Basic Information

Faculty

• Faculty of Science

Email Address

• Email Address

  matsunaga.shigeki.5xkyoto-u.ac.jp

Professional Memberships

• THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN
• THE RARE EARTH SOCIETY OF JAPAN
• the American Chemical Scoety
• THE JAPANESE SOCIETY FOR PROCESS CHEMISTRY
• THE CHEMICAL SOCIETY OF JAPAN
• THE PHARMACEUTICAL SOCIETY OF JAPAN

Academic Degree

• 29 Mar. 2000

  東京大学修士（薬学）
• 19 Nov. 2003

  東京大学博士（薬学）

Academic Resume (Undergraduate School/Majors)

• 東京大学, 薬学部薬学科, 卒業

Research History

• From Apr. 2023, To Present

  Kyoto University, Graduate School of Science, Division of Chemistry, Professor
• From Oct. 2020, To Mar. 2023

  Hokkaido University, 総長補佐
• From Jul. 2021, To Present

  Angew Chem Int Ed International Advisory Board
• From Apr. 2015, To Mar. 2023

  Hokkaido University, Faculty of Pharmaceutical Sciences, Professor
• From Apr. 2011, To Mar. 2015

  The University of Tokyo, 薬学研究科(研究院), 准教授
• From Apr. 2008, To Mar. 2011

  University of Tokyo, Graduate School of Pharmaceutical Sciences, Senior Lecturer
• From Apr. 2001, To Mar. 2008

  The University of Tokyo, Graduate School of Pharmaceutical Sciences, 助手、助教

Profile

• Profile

  • 2001.4-2007.3 東京大学大学院薬学系研究科 助手
  
  
  • 2007.4-2008.3 東京大学大学院薬学系研究科 助教
  
  
  • 2008.4-2011.3 東京大学大学院薬学系研究科 講師
  
  
  • 2011.4-2-15.3 東京大学大学院薬学系研究科 准教授
  
  
  • 2015.4-2023.3 北海道大学大学院薬学研究院 教授
  
  
  • 2020.10-2023.3　北海道大学　総長補佐（学生支援）
  
  
  • 2023.4 京都大学大学院理学研究科　教授
  
  

ID,URL

• ORCID ID

  0000-0003-4136-3548

• J-Global ID

  201501030232250838

• External link

  https://kaken.nii.ac.jp/d/r/50334339.ja.html

researchmap URL

• https://researchmap.jp/smatsuna

Research

Research Interests

• セラノスティクス
• C-H官能基化
• 不斉触媒
• 不斉合成
• シッフ塩基
• 医薬合成
• 触媒
• イミン
• 医薬リード
• 医薬品合成
• 複核錯体
• マンニッヒ反応
• 希土類金属
• アート錯体
• 非天然アミノ酸
• 天然物合成
• 分子活性化
• 協奏機能
• サレン
• 直截変換
• 活性エステル
• 亜鉛触媒
• 有機合成反応
• 希土類触媒
• ビナフトール
• ニトロアルカン
• ピロール
• 医薬化学
• 多点制御
• アルドール反応
• 不斉アルドール反応
• 触媒的不斉Strecker反応

Research Areas

• Life sciences, Pharmaceuticals - chemistry and drug development
• Nanotechnology/Materials, Synthetic organic chemistry

Papers

• Enantioselective C–H Amidation of Sulfondiimines for the Synthesis of 1,2,4-Benzothiadiazine-1-Imines under Cobalt Catalysis

  Ayami Murata; Tomonori Endo; Yuki Hirata; Kosuke Higashida; Tatsuhiko Yoshino; Shigeki Matsunaga

  Organic Chemistry Frontiers, 2025, Peer-reviewed, Invited, Last author, Corresponding author

  
• Multiple Deuterium Atom Transfer Perdeuteration of Unactivated Alkenes under Base‐Assisted Cobalt/Photoredox Dual Catalysis

  Akihiko Suzuki; Kosuke Higashida; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie International Edition, 14 Feb. 2025, Peer-reviewed, Last author, Corresponding author

  
• Site‐selective C(sp3)–H and Switchable C(sp3)–H/C(sp2)–H Functionalization Enabled by Electron‐deficient Cp*CF3Ir(III) Catalyst and Photosensitizer

  Yuki Hirata; Shunsuke Kimura; Kosuke Higashida; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie International Edition, 16 Dec. 2024, Peer-reviewed, Last author, Corresponding author

  
• Enantioselective Intermolecular Benzylic C–H Amination under Chiral Paddle-Wheel Diruthenium Catalysis

  Kotoko Makino; Kohei Mori; Shoichi Kiryu; Taku Miyazawa; Yuhei Kumagai; Kosuke Higashida; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  ACS Catalysis, 20 Dec. 2024, Peer-reviewed, Last author, Corresponding author

  
• Direct catalytic asymmetric michael reaction of α-hydroxyketone promoted by Et2Zn/linkedbinol complex

  Masakatsu Shibasaki; Shigeki Matsunaga; Naoya Kumagai

  Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions, 01 Jan. 2005

  
• Cobalt/Photoredox Dual-Catalyzed Cross-Radical Coupling of Alkenes via Hydrogen Atom Transfer and Homolytic Substitution

  Yuto Yamaguchi; Yuki Hirata; Kosuke Higashida; Tatsuhiko Yoshino; Shigeki Matsunaga

  Organic Letters, 05 Jun. 2024, Peer-reviewed, Last author, Corresponding author

  
• Synthesis of Benzo[c]azepine‐1,3(2H)‐diones via C–H Alkylation/Cyclization with α,β‐Unsaturated Acyl Fluorides

  Satoko Hosoi; Yuki Hirata; Takumaru Kurihara; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Asian Journal of Organic Chemistry, 17 May 2023, Peer-reviewed, Last author, Corresponding author

  
• Enantioselective Synthesis of 1,2‐Benzothiazine 1‐Imines via RuII/Chiral Carboxylic Acid‐Catalyzed C–H Alkylation/Cyclization

  Long-Tao Huang; Yuta Kitakawa; Kodai Yamada; Futa Kamiyama; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie International Edition, 17 May 2023, Peer-reviewed, Last author, Corresponding author

  
• Noble-Metal-Free C–H Allylation of Tetrahydroisoquinolines Using a Cobalt-Organophotoredox Dual Catalyst System

  Shunta Sato; Wataru Sasaki; Tomoyuki Sekino; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Chemical and Pharmaceutical Bulletin, 01 Feb. 2023, Peer-reviewed, Invited, Last author, Corresponding author

  
• Catalytic Enantioselective Amination of Enol Silyl Ethers Using a Chiral Paddle-Wheel Diruthenium Complex

  Kotoko Makino; Yuhei Kumagai; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Organic Letters, 12 May 2023, Peer-reviewed, Last author, Corresponding author

  
• Synthesis of Polysubstituted Enamides by Hydrogen Atom Transfer Alkene Isomerization Using Dual Cobalt/Photoredox Catalysis

  Yusuke Seino; Yuto Yamaguchi; Akihiko Suzuki; Masaaki Yamashita; Yuji Kamei; Futa Kamiyama; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Chemistry – A European Journal, 09 May 2023, Peer-reviewed, Last author, Corresponding author

  
• Formation of Isolable Dearomatized [4 + 2] Cycloadducts from Benzenes, Naphthalenes, and N-Heterocycles Using 1,2-Dihydro-1,2,4,5-tetrazine-3,6-diones as Arenophiles under Visible Light Irradiation

  Kazuki Ikeda; Riku Kojima; Kentaro Kawai; Takayasu Murakami; Takashi Kikuchi; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Journal of the American Chemical Society, 26 Apr. 2023, Peer-reviewed, Last author, Corresponding author

  
• Iron/Photosensitizer-Catalyzed Directed C–H Activation Triggered by the Formation of an Iron Metallacycle

  Yoshimi Kato; Tatsuhiko Yoshino; Shigeki Matsunaga

  ACS Catalysis, 07 Apr. 2023, Peer-reviewed, Last author, Corresponding author

  
• An Electron-Deficient CpE Iridium(III) Catalyst: Synthesis, Characterization, and Application to Ether-Directed C-H Amidation.

  Eiki Tomita; Masahiro Kojima; Yuki Nagashima; Ken Tanaka; Haruki Sugiyama; Yasutomo Segawa; Atsushi Furukawa; Katsumi Maenaka; Satoshi Maeda; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie (International ed. in English), 14 Mar. 2023

  
• Photocatalytic Deuterium Atom Transfer Deuteration of Electron‐Deficient Alkenes with High Functional Group Tolerance

  Akihiko Suzuki; Yuji Kamei; Masaaki Yamashita; Yusuke Seino; Yuto Yamaguchi; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Angewandte Chemie International Edition, 16 Jan. 2023, Peer-reviewed, Last author, Corresponding author

  
• Native Amide-Directed C(sp3)-H Amidation Enabled by Electron-Deficient Rh(III) Catalyst and Electron-Deficient 2-Pyridone Ligand.

  Takumi Wakikawa; Daichi Sekine; Yuta Murata; Youka Bunno; Masahiro Kojima; Yuki Nagashima; Ken Tanaka; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie (International ed. in English), 28 Oct. 2022, Peer-reviewed, Last author, Corresponding author

  
• Iron/Photosensitizer Hybrid System Enables the Synthesis of Polyaryl-Substituted Azafluoranthenes

  Yoshimi Kato; Tatsuhiko Yoshino; Min Gao; Jun-ya Hasegawa; Masahiro Kojima; Shigeki Matsunaga

  Journal of the American Chemical Society, 12 Oct. 2022, Peer-reviewed, Last author, Corresponding author

  
• Photo-Induced Nickel-Catalyzed Carbon-Heteroatom Coupling.

  Hang Luo; Guohua Wang; Yunhui Feng; Wanyao Zheng; Lingya Kong; Yunpeng Ma; Shigeki Matsunaga; Luqing Lin

  Chemistry (Weinheim an der Bergstrasse, Germany), 10 Oct. 2022, Peer-reviewed

  
• Light-Promoted Nickel-Catalyzed Aromatic Halogen Exchange

  Yunhui Feng; Hang Luo; Wanyao Zheng; Shigeki Matsunaga; Luqing Lin

  ACS Catalysis, 16 Sep. 2022, Peer-reviewed

  
• Design and Synthesis of Cyclopropane Congeners of Resolvin E3, an Endogenous Pro-Resolving Lipid Mediator, as Its Stable Equivalents

  Shota Arai; Koichi Fujiwara; Masahiro Kojima; Haruka Aoki-Saito; Masakiyo Yatomi; Tsugumichi Saito; Yasuhiko Koga; Hayato Fukuda; Mizuki Watanabe; Shigeki Matsunaga; Takeshi Hisada; Satoshi Shuto

  The Journal of Organic Chemistry, 05 Aug. 2022, Peer-reviewed

  
• Cobalt(III)/Chiral Carboxylic Acid‐Catalyzed Enantioselective Synthesis of Benzothiadiazine‐1‐oxides via C−H Activation

  Yuki Hirata; Daichi Sekine; Yoshimi Kato; Luqing Lin; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie International Edition, 19 May 2022, Peer-reviewed, Last author, Corresponding author

  
• Achiral Cp*Rh(III)/Chiral Lewis Base Cooperative Catalysis for Enantioselective Cyclization via C–H Activation

  Takumaru Kurihara; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Journal of the American Chemical Society, 27 Apr. 2022, Peer-reviewed, Last author, Corresponding author

  
• Intramolecular Hydrogen Atom Transfer Hydroarylation of Alkenes toward δ-Lactams Using Cobalt-Photoredox Dual Catalysis

  Yuto Yamaguchi; Yusuke Seino; Akihiko Suzuki; Yuji Kamei; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Organic Letters, 01 Apr. 2022, Peer-reviewed, Last author, Corresponding author

  
• 1,2-Disubstituted 1,2-Dihydro-1,2,4,5-tetrazine-3,6-dione as a Dynamic Covalent Bonding Unit at Room Temperature

  Kentaro Kawai; Kazuki Ikeda; Akane Sato; Akira Kabasawa; Masahiro Kojima; Kenta Kokado; Akira Kakugo; Kazuki Sada; Tatsuhiko Yoshino; Shigeki Matsunaga

  Journal of the American Chemical Society, 26 Jan. 2022, Peer-reviewed, Last author, Corresponding author

  
• Regioselective Deaminative Allylation of Aliphatic Amines via Dual Cobalt and Organophotoredox Catalysis

  Tomoyuki Sekino; Shunta Sato; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Organic Letters, 2022, Peer-reviewed, Last author, Corresponding author

  
• Cp*Rh(iii)/boron hybrid catalysis for directed C–H addition to β-substituted α,β-unsaturated carboxylic acids

  Ryo Tanaka; Yuki Hirata; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Chemical Communications, 2022, Peer-reviewed, Last author, Corresponding author

  
• Cp*RhIII/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes

  Jumpei Hirose; Takumi Wakikawa; Shun Satake; Masahiro Kojima; Manabu Hatano; Kazuaki Ishihara; Tatsuhiko Yoshino; Shigeki Matsunaga

  ACS Catalysis, 07 Dec. 2021, Peer-reviewed, Last author, Corresponding author

  
• Ruthenium(II)/Chiral Carboxylic Acid Catalyzed Enantioselective C–H Functionalization of Sulfoximines

  Tatsuhiko Yoshino; Shigeki Matsunaga; Long-Tao Huang; Yuki Hirata; Yoshimi Kato; Luqing Lin; Masahiro Kojima

  Synthesis, 16 Aug. 2021, Peer-reviewed, Last author, Corresponding author

  
• Chiral Carboxylic Acid Assisted Enantioselective C–H Activation with Achiral CpxMIII (M = Co, Rh, Ir) Catalysts

  Tatsuhiko Yoshino; Shigeki Matsunaga

  ACS Catalysis, 04 Jun. 2021, Peer-reviewed, Last author, Corresponding author

  
• Transition-metal-free nucleophilic 211At-astatination of spirocyclic aryliodonium ylides

  Keitaro Matsuoka; Honoka Obata; Kotaro Nagatsu; Masahiro Kojima; Tatsuhiko Yoshino; Mikako Ogawa; Shigeki Matsunaga

