28pTD-5 Physical property of MX-Ladder complex under high pressure

  Kobayashi Atsushi; Otsubo Kazuya; Kitagawa Hiroshi; Hedo Masato; Uwatoko Yoshiya; Sagayama Hajime; Wakabayashi Yusuke; Sawa Hiroshi

  Meeting abstracts of the Physical Society of Japan, 04 Mar. 2006

  
• 27aYF-6 Synthesis and physical properties of 4-legged MX-Ladder complex, [Pt(en)(bpy)I]_4(NO_3)_8・16H_2O

  Otsubo Kazuya; Kitagawa Hiroshi; Wakabayashi Yusuke; Ohara Jun; Yamamoto Shoji; Matsuzaki Hiroyuki; Okamoto Hiroshi

  Meeting abstracts of the Physical Society of Japan, 03 Mar. 2009

  
• 27aYF-7 Valence Arrangement of Pt Ions in the Tube Type MX Complex [Pt(en)(bpy)I]_4(NO_3)_8・16H_2O

  Wakabayashi Y.; Otsubo K.; Kitagawa H.

  Meeting abstracts of the Physical Society of Japan, 03 Mar. 2009

  
• 27aYF-9 Optical Analysis of Tube-Shaped Iodine-Bridged Platinum Complexes

  Yamamoto Shoji; Ohara Jun; Otsubo Kazuya; Kitagawa Hiroshi; Okamoto Hiroshi

  Meeting abstracts of the Physical Society of Japan, 03 Mar. 2009

  
• 金属錯体をパーツとして組みあがったナノチューブ (材料開発最前線 新しいナノチューブ)

