Basic Information

Faculty

• 工学部

Professional Memberships

• THE SOCIETY OF POLYMER SCIENCE, JAPAN
• THE CHEMICAL SOCIETY OF JAPAN
• From Nov. 2019, To Present

  有機合成化学協会
• From May 2019, To Present

  American Chemical Society

Academic Degree

• 修士(工学)(京都大学)
• 博士（工学）(京都大学)

ID,URL

• J-Global ID

  201801001597732648

• Researcher number

  30826219

• External link

  http://www.living.polym.kyoto-u.ac.jp/nishikawa.html

researchmap URL

• https://researchmap.jp/7000023134

Research

Research Topics, Overview of the research

• Research Topics

  Chain-Growth Polymerization and Novel Polymer Synthesis Based Main-Group Elements

Research Interests

• Main-Group Element
• Polymer Synthesis
• Asymmetric Synthesis
• Supramolecules
• Functional Polymers

Research Areas

• Nanotechnology/Materials, Polymer materials
• Nanotechnology/Materials, Polymer chemistry
• Nanotechnology/Materials, Structural/physical organic chemistry

Papers

• Vinylboronic acid pinacol ester as a vinyl alcohol-precursor monomer in radical copolymerization with styrene (July, 10.1039/D1CC02603H, 2021)

  Hiroshi Makino; Tsuyoshi Nishikawa; Makoto Ouchi

  CHEMICAL COMMUNICATIONS, Aug. 2021

  
• 側鎖元素置換による従来合成が困難であった高分子の合成

  大内 誠; 西川 剛

  日本化学繊維研究所講演集 Annual report of the Research Institute for Chemical Fibers, Japan, 2020

  
• RAFT polymerization of isopropenyl boronate pinacol ester and subsequent terminal olefination: precise synthesis of poly(alkenyl boronate)s and evaluation of their thermal properties

  Tomoaki Kanazawa; Tsuyoshi Nishikawa; Makoto Ouchi

  Polymer Journal, 24 May 2021, Peer-reviewed, Corresponding author

  
• Recent Development in Polymer Reactions for Overcoming Synthetic Limitations in Chain-growth Polymerization

  Tsuyoshi Nishikawa; Makoto Ouchi

  Chemistry Letters, 05 Mar. 2021, Peer-reviewed, Lead author

  
• Vinylboronic acid pinacol ester as a vinyl alcohol-precursor monomer in radical copolymerization with styrene

  Hiroshi Makino; Tsuyoshi Nishikawa; Makoto Ouchi

  Chemical Communications, 2021, Peer-reviewed, Corresponding author

  
• Elucidating Monomer Character of an Alkenyl Boronate through Radical Copolymerization Leads to Copolymer Synthesis beyond the Limitation of Copolymerizability by Side-Chain Replacement

  Hiroshi Makino; Tsuyoshi Nishikawa; Makoto Ouchi

  ACS Macro Letters, 16 Jun. 2020, Peer-reviewed, Corresponding author

  
• An Alkenyl Boronate as a Monomer for Radical Polymerizations: Boron as a Guide for Chain Growth and as a Replaceable Side Chain for Post-Polymerization Transformation

  Tsuyoshi Nishikawa; Makoto Ouchi

  Angewandte Chemie International Edition, Sep. 2019, Peer-reviewed, Lead author

  
• Hydrophobicity and CH/π-interaction-driven self-assembly of amphiphilic aromatic hydrocarbons into nanosheets

  Nishikawa Tsuyoshi; Narita Hiroki; Ogi Soichiro; Sato Yoshikatsu; Yamaguchi Shigehiro

  Chem. Commun., 2019, Peer-reviewed, Lead author

  
• A bidirectional screw-sense induction of poly(quinoxaline-2,3-diyl)s that depends on the degree of polymerization

  Yuuya Nagata; Tsuyoshi Nishikawa; Ken Terao; Hirokazu Hasegawa; Michinori Suginome

  Journal of Polymer Science Part A: Polymer Chemistry, 2019, Peer-reviewed

  
• Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome; Sota Sato; Masaaki Sugiyama; Lionel Porcar; Anne Martel; Rintaro Inoue; Nobuhiro Sato

  Journal of the American Chemical Society, 28 Feb. 2018, Peer-reviewed

  
• A Planar-Chiral Pillar [5] arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis

  Nagata Yuuya; Shimada Yasuo; Nishikawa Tsuyoshi; Takeda Ryohei; Uno Makoto; Ogoshi Tomoki; Suginome Michinori

  Synlett, 2018, Peer-reviewed

  
• Abnormal sergeants-and-soldiers effects of poly(quinoxaline-2,3-diyl)s enabling discrimination of one-carbon homologous: N -alkanes through a highly sensitive solvent-dependent helix inversion

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  Chemical Communications, 2018, Peer-reviewed

  
• Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations.