  Organic & Biomolecular Chemistry, Jun. 2021, Peer-reviewed, Last author, Corresponding author

  
• Development of Pseudo-C2-symmetric Chiral Binaphthyl Monocarboxylic Acids for Enantioselective C(sp3)–H Functionalization Reactions under Rh(III) Catalysis

  Yoshimi Kato; Luqing Lin; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  ACS Catalysis, 02 Apr. 2021, Peer-reviewed, Last author, Corresponding author

  
• Metal-Containing Schiff Base/Sulfoxide Ligands for Pd(II)-Catalyzed Asymmetric Allylic C–H Aminations

  Youka Bunno; Yuta Tsukimawashi; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  ACS Catalysis, 05 Mar. 2021, Peer-reviewed, Last author, Corresponding author

  
• Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis

  Yuji Kamei; Yusuke Seino; Yuto Yamaguchi; Tatsuhiko Yoshino; Satoshi Maeda; Masahiro Kojima; Shigeki Matsunaga

  Nature Communications, Feb. 2021, Peer-reviewed, Last author, Corresponding author

  
• Chemoselective Cleavage of Si–C(sp3) Bonds in Unactivated Tetraalkylsilanes Using Iodine Tris(trifluoroacetate)

  Keitaro Matsuoka; Narumi Komami; Masahiro Kojima; Tsuyoshi Mita; Kimichi Suzuki; Satoshi Maeda; Tatsuhiko Yoshino; Shigeki Matsunaga

  Journal of the American Chemical Society, 13 Jan. 2021, Peer-reviewed, Last author, Corresponding author

  
• Cp*Ir(iii)/chiral carboxylic acid-catalyzed enantioselective C–H alkylation of ferrocene carboxamides with diazomalonates

  Qi Mou; Ruyuan Zhao; Ruihan Niu; Seiya Fukagawa; Taiki Shigeno; Tatsuhiko Yoshino; Shigeki Matsunaga; Bo Sun

  Organic Chemistry Frontiers, 2021, Peer-reviewed, Corresponding author

  
• Generation of Monoaryl-λ3-iodanes from Arylboron Compounds through ipso-Substitution

  Ayako Nakano; Yukino Okabe; Keitaro Matsuoka; Narumi Komami; Keito Watanabe; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  HETEROCYCLES, Jan. 2021, Peer-reviewed, Last author, Corresponding author

  
• Rhodium(III)/Chiral Carboxylic Acid Catalyzed Enantioselective C(sp3)–H Alkylation of 8-Ethylquinolines with α,β-Unsaturated Carbonyl Compounds

  Long-Tao Huang; Seiya Fukagawa; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Organic Letters, 06 Nov. 2020, Peer-reviewed, Last author, Corresponding author

  
• Chiral paddle-wheel diruthenium complexes for asymmetric catalysis

  Taku Miyazawa; Takuro Suzuki; Yuhei Kumagai; Koji Takizawa; Takashi Kikuchi; Shunsuke Kato; Akira Onoda; Takashi Hayashi; Yuji Kamei; Futa Kamiyama; Masahiro Anada; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Nature Catalysis, Oct. 2020, Peer-reviewed, Last author, Corresponding author

  
• Allyl 4-Chlorophenyl Sulfone as a Versatile 1,1-Synthon for Sequential α-Alkylation/Cobalt-Catalyzed Allylic Substitution

  Tomoyuki Sekino; Shunta Sato; Kazuki Kuwabara; Koji Takizawa; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Synthesis, 27 Jul. 2020, Peer-reviewed, Last author, Corresponding author

  
• Iridium(III) Catalysts with an Amide‐Pendant Cyclopentadienyl Ligand: Double Aromatic Homologation Reactions of Benzamides by Fourfold C−H Activation

  Eiki Tomita; Kodai Yamada; Yu Shibata; Ken Tanaka; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie, 22 Jun. 2020, Peer-reviewed, Last author, Corresponding author

  
• Iridium(III) Catalysts with an Amide‐Pendant Cyclopentadienyl Ligand: Double Aromatic Homologation Reactions of Benzamides by Fourfold C−H Activation

  Eiki Tomita; Kodai Yamada; Yu Shibata; Ken Tanaka; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie International Edition, 22 Jun. 2020, Peer-reviewed, Last author, Corresponding author

  
• Frontispiece: Diverse Approaches for Enantioselective C−H Functionalization Reactions Using Group 9 Cp x M III Catalysts

  Tatsuhiko Yoshino; Shun Satake; Shigeki Matsunaga

  Chemistry – A European Journal, 10 Jun. 2020, Peer-reviewed, Last author, Corresponding author

  
• The Merger of Photoredox and Cobalt Catalysis

  Masahiro Kojima; Shigeki Matsunaga

  Trends in Chemistry, May 2020, Peer-reviewed, Last author, Corresponding author

  
• Cp*Co III /Chiral Carboxylic Acid‐Catalyzed Enantioselective 1,4‐Addition Reactions of Indoles to Maleimides

  Takumaru Kurihara; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Asian Journal of Organic Chemistry, 28 Mar. 2020, Peer-reviewed, Last author, Corresponding author

  
• Catalytic Enantioselective Methylene C(sp 3 )−H Amidation of 8‐Alkylquinolines Using a Cp*Rh III /Chiral Carboxylic Acid System

  Seiya Fukagawa; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie International Edition, 09 Dec. 2019, Peer-reviewed, Last author, Corresponding author

  
• Catalytic Enantioselective Methylene C(sp 3 )−H Amidation of 8‐Alkylquinolines Using a Cp*Rh III /Chiral Carboxylic Acid System

  Seiya Fukagawa; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie, 09 Dec. 2019, Peer-reviewed, Last author, Corresponding author

  
• Chiral 2-Aryl Ferrocene Carboxylic Acids for the Catalytic Asymmetric C(sp3)–H Activation of Thioamides

  Daichi Sekine; Kazuki Ikeda; Seiya Fukagawa; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Organometallics, 28 Oct. 2019, Peer-reviewed, Last author, Corresponding author

  
• Imidate as the Intact Directing Group for the Cobalt-Catalyzed C–H Allylation

  Ryo Tanaka; Iku Tanimoto; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  The Journal of Organic Chemistry, 18 Oct. 2019, Peer-reviewed, Last author, Corresponding author

  
• Cobalt-catalyzed Synthesis of Homoallylic Amines from Imines and Terminal Alkenes

  Ryo Tanaka; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Chemistry Letters, Sep. 2019, Peer-reviewed, Last author, Corresponding author

  
• Cobalt‐Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis

  Koji Takizawa; Tomoyuki Sekino; Shunta Sato; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Angewandte Chemie, 24 Jul. 2019, Peer-reviewed, Last author, Corresponding author

  
• Synthesis of Heteroaryl Iodanes(III) via ipso ‐Substitution Reactions Using Iodine Triacetate Assisted by HFIP

  Keitaro Matsuoka; Narumi Komami; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Asian Journal of Organic Chemistry, 07 Jul. 2019, Peer-reviewed, Last author, Corresponding author

  
• Cp*Co (III) -Catalyzed C-H Functionalization and Asymmetric Reactions Using External Chiral Sources

  Tatsuhiko Yoshino; Shigeki Matsunaga

  SYNLETT, Jul. 2019, Peer-reviewed, Last author, Corresponding author

  
• Cobalt‐Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis

  Koji Takizawa; Tomoyuki Sekino; Shunta Sato; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Angewandte Chemie International Edition, 01 Jul. 2019, Peer-reviewed, Last author, Corresponding author

  
• C–H γ,γ,γ-Trifluoroalkylation of Quinolines via Visible-Light-Induced Sequential Radical Additions

  Yuhei Kumagai; Nanami Murakami; Futa Kamiyama; Ryo Tanaka; Tatsuhiko Yoshino; Masahiro Kojima; Shigeki Matsunaga

  Organic Letters, 17 May 2019, Peer-reviewed, Last author, Corresponding author

  
• Unique Reactivity of High-valent Cobalt Catalysis in C-H Functionalization and Development of Catalytic Asymmetric C-H Functionalization Reactions

  Tatsuhiko Yoshino; Shigeki Matsunaga

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Apr. 2019, Peer-reviewed, Last author, Corresponding author

  
• Synthesis of Functionalized Monoaryl-λ3 -iodanes through Chemo- and Site-Selective ipso -Substitution Reactions

  Narumi Komami; Keitaro Matsuoka; Ayako Nakano; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Chemistry - A European Journal, 24 Jan. 2019, Peer-reviewed, Last author, Corresponding author

  
• Enantioselective C(sp 3 )–H Amidation of Thioamides Catalyzed by a Cobalt III /Chiral Carboxylic Acid Hybrid System

  Seiya Fukagawa; Yoshimi Kato; Ryo Tanaka; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie, 21 Jan. 2019, Peer-reviewed, Last author, Corresponding author

  
• Enantioselective C(sp 3 )–H Amidation of Thioamides Catalyzed by a Cobalt III /Chiral Carboxylic Acid Hybrid System

  Seiya Fukagawa; Yoshimi Kato; Ryo Tanaka; Masahiro Kojima; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie International Edition, 21 Jan. 2019, Peer-reviewed, Last author, Corresponding author

  
• Author Correction: Pentamethylcyclopentadienyl rhodium(iii)–chiral disulfonate hybrid catalysis for enantioselective C–H bond functionalization

  Shun Satake; Takumaru Kurihara; Keisuke Nishikawa; Takuya Mochizuki; Manabu Hatano; Kazuaki Ishihara; Tatsuhiko Yoshino; Shigeki Matsunaga

  Nature Catalysis, 03 Jan. 2019, Peer-reviewed, Last author, Corresponding author

  
• One-Step Synthesis of 4H-3,1-Benzoxazin-4-ones from Weinreb Amides and 1,4,2-Dioxazol-5-ones via Cobalt-Catalyzed C–H Bond Activation

  Iku Tanimoto; Kentaro Kawai; Akane Sato; Tatsuhiko Yoshino; Shigeki Matsunaga

  HETEROCYCLES, Jan. 2019, Peer-reviewed, Last author, Corresponding author

  
• Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C−H Functionalization

  Luqing Lin; Seiya Fukagawa; Daichi Sekine; Eiki Tomita; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie, 10 Sep. 2018, Peer-reviewed, Last author, Corresponding author

  
• Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C−H Functionalization

  Luqing Lin; Seiya Fukagawa; Daichi Sekine; Eiki Tomita; Tatsuhiko Yoshino; Shigeki Matsunaga

  Angewandte Chemie International Edition, 10 Sep. 2018, Peer-reviewed, Last author, Corresponding author

  
• Synthesis of 1,1′-Spirobiindane-7,7′-Disulfonic Acid and Disulfonimide: Application for Catalytic Asymmetric Aminalization

  Takumaru Kurihara; Shun Satake; Manabu Hatano; Kazuaki Ishihara; Tatsuhiko Yoshino; Shigeki Matsunaga

  Chemistry - An Asian Journal, 04 Sep. 2018, Peer-reviewed, Last author, Corresponding author

  
• 5-((3-Bromoallyl)Sulfonyl)-1H-Tetrazoles for Bromodiene Synthesis

  Takuro Suzuki; Seiya Fukagawa; Tatsuhiko Yoshino; Masahiro Anada; Shigeki Matsunaga

  Heterocycles, Sep. 2018, Peer-reviewed, Last author, Corresponding author

  
• Pentamethylcyclopentadienyl rhodium(III)–chiral disulfonate hybrid catalysis for enantioselective C–H bond functionalization

  Shun Satake; Takumaru Kurihara; Keisuke Nishikawa; Takuya Mochizuki; Manabu Hatano; Kazuaki Ishihara; Tatsuhiko Yoshino; Shigeki Matsunaga

  Nature Catalysis, Aug. 2018, Peer-reviewed, Last author, Corresponding author

  
• Weinreb Amide Directed Versatile C−H Bond Functionalization under (η5 -Pentamethylcyclopentadienyl)cobalt(III) Catalysis

  Kentaro Kawai; Youka Bunno; Tatsuhiko Yoshino; Shigeki Matsunaga

  Chemistry - A European Journal, 17 Jul. 2018, Peer-reviewed, Last author, Corresponding author

  
• Cobalt-Catalyzed C(sp3 )−H Functionalization Reactions

  Tatsuhiko Yoshino; Shigeki Matsunaga

  Asian Journal of Organic Chemistry, Jul. 2018, Peer-reviewed, Last author, Corresponding author

  
• Palladium-Catalyzed Germylation of Aryl Bromides and Aryl Triflates Using Hexamethyldigermane

  Narumi Komami; Keitaro Matsuoka; Tatsuhiko Yoshino; Shigeki Matsunaga

  Synthesis (Germany), 17 May 2018, Peer-reviewed, Last author, Corresponding author

  
• DOCK1 inhibition suppresses cancer cell invasion and macropinocytosis induced by self-activating Rac1P29S mutation

  Takahiro Tomino; Hirotada Tajiri; Takaaki Tatsuguchi; Takahiro Shirai; Kounosuke Oisaki; Shigeki Matsunaga; Fumiyuki Sanematsu; Daiji Sakata; Tomoharu Yoshizumi; Yoshihiko Maehara; Motomu Kanai; Jean-François Cote; Yoshinori Fukui; Takehito Uruno

  Biochemical and Biophysical Research Communications, Feb. 2018, Peer-reviewed

  
• Synthesis of fluorine-containing 6-arylpurine derivatives via Cp∗Co(III)-catalyzed C-H bond activation

  Nanami Murakami; Misaki Yoshida; Tatsuhiko Yoshino; Shigeki Matsunaga

  Chemical and Pharmaceutical Bulletin, Jan. 2018, Peer-reviewed, Last author, Corresponding author

  
• Structural and thermodynamic analyses reveal critical features of glycopeptide recognition by the human PILR alpha immune cell receptor

  Atsushi Furukawa; Kosuke Kakita; Tomoki Yamada; Mikihiro Ishizuka; Jiro Sakamoto; Nanao Hatori; Naoyoshi Maeda; Fumina Ohsaka; Takashi Saitoh; Takao Nomura; Kimiko Kuroki; Hisanori Nambu; Hisashi Arase; Shigeki Matsunaga; Masahiro Anada; Toyoyuki Ose; Shunichi Hashimoto; Katsumi Maenaka

