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Ohmiya, Hirohisa

Institute for Chemical Research (ICR) Professor

Ohmiya, Hirohisa
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    Last Updated :2022/11/23

    Basic Information

    Affiliated programs (koza)

    • Graduate School of Pharmaceutical Sciences, 薬科学専攻 精密有機合成化学講座, 教授

    Professional Memberships

    • THE PHARMACEUTICAL SOCIETY OF JAPAN
    • KINKI CHEMICAL SOCIETY, JAPAN
    • THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN
    • THE CHEMICAL SOCIETY OF JAPAN

    Academic Degree

    • 13 Mar. 2004
      京都薬科大学修士(薬学)
    • 23 Mar. 2007
      京都大学博士(工学)

    Academic Resume (Graduate Schools)

    • 京都大学, 大学院工学研究科博士後期課程材料化学専攻, 修了
    • 京都薬科大学, 大学院薬学研究科修士課程薬学専攻, 修了

    Academic Resume (Undergraduate School/Majors)

    • 京都薬科大学, 薬学部薬学科, 卒業

    High School

    • High School

      Takatsuki Senior High School

    Research History

    • From Apr. 2022, To Present
      Kyoto University, Institute for Chemical Research, Professor
    • From Apr. 2022, To Present
      Kanazawa University, 医薬保健研究域 薬学系, 客員教授
    • From Oct. 2019, To Present
      Japan Science and Technology Agency, さきがけ研究員(兼任)
    • From Apr. 2017, To Mar. 2022
      Kanazawa University, 医薬保健研究域 薬学系, 教授
    • From Dec. 2010, To Mar. 2017
      Hokkaido University, 大学院理学研究院 化学部門, 准教授
    • From Apr. 2008, To Dec. 2010
      Hokkaido University, 大学院理学研究院 化学部門, 助教
    • From Apr. 2007, To Mar. 2008
      Kyoto University, 大学院工学研究科 材料化学専攻, 博士研究員

    ID,URL

    researchmap URL

    list
      Last Updated :2022/11/23

      Research

      Research Interests

      • 有機合成化学

      Research Areas

      • Nanotechnology/Materials, Synthetic organic chemistry
      • Life sciences, Bioorganic chemistry