  大坪 主弥; 北川 宏

  未来材料, Apr. 2012

  
• 23aTF-8 Synthesis and physical properties of 4-legged MX-Ladder complexes

  Otsubo Kazuya; Kitagawa Hiroshi

  Meeting abstracts of the Physical Society of Japan, 29 Feb. 2008

  
• シアノ基を付与したジチオカルボン酸を配位子に持つ新規白金複核錯体の合成と物性

  森山隼人; 大坪主弥; 青木健太郎; 前里光彦; 杉本邦久; 杉本邦久; 北川宏; 北川宏

  京都大学物性科学センター誌, 2020

  
• 環状三角形錯体中への極性および非極性のゲスト分子の包接

  青木健太郎; 大坪主弥; HANAN Garry; 杉本邦久; 北川宏

  ホスト-ゲスト・超分子化学シンポジウム講演要旨集, 2019

  
• シアノ基を付与したジチオカルボン酸を配位子に持つ新規Pt(III)複核錯体の合成と物性

  森山隼人; 大坪主弥; 青木健太郎; 前里光彦; 杉本邦久; 杉本邦久; 北川宏; 北川宏

  錯体化学会討論会講演要旨集, 2019

  
• 電子アクセプター性を有する新規4本鎖MX‐tube錯体の合成

  青木健太郎; 大坪主弥; 北川宏

  京都大学物性科学センター誌, Jun. 2018

  
• アニオン性無機配位子を有する多孔性配位高分子を用いた新規結晶配向性ナノ薄膜の創製

  渡邉雄貴; 原口知之; 大坪主弥; 坂田修身; 藤原明比彦; 北川宏

  錯体化学会討論会講演要旨集, 01 Sep. 2017

  
• 多孔性金属錯体のナノ薄膜化による隠されたガス分子吸着特性の発現

  原口知之; 大坪主弥; 北川宏

  Isotope News (Web), Aug. 2017

  
• ナノサイズの薄膜化により動的なゲート開閉挙動を示す金属有機構造体

  大坪主弥; 北川宏

  応用物理, 10 Jun. 2017

  
• Hofmann型多孔性配位高分子によるヘテロ接合型ナノ薄膜の構築とスピン転移の制御

  原口知之; 大坪主弥; 坂田修身; 藤原明比古; 北川宏

  京都大学物性科学センター誌, Jun. 2017

  
• 特異なあみだくじ状シート構造を有するニッケルMX‐Ghost‐Leg錯体の合成と電子物性

  橋口良太; 大坪主弥; 前里光彦; 北川宏

  京都大学物性科学センター誌, Jun. 2017

  
• 二次元物質の科学 グラフェンなどの分子シートが生み出す新世界 日本化学会編 18 多孔性金属錯体の表面ナノアーキテクチャ

  牧浦理恵; 大坪主弥; 北川宏

  CSJ Current Review, 30 Mar. 2017

  
• アニオン性ピラー配位子を有する多孔性配位高分子を用いた新規結晶配向性ナノ薄膜の構築

  渡邉雄貴; 原口知之; 大坪主弥; 坂田修身; 藤原明比古; 北川宏

  日本化学会春季年会講演予稿集(CD-ROM), 03 Mar. 2017

  
• 特異な二次元シート構造を有するニッケルMX‐Ghost Leg錯体の合成と電子物性

  橋口良太; 大坪主弥; 前里光彦; 河口彰吾; 杉本邦久; 藤原明比古; 北川宏

  分子科学討論会講演プログラム&要旨(Web), 2016

  
• Hierarchical structural Fabrications Based on Transition-Metal Complexes in the Nanoscale

  大坪 主弥; 北川 宏

  ナノ学会会報 = The bulletin of the Society of Nano Science and Technology, Apr. 2013

  
• 27aXF-8 Crystal Structure and Electronic State of a Novel 4-legged MX-tube Platinum Complex with a short inter-chain distance

  Otake Ken-ichi; Otsubo Kazuya; Sugimoto Kunihisa; Fujiwara Akihiko; Kitagawa Hiroshi

  Meeting Abstracts of the Physical Society of Japan, 2013

  
• 21aEB-8 Crystal Structure and Electronic State of a Novel 4-legged MX-tube typed Platinum Complex with Bulky Chelate Ligands

  Otake Ken-ichi; Otsubo Kazuya; Sugimito Kunihisa; Fujiwara Akihiko; Kitagawa Hiroshi

  Meeting Abstracts of the Physical Society of Japan, 2012

  
• 新規水素結合型電荷移動錯体の合成・構造と電子状態

  柴原壮太; 大坪主弥; 山田鉄兵; 北川宏; 小澤芳樹; 鳥海幸四郎; 久保孝史; 中筋一弘

  錯体化学討論会講演要旨集, 08 Sep. 2006

  
• 新規水素結合型電荷移動錯体[Ni(Hmepydt)₂]TCNQの構造と物性

  柴原壮太; 大坪主弥; 稲垣祐二; 山田鉄兵; 北川宏; 小澤芳樹; 鳥海幸四郎; 久保孝史; 中筋一弘

  日本化学会講演予稿集, 13 Mar. 2006

  

Presentations

• Creation of Novel Materials Situated in Dimensional Crossover Region and Investigation of Their Physical Properties

  Kazuya Otsubo

  日本化学会第98春季年会2018, 20 Mar. 2018, Invited

  
• SPring-8の高輝度放射光を利用した 多孔性金属錯体の研究例

  大坪 主弥

  新学術領域研究「配位アシンメトリ」融合基礎・実習コース 「SPring-8における放射光先端計測の利活用法 / SPring-8/SACLA見学会」, 17 Jan. 2018, Invited

  
• Confined Water in a Hydrophobic Channel of a Metal–Organic Nanotube: Ice-tube Formation and High Proton Conduction

  Kazuya Otsubo

  2nd Korea-Japan Joint Symposium on Hydrogen in Materials, 19 Nov. 2016, Invited

  
• Confined Water in a Hydrophobic Channel of a Synthetic Nanotube: Ice-tube Formation and High Proton Conduction