  JOURNAL OF BIOLOGICAL CHEMISTRY, Dec. 2017, Peer-reviewed

  
• Total Synthesis of Brasilicardins A and C

  Masahiro Anada; Taiki Hanari; Kosuke Kakita; Yasunobu Kurosaki; Kazuki Katsuse; Yuta Sunadoi; Yu Jinushi; Koji Takeda; Shigeki Matsunaga; Shunichi Hashimoto

  ORGANIC LETTERS, Oct. 2017, Peer-reviewed

  
• 2-Hydroxyindoline-3-triethylammonium Bromide: A Reagent for Formal C3-Electrophilic Reactions of Indoles

  Takumi Abe; Takuro Suzuki; Masahiro Anada; Shigeki Matsunaga; Koji Yamada

  ORGANIC LETTERS, Aug. 2017, Peer-reviewed

  
• (CpCoIII)-Co-*-Catalyzed CH Alkenylation/Annulation Reactions of Indoles with Alkynes: A DFT Study

  Ken Sakata; Masami Eda; Yuri Kitaoka; Tatsuhiko Yoshino; Shigeki Matsunaga

  JOURNAL OF ORGANIC CHEMISTRY, Jul. 2017, Peer-reviewed, Last author

  
• CATALYTIC ENANTIOSELECTIVE DESYMMETRIZATION OF meso-AZIRIDINES WITH FLUOROMALONATES

  Seiya Fukagawa; Yingjie Xu; Masahiro Anada; Tatsuhiko Yoshino; Shigeki Matsunaga

  HETEROCYCLES, Jul. 2017, Peer-reviewed, Last author, Corresponding author

  
• Stereoselective Synthesis of Tetrasubstituted Alkenes via a Cp*Co-III-Catalyzed C-H Alkenylation/Directing Group Migration Sequence

  Hideya Ikemoto; Ryo Tanaka; Ken Sakata; Motomu Kanai; Tatsuhiko Yoshino; Shigeki Matsunaga

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Jun. 2017, Peer-reviewed, Last author, Corresponding author

  
• Cp*Co-III-catalyzed directed C-H trifluoromethylthiolation of 2-phenylpyridines and 6-arylpurines

  Misaki Yoshida; Kentaro Kawai; Ryo Tanaka; Tatsuhiko Yoshino; Shigeki Matsunaga

  CHEMICAL COMMUNICATIONS, Jun. 2017, Peer-reviewed, Last author, Corresponding author

  
• Cp*Co-III-catalyzed directed C-H trifluoromethylthiolation of 2-phenylpyridines and 6-arylpurines

  Misaki Yoshida; Kentaro Kawai; Ryo Tanaka; Tatsuhiko Yoshino; Shigeki Matsunaga

  CHEMICAL COMMUNICATIONS, Jun. 2017, Peer-reviewed, Last author, Corresponding author

  
• Targeting Ras-Driven Cancer Cell Survival and Invasion through Selective Inhibition of DOCK1

  Hirotada Tajiri; Takehito Uruno; Takahiro Shirai; Daisuke Takaya; Shigeki Matsunaga; Daiki Setoyama; Mayuki Watanabe; Mutsuko Kukimoto-Niino; Kounosuke Oisaki; Miho Ushijima; Fumiyuki Sanematsu; Teruki Honma; Takaho Terada; Eiji Oki; Senji Shirasawa; Yoshihiko Maehara; Dongchon Kang; Jean-Francois Cote; Shigeyuki Yokoyama; Motomu Kanai; Yoshinori Fukui

  CELL REPORTS, May 2017, Peer-reviewed

  
• A Novel Spiro-Heterocyclic Compound Identified by the Silkworm Infection Model Inhibits Transcription in Staphylococcus aureus

  Atmika Paudel; Hiroshi Hamamoto; Suresh Panthee; Keiichi Kaneko; Shigeki Matsunaga; Motomu Kanai; Yutaka Suzuki; Kazuhisa Sekimizu

  FRONTIERS IN MICROBIOLOGY, Apr. 2017, Peer-reviewed

  
• (Pentamethylcyclopentadienyl)cobalt(III)-Catalyzed C-H Bond Functionalization: From Discovery to Unique Reactivity and Selectivity

  Tatsuhiko Yoshino; Shigeki Matsunaga

  ADVANCED SYNTHESIS & CATALYSIS, Apr. 2017, Peer-reviewed, Invited, Last author, Corresponding author

  
• Hybrid Catalysis Enabling Room-Temperature Hydrogen Gas Release from N-Heterocycles and Tetrahydronaphthalenes

  Shota Kato; Yutaka Saga; Masahiro Kojima; Hiromu Fuse; Shigeki Matsunaga; Arisa Fukatsu; Mio Kondo; Shigeyuki Masaoka; Motomu Kanai

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2017, Peer-reviewed

  
• DIASTEREO- AND ENANTIOSELECTIVE CONSTRUCTION OF 6,7-DIOXABICYCLO[2.2.1]HEPTANE DERIVATIVES BY A DIRHODIUM(II)-CATALYZED INTRAMOLECULAR C-H INSERTION REACTION

  Taku Miyazawa; Kozue Imai; Motoki Ito; Koji Takeda; Masahiro Anada; Shigeki Matsunaga; Shunichi Hashimoto

  HETEROCYCLES, Jan. 2017, Peer-reviewed, Invited

  
• DIASTEREO- AND ENANTIOSELECTIVE CONSTRUCTION OF 6,7-DIOXABICYCLO[2.2.1]HEPTANE DERIVATIVES BY A DIRHODIUM(II)-CATALYZED INTRAMOLECULAR C-H INSERTION REACTION

  Taku Miyazawa; Kozue Imai; Motoki Ito; Koji Takeda; Masahiro Anada; Shigeki Matsunaga; Shunichi Hashimoto

  HETEROCYCLES, Jan. 2017, Peer-reviewed

  
• High-Valent Cobalt-Catalyzed C-H Bond Functionalization

  Tatsuhiko Yoshino; Shigeki Matsunaga

  ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 68, 2017, Peer-reviewed, Last author, Corresponding author

  
• Rapid Screening by Cell-Based Fusion Assay for Identifying Novel Antivirals of Glycoprotein B-Mediated Herpes Simplex Virus Type 1 Infection

  Naoyoshi Maeda; Atsushi Furukawa; Kosuke Kakita; Masahiro Anada; Shunichi Hashimoto; Shigeki Matsunaga; Kimiko Kuroki; Toyoyuki Ose; Akihisa Kato; Jun Arii; Yasushi Kawaguchi; Hisashi Arase; Katsumi Maenaka

  BIOLOGICAL & PHARMACEUTICAL BULLETIN, Nov. 2016, Peer-reviewed

  
• Site- and Regioselective Monoalkenylation of Pyrroles with Alkynes via Cp*Co-III Catalysis

  Ryo Tanaka; Hideya Ikemoto; Motomu Kanai; Tatsuhiko Yoshino; Shigeki Matsunaga

  ORGANIC LETTERS, Nov. 2016, Peer-reviewed, Last author, Corresponding author

  
• Enantio-and diastereoselective desymmetrization of alpha-alkyl-alpha-diazoesters by dirhodium(II)-catalyzed intramolecular C-H insertion

  Taku Miyazawa; Kazushi Minami; Motoki Ito; Masahiro Anada; Shigeki Matsunaga; Shunichi Hashimoto

  TETRAHEDRON, Jul. 2016, Peer-reviewed

  
• Cp*Co-III-Catalyzed Dehydrative C-H Allylation of 6-Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols

  Bunno, Y.; Murakami, N.; Suzuki, Y.; Kanai, M.; Yoshino, T.; Matsunaga, S.

  Organic Letters, 2016, Peer-reviewed, Last author, Corresponding author

  
• Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols

  Lin, L. Q.; Yamamoto, K.; Mitsunuma, H.; Kanzaki, Y.; Matsunaga, S.; Kanai, M.

  Journal of the American Chemical Society, 2015, Peer-reviewed, Corresponding author

  
• Cp*Co-III Catalyzed Site-Selective CH Activation of Unsymmetrical O-Acyl Oximes: Synthesis of Multisubstituted Isoquinolines from Terminal and Internal Alkynes

  Sun, B.; Yoshino, T.; Kanai, M.; Matsunaga, S.

  Angewandte Chemie-International Edition, 2015, Peer-reviewed, Last author, Corresponding author

  
• Dehydrative Direct C-H Allylation with Allylic Alcohols under Cp*Co-III Catalysis

  Suzuki, Y.; Sun, B.; Sakata, K.; Yoshino, T.; Matsunaga, S.; Kanai, M.

  Angewandte Chemie-International Edition, 2015, Peer-reviewed, Corresponding author

  
• Cp*Co(III)-catalyzed oxidative C-H alkenylation of benzamides with ethyl acrylate

  Suzuki, Y.; Sun, B.; Yoshino, T.; Kanai, M.; Matsunaga, S.

  Tetrahedron, 2015, Peer-reviewed, Invited, Last author, Corresponding author

  
• COBALT-CATALYZED C5-SELECTIVE C-H FUNCTIONALIZATION OF 4-Me-QUINOLINES WITH STYRENES: AN APPROACH TO 5,6-DIHYDRO-4H-BENZO de QUINOLINES

  Yamamoto, S.; Matsunaga, S.; Kanai, M.

  Heterocycles, 2015, Peer-reviewed, Corresponding author

  
• A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles

  Sun, B.; Yoshino, T.; Matsunaga, S.; Kanai, M.

  Chemical Communications, 2015, Peer-reviewed, Corresponding author

  
• COBALT-CATALYZED C5-SELECTIVE C-H FUNCTIONALIZATION OF 4-Me-QUINOLINES WITH STYRENES: AN APPROACH TO 5,6-DIHYDRO-4H-BENZO[de]QUINOLINES

  Shohei Yamamoto; Shigeki Matsunaga; Motomu Kanai

  HETEROCYCLES, Jan. 2015, Peer-reviewed, Corresponding author

  
• A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles

  Bo Sun; Tatsuhiko Yoshino; Shigeki Matsunaga; Motomu Kanai

  CHEMICAL COMMUNICATIONS, 2015, Peer-reviewed, Corresponding author

  
• Structure-activity relationship study of novel iminothiadiazolo-pyrimidinone antimicrobial agents (vol 66, pg 663, 2013)

  Paudel, A.; Kaneko, K.; Watanabe, A.; Matsunaga, S.; Kanai, M.; Hamamoto, H.; Sekimizu, K.

  Journal of Antibiotics, 2014, Peer-reviewed

  
• ENANTIOSELECTIVE SYNTHESIS OF SPIROOXINDOLES VIA DIRECT CATALYTIC ASYMMETRIC ALDOL-TYPE REACTION OF ISOTHIOCYANATO OXINDOLES

  Kato, S.; Kanai, M.; Matsunaga, S.

  Heterocycles, 2014, Peer-reviewed, Corresponding author

  
• ENANTIOSELECTIVE SYNTHESIS OF SPIROOXINDOLES VIA DIRECT CATALYTIC ASYMMETRIC ALDOL-TYPE REACTION OF ISOTHIOCYANATO OXINDOLES

  Shota Kato; Motomu Kanai; Shigeki Matsunaga

  HETEROCYCLES, Jan. 2014, Peer-reviewed, Corresponding author

  
• Cobalt-Catalyzed C-4 Selective Alkylation of Quinolines

  Yamamoto, S.; Saga, Y.; Andou, T.; Matsunaga, S.; Kanai, M.

  Advanced Synthesis & Catalysis, 2014, Peer-reviewed, Corresponding author

  
• Air-Stable Carbonyl(pentamethylcyclopentadienyl)cobalt Diiodide Complex as a Precursor for Cationic (Pentamethylcyclopentadienyl)cobalt(III) Catalysis: Application for Directed C-2 Selective C-H Amidation of Indoles

  Sun, B.; Yoshino, T.; Matsunaga, S.; Kanai, M.

  Advanced Synthesis & Catalysis, 2014, Peer-reviewed, Corresponding author

  
• Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes

  Matsunaga, S.; Shibasaki, M.

  Chemical Communications, 2014, Peer-reviewed, Lead author, Corresponding author

  
• Pyrroloindolone Synthesis via a Cp*Co-III-Catalyzed Redox-Neutral Directed C-H Alkenylation/Annulation Sequence

  Ikemoto, H.; Yoshino, T.; Sakata, K.; Matsunaga, S.; Kanai, M.

  Journal of the American Chemical Society, 2014, Peer-reviewed, Corresponding author

  
• Regiodivergent Kinetic Resolution of Terminal and Internal rac-Aziridines with Malonates under Dinuclear Schiff Base Catalysis

  Xu, Y. J.; Kaneko, K.; Kanai, M.; Shibasaki, M.; Matsunaga, S.