      Papers

      • Direct photoexcitable iodomethylborate enabling cyclopropanation of reactive alkenes
        Rikako Nakamura; Yuto Sumida; Hirohisa Ohmiya
        Bulletin of the Chemical Society of Japan, 27 May 2022
      • Carbocation Generation by Organophotoredox Catalysis
        Kazunori Nagao; Hirohisa Ohmiya
        Journal of Synthetic Organic Chemistry, Japan, 01 Nov. 2021
      • A Triple Photoredox/Cobalt/Brønsted Acid Catalysis Enabling Markovnikov Hydroalkoxylation of Unactivated Alkenes
        Masanari Nakagawa; Yuki Matsuki; Kazunori Nagao; Hirohisa Ohmiya
        Journal of the American Chemical Society, 27 Apr. 2022
      • Reductive Cross‐Coupling between Arylaldehydes and (Hetero)aryl Electrophiles Using Silylboronate Reductant
        Koh Watanabe; Mitsutaka Takeda; Kazunori Nagao; Hirohisa Ohmiya
        European Journal of Organic Chemistry, 24 Feb. 2022
      • Direct Photoexcitation of Borate Enabling Minisci Reaction
        Marin Kemmochi; Yusuke Miyamoto; Yuto Sumida; Hirohisa Ohmiya
        Asian Journal of Organic Chemistry, Jan. 2022
      • Aryl radical-mediated N-heterocyclic carbene catalysis
        Yuki Matsuki; Nagisa Ohnishi; Yuki Kakeno; Shunsuke Takemoto; Takuya Ishii; Kazunori Nagao; Hirohisa Ohmiya
        Nature Communications, Dec. 2021
      • Light-Driven N-Heterocyclic Carbene Catalysis Using Alkylborates
        Yukiya Sato; Yamato Goto; Kei Nakamura; Yusuke Miyamoto; Yuto Sumida; Hirohisa Ohmiya
        ACS Catalysis, 05 Nov. 2021
      • Radical Relay Trichloromethylacylation of Alkenes through N-Heterocyclic Carbene Catalysis
        Mayu Kusakabe; Kazunori Nagao; Hirohisa Ohmiya
        Organic Letters, 17 Sep. 2021
      • Organophotoredox‐Catalyzed Decarboxylative N‐Alkylation of Sulfonamides
        Masanari Nakagawa; Kazunori Nagao; Zenichi Ikeda; Matthew Reynolds; Ignacio Ibáñez; Junsi Wang; Norihito Tokunaga; Yusuke Sasaki; Hirohisa Ohmiya
        ChemCatChem, 17 Sep. 2021
      • Molecular Field Analysis Using Computational-Screening Data in Asymmetric N-Heterocyclic Carbene-Copper Catalysis toward Data-driven in silico Catalyst Optimization
        Masakiyo Mukai; Kazunori Nagao; Shigeru Yamaguchi; Hirohisa Ohmiya
        04 Aug. 2021
      • Generation of Functionalized Alkyl Radicals via the Direct Photoexcitation of 2,2′-(Pyridine-2,6-diyl)diphenol-Based Borates
        Yusuke Miyamoto; Yuto Sumida; Hirohisa Ohmiya
        Organic Letters, 08 Jul. 2021
      • Radical N-heterocyclic carbene catalysis for β-ketocarbonyl synthesis
        Takuya Ishii; Kazunori Nagao; Hirohisa Ohmiya
        Tetrahedron, Jul. 2021
      • Decarboxylative N-Alkylation of Azoles through Visible-Light-Mediated Organophotoredox Catalysis
        Rino Kobayashi; Shotaro Shibutani; Kazunori Nagao; Zenichi Ikeda; Junsi Wang; Ignacio Ibáñez; Matthew Reynolds; Yusuke Sasaki; Hirohisa Ohmiya
        Organic Letters, 17 Jun. 2021
      • Synthesis of Sterically Hindered α-Hydroxycarbonyls through Radical–Radical Coupling
        Kenji Ota; Kazunori Nagao; Hirohisa Ohmiya
        Organic Letters, 04 Jun. 2021
      • Fluorescent-Oxaboroles: Synthesis and Optical Property by Sugar Recognition
        Misaki Nakano; Rikako Nakamura; Yuto Sumida; Kazunori Nagao; Taniyuki Furuyama; Fuyuhiko Inagaki; Hirohisa Ohmiya
        Chemical and Pharmaceutical Bulletin, 01 Jun. 2021
      • Catalytic Reductive Cross‐Coupling between Aromatic Aldehydes and Arylnitriles
        Atsuhisa Mitsui; Kazunori Nagao; Hirohisa Ohmiya
        Chemistry – A European Journal, 26 Apr. 2021
      • Organophotoredox-Catalyzed Three-Component Coupling of Heteroatom Nucleophiles, Alkenes, and Aliphatic Redox Active Esters
        Shotaro Shibutani; Kazunori Nagao; Hirohisa Ohmiya
        Organic Letters, 05 Mar. 2021
      • Copper-Catalyzed Reactions of Alkylboranes
        Hirohisa Ohmiya; Masaya Sawamura
        Bulletin of the Chemical Society of Japan, 15 Jan. 2021
      • Direct excitation strategy for radical generation in organic synthesis
        Yuto Sumida; Hirohisa Ohmiya
        Chemical Society Reviews, 2021
      • Transition‐Metal‐Free Cross‐Coupling by Using Tertiary Benzylic Organoboronates
        Mitsutaka Takeda; Kazunori Nagao; Hirohisa Ohmiya