  Kazuya Otsubo

  The 18th International Conference on Solid State Protonic Conductors (SSPC-18), 20 Sep. 2016, Invited

  
• 多孔性金属－有機ナノチューブにおけるプロトン輸送空間

  大坪 主弥

  分子研研究会「金属錯体の非対称配位圏設計と異方集積化が拓く新物質創成科学」, 05 Mar. 2016, Invited

  
• プロトン輸送空間材料としての多孔性金属–有機ナノチューブの創成

  大坪 主弥

  第二回放射光分析を用いたその場観察研究最前線, 12 Sep. 2015, Invited

  
• プロトン輸送空間材料としての多孔性金属-有機ナノチューブ

  大坪 主弥

  錯体化学若手の会勉強会・東北支部講演会, Invited

  

Awards

• 30 Mar. 2017

  The Chemical Society of Japan, CSJ Presentation Award 2017
• 21 Mar. 2018

  The Chemical Society of Japan, 日本化学会 第67回 進歩賞
• 02 May 2018

  錯体化学会, 錯体化学会 平成30年度 研究奨励賞

External funds: Kakenhi

• ボトムアップ合成に立脚した錯体ナノチューブの空間構築と伝導機構解明

  Grant-in-Aid for Scientific Research (C)

  Basic Section 34010:Inorganic/coordination chemistry-related

  Kyoto University

  大坪 主弥

  From 01 Apr. 2019, To 31 Mar. 2022, Granted

  ナノチューブ;疎水性空間;水クラスター;プロトン伝導;薄膜材料

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K05494/
• 非対称要素の導入による機能性次元クロスオーバー錯体の開発

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  大坪 主弥

  From 01 Apr. 2019, To 31 Mar. 2021, Project Closed

  梯子型錯体;ナノチューブ;らせん錯体;多孔性配位高分子;薄膜

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-19H04572/
• Investigation of physical properties in dimensional crossover complexes with asymmetric components

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  大坪 主弥

  From 01 Apr. 2017, To 31 Mar. 2019, Project Closed

  金属-有機構造体;ナノチューブ;らせん錯体;混合原子価錯体;プロトン伝導;多孔性物質;混合原子価;らせん構造;キラリティー

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-17H05366/
• Novel Solid-state Chemistry in Dimensional Crossover Region

  Grant-in-Aid for Scientific Research (A)

  Kyoto University

  Hiroshi Kitagawa

  From 01 Apr. 2017, To 31 Mar. 2020, Project Closed

  金属錯体化学;無機化学;固体物性化学

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H01196/
• Creation and physical properties of functional materials based on the metal-organic nanotubes

  Grant-in-Aid for Young Scientists (A)

  Kyoto University

  Kazuya OTSUBO

  From 01 Apr. 2015, To 31 Mar. 2018, Project Closed

  ナノチューブ;金属-有機構造体;水クラスター;プロトン伝導;水分子クラスター;多孔性物質;疎水場;クラスター

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15H05479/
• Creation of one-direction proton-transport surface MOFs

  Grant-in-Aid for Scientific Research (A)

  Kyoto University

  Hiroshi Kitagawa

  From 01 Apr. 2014, To 31 Mar. 2017, Project Closed

  無機化学;金属錯体化学;無機固体化学;ナノ化学

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26248019/
• Fabrication and Physical Properties of Growth-Controlled Metal-Organic Framework Thin Films

  Grant-in-Aid for Young Scientists (B)

  Kyoto University

  Kazuya OTSUBO

  From 01 Apr. 2013, To 31 Mar. 2015, Project Closed

  多孔性配位高分子;薄膜;ナノ界面技術;多孔性物質;金属有機構造体;ヘテロ接合

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25810039/
• 錯体ナノチューブにおける内空間を舞台とした物性開拓

  Grant-in-Aid for Scientific Research (C)