  Journal of the American Chemical Society, 2014, Peer-reviewed, Last author, Corresponding author

  
• Rh-catalyzed aldehyde - Aldehyde cross-aldol reaction under base-free conditions: In situ aldehyde-derived enolate formation through orthogonal activation

  Luqing Lin; Kumiko Yamamoto; Shigeki Matsunaga; Motomu Kanai

  Chemistry - An Asian Journal, Dec. 2013, Peer-reviewed, Corresponding author

  
• Structure-activity relationship study of novel iminothiadiazolo- pyrimidinone antimicrobial agents

  Atmika Paudel; Keiichi Kaneko; Ayako Watanabe; Matsunaga Shigeki; Kanai Motomu; Hiroshi Hamamoto; Kazuhisa Sekimizu

  Journal of Antibiotics, Nov. 2013, Peer-reviewed

  
• Catalytic asymmetric synthesis of spirooxindoles via addition of isothiocyanato oxindoles to aldehydes under dinuclear nickel schiff base catalysis

  Shota Kato; Motomu Kanai; Shigeki Matsunaga

  Chemistry - An Asian Journal, Aug. 2013, Peer-reviewed, Last author, Corresponding author

  
• Cp*Co-III-Catalyzed C2-Selective Addition of Indoles to Imines

  Tatsuhiko Yoshino; Hideya Ikemoto; Shigeki Matsunaga; Motomu Kanai

  CHEMISTRY-A EUROPEAN JOURNAL, Jul. 2013, Peer-reviewed, Corresponding author

  
• Cobalt-Catalyzed C4-Selective Direct Alkylation of Pyridines

  Kanai Motomu; Matsunaga Shigeki

  SYNTHESIS-STUTTGART, Jun. 2013, Peer-reviewed

  
• Sultam Synthesis via Cu-Catalyzed Intermolecular Carboamination of Alkenes with N-Fluorobenzenesulfonimide

  Keiichi Kaneko; Tatsuhiko Yoshino; Shigeki Matsunaga; Motomu Kanai

  ORGANIC LETTERS, May 2013, Peer-reviewed, Corresponding author

  
• Multimetallic Schiff Base Complexes as Cooperative Asymmetric Catalysts

  Shigeki Matsunaga; Masakatsu Shibasaki

  SYNTHESIS-STUTTGART, Feb. 2013, Peer-reviewed, Lead author, Corresponding author

  
• A Cationic High-Valent Cp*Co-III Complex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed C-H Bond Activation

  Yoshino, T.; Ikemoto, H.; Matsunaga, S.; Kanai, M.

  Angewandte Chemie-International Edition, 2013, Peer-reviewed

  
• Cobalt-Catalyzed C4-Selective Direct Alkylation of Pyridines

  Takashi Andou; Yutaka Saga; Hirotomo Komai; Shigeki Matsunaga; Motomu Kanai

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, Peer-reviewed

  
• DIRECT CATALYTIC ASYMMETRIC VINYLOGOUS MICHAEL REACTION OF alpha,beta-UNSATURATED gamma-BUTYROLACTAM UNDER DINUCLEAR NICKEL SCHIFF BASE CATALYSIS

  Hirooki Tanabe; Yingjie Xu; Bo Sun; Shigeki Matsunaga; Masakatsu Shibasaki

  HETEROCYCLES, Dec. 2012, Peer-reviewed, Corresponding author

  
• Lewis Acid Catalyzed Benzylic C-H Bond Functionalization of Azaarenes; Addition to Imines and Enones

  Hirotomo Komai; Tatsuhiko Yoshino; Shigeki Matsunaga; Motomu Kanai

  SYNTHESIS-STUTTGART, Jul. 2012, Peer-reviewed, Corresponding author

  
• Mg-Catalyzed Enantioselective Benzylic C-H Bond Functionalization of Isoindolinones: Addition to Imines

  Yudai Suzuki; Motomu Kanai; Shigeki Matsunaga

  CHEMISTRY-A EUROPEAN JOURNAL, Jun. 2012, Peer-reviewed, Last author, Corresponding author

  
• Lecture Tour upon Receiving the 7th Lectureship Award MBLA

  Shigeki Matsunaga

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Mar. 2012, Peer-reviewed

  
• Enantioselective Synthesis of 2,2-Disubstituted Terminal Epoxides via Catalytic Asymmetric Corey-Chaykovsky Epoxidation of Ketones

  Toshihiko Sone; Akitake Yamaguchi; Shigeki Matsunaga; Masakatsu Shibasaki

  MOLECULES, Feb. 2012, Peer-reviewed, Corresponding author

  
• CATALYTIC ASYMMETRIC AMINATION OF OXINDOLES UNDER DINUCLEAR NICKEL SCHIFF BASE CATALYSIS

  Shinsuke Mouri; Zhihua Chen; Shigeki Matsunaga; Masakatsu Shibasaki

  HETEROCYCLES, Jan. 2012, Peer-reviewed, Corresponding author

  
• Cationic Bismuth-Catalyzed Hydroamination and Direct Substitution of the Hydroxy Group in Alcohols with Amides

  Shigeki Matsunaga; Masakatsu Shibasaki

  BISMUTH-MEDIATED ORGANIC REACTIONS, 2012, Peer-reviewed, Corresponding author

  
• Catalytic Asymmetric Total Synthesis of Chimonanthine, Folicanthine, and Calycanthine through Double Michael Reaction of Bisoxindole

  Harunobu Mitsunuma; Masakatsu Shibasaki; Motomu Kanai; Shigeki Matsunaga

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, Peer-reviewed, Last author, Corresponding author

  
• Catalytic Asymmetric Synthesis of Spirooxindoles by a Mannich-Type Reaction of Isothiocyanato Oxindoles

  Shota Kato; Tatsuhiko Yoshino; Masakatsu Shibasaki; Motomu Kanai; Shigeki Matsunaga

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, Peer-reviewed

  
• Rhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols

  Luqing Lin; Kumiko Yamamoto; Shigeki Matsunaga; Motomu Kanai

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, Peer-reviewed, Corresponding author

  
• Construction of Contiguous Tetrasubstituted Chiral Carbon Stereocenters via Direct Catalytic Asymmetric Aldol and Mannich-Type Reactions

  Shigeki Matsunaga; Tatsuhiko Yoshino

  CHEMICAL RECORD, Sep. 2011, Peer-reviewed, Lead author, Corresponding author

  
• BINOL

  Masakatsu Shibasaki; Shigeki Matsunaga

  Privileged Chiral Ligands and Catalysts, 07 Apr. 2011, Peer-reviewed

  
• Lewis Acid Catalyzed Benzylic C-H Bond Functionalization of Azaarenes: Addition to Enones

  Hirotomo Komai; Tatsuhiko Yoshino; Shigeki Matsunaga; Motomu Kanai

  ORGANIC LETTERS, Apr. 2011, Peer-reviewed, Corresponding author

  
• Catalytic Asymmetric Ring-Opening of meso-Aziridines with Malonates under Heterodinuclear Rare Earth Metal Schiff Base Catalysis

  Yingjie Xu; Luqing Lin; Motomu Kanai; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2011, Peer-reviewed, Corresponding author

  
• Multimetallic Multifunctional Catalysts for Asymmetric Reactions

  Masakatsu Shibasaki; Motomu Kanai; Shigeki Matsunaga; Naoya Kumagai

  BIFUNCTIONAL MOLECULAR CATALYSIS, 2011, Peer-reviewed

  
• Dinuclear Ni-2-Schiff base complex-catalyzed asymmetric 1,4-addition of beta-keto esters to nitroethylene toward gamma(2,2)-amino acid synthesis

  Harunobu Mitsunuma; Shigeki Matsunaga

  CHEMICAL COMMUNICATIONS, 2011, Peer-reviewed

  
• Stereodivergent Direct Catalytic Asymmetric Mannich-Type Reactions of alpha-Isothiocyanato Ester with Ketimines

  Gang Lu; Tatsuhiko Yoshino; Hiroyuki Morimoto; Shigeki Matsunaga; Masakatsu Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, Peer-reviewed

  
• Bifunctional Asymmetric Catalysis Based on Dinuclear Schiff Base Complexes

  Masakatsu Shibasaki; Shigeki Matsunaga

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Nov. 2010, Peer-reviewed

  
• Catalytic Asymmetric Aza-Morita-Baylis-Hillman Reaction of Methyl Acrylate: Role of a Bifunctional La(O-iPr)(3)/Linked-BINOL Complex

  Takafumi Yukawa; Bianca Seelig; Yingjie Xu; Hiroyuki Morimoto; Shigeki Matsunaga; Albrecht Berkessel; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 2010, Peer-reviewed

  
• syn-Selective Catalytic Asymmetric 1,4-Addition of alpha-Ketoanilides to Nitroalkenes under Dinuclear Nickel Catalysis

  Yingjie Xu; Shigeki Matsunaga; Masakatsu Shibasaki

  ORGANIC LETTERS, Jul. 2010, Peer-reviewed, Corresponding author

  
• Heterobimetallic Transition Metal/Rare Earth Metal Bifunctional Catalysis: A Cu/Sm/Schiff Base Complex for Syn-Selective Catalytic Asymmetric Nitro-Mannich Reaction

  Shinya Handa; Vijay Gnanadesikan; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2010, Peer-reviewed, Corresponding author

  
• Direct Catalytic Asymmetric Vinylogous Mannich-Type and Michael Reactions of an alpha,beta-Unsaturated gamma-Butyrolactam under Dinuclear Nickel Catalysis

  Nicholas E. Shepherd; Hirooki Tanabe; Yingjie Xu; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2010, Peer-reviewed

  
• Catalytic Asymmetric Synthesis of 3-Aminooxindoles: Enantiofacial Selectivity Switch in Bimetallic vs Monometallic Schiff Base Catalysis

  Shinsuke Mouri; Zhihua Chen; Harunobu Mitsunuma; Makoto Furutachi; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2010, Peer-reviewed

  
• Catalytic Asymmetric 1,4-Additions of beta-Keto Esters to Nitroalkenes Promoted by a Bifunctional Homobimetallic Co-2-Schiff Base Complex

  Makoto Furutachi; Zhihua Chen; Shigeki Matsunaga; Masakatsu Shibasaki

  MOLECULES, Jan. 2010, Peer-reviewed

  
• A Heterobimetallic Ni/La-salan Complex for Catalytic Asymmetric Decarboxylative 1,4-Addition of Malonic Acid Half-Thioester

  Makoto Furutachi; Shinsuke Mouri; Shigeki Matsunaga; Masakatsu Shibasaki

  CHEMISTRY-AN ASIAN JOURNAL, 2010, Peer-reviewed

  
• Construction of Contiguous Tetrasubstituted Chiral Carbon Stereocenters via Direct Catalytic Asymmetric Aldol Reaction of alpha-Isothlocyanato Esters with Ketones

  Tatsuhiko Yoshino; Hiroyuki Morimoto; Gang Lu; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2009, Peer-reviewed

  
• Catalytic Asymmetric Synthesis of alpha-Alkylidene-beta-hydroxy Esters via Dynamic Kinetic Asymmetric Transformation Involving Ba-Catalyzed Direct Aldol Reaction

  Akitake Yamaguchi; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2009, Peer-reviewed

  
• Recent Progress in Asymmetric Bifunctional Catalysis Using Multimetallic Systems

  Masakatsu Shibasaki; Motomu Kanai; Shigeki Matsunaga; Naoya Kumagai

  ACCOUNTS OF CHEMICAL RESEARCH, Aug. 2009, Peer-reviewed

  
• A Homodinuclear Mn(III)(2)-Schiff Base Complex for Catalytic Asymmetric 1,4-Additions of Oxindoles to Nitroalkenes

  Yuko Kato; Makoto Furutachi; Zhihua Chen; Harunobu Mitsunuma; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2009, Peer-reviewed

  
• Mixed La-Li heterobimetallic complexes for tertiary nitroaldol resolution

  Keiichi Hara; Shin-Ya Tosaki; Vijay Gnanadesikan; Hiroyuki Morimoto; Shinji Harada; Mari Sugita; Noriyuki Yamagiwa; Shigeki Matsunaga; Masakatsu Shibasaki

  TETRAHEDRON, Jun. 2009, Peer-reviewed

  
• Catalytic Asymmetric Synthesis of Nitrogen-Containing gem-Bisphosphonates Using a Dinuclear Ni-2-Schiff Base Complex

  Yuko Kato; Zhihua Chen; Shigeki Matsunaga; Masakatsu Shibasaki

  SYNLETT, Jun. 2009, Peer-reviewed

  
• A Heterobimetallic Ga/Yb-Schiff Base Complex for Catalytic Asymmetric alpha-Addition of Isocyanides to Aldehydes

  Hisashi Mihara; Yingjie Xu; Nicholas E. Shepherd; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jun. 2009, Peer-reviewed

  
• Catalytic Asymmetric Synthesis of 2,2-Disubstituted Oxetanes from Ketones by Using a One-Pot Sequential Addition of Sulfur Ylide

  Toshihiko Sone; Gang Lu; Shigeki Matsunaga; Masakatsu Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, Peer-reviewed

  
• A Stable Homodinuclear Biscobalt(III)-Schiff Base Complex for Catalytic Asymmetric 1,4-Addition Reactions of beta-Keto Esters to Alkynones

  Zhihua Chen; Makoto Furutachi; Yuko Kato; Shigeki Matsunaga; Masakatsu Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, Peer-reviewed

  
• Direct anti-Selective Catalytic Asymmetric Mannich-Type Reactions of alpha-Ketoanilides for the Synthesis of gamma-Amino Amides and Azetidine-2-amides

  Yingjie Xu; Gang Lu; Shigeki Matsunaga; Masakatsu Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, Peer-reviewed

  
• Direct catalytic asymmetric aldol reaction of beta-keto esters with formaldehyde promoted by a dinuclear Ni-2-Schiff base complex

  Shinsuke Mouri; Zhihua Chen; Shigeki Matsunaga; Masakatsu Shibasaki

  CHEMICAL COMMUNICATIONS, 2009, Peer-reviewed

  
• A DyI3-catalyzed Mannich-type Reaction of 1-Methylcyclopropanecarboxylate-type Donors for the Stereoselective Synthesis of Pyrrolidines with Quaternary Stereocenters

  Hidetoshi Noda; Sean H. Wiedemann; Shigeki Matsunaga; Masakatsu Shibasaki

  CHEMISTRY LETTERS, Nov. 2008, Peer-reviewed

  
• Direct catalytic asymmetric Mannich-type reaction of beta-keto phosphonate using a dinuclear Ni(2)-Schiff base complex

  Zhihua Chen; Kenichiro Yakura; Shigeki Matsunaga; Masakatsu Shibasaki

  ORGANIC LETTERS, Aug. 2008, Peer-reviewed

  
• Catalytic asymmetric synthesis of 2,2-disubstituted terminal epoxides via dimethyloxosulfonium methylide addition to ketones

  Toshihiko Sone; Akitake Yamaguchi; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2008, Peer-reviewed

  
• Strategies for constructing diverse chiral environments in multimetallic bifunctional asymmetric catalysis

  Masakatsu Shibasaki; Shigeki Matsunaga; Naoya Kumagai

  SYNLETT, Jul. 2008, Peer-reviewed

  
• Direct catalytic asymmetric Mannich-type reactions of gamma-butenolides: Effectiveness of Bronsted acid in chiral metal catalysis