  Franco King-Chi Leung; Fumitaka Ishiwari; Yoshiaki Shoji; Tsuyoshi Nishikawa; Ryohei Takeda; Yuuya Nagata; Michinori Suginome; Yasuhiro Uozumi; Yoichi M A Yamada; Takanori Fukushima

  ACS omega, 31 May 2017, Peer-reviewed

  
• Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness

  Tsuyoshi Nishikawa; Yuuya Nagata; Michinori Suginome

  ACS MACRO LETTERS, Apr. 2017, Peer-reviewed, Lead author

  
• Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  ACS MACRO LETTERS, Apr. 2016, Peer-reviewed

  
• Exerting Control over the Helical Chirality in the Main Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2015, Peer-reviewed

  
• Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main-Chain Helical Chirality

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2014, Peer-reviewed

  
• Chirality-switchable circularly polarized luminescence in solution based on the solvent-dependent helix inversion of poly(quinoxaline-2,3-diyl)s

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  CHEMICAL COMMUNICATIONS, Sep. 2014, Peer-reviewed

  
• Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2012, Peer-reviewed

  
• Disruption of reverse micelles and release of trapped ribonuclease A photochemically induced by Malachite Green leuconitrile derivative

  Ryoko M. Uda; Tsuyoshi Nishikawa; Yoshitsugu Morita

  JOURNAL OF COLLOID AND INTERFACE SCIENCE, Mar. 2011, Peer-reviewed

  

Awards

• Jul. 2013

  25th International Synposium on Chirality (ISCD-25), Biotool Poster Award
• Jul. 2014

  高分子学会関西支部, 第60回高分子研究発表会 エクセレントポスター賞
• Mar. 2016

  The Chemical Society of Japan, 日本化学会第96春季年会　学生講演賞
• Mar. 2019

  The Chemical Society of Japan, 日本化学会第99春季年会　優秀講演賞(学術)
• May 2019

  The Society of Polymer Science, Japan, 第68回高分子学会年次大会　優秀ポスター賞(一般部門)
• 09 Dec. 2020

  The Society of Synthetic Organic Chemistry, Nippon Syokubai Award in Synthetic Organic Chemistry, Japan

External funds: Kakenhi

• アルケニルボロン酸エステルの精密ラジカル重合が拓く新規機能性ビニルポリマー創製

  Grant-in-Aid for Early-Career Scientists

  Basic Section 35010:Polymer chemistry-related

  Kyoto University

  西川 剛

  From 01 Apr. 2019, To 31 Mar. 2022, Granted

  ラジカル重合;制御重合;ホウ素;高分子反応;量子化学計算;ビニルポリマー;ブロックコポリマー;リビング重合

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K15622/
• らせん高分子集合体を反応場として利用する精密重合システムの開発

  Grant-in-Aid for Research Activity Start-up

  0501:Physical chemistry, functional solid state chemistry, organic chemistry, polymers, organic materials, biomolecular chemistry, and related fields

  Kyoto University

  西川 剛

  From 24 Aug. 2018, To 31 Mar. 2020, Project Closed

  ビニルポリマー;制御重合;ホウ素;精密重合;らせん高分子;超分子;反応場形成

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18H05975/
• ビニルボロン酸誘導体の重合化学：モノマー設計と側鎖置換を鍵とした革新的高分子合成

  Grant-in-Aid for Early-Career Scientists

  Basic Section 35010:Polymer chemistry-related

  Kyoto University

  西川 剛

  From 01 Apr. 2022, To 31 Mar. 2025, Adopted

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22K14724/

Education

Teaching subject(s)

• From 01 Apr. 2022, To 31 Mar. 2023

  Polymer Synthesis

  H649, Spring, Graduate School of Engineering, 1.5
• From Apr. 2019, To Mar. 2020

  Fundamental Chemical Experiments

  Spring, 全学共通科目
• From Apr. 2021, To Mar. 2022

  Polymer Synthesis

  Spring, 工学研究科