  Basic Section 34010:Inorganic/coordination chemistry-related

  Kyoto University

  大坪 主弥

  From 01 Apr. 2022, To 31 Mar. 2025, Granted

  ナノチューブ;疎水性空間;水クラスター;混合伝導性

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22K05142/

Education

Teaching subject(s)

• From 01 Apr. 2022, To 31 Mar. 2023

  Advanced Correlation Chemistry IC

  7202, Spring, Graduate School of Science, 1
• From 01 Apr. 2022, To 31 Mar. 2023

  Seminar on Correlation Chemistry IB

  7097, Fall, Graduate School of Science, 1
• From 01 Apr. 2022, To 31 Mar. 2023

  Advanced Correlation Chemistry ID

  7203, Fall, Graduate School of Science, 1
• From 01 Apr. 2022, To 31 Mar. 2023

  Chemical Laboratory A

  8634, Spring, Faculty of Science, 8
• From 01 Apr. 2022, To 31 Mar. 2023

  Advanced Correlation Chemistry IA

  7200, Spring, Graduate School of Science, 1
• From 01 Apr. 2022, To 31 Mar. 2023

  Chemical Laboratory B

  8635, Fall, Faculty of Science, 8
• From 01 Apr. 2022, To 31 Mar. 2023

  Seminar on Correlation Chemistry IA

  7096, Spring, Graduate School of Science, 1
• From 01 Apr. 2022, To 31 Mar. 2023

  Frontier in Chemistry II

  N358, Fall, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Advanced Correlation Chemistry IB

  7201, Fall, Graduate School of Science, 1
• From 01 Apr. 2022, To 31 Mar. 2023

  Special study course II (Chemistry) 1

  5628, Year-long, Faculty of Science, 12
• From 01 Apr. 2022, To 31 Mar. 2023

  Seminar on Correlation Chemistry IC

  7098, Spring, Graduate School of Science, 1
• From 01 Apr. 2022, To 31 Mar. 2023

  Seminar on Correlation Chemistry ID

  7099, Fall, Graduate School of Science, 1
• From Apr. 2014, To Mar. 2015

  Special study course II (Chemistry) 1

  Year-long, 理学部
• From Apr. 2014, To Mar. 2015

  Seminar on Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2014, To Mar. 2015

  Seminar on Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2014, To Mar. 2015

  Seminar on Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2014, To Mar. 2015

  Seminar on Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2014, To Mar. 2015

  Advanced Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2014, To Mar. 2015

  Advanced Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2014, To Mar. 2015

  Advanced Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2014, To Mar. 2015

  Advanced Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2015, To Mar. 2016

  Special study course II (Chemistry) 1

  Year-long, 理学部
• From Apr. 2015, To Mar. 2016

  Seminar on Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2015, To Mar. 2016

  Seminar on Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2015, To Mar. 2016

  Seminar on Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2015, To Mar. 2016

  Seminar on Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2015, To Mar. 2016

  Advanced Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2015, To Mar. 2016

  Advanced Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2015, To Mar. 2016

  Advanced Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2015, To Mar. 2016

  Advanced Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2016, To Mar. 2017

  Frontier in Chemistry II

  Fall, 全学共通科目
• From Apr. 2016, To Mar. 2017

  Special study course II (Chemistry) 1

  Year-long, 理学部
• From Apr. 2016, To Mar. 2017

  Fundamental Chemical Experiments

  Fall, 全学共通科目
• From Apr. 2016, To Mar. 2017

  Seminar on Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2016, To Mar. 2017

  Seminar on Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2016, To Mar. 2017

  Seminar on Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2016, To Mar. 2017

  Seminar on Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2016, To Mar. 2017

  Advanced Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2016, To Mar. 2017

  Advanced Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2016, To Mar. 2017

  Advanced Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2016, To Mar. 2017

  Advanced Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2017, To Mar. 2018

  Frontier in Chemistry II

  Fall, 全学共通科目
• From Apr. 2017, To Mar. 2018

  Special study course II (Chemistry) 1

  Year-long, 理学部
• From Apr. 2017, To Mar. 2018

  Fundamental Chemical Experiments

  Fall, 全学共通科目
• From Apr. 2017, To Mar. 2018

  Seminar on Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2017, To Mar. 2018