  Akitake Yamaguchi; Shigeki Matsunaga; Masakatsu Shibasaki

  ORGANIC LETTERS, Jun. 2008, Peer-reviewed

  
• Stereodivergent catalytic doubly diastereoselective nitroaldol reactions using heterobimetalic complexes

  Yoshihiro Sohtome; Yuko Kato; Shinya Handa; Naohiro Aoyama; Keita Nagawa; Shigeki Matsunaga; Masakatsu Shibasaki

  ORGANIC LETTERS, Jun. 2008, Peer-reviewed

  
• Sc3+-catalyzed aldol-type additions of N-benzoylcyclopropanecarboxamides via iodide-mediated ring-opening: Stereoselective synthesis of gamma-lactams

  Sean H. Wiedemann; Hidetoshi Noda; Shinji Harada; Shigeki Matsunaga; Masakatsu Shibasaki

  ORGANIC LETTERS, Apr. 2008, Peer-reviewed

  
• A bench-stable homodinuclear Ni(2)-chiff base complex for catalytic asymmetric synthesis of alpha-tetrasubstituted anti-alpha,beta-diamino acid surrogates

  Zhihua Chen; Hiroyuki Morimoto; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2008, Peer-reviewed

  
• Catalytic enantioselective addition of terminal alkynes to aldehydes: Preparation of (S)-(-)-1,3-diphenyl-2-propyn-1-OL and (5)-(-)-4-methyl-1-phenyl- 2-pentyn-1,4-diol

  Takita R; Harada S; Ohshima T; Matsunaga S; Shibasaki M

  Organic Syntheses, 2008, Peer-reviewed

  
• Multimetallic bifunctional asymmetric catalysis based on proximity effect control

  Shigeki Matsunaga; Masakatsu Shibasaki

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Jan. 2008, Peer-reviewed

  
• A method for the synthesis of an oseltamivir PET tracer

  Masataka Morita; Toshihiko Sone; Kenzo Yamatsugu; Yoshihiro Sohtome; Shigeki Matsunaga; Motomu Kanaia; Watanabe B. Yasuyoshi; Masakatsu Shibasaki

  BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, Jan. 2008, Peer-reviewed

  
• Chiral-catalyst-based convergent synthesis of HIV protease inhibitor GRL-06579A

  Hisashi Mihara; Yoshihiro Sohtome; Shigeki Matsunaga; Masakatsu Shibasaki

  CHEMISTRY-AN ASIAN JOURNAL, 2008, Peer-reviewed

  
• A heterobimetallic Pd/La/Schiff base complex for anti-selective catalytic asymmetric nitroaldol reactions and applications to short syntheses of beta-adrenoceptor agonists

  Shinya Handa; Keita Nagawa; Yoshihiro Sohtome; Shigeki Matsunaga; Masakatsit Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, Peer-reviewed

  
• Catalytic asymmetric epoxidation of alpha,beta-unsaturated phosphane oxides with a Y(O-iPr)3/biphenyldiol complex

  Keiichi Hara; So-Young Park; Noriyuki Yamagiwa; Shigeki Matsunaga; Masakatsu Shibasaki

  CHEMISTRY-AN ASIAN JOURNAL, 2008, Peer-reviewed

  
• Chiral gamma-amino amide synthesis by heterobimetallic lanthanum/lithium/pybox-catalyzed direct asymmetric Mannich-type reactions of alpha-keto anilides

  Gang Lu; Hiroyuki Morimoto; Shigeki Matsunaga; Masakatsu Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, Peer-reviewed

  
• Lewis Base Assisted Bronsted Base Catalysis: Bidentate Phosphine Oxides as Activators and Modulators of Bronsted Basic Lanthanum-Aryloxides

  Hiroyuki Morimoto; Tatsuhiko Yoshino; Takafumi Yukawa; Gang Lu; Shigeki Matsunaga; Masakatsu Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, Peer-reviewed

  
• Catalytic asymmetric cyclopropanation of enones with dimethyloxosulfonium methylide promoted by a La-Li-3-(Biphenyldiolate)(3)+NaI complex

  Hiroyuki Kakei; Toshihiko Sone; Yoshihiro Sohtome; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2007, Peer-reviewed

  
• Catalytic nucleophilic activation of acetonitrile via a cooperative catalysis of cationic Ru complex, DBU, and NaPF6

  Naoya Kumagai; Shigeki Matsunaga; Masakatsu Shibasaki

  TETRAHEDRON, Aug. 2007, Peer-reviewed

  
• Lanthanum aryloxide/pybox-catalyzed direct asymmetric mannich-type reactions using a trichloromethyl ketone as a propionate equivalent donor

  Hiroyuki Morimoto; Gang Lu; Naohiro Aoyama; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2007, Peer-reviewed

  
• Ba-catalyzed direct mannich-type reactions of a beta,gamma-unsaturated ester providing beta-methyl aza-morita-baylis-hillman-type products

  Akitake Yamaguchi; Naohiro Aoyama; Shigeki Matsunaga; Masakatsu Shibasaki

  ORGANIC LETTERS, Aug. 2007, Peer-reviewed

  
• Catalytic asymmetric Michael reactions of dibenzyl malonate to alpha,beta-unsaturated N-acylpyrroles using a La(O-iPr)(3)/Ph-linked-BINOL complex

  So-Young Park; Hiroyuki Morimoto; Shigeki Matsunaga; Masakatsu Shibasaki

  TETRAHEDRON LETTERS, Apr. 2007, Peer-reviewed

  
• syn-selective catalytic asymmetric nitro-Mannich reactions using a heterobimetallic Cu-Sm-Schiff base complex

  Shinya Handa; Vijay Gnanadesikan; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2007, Peer-reviewed

  
• Ligand accelerated indium(III)-catalyzed asymmetric alkynylation of aldehydes with 2-methyl-3-butyn-2-ol as an ethyne equivalent donor

  Shinji Harada; Ryo Takita; Takashi Ohshima; Shigeki Matsunaga; Masakatsu Shibasaki

  CHEMICAL COMMUNICATIONS, Mar. 2007, Peer-reviewed

  
• Catalytic asymmetric epoxidation of alpha,beta-unsaturated esters with chiral yttrium-biaryldiol complexes

  Hiroyuki Kakei; Riichiro Tsuji; Takashi Ohshima; Hiroyuki Morimoto; Shigeki Matsunaga; Masakatsu Shibasaki

  CHEMISTRY-AN ASIAN JOURNAL, 2007, Peer-reviewed

  
• Bismuth- and hafnium-catalyzed hydroamination of vinyl arenes with sulfonamides, carbamates, and carboxamides

  Hongbo Qin; Noriyuki Yamagiwa; Shigeki Matsunaga; Masakatsu Shibasaki

  CHEMISTRY-AN ASIAN JOURNAL, 2007, Peer-reviewed

  
• Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides

  Hongbo Qin; Noriyuki Yamagiwa; Shigeki Matsunaga; Masakatsu Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, Peer-reviewed

  
• syn-selective direct catalytic asymmetric Mannich-type reactions of aromatic and heteroaromatic hydroxy ketones promoted by Y[N(SiMe3)(2)](3)/linked-BINOL complexes

  Shigeki Matsunaga; Mari Sugita; Noriyuki Yamagiwa; Shinya Handa; Akitake Yamaguchi; Masakatsu Shibasaki

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Dec. 2006, Peer-reviewed

  
• Catalytic asymmetric epoxidation of alpha-methyl alpha,beta-unsaturated anilides as ester surrogates

  Zhihua Chen; Hiroyuki Morimoto; Shigeki Matsunaga; Masakatsu Shibasaki

  SYNLETT, Dec. 2006, Peer-reviewed

  
• Mixed La-Li heterobimetallic complexes for tertiary nitroaldol resolution

  Shin-ya Tosaki; Keiichi Hara; Vijay Gnanadesikan; Hiroyuki Morimoto; Shinji Harada; Mari Sugita; Noriyuki Yamagiwa; Shigeki Matsunaga; Masakatsu Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 2006, Peer-reviewed

  
• Recent progress in catalytic intermolecular hydroamination

  Shigeki Matsunaga

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Jul. 2006, Peer-reviewed

  
• Catalytic asymmetric epoxidation of alpha,beta-unsaturated N-acylpyrroles as monodentate and activated ester equivalent acceptors

  S Matsunaga; H Qin; M Sugita; S Okada; T Kinoshita; N Yamagiwa; M Shibasaki

  TETRAHEDRON, Jul. 2006, Peer-reviewed

  
• Recent Progress in Catalytic Intermolecular Hydroamination

  MATSUNAGA Shigeki

  J. Synth. Org. Chem. Jpn., 01 Jul. 2006

  
• Direct catalytic asymmetric Mannich-type reactions of isomerizable aliphatic imines: chemoselective enolate formation from a hydroxyketone by a Zn-catalyst

  Akitake Yamaguchi; Shigeki Matsunaga; Masakatsu Shibasaki

  TETRAHEDRON LETTERS, Jun. 2006, Peer-reviewed

  
• Metal/linked-BINOL complexes: Applications in direct catalytic asymmetric Mannich-type reactions

  M Shibasaki; S Matsunaga

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, May 2006, Peer-reviewed

  
• Bismuth-catalyzed intermolecular hydroamination of 1,3-dienes with carbarnates, sulfonamides, and carboxamides (vol 128, pg 1611, 2006)

  HB Qin; N Yamagiwa; S Matsunaga; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2006, Peer-reviewed

  
• Catalytic asymmetric cyano-phosphorylation of aldehydes using a YLi(3)tris(binaphthoxide) complex (YLB)

  N Yamagiwa; Y Abiko; M Sugita; J Tian; S Matsunaga; M Shibasaki

  TETRAHEDRON-ASYMMETRY, Feb. 2006, Peer-reviewed

  
• Bismuth-catalyzed intermolecular hydroamination of 1,3-dienes with carbamates, sulfonamides, and carboxamides

  H Qin; N Yamagiwa; S Matsunaga; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2006, Peer-reviewed

  
• Chiral, poly(rare-earth metal) complexes in asymmetric catalysis

  M Shibasaki; M Kanai; S Matsunaga

  ALDRICHIMICA ACTA, 2006, Peer-reviewed

  
• Design and application of linked-BINOL chiral ligands in bifunctional asymmetric catalysis

  M Shibasaki; S Matsunaga

  CHEMICAL SOCIETY REVIEWS, 2006, Peer-reviewed

  
• Trichloromethyl ketones as synthetically versatile donors: Application in direct catalytic Mannich-type reactions and the stereoselective synthesis of azetidines

  Hiroyuki Morimoto; Seat H. Wiedemann; Akitake Yamaguchi; Shinji Harada; Zhihua Chen; Shigeki Matsunaga; Masakatsu Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, Peer-reviewed

  
• syn-selective direct catalytic asymmetric Mannich-type reactions of hydroxyketones using Y{N(SiMe3)(2)}(3)/linked-BINOL complexes

  M Sugita; A Yamaguchi; N Yamagiwa; S Handa; S Matsunaga; M Shibasaki

  ORGANIC LETTERS, Nov. 2005, Peer-reviewed

  
• Lewis acid-Lewis acid heterobimetallic cooperative catalysis: Mechanistic studies and application in enantioselective aza-Michael reaction

  N Yamagiwa; HB Qin; S Matsunaga; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 2005, Peer-reviewed

  
• Catalytic asymmetric cyano-ethoxycarbonylation reaction of aldehydes using a YLi(3)Tris(binaphthoxide) (YLB) complex: Mechanism and roles of achiral additives

  N Yamagiwa; J Tian; S Matsunaga; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2005, Peer-reviewed

  
• Non-C-2-symmetric, chirally economical, and readily tunable linked-binols: Design and application in a direct catalytic asymmetric Mannich-type reaction

  T Yoshida; H Morimoto; N Kumagai; S Matsunaga; M Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, Peer-reviewed

  
• Direct catalytic asymmetric Mannich-type reactions of N-(2-hydroxyacetyl)pyrrole as an ester-equivalent donor

  S Harada; S Handa; S Matsunaga; M Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, Peer-reviewed

  
• Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination

  N Kumagai; S Matsunaga; M Shibasaki

  CHEMICAL COMMUNICATIONS, 2005, Peer-reviewed

  
• Catalytic asymmetric cyano-phosphorylation of aldehydes promoted by heterobimetallic YLi(3)tris(binaphthoxide) (YLB) complex

  Y Abiko; N Yamagiwa; M Sugita; J Tian; S Matsunaga; M Shibasaki

  SYNLETT, Nov. 2004, Peer-reviewed

  
• Cooperative catalysis of a cationic ruthenium complex, amine base, and Na salt: Catalytic activation of acetonitrile as a nucleophile

  N Kumagai; S Matsunaga; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Oct. 2004, Peer-reviewed

  
• Direct catalytic asymmetric Mannich-type reaction of hydroxyketone using a Et2Zn/Linked-BINOL complex: Synthesis of either anti- or syn-beta-amino alcohols

  S Matsunaga; T Yoshida; H Morimoto; N Kumagai; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2004, Peer-reviewed

  
• Catalytic asymmetric 1,4-addition reactions using alpha,beta-unsaturated N-acylpyrroles as highly reactive monodentate alpha,beta-unsaturated ester surrogates

  S Matsunaga; T Kinoshita; S Okada; S Harada; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jun. 2004, Peer-reviewed

  
• An efficient synthesis of bicyclic amidines by intramolecular cyclization

  N Kumagai; S Matsunaga; M Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, Peer-reviewed

  
• Mechanistic studies of a reaction promoted by the [YLi3{triS(binaphthoxide)}] complex: Are three 1,1 '-Bi-2-naphthol units in a rare-earth-alkali-metal heterobimetallic complex necessary?