        Angewandte Chemie International Edition, 13 Oct. 2020
      • Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis
        Yuki Kakeno; Mayu Kusakabe; Kazunori Nagao; Hirohisa Ohmiya
        ACS Catalysis, 21 Jul. 2020, Peer-reviewed
      • N-Heterocyclic Carbene-Based Catalysis Enabling Cross-Coupling Reactions
        Hirohisa Ohmiya
        ACS Catalysis, 19 Jun. 2020, Peer-reviewed
      • Generation of Alkyl Radical through Direct Excitation of Boracene-Based Alkylborate
        Yukiya Sato; Kei Nakamura; Yuto Sumida; Daisuke Hashizume; Takamitsu Hosoya; Hirohisa Ohmiya
        Journal of the American Chemical Society, 03 Jun. 2020, Peer-reviewed
      • N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls
        Kenji Ota; Kazunori Nagao; Hirohisa Ohmiya
        Organic Letters, 15 May 2020, Peer-reviewed
      • Allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions
        Akihiro Yuasa; Kazunori Nagao; Hirohisa Ohmiya
        Beilstein Journal of Organic Chemistry, 07 Feb. 2020, Peer-reviewed
      • Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines
        Atsuhisa Mitsui; Kazunori Nagao; Hirohisa Ohmiya
        Organic Letters, 07 Feb. 2020, Peer-reviewed
      • Organophotoredox-Catalyzed Decarboxylative C(sp3)–O Bond Formation
        Shotaro Shibutani; Taiga Kodo; Mitsutaka Takeda; Kazunori Nagao; Norihito Tokunaga; Yusuke Sasaki; Hirohisa Ohmiya
        Journal of the American Chemical Society, 22 Jan. 2020, Peer-reviewed
      • 5 anti Boron Addition to Alkynes
        M. Sawamura; H. Ohmiya
        Advances in Organoboron Chemistry towards Organic Synthesis, 2020
      • Boracene-Based Alkylborate Enabling Ni/Ir Hybrid Catalysis
        Yukiya Sato; Yusuke Miyamoto; Yuto Sumida; Takamitsu Hosoya; Hirohisa Ohmiya
        Organic & Biomolecular Chemistry, 2020, Peer-reviewed
      • Reductive umpolung for asymmetric synthesis of chiral α-allenic alcohols
        Yui Kondo; Kazunori Nagao; Hirohisa Ohmiya
        Chemical Communications, 2020, Peer-reviewed
      • Recent advances in N-heterocyclic carbene-based radical catalysis
        Takuya Ishii; Kazunori Nagao; Hirohisa Ohmiya
        Chemical Science, 2020, Peer-reviewed
      • Aliphatic Oxaboroles Enabling Remarkable Recognition of Diols
        Arakawa N; Nagao K; Murakami R; Sumida Y; Arakawa H; Inagaki F; Ohmiya H
        Bulletin of the Chemical Society of Japan, 2020, Peer-reviewed
      • N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis
        Kazunori Nagao; Hirohisa Ohmiya
        Topics in Current Chemistry, Dec. 2019, Peer-reviewed
      • N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes
        Takuya Ishii; Kenji Ota; Kazunori Nagao; Hirohisa Ohmiya
        Journal of the American Chemical Society, Sep. 2019, Peer-reviewed
      • Synergistic N‐Heterocyclic Carbene/Palladium‐Catalyzed Aldehyde Acylation of Allylic Amines
        Nagisa Ohnishi; Shigeo Yasuda; Kazunori Nagao; Hirohisa Ohmiya
        Asian Journal of Organic Chemistry, Jul. 2019, Peer-reviewed
      • Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand
        Koji Imai; Yurie Takayama; Hiroaki Murayama; Hirohisa Ohmiya; Yohei Shimizu; Masaya Sawamura
        Organic Letters, Mar. 2019, Peer-reviewed
      • N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes
        Takuya Ishii; Yuki Kakeno; Kazunori Nagao; Hirohisa Ohmiya
        Journal of the American Chemical Society, Mar. 2019, Peer-reviewed
      • Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis
        Mitsutaka Takeda; Atsuhisa Mitsui; Kazunori Nagao; Hirohisa Ohmiya
        Journal of the American Chemical Society, Jan. 2019, Peer-reviewed
      • Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis
        Hiroki Haruki; Shigeo Yasuda; Kazunori Nagao; Hirohisa Ohmiya
        Chemistry - A European Journal, Jan. 2019, Peer-reviewed
      • Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions
        Kenya Yabushita; Akihiro Yuasa; Kazunori Nagao; Hirohisa Ohmiya
        Journal of the American Chemical Society, Jan. 2019, Peer-reviewed
      • Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis
        Hiroki Haruki; Shigeo Yasuda; Kazunori Nagao; Hirohisa Ohmiya
        Chemistry - A European Journal, Jan. 2019, Peer-reviewed