  Seminar on Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2017, To Mar. 2018

  Seminar on Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2017, To Mar. 2018

  Seminar on Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2017, To Mar. 2018

  Advanced Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2017, To Mar. 2018

  Advanced Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2017, To Mar. 2018

  Advanced Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2017, To Mar. 2018

  Advanced Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2018, To Mar. 2019

  Frontier in Chemistry II

  Fall, 全学共通科目
• From Apr. 2018, To Mar. 2019

  Special study course II (Chemistry) 1

  Year-long, 理学部
• From Apr. 2018, To Mar. 2019

  Seminar on Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2018, To Mar. 2019

  Seminar on Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2018, To Mar. 2019

  Seminar on Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2018, To Mar. 2019

  Seminar on Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2018, To Mar. 2019

  Advanced Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2018, To Mar. 2019

  Advanced Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2018, To Mar. 2019

  Advanced Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2018, To Mar. 2019

  Advanced Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2019, To Mar. 2020

  Frontier in Chemistry II

  Fall, 全学共通科目
• From Apr. 2019, To Mar. 2020

  Special study course II (Chemistry) 1

  Year-long, 理学部
• From Apr. 2019, To Mar. 2020

  Seminar on Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2019, To Mar. 2020

  Seminar on Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2019, To Mar. 2020

  Seminar on Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2019, To Mar. 2020

  Seminar on Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2019, To Mar. 2020

  Advanced Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2019, To Mar. 2020

  Advanced Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2019, To Mar. 2020

  Advanced Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2019, To Mar. 2020

  Advanced Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2020, To Mar. 2021

  Frontier in Chemistry II

  Fall, 全学共通科目
• From Apr. 2020, To Mar. 2021

  Chemical Laboratory A

  Spring, 理学部
• From Apr. 2020, To Mar. 2021

  Chemical Laboratory B

  Fall, 理学部
• From Apr. 2020, To Mar. 2021

  Special study course II (Chemistry) 1

  Year-long, 理学部
• From Apr. 2020, To Mar. 2021

  Seminar on Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2020, To Mar. 2021

  Seminar on Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2020, To Mar. 2021

  Seminar on Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2020, To Mar. 2021

  Seminar on Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2020, To Mar. 2021

  Advanced Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2020, To Mar. 2021

  Advanced Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2020, To Mar. 2021

  Advanced Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2020, To Mar. 2021

  Advanced Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2021, To Mar. 2022

  Frontier in Chemistry II

  Fall, 全学共通科目
• From Apr. 2021, To Mar. 2022

  Chemical Laboratory A

  Spring, 理学部
• From Apr. 2021, To Mar. 2022

  Chemical Laboratory B

  Fall, 理学部
• From Apr. 2021, To Mar. 2022

  Special study course II (Chemistry) 1

  Year-long, 理学部
• From Apr. 2021, To Mar. 2022

  Fundamental Chemical Experiments

  Fall, 全学共通科目
• From Apr. 2021, To Mar. 2022

  Seminar on Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2021, To Mar. 2022

  Seminar on Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2021, To Mar. 2022

  Seminar on Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2021, To Mar. 2022

  Seminar on Correlation Chemistry ID

  Fall, 理学研究科
• From Apr. 2021, To Mar. 2022

  Advanced Correlation Chemistry IA

  Spring, 理学研究科
• From Apr. 2021, To Mar. 2022

  Advanced Correlation Chemistry IB

  Fall, 理学研究科
• From Apr. 2021, To Mar. 2022

  Advanced Correlation Chemistry IC

  Spring, 理学研究科
• From Apr. 2021, To Mar. 2022

  Advanced Correlation Chemistry ID

  Fall, 理学研究科