  N Yamagiwa; S Matsunaga; M Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, Peer-reviewed

  
• Heterobimetallic catalysis in asymmetric 1,4-addition of O-alkylhydroxylamine to enones

  N Yamagiwa; S Matsunaga; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2003, Peer-reviewed

  
• Efficient two-step conversion of alpha,beta-unsaturated aldehydes to optically active gamma-oxy-alpha,beta-unsaturated nitriles and its application to the total synthesis of (+)-patulolide C

  J Tian; N Yamagiwa; S Matsunaga; M Shibasaki

  ORGANIC LETTERS, Aug. 2003, Peer-reviewed

  
• Direct catalytic aldol-type reactions using RCH2CN

  Y Suto; N Kumagai; S Matsunaga; M Kanai; M Shibasaki

  ORGANIC LETTERS, Aug. 2003, Peer-reviewed

  
• anti-selective direct catalytic asymmetric Mannich-type reaction of hydroxyketone providing beta-amino alcohols

  S Matsunaga; N Kumagai; S Harada; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2003, Peer-reviewed

  
• Direct catalytic asymmetric Michael reaction of hydroxyketones: Asymmetric Zn catalysis with a Et2Zn/linked-BINOL complex

  S Harada; N Kumagai; T Kinoshita; S Matsunaga; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2003, Peer-reviewed

  
• Direct catalytic asymmetric aldol reaction of hydroxyketones: Asymmetric Zn catalysis with a Et2Zn/linked-BINOL complex

  N Kumagai; S Matsunaga; T Kinoshita; S Harada; S Okada; S Sakamoto; K Yamaguchi; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2003, Peer-reviewed

  
• Sequential Wittig olefination-catalytic asymmetric epoxidation with reuse of waste Ph3P(O): Application of alpha,beta-unsaturated N-acyl pyrroles as ester surrogates

  T Kinoshita; S Okada; Park, SR; S Matsunaga; M Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, Peer-reviewed

  
• Linked-BINOL: An approach towards practical asymmetric multifunctional catalysis

  S Matsunaga; T Ohshima; M Shibasaki

  ADVANCED SYNTHESIS & CATALYSIS, Jan. 2002, Peer-reviewed

  
• An asymmetric cyanation reaction and sequential asymmetric cyanation-nitroaldol reaction using a [YLi3{tris(binaphthoxide)}] single catalyst component: Catalyst tuning with achiral additives

  J Tian; N Yamagiwa; S Matsunaga; M Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, Peer-reviewed

  
• An asymmetric cyanation reaction and sequential asymmetric cyanation-nitroaldol reaction using a [YLi3{tris(binaphthoxide)}] single catalyst component: Catalyst tuning with achiral additives

  J Tian; N Yamagiwa; S Matsunaga; M Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, Peer-reviewed

  
• Enantioselective 1,4-addition of unmodified ketone catalyzed by a bimetallic Zn-Zn-linked-BINOL complex

  N Kumagai; S Matsunaga; M Shibasaki

  ORGANIC LETTERS, Dec. 2001, Peer-reviewed

  
• Direct catalytic enantio- and diastereoselective aldol reaction using a Zn-Zn-linked-BINOL complex: A practical synthesis of syn-1,2-diols

  N Kumagai; S Matsunaga; N Yoshikawa; T Ohshima; M Shibasaki

  ORGANIC LETTERS, May 2001, Peer-reviewed

  
• Direct catalytic asymmetric aldol reaction: Synthesis of either syn- or anti-alpha,beta-Dihydroxy ketones (vol 123, pg 2466, 2001)

  N Yoshikawa; N Kumagai; S Matsunaga; G Moll; T Ohshima; T Suzuki; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2001, Peer-reviewed

  
• Direct catalytic asymmetric aldol reaction: Synthesis of either syn- or anti-alpha,beta-dihydroxy ketones

  N Yoshikawa; N Kumagai; S Matsunaga; G Moll; T Ohshima; T Suzuki; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2001, Peer-reviewed

  
• Enantioselective Strecker-type reaction promoted by polymer-supported bifunctional catalyst

  H Nogami; S Matsunaga; M Kanai; M Shibasaki

  TETRAHEDRON LETTERS, Jan. 2001, Peer-reviewed

  
• 25 Studies toward the Asymmetric Total Synthesis of Strychnos Alkaloid (-)-Strychnine

  Ohshima Takashi; Xu Youjun; Kim Yun Sik; Matsunaga Shigeki; Ohori Ken; Shibasaki Masakatsu

  Symposium on the Chemistry of Natural Products, symposium papers, 01 Oct. 2000

  
• Immobilization of asymmetric multifunctional catalysts on an insoluble polymer

  S Matsunaga; T Ohshima; M Shibasaki

  TETRAHEDRON LETTERS, Oct. 2000, Peer-reviewed

  
• Stable, storable, and reusable asymmetric catalyst: A novel La-linked-BINOL complex for the catalytic asymmetric Michael reaction

  YS Kim; S Matsunaga; J Das; A Sekine; T Ohshima; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2000, Peer-reviewed

  
• Catalytic enantioselective meso-epoxide ring opening reaction with phenolic oxygen nucleophile promoted by gallium heterobimetallic multifunctional complexes

  S Matsunaga; J Das; J Roels; EM Vogl; N Yamamoto; T Iida; K Yamaguchi; M Shibasaki

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2000, Peer-reviewed

  
• Linking BINOL: C-2-symmetric ligands for investigations on asymmetric catalysis

  EM Vogl; S Matsunaga; M Kanai; T Iida; M Shibasaki

  TETRAHEDRON LETTERS, Oct. 1998, Peer-reviewed

  
• Enantioselective ring opening of epoxides with 4-methoxyphenol catalyzed by gallium heterobimetallic complexes: An efficient method for the synthesis of optically active 1,2-diol monoethers

  T Iida; N Yamamoto; S Matsunaga; HG Woo; M Shibasaki

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Aug. 1998, Peer-reviewed

  

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• コバルト触媒を用いたC4選択的直截的ピリジン環アルキル化法の開発

  安藤高史; 嵯峨裕; 嵯峨裕; 駒井宏友; 山本昇平; 松永茂樹; 松永茂樹; 金井求; 金井求

  日本薬学会年会要旨集(CD-ROM), 2013

  
• コバルト触媒によるキノリンの位置選択的アルキル化反応

  山本昇平; 嵯峨裕; 嵯峨裕; 安藤高史; 松永茂樹; 松永茂樹; 金井求; 金井求

  日本薬学会年会要旨集(CD-ROM), 2013

  
• コバルト触媒を用いた直截的複素環アルキル化法の開発

  安藤高史; 嵯峨裕; 嵯峨裕; 駒井宏友; 山本昇平; 松永茂樹; 松永茂樹; 金井求; 金井求

  反応と合成の進歩シンポジウム講演要旨集, 2012

  
• Synthesis of electron-deficient Cp^EIr(III) complex and its application for ether-directed C-H functionalization

  冨田永希; 小島正寛; 永島佑貴; 田中健; 杉山晴紀; 瀬川泰知; 古川敦; 前仲勝実; 前仲勝実; 前田理; 前田理; 吉野達彦; 吉野達彦; 松永茂樹; 松永茂樹

  日本薬学会年会要旨集(Web), 2023

  
• Catalytic Asymmetric Reactions Using N-Acylpyrroles as Activated Monodentate Ester Surrogates

  Matsunaga Shigeki; Harada Shinji; Qin Hongbo; Yamagiwa Noriyuki; Handa Shinya; Shibasaki Masakatsu

  Proceedings of the Symposium on Progress in Organic Reactions and Syntheses, 2005

  
• 電子不足Cp^EIr(III)錯体の合成及びエーテルを配向基として用いたC-H官能基化反応への応用

  冨田永希; 小島正寛; 永島佑貴; 田中健; 杉山晴紀; 杉山晴紀; 瀬川泰知; 瀬川泰知; 古川敦; 前仲勝実; 前仲勝実; 前田理; 前田理; 前田理; 吉野達彦; 吉野達彦; 松永茂樹; 松永茂樹

  次世代を担う有機化学シンポジウム講演要旨集, 2022

  
• アリールヨードニウムイリドを用いた求核的アスタチン標識反応の開発

  松岡慶太郎; 尾幡穂乃香; 尾幡穂乃香; 永津弘太郎; 小島正寛; 吉野達彦; 小川美香子; 小川美香子; 松永茂樹; 松永茂樹

  反応と合成の進歩シンポジウム講演要旨集, 2021

  
• 新規外輪型キラル二核ルテニウム(II,III)錯体の創製と合成応用

  宮澤拓; 滝沢昂嗣; 鈴木拓郎; 熊谷悠平; 亀井雄大; 小島正寛; 穴田仁洋; 吉野達彦; 松永茂樹

  万有仙台シンポジウム, 29 Jun. 2019

  
• アキラルなCp配位子を有する高原子価第9族金属触媒とキラルカルボン酸を用いた不斉C‐H活性化反応

  深川聖弥; LIN Luqing; 加藤佳美; 田中亮; 関根大地; 冨田永希; 小島正寛; 吉野達彦; 松永茂樹

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• 有機ゲルマニウム化合物の新規合成法の開発とその応用

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  Abstracts. Annual Meeting of the NMR Society of Japan, 03 Sep. 2018

  
• HSV-1感染における糖ペプチドと免疫受容体PILRα相互作用解析

  野村 尚生; 柿田 浩輔; 古川 敦; 穴田 仁洋; 橋下 俊一; 松永 茂樹; 齊藤 貴士; 前仲 勝実

  日本薬学会年会要旨集, Mar. 2018

  
• HSV‐1感染における糖ペプチドと免疫受容体PILRα相互作用解析

  野村尚生; 柿田浩輔; 古川敦; 穴田仁洋; 橋下俊一; 松永茂樹; 齊藤貴士; 前仲勝実; 前仲勝実

  日本薬学会年会要旨集(CD-ROM), Mar. 2018

  
• インドール-2,3-エポキシド等価体の合成と求核試薬との反応

  山田康司; 鈴木拓郎; 穴田仁洋; 松永茂樹; 阿部匠

  反応と合成の進歩シンポジウム講演要旨集, 2017

  
• ハイブリッド触媒系を用いた有機分子からの水素放出反応の開発

  布施拡; 加藤将太; 嵯峨裕; 嵯峨裕; 小島正寛; 松永茂樹; 松永茂樹; 深津亜里紗; 近藤美欧; 近藤美欧; 正岡重行; 金井求; 金井求

  日本薬学会年会要旨集(CD-ROM), 2017

  
• 単純ヘルペスウイルス感染阻害活性を示す糖ペプチドの合成研究

  柿田浩輔; 古川敦; 穴田仁洋; 南部寿則; 前仲勝実; 松永茂樹; 橋本俊一

  日本薬学会年会要旨集(CD-ROM), Mar. 2016

  
• 二核ロジウム(II)カルボキシラート錯体を用いたα-ジアゾエステルの分子内不斉C-H挿入反応

  宮澤拓; 南和志; 今井こずえ; 竹田幸司; 穴田仁洋; 松永茂樹; 松永茂樹; 橋本俊一

  日本薬学会年会要旨集(CD-ROM), 2016

  
• 進化するキラル化学のイノベーション キラル多核錯体の設計と触媒的不斉合成への応用

  MATSUNAGA SHIGEKI; MATSUNAGA SHIGEKI; SHIBASAKI MASAKATSU

  化学工業, 01 Feb. 2015

  
• 触媒的多連続不斉アルドール反応の開発

  山本久美子; 林禄清; 三ツ沼治信; 井田貴志; 松永茂樹; 松永茂樹; 松永茂樹; 金井求; 金井求

  次世代を担う有機化学シンポジウム講演要旨集, 2015

  
• 次世代型1,3ポリオール合成法の確立に向けた触媒的不斉多重アルドール反応の開発

  三ツ沼治信; 林禄清; 山本久美子; 井田貴志; 松永茂樹; 松永茂樹; 金井求; 金井求

  日本薬学会年会要旨集(CD-ROM), 2015

  
• アセトアルデヒド等価体エノラートを用いた触媒的不斉交差アルドール反応の開発

  井田貴志; 山本久美子; 三ツ沼治信; 松永茂樹; 金井求

  日本化学会講演予稿集, 2015

  
• 二核ロジウム(II)錯体を用いたα-ジアゾエステルの分子内不斉C-H挿入反応

  宮澤拓; 南和志; 今井こずえ; 竹田幸司; 穴田仁洋; 松永茂樹; 松永茂樹; 橋本俊一

  複素環化学討論会講演要旨集, 2015

  
• Rh(II)カルボキシラート錯体を用いたアリールジアゾアセタートの分子内不斉シクロプロパン化反応

  滋野大喜; 竹田幸司; 穴田仁洋; 松永茂樹; 松永茂樹; 橋本俊一

  反応と合成の進歩シンポジウム講演要旨集, 2015

  
• From Chiral Base Catalysts to Redox-Active Catalysts: Chasing the Identity of Metal Catalysts in Carbon-Carbon Bond-Forming Reactions

  Motomu Kanai; Shigeki Matsunaga; Kounosuke Oisaki; Yohei Shimizu

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, May 2013

  
• スピロオキシインドールの触媒的不斉合成法の開発(2)

  KITAHARA SEIKO; KATO SHOTA; KANAI MOTOMU; MATSUNAGA SHIGEKI

  日本薬学会年会要旨集(CD-ROM), 2013

  
• 進化を続ける触媒~環境にやさしいものづくりを目指して

  MATSUNAGA SHIGEKI

  化学と教育, 20 Jul. 2012

  
• 進化を続ける触媒 : 環境にやさしいものづくりを目指して(レーダー)

  松永 茂樹

  化学と教育, 20 Jul. 2012

  
• イソインドリノン類を用いた直接的触媒的不斉マンニッヒ型反応

  SUZUKI YUDAI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本化学会講演予稿集, 09 Mar. 2012

  
• Chimonanthineの触媒的不斉全合成

  MITSUNUMA HARUNOBU; MATSUNAGA SHIGEKI; SHIBASAKI MASAKATSU; KANAI MOTOMU

  日本化学会講演予稿集, 09 Mar. 2012

  
• ルイス酸触媒を用いたMichael反応によるC‐H結合官能基化反応

  KOMAI HIROTOMO; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本化学会講演予稿集, 09 Mar. 2012