      • Front Cover: Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis (Chem. Eur. J. 3/2019)
        Hiroki Haruki; Shigeo Yasuda; Kazunori Nagao; Hirohisa Ohmiya
        Chemistry - A European Journal, Jan. 2019, Peer-reviewed
      • Copper-Catalyzed Enantioselective Coupling between Allyl-boronates and Phosphates Using a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes
        Yuto Yasuda; Hirohisa Ohmiya; Masaya Sawamura
        Synthesis (Germany), 01 Jun. 2018, Peer-reviewed
      • Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates
        Shigeo Yasuda; Takuya Ishii; Shunsuke Takemoto; Hiroki Haruki; Hirohisa Ohmiya
        Angewandte Chemie - International Edition, 05 Mar. 2018, Peer-reviewed
      • Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates
        Shigeo Yasuda; Takuya Ishii; Shunsuke Takemoto; Hiroki Haruki; Hirohisa Ohmiya
        Angewandte Chemie, Mar. 2018, Peer-reviewed
      • Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of α-ketoesters with terminal alkynes: OH⋯O/sp3-CH⋯O two-point hydrogen bonding combined with dispersive attractions
        Martin C. Schwarzer; Akane Fujioka; Takaoki Ishii; Hirohisa Ohmiya; Seiji Mori; Masaya Sawamura
        Chemical Science, 2018, Peer-reviewed
      • Phosphine-Catalyzed Anti -Hydroboration of Internal Alkynes
        Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
        Organic Letters, 2018, Peer-reviewed
      • Synergistic palladium/copper-catalyzed Csp3-Csp2 cross-couplings using aldehydes as latent α-alkoxyalkyl anion equivalents
        Mitsutaka Takeda; Kenya Yabushita; Shigeo Yasuda; Hirohisa Ohmiya
        Chemical Communications, 2018, Peer-reviewed
      • Phosphine-Catalyzed anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multisubstituted γ-Borylallylboranes
        Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
        Angewandte Chemie - International Edition, 2018, Peer-reviewed
      • Phosphine-Catalyzed anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multisubstituted γ-Borylallylboranes
        Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
        Angewandte Chemie - International Edition, 2018, Peer-reviewed
      • Copper-catalyzed enantioselective intramolecular alkylboron allylic alkylation
        Kentaro Hojoh; Yoshinori Shido; Hirohisa Ohmiya; Masaya Sawamura
        Chemistry Letters, 2018, Peer-reviewed
      • Asymmetric Synthesis of beta-Lactams through Copper-Catalyzed Alkyne-Nitrone Coupling with a Prolinol-Phosphine Chiral Ligand
        Yurie Takayama; Takaoki Ishii; Hirohisa Ohmiya; Tomohiro Iwai; Martin C. Schwarzer; Seiji Mori; Tohru Taniguchi; Kenji Monde; Masaya Sawamura
        CHEMISTRY-A EUROPEAN JOURNAL, Jun. 2017, Peer-reviewed
      • Synthesis of alpha-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides
        Kentaro Hojoh; Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2017, Peer-reviewed
      • Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand
        Yuto Yasuda; Hirohisa Ohmiya; Masaya Sawamura
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Aug. 2016, Peer-reviewed
      • Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles
        Hirohisa Ohmiya; Heng Zhang; Saori Shibata; Ayumi Harada; Masaya Sawamura
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Apr. 2016, Peer-reviewed
      • Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates
        Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
        Organic Letters, 2016, Peer-reviewed
      • Copper-catalyzed semihydrogenation of internal alkynes with molecular hydrogen
        Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
        Organometallics, 2016, Peer-reviewed
      • Silica-Supported Triptycene-Type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki-Miyaura Cross-Coupling of Chloroarenes
        Tomohiro Iwai; Shota Konishi; Tatsuya Miyazaki; Soichiro Kawamorita; Natsumi Yokokawa; Hirohisa Ohmiya; Masaya Sawamura
        ACS CATALYSIS, Dec. 2015, Peer-reviewed
      • Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron
        Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.
        Angewandte Chemie - International Edition, 2015, Peer-reviewed