  
• チモナンチンの触媒的不斉全合成

  MITSUNUMA HARUNOBU; MATSUNAGA SHIGEKI; SHIBASAKI MASAKATSU; KANAI MOTOMU

  日本薬学会年会要旨集, 05 Mar. 2012

  
• ルイス酸触媒を用いたMichael付加反応によるC‐H結合官能基化反応

  KOMAI HIROTOMO; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集, 05 Mar. 2012

  
• ヘテロ二核シッフ塩基錯体によるマロン酸エステルを求核剤としたメソ‐アジリジンに対する触媒的不斉開環反応の開発

  KYO OKETSU; RIN ROKUSEI; KANAI MOTOMU; MATSUNAGA SHIGEKI; SHIBASAKI MASAKATSU

  日本薬学会年会要旨集, 05 Mar. 2012

  
• 新規抗腫瘍薬の開発を志向したスピロイミダゾリン‐インドリノン骨格の構築

  KATO SHOTA; KITAHARA SEIKO; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集, 05 Mar. 2012

  
• 2‐Amino‐1,3,4‐thiadiazoleの直截的C‐H官能基化反応の開発

  KANEKO KEIICHI; KYO OKETSU; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集, 05 Mar. 2012

  
• イソインドリノン類を用いた直接的触媒的不斉Mannich型反応

  SUZUKI YUDAI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集, 05 Mar. 2012

  
• Lecture Tour upon Receiving the 7th Lectureship Award MBLA

  MATSUNAGA Shigeki

  J. Synth. Org. Chem. Jpn., 01 Mar. 2012

  
• Chimonanthine及び類縁体の触媒的不斉全合成

  三ツ沼治信; 柴崎正勝; 金井求; 松永茂樹

  次世代を担う有機化学シンポジウム講演要旨集, 2012

  
• 振動円二色性分光法の金属錯体触媒不斉合成反応への応用

  SATO HISAKO; MATSUNAGA SHIGEKI; KANAI MOTOMU; SHIBASAKI MASAKATSU; YAMAGISHI AKIHIKO

  錯体化学会討論会講演要旨集, 01 Sep. 2011

  
• Development of Dinuclear Schiff Base Catalysts Containing Rare Earth Metal and Their Applications to Organic Synthesis

  MATSUNAGA Shigeki

  希土類 = Rare earths, 20 May 2010

  
• 3-アミノオキシインドールの触媒的不斉合成

  毛利伸介; 陳志華; 古舘信; 三ツ沼治信; 松永茂樹; 柴崎正勝

  日本薬学会年会要旨集, 2010

  
• 複核シッフ塩基触媒を用いたニトロエチレンに対する触媒的不斉マイケル反応

  三ツ沼治信; 松永茂樹; 金井求; 柴崎正勝

  日本薬学会関東支部大会講演要旨集, 2010

  
• Development of asymmetric catalysis based on rare earth metals and their applications to biologically active compounds synthesis

  柴崎 正勝; 松永 茂樹

  化学工業, Oct. 2007

  
• Direct Catalytic Asymmetric Mannich-Type Reactions Using Rare Earth Metal Phenoxide-PyBox Complexes

  MORIMOTO Hiroyuki; LU Gang; AOYAMA Naohiro; MATSUNAGA Shigeki; SHIBASAKI Masakatsu

  希土類 = Rare earths, 10 May 2007

  
• Development of Atom-Efficient Catalytic Asymmetric Reactions Based on Proximity-Effect-Controlling Catalysis

  松永 茂樹

  化学と工業 = Chemistry and chemical industry, 01 Mar. 2007

  
• 多点認識概念に基づく触媒的不斉アルドール反応 : 原子効率100%をめざして(最前線,<特集>新しい発想の有機合成: グリーンケミストリーをめざして)

  松永 茂樹

  ファルマシア, 01 Jul. 2005

  
• Catalytic Asymmetric Conjugate Addition of O-Methylhydroxylamine to α, β-Unsaturated Ketones Using YL_3tris(binaphthoxide) (YLB) Complex

  YAMAGIWA Noriyuki; MATSUNAGA Shigeki; SHIBASAKI Masakatsu

  希土類 = Rare earths, 13 May 2004

  
• 不斉アルドール(有用触媒反応,<特集>実践的触媒反応)

  松永 茂樹

  ファルマシア, 01 Jul. 2003

  
• 実験中の火災と爆発(実験ガイド)

  大嶋 孝志; 松永 茂樹; 金井 求

  ファルマシア, 01 Aug. 2002

  

Presentations

• Synthesis of N-Fused Indole Core with the Unique Reactivity of Cp*Co(III) Catalyst

  IKEMOTO HIDEYA; YOSHINO TATSUHIKO; SAKATA KEN; MATSUNAGA SHIGEKI; KANAI MOTOMU

  Symp Organomet Chem Jpn, 08 Sep. 2014

  
• Cp^*Co(III)触媒の特性を活かしたN‐縮環型インドール骨格構築法の開発

  IKEMOTO HIDEYA; YOSHINO TATSUHIKO; SAKATA KEN; MATSUNAGA SHIGEKI; KANAI MOTOMU

  複素環化学討論会講演要旨集, 25 Aug. 2014

  
• Cp^*Co(III)触媒の特性を活かしたN‐縮環型インドール骨格構築法の開発

  IKEMOTO HIDEYA; YOSHINO TATSUHIKO; SAKATA KEN; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本プロセス化学会サマーシンポジウム講演要旨集, 01 Jul. 2014

  
• 含窒素複素環化合物の効率的な合成ルートの確立

  SHIRAI TAKAHIRO; KANEKO KEIICHI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2014

  
• Cp^*Co(III)触媒によるインドールのC‐Hアルケニル化反応および環化反応

  IKEMOTO HIDEYA; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2014

  
• スピロオキシインドールの触媒的不斉合成法の開発

  KITAHARA SEIKO; KATO MASAHIRO; KANAI MOTOMU; MATSUNAGA SHIGEKI

  日本薬学会関東支部大会講演要旨集, 15 Oct. 2013

  
• Dinuclear Schiff Base Complexes as Bifunctional Asymmetric Catalysts

  MATSUNAGA SHIGEKI

  錯体化学会討論会講演要旨集, 15 Oct. 2013

  
• Cp^*Co(III)触媒による芳香族C‐H結合の官能基化

  IKEMOTO HIDEYA; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会関東支部大会講演要旨集, 15 Oct. 2013

  
• Cationic Cp*Co(III) Catalyzed Aromatic C-H Bond Functionalization

  IKEMOTO HIDEYA; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  Symp Organomet Chem Jpn, 27 Aug. 2013

  
• 銅触媒によるアルケンの分子間アミノ‐アリール化反応を用いた一工程スルタム骨格構築法の開発

  KANEKO KEIICHI; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本プロセス化学会サマーシンポジウム講演要旨集, 21 Jun. 2013

  
• Cp^*Co(III)触媒によるインドールのC2選択的活性化およびイミンへの付加

  IKEMOTO HIDEYA; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本プロセス化学会サマーシンポジウム講演要旨集, 21 Jun. 2013

  
• カチオン性コバルト(III)触媒を用いた芳香族C‐H結合の直截的官能基化:極性求電子剤への付加反応

  YOSHINO TATSUHIKO; IKEMOTO HIDEYA; MATSUNAGA SHIGEKI; KANAI MOTOMU

  有機合成シンポジウム講演要旨集, 27 May 2013

  
• カチオン性コバルト(III)触媒による芳香族C‐H結合の極性求電子剤に対する付加反応

  YOSHINO TATSUHIKO; IKEMOTO HIDEYA; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本化学会講演予稿集, 08 Mar. 2013

  
• コバルト触媒によるキノリンの位置選択的アルキル化反応

  YAMAMOTO SHOHEI; SAGA YU; ANDO TAKASHI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2013

  
• アリルアルコール異性化を起点とする触媒的アルデヒド交差アルドール反応の開発とダブルアルドール反応への応用

  YAMAMOTO KUMIKO; RIN ROKUSEI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2013

  
• コバルト触媒を用いたC4選択的直截的ピリジン環アルキル化法の開発

  ANDO TAKASHI; SAGA YU; KOMAI HIROTOMO; YAMAMOTO SHOHEI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2013

  
• コバルト(III)触媒によるC‐H結合活性化とエノンへの付加

  IKEMOTO HIDEYA; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2013

  
• ヘテロ二核シッフ塩基錯体によるラセミ体アジリジンに対するRegiodivergent様式な開環反応の開発

  KYO OKETSU; KANAI MOTOMU; MATSUNAGA SHIGEKI

  日本薬学会年会要旨集(CD-ROM), 2013

  
• スピロオキシインドールの触媒的不斉合成法の開発(1)

  KATO SHOTA; KITAHARA SEIKO; YOSHINO TATSUHIKO; KANAI MOTOMU; MATSUNAGA SHIGEKI

  日本薬学会年会要旨集(CD-ROM), 2013

  
• カチオン性コバルト(III)触媒による芳香族C‐H結合のイミンに対する付加反応

  YOSHINO TATSUHIKO; IKEMOTO HIDEYA; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2013

  
• 銅触媒による6員環スルタムの合成

  KANEKO KEIICHI; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2013

  
• アルキルアザアレーンの直截的触媒的ベンジル位C(sp3)‐H結合官能基化反応;不活性アルケンへの付加

  KOMAI HIROTOMO; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  日本薬学会年会要旨集(CD-ROM), 2013

  
• 新規抗腫瘍薬の開発を志向したスピロイミダゾリン‐インドリノン骨格の構築

  KATO MASAHIRO; KITAHARA SEIKO; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  有機合成シンポジウム講演要旨集, 30 Oct. 2012

  
• コバルト触媒を用いた直截的複素環アルキル化法の開発

  ANDO TAKASHI; SAGA YU; KOMAI HIROTOMO; YAMAMOTO SHOHEI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  反応と合成の進歩シンポジウム講演要旨集, 15 Oct. 2012

  
• ロジウム触媒によるアリルアルコールの異性化を利用した交差アルドール型反応の開発とダブルアルドール反応への応用

  YAMAMOTO KUMIKO; RIN ROKUSEI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  反応と合成の進歩シンポジウム講演要旨集, 15 Oct. 2012

  
• コバルト(III)触媒を用いたC‐H結合官能基化反応の開発研究

  YOSHINO TATSUHIKO; IKEMOTO HIDEYA; MATSUNAGA SHIGEKI; KANAI MOTOMU

  反応と合成の進歩シンポジウム講演要旨集, 15 Oct. 2012

  
• ヘテロ二核シッフ塩基錯体によるマロン酸エステルを求核剤としたアジリジンに対する触媒的不斉開環反応の開発

  XU YINGJIE; SHIBASAKI MASAKATSU; KANAI MOTOMU; MATSUNAGA SHIGEKI

  複素環化学討論会講演要旨集, 30 Sep. 2012

  
• ロジウム触媒によるアリルアルコールの異性化を利用した交差アルドール反応の開発とダブルアルドール反応への応用

  YAMAMOTO KUMIKO; HAYASHI TOSHIKIYO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  有機合成化学セミナー講演予稿集, 05 Sep. 2012

  
• イソインドリノン類のベンジル位活性化によるイミンへの触媒的不斉付加反応

  SUZUKI YUDAI; MATSUNAGA SHIGEKI; KANAI MOTOMU

  シンポジウム「モレキュラー・キラリティー」講演要旨集, 17 May 2012

  
• 新規抗腫瘍薬の開発を志向したスピロイミダゾリン‐インドリノン骨格の構築

  KATO SHOTA; KITAHARA SEIKO; YOSHINO TATSUHIKO; MATSUNAGA SHIGEKI; KANAI MOTOMU

  シンポジウム「モレキュラー・キラリティー」講演要旨集, 17 May 2012

  
• Chimonanthine及び類縁体の触媒的不斉全合成

  MITSUNUMA HARUNOBU; SHIBASAKI MASAKATSU; KANAI MOTOMU; MATSUNAGA SHIGEKI

  次世代を担う有機化学シンポジウム講演要旨集, 11 May 2012

  

Awards

• 03 Feb. 2023

  井上学術賞（井上科学振興財団）
• 17 Sep. 2020

  Mukaiyama Award 2020（有機合成化学協会）
• 22 Feb. 2019

  北海道大学教育研究総長表彰
• 04 Nov. 2018

  Asian Core Program Lectureship Award (Singapore)
• 04 Nov. 2018

  Asian Core Program Lectureship Award (China)
• 05 Mar. 2018

  ACT-C根岸賞（先導的物質変換領域（JST,ACT-C））
• 31 Jan. 2017

  北海道大学研究奨励総長表彰
• 07 Jul. 2016

  トムソン・ロイターリサーチフロントアウォード2016
• 05 Nov. 2015

  Asian Core Program Lectureship Award (Thailand)
• 05 Nov. 2015

  Asian Core Program Lectureship Award (Korea)
• 19 Aug. 2013

  Asian Rising Stars (15th Asian Chemical Congress)（アジア化学連合）
• 21 May 2011

  Merck-Banyu Lectureship Award (MBLA 2010)（MSD生命科学財団）
• 04 Feb. 2010

  井上リサーチアウォード（井上科学振興財団）
• 07 Jan. 2010

  Chem. Commun. Emerging Investigator選出（イギリス化学会）
• 01 Dec. 2009

  Banyu Chemist Award 2009（MSD生命科学財団）
• 11 Mar. 2009

  Mitsui Chemicals Catalysis Science Award of Encouragement（三井化学）
• 26 Mar. 2007

  日本化学会進歩賞（日本化学会）

External funds: Kakenhi

• Asymmetric Remote C~H Functionalization based on Synergy of Two Metals under Chiral Dinuclear Catalysis

  Grant-in-Aid for Scientific Research (A)

  Medium-sized Section 33:Organic chemistry and related fields

  Kyoto University

  松永 茂樹

  From 01 Apr. 2023, To 31 Mar. 2027, Granted

  不斉触媒;不斉合成;C-H活性化;アミノ化;金属触媒

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23H00293/
• Upgrading Chiral Dinuclear Ru Catalysts for Surpassing Chiral Paddlewheel Dinuclear Rh Catalysts

  Grant-in-Aid for Challenging Research (Exploratory)