      • Copper-catalyzed stereoselective conjugate addition of alkylboranes to alkynoates
        Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
        Beilstein Journal of Organic Chemistry, 2015, Peer-reviewed
      • Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes
        Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M.
        Chemistry - A European Journal, 2015, Peer-reviewed
      • Copper-catalyzed enantioselective allylic cross-coupling with alkylboranes
        Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.
        Tetrahedron, 2015, Peer-reviewed
      • Copper(I)-catalyzed intramolecular hydroalkoxylation of unactivated alkenes
        Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
        Organic Letters, 2015, Peer-reviewed
      • Anti-selective vicinal silaboration and diboration of alkynoates through phosphine organocatalysis
        Nagao, K.; Ohmiya, H.; Sawamura, M.
        Organic Letters, 2015, Peer-reviewed
      • Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes
        Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Nov. 2014, Peer-reviewed
      • Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles
        Ayumi Harada; Yusuke Makida; Tatsunori Sato; Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Oct. 2014, Peer-reviewed
      • Construction of Quaternary Stereogenic Carbon Centers through Copper- Catalyzed Enantioselective Allylic Cross- Coupling with Alkylboranes**
        Kentaro Hojoh; Yoshinori Shido; Hirohisa Ohmiya; Masaya Sawamura
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, May 2014, Peer-reviewed
      • Phosphine-catalyzed anti-carboboration of alkynoates with alkyl-, alkenyl-, and arylboranes
        Nagao, K.; Ohmiya, H.; Sawamura, M.
        Journal of the American Chemical Society, 2014, Peer-reviewed
      • Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling of Alkylboranes, Alkynoates, and Tributyltin Methoxide
        Takamichi Wakamatsu; Kazunori Nagao; Hirohisa Ohmiya; Masaya Sawamura
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Oct. 2013, Peer-reviewed
      • Cooperative Catalysis of Metal and O-H center dot center dot center dot O/sp(3)-C-H center dot center dot center dot O Two-Point Hydrogen Bonds in Alcoholic Solvents: Cu-Catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes
        Takaoki Ishii; Ryo Watanabe; Toshimitsu Moriya; Hirohisa Ohmiya; Seiji Mori; Masaya Sawamura
        CHEMISTRY-A EUROPEAN JOURNAL, Sep. 2013, Peer-reviewed
      • Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters
        Hideto Ito; Ayumi Harada; Hirohisa Ohmiya; Masaya Sawamura
        ADVANCED SYNTHESIS & CATALYSIS, Mar. 2013, Peer-reviewed
      • Copper-Catalyzed gamma-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes
        Yusuke Makida; Yurie Takayama; Hirohisa Ohmiya; Masaya Sawamura
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, Peer-reviewed
      • Conjugate Reduction of alpha,beta-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane-Copper Complex
        Soichiro Kawamorita; Kenji Yamazaki; Hirohisa Ohmiya; Tomohiro Iwai; Masaya Sawamura
        ADVANCED SYNTHESIS & CATALYSIS, Dec. 2012, Peer-reviewed
      • Synthesis of Allenylsilanes through Copper-Catalyzed gamma-Selective Coupling between gamma-Silylated Propargylic Phosphates and Alkylboranes
        Umi Yokobori; Hirohisa Ohmiya; Masaya Sawamura
        ORGANOMETALLICS, Nov. 2012, Peer-reviewed
      • Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex
        Masaya Sawamura; Hirohisa Ohmiya; Mika Yoshida
        SYNTHESIS-STUTTGART, Nov. 2012, Peer-reviewed
      • Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes
        Yoshinori Shido; Mika Yoshida; Masahito Tanabe; Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2012, Peer-reviewed
      • Rh-Catalyzed Borylation of N-Adjacent C(sp(3))-H Bonds with a Silica-Supported Triarylphosphine Ligand
        Soichiro Kawamorita; Tatsuya Miyazaki; Tomohiro Iwai; Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2012, Peer-reviewed
      • Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex
        Mika Yoshida; Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2012, Peer-reviewed
      • Reversible 1,3-anti/syn-Stereochemical