  Medium-sized Section 33:Organic chemistry and related fields

  Hokkaido University

  松永 茂樹

  From 09 Jul. 2021, To 31 Mar. 2024, Granted

  不斉触媒;不斉合成;ルテニウム;アミノ化;ルイス酸;C-Hアミノ化;反応場

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K18946/
• Fine Tuning of Group 9 Metal-Chiral Acid Hybrid Catalysts Towards Deepening and Extension of Asymmetric C-H Functionalization

  Grant-in-Aid for Scientific Research (B)

  Basic Section 33020:Synthetic organic chemistry-related

  Hokkaido University

  松永 茂樹

  From 01 Apr. 2020, To 31 Mar. 2023, Granted

  不斉合成;不斉触媒;C-H官能基化;遷移金属触媒;キラル酸;キラル塩基

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20H02730/
• Development of Hypervalent Iodine Transfer and Rapid Halogen Labelling for Theranostics

  Grant-in-Aid for Challenging Research (Exploratory)

  Medium-sized Section 33:Organic chemistry and related fields

  Hokkaido University

  Shigeki Matsunaga

  From 28 Jun. 2019, To 31 Mar. 2022, Project Closed

  超原子価ヨウ素;アスタチン;セラノスティクス;イプソ位置換;放射標識;固相反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K22177/
• Development of Novel Chiral Dinuclear Complexes for Catalytic Asymmetric C-H Bond Functionalization

  Grant-in-Aid for Scientific Research (B)

  Hokkaido University

  Shigeki Matsunaga

  From 01 Apr. 2017, To 31 Mar. 2020, Project Closed

  不斉触媒;不斉合成;C-H活性化;パラジウム;シッフ塩基;複核触媒;不斉配位子

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H03049/
• Asymmetric C-H bond allylation of aziridines based on chiral ion strategy and its application to natural product synthesis

  Grant-in-Aid for JSPS Fellows

  Hokkaido University

  松永 茂樹

  From 07 Nov. 2016, To 31 Mar. 2019, Project Closed

  不斉触媒;不斉合成;医薬合成;分子活性化;ロジウム;コバルト;炭素－水素結合活性化;不活性分子活性化;カルボン酸;炭素-水素結合活性化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16F16409/
• Generation of metal-carbene species without using diazo-comoounds and its synthetic application

  Grant-in-Aid for Challenging Exploratory Research

  Hokkaido University

  Shigeki MATSUNAGA

  From 01 Apr. 2015, To 31 Mar. 2018, Project Closed

  遷移金属触媒;遷移金属カルベン;直接変換;シクロプロパン;コバルト;ルテニウム;シクロプロパン化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K13686/
• Design of Catalytically Active Sites for Multi-Centers Control and Their Application to Organic Transformation

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Hokkaido University

  Shigeki Matsunaga

  From 29 Jun. 2015, To 31 Mar. 2020, Project Closed

  精密制御触媒;不斉合成;不斉触媒;触媒活性点;炭素-水素結合活性化;C-H官能基化;遷移金属触媒;キラル酸;C-H活性化;触媒;多核触媒;協奏触媒

  https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-15H05802/
• Asymmetric C-H Bond Functionalization with Heterodinuclear Asymmetric Catalysts

  Grant-in-Aid for Scientific Research (B)

  Hokkaido University;The University of Tokyo

  Shigeki MATSUNAGA

  From 01 Apr. 2014, To 31 Mar. 2018, Project Closed

  C-H活性化;触媒;不斉触媒;脱水素;立体制御;複素環;有機金属;生物活性化合物

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26288043/
• 求核的活性種の触媒的発生法の開発と直截分子変換への応用

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  The University of Tokyo

  松永 茂樹

  From 01 Apr. 2013, To 31 Mar. 2015, Project Closed

  有機金属;触媒;不活性結合活性化;求核剤;有機合成

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-25105712/
• Innovative Molecular Transformation and Drug Lead Development Based on Fine Design of Multinuclear Catalysis

  Grant-in-Aid for Young Scientists (A)

  The University of Tokyo

  Shigeki MATSUNAGA

  From 01 Apr. 2011, To 31 Mar. 2015, Project Closed

  触媒;医薬合成;不斉触媒;不斉合成;キラル化合物;シッフ塩基;複素環;アミノ酸;協同機能触媒;医薬リード;複核金属触媒;天然物合成;複核錯体

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23689002/
• 歪みを内包する複核遷移金属フェノキシド錯体の設計と炭素―水素結合直截変換

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  The University of Tokyo

  松永 茂樹

  From 01 Apr. 2011, To 31 Mar. 2013, Project Closed

  触媒;分子活性化;C-H官能基化;均一系触媒;炭素－炭素結合形成;有機金属触媒;直截変換;シッフ塩基;有機合成反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-23105509/
• Studies on the Transition Metal-Rare Earth Metal/Dinuclear Schiff Base Catalysts, Mechanistic Studies and Application to New Asymmetric Reactions

  Grant-in-Aid for Young Scientists (A)

  The University of Tokyo

  Shigeki MATSUNAGA

  From 01 Apr. 2008, To 31 Mar. 2011, Project Closed

  触媒;不斉合成;不斉触媒;サレン;非天然アミノ酸;医薬品合成;希土類触媒;シッフ塩基;複核錯体

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20685008/
• Innovative Asymmetris Synthesis of Pharmaceuticals Through Strategic Development of Multifunctional and Multimetallic Catalysts

  Grant-in-Aid for Scientific Research (S)

  Microbial Chemistry Research Foundation;The University of Tokyo

  Masakatsu SHIBASAKI

  From 01 Apr. 2008, To 31 Mar. 2013, Project Closed

  不斉触媒;不斉合成;原子効率;医薬合成;環境調和型合成;協奏機能型触媒;不斉反応;C-C結合;プロトン移動型反応;医薬品合成;金属触媒;多核錯体;集積錯体;触媒的不斉反応;不斉4置換炭素構築;環境調和

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20229001/
• 希土類-アルカリ金属アート型複核金属不斉触媒の新展開

  Grant-in-Aid for Scientific Research on Priority Areas

  Science and Engineering

  The University of Tokyo

  松永 茂樹

  From 01 Apr. 2008, To 31 Mar. 2010, Project Closed

  希土類金属;不斉触媒;不斉合成;協奏機能;アート錯体

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20037010/
• 高活性化エステル等価体の精密設計に基づく触媒的不斉炭素-炭素結合形成反応の開発

  Grant-in-Aid for Young Scientists (B)

  The University of Tokyo

  松永 茂樹

  From 01 Apr. 2005, To 31 Mar. 2007, Project Closed

  不斉触媒;不斉合成;活性エステル;イミン;医薬化学;マンニッヒ反応;ピロール

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17790009/
• Innovational Asymmetric Catalysis縲廾ptimization and New Development

  Grant-in-Aid for Specially Promoted Research

  Science and Engineering

  The University of Tokyo

  Masakatsu SHIBASAKI

  From 01 Apr. 2003, To 31 Mar. 2008, Project Closed

  不斉触媒;不斉四置換炭素;抗インフルエンザ薬;多点認識不斉触媒;医薬合成;Mannich反応;抗糖尿病薬;Strecker反応;不斉合成;医薬品合成;多点制御;4置換炭素;希土類;多段階反応;アルドール反応;段階反応, asymmetric catalyst;chral tetrasubstituted carbon;anti-influenza drug;bifunctional asymmetric catalyst;pharmaceutical synthesis;Mannich reaction;anti-diabetic agent;Strecker reaction

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15002003/
• 触媒的不斉ニトロマンニッヒ型反応の開発と高立体選択的な医薬合成への展開

  Grant-in-Aid for Young Scientists (B)

  The University of Tokyo

  松永 茂樹

  From 01 Apr. 2002, To 31 Mar. 2005, Project Closed

  不斉触媒;不斉合成;イミン;マンニッヒ反応;亜鉛触媒;ビナフトール;医薬合成;ニトロアルカン

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-14771240/
• Creation of Asymmetric Catalysts Based on New Concept, and Their Application to Efficient Synthesis of Pharmaceutical Lead Compounds

  Grant-in-Aid for Scientific Research (A)

  The University of Tokyo

  Motomu KANAI

  From 01 Apr. 2001, To 31 Mar. 2004, Project Closed

  不斉触媒;多点認識;医薬リード;不斉合成;生物活性天然物;不斉シアノシリル化;不斉アルドール反応;不斉Mannich型反応;フッ化銅;アルドール反応;シアノアルキル化反応;直接的触媒的アルドール反応;触媒的不斉反応;触媒的不斉Strecker反応;ジ置換アミノ酸;多点制御;ルイス酸;ブレンステツド塩基;ルイス塩基;触媒的不斉全合成;多段階促進型不斉触媒;医薬品リード化合物;固相担持触媒;4級不斉中心, asymmetric catalyst;bifunctional catalysis;pharmaceutical lead;asymmetric synthesis;biologically active natural products;asymmetric cyanosil lation;asymmetric aldol reaction;asymmetric Mannich reaction

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13307062/
• Asymmetric Alkane C-H Oxidation via Hypervalent Iodine and Chiral Strong Acid Combination

  Grant-in-Aid for Challenging Research (Exploratory)

  Medium-sized Section 33:Organic chemistry and related fields

  Kyoto University

  松永 茂樹

  From 30 Jun. 2023, To 31 Mar. 2025, Granted

  酸化;不斉合成;超原子価ヨウ素;C-H官能基化;キラル酸

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23K17909/
• Stereochemical Re-Programming via C-H Cleavage and Stereo-Controlled Functionalization

  Grant-in-Aid for Transformative Research Areas (A)

  Transformative Research Areas, Section (II)

  Kyoto University

  松永 茂樹

  From 01 Apr. 2024, To 31 Mar. 2029, Granted

  化学構造リプログラミング;C-H活性化;立体制御;立体化学編集;キラル触媒

  https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-24H02209/

Education

Teaching subject(s)

• From 01 Apr. 2024, To 31 Mar. 2025

  Basic Organic Chemistry II

  N348, Fall, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Advanced Organic Chemistry IIIA

  7188, Spring, Graduate School of Science, 1
• From 01 Apr. 2024, To 31 Mar. 2025

  Seminar on Organic Chemistry IIID

  7087, Fall, Graduate School of Science, 1
• From 01 Apr. 2024, To 31 Mar. 2025

  Seminar on Organic Chemistry IIIC

  7086, Spring, Graduate School of Science, 1
• From 01 Apr. 2024, To 31 Mar. 2025

  Advanced Organic Chemistry IIID

  7191, Fall, Graduate School of Science, 1
• From 01 Apr. 2024, To 31 Mar. 2025

  Advanced Organic Chemistry IIIC

  7190, Spring, Graduate School of Science, 1
• From 01 Apr. 2024, To 31 Mar. 2025

  Advanced Organic Chemistry IIIB

  7189, Fall, Graduate School of Science, 1
• From 01 Apr. 2024, To 31 Mar. 2025

  Seminar on Organic Chemistry IIIB

  7085, Fall, Graduate School of Science, 1
• From 01 Apr. 2024, To 31 Mar. 2025

  Seminar on Organic Chemistry IIIA

  7084, Spring, Graduate School of Science, 1
• From 01 Apr. 2024, To 31 Mar. 2025

  Special study course II (Chemistry) 15

  5642, Year-long, Faculty of Science, 12
• From 01 Apr. 2024, To 31 Mar. 2025

  Chemistry of Assembled Organic Compounds

  7027, Spring, Graduate School of Science, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Organic Chemistry II

  3614, Spring, Faculty of Science, 4
• From 01 Apr. 2023, To 31 Mar. 2024

  Advanced Organic Chemistry IIIC

  7190, Spring, Graduate School of Science, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Advanced Organic Chemistry IIIB

  7189, Fall, Graduate School of Science, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Advanced Organic Chemistry IIIA

  7188, Spring, Graduate School of Science, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Advanced Organic Chemistry IIID

  7191, Fall, Graduate School of Science, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Seminar on Organic Chemistry IIID

  7087, Fall, Graduate School of Science, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Seminar on Organic Chemistry IIIC

  7086, Spring, Graduate School of Science, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Seminar on Organic Chemistry IIIB

  7085, Fall, Graduate School of Science, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Seminar on Organic Chemistry IIIA

  7084, Spring, Graduate School of Science, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Special study course II (Chemistry) 15

  5642, Year-long, Faculty of Science, 12
• From 01 Apr. 2023, To 31 Mar. 2024

  Chemistry of Assembled Organic Compounds

  7027, Spring, Graduate School of Science, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Organic Chemistry II

  3614, Spring, Faculty of Science, 4

Participation in PhD Defense

• Synthesis of Organoboron Compounds via Reductive Carbon-Carbon Bond Cleavage by Means of Electron Injection

  FUKAZAWA MIZUKI, Graduate School of Science, Sub-chief Examiner

  25 Mar. 2024
• Development of Saddle- or Helical-distorted Nitrogen-doped Nanographenes via Oxidative Fusion Reactions

  MATSUO YUSUKE, Graduate School of Science, Sub-chief Examiner

  25 Mar. 2024
• Studies on Photoresponsive Properties of Flapping Molecules in Condensed Systems

  KIMURA RYO, Graduate School of Science, Sub-chief Examiner

  25 Mar. 2024
• Development of the Cross-Coupling Reactions Using α-Bromocarbonyl Compounds

  TAKESHIMA AIKA, Graduate School of Science, Sub-chief Examiner

  25 Mar. 2024
• Development of Efficient Methods for the Synthesis of Organosulfur (IV) Compounds

  TSUZUKI SAORI, Graduate School of Science, Sub-chief Examiner

  25 Mar. 2024

Administration

School management (title, position)

• From 01 Apr. 2024, To 31 Mar. 2025

  国際高等教育院 企画評価専門委員会 化学部会
• From 01 Apr. 2023, To 31 Mar. 2024

  国際高等教育院 企画評価専門委員会 化学部会 委員

Faculty management (title, position)

• From 01 Apr. 2024, To 31 Mar. 2025

  理学部・教育委員会委員
• From 01 Apr. 2024, To 31 Mar. 2025

  理学部・教育委員会　全学共通教育委員会委員
• From 01 Apr. 2024, To 31 Mar. 2025

  理学研究科将来計画委員会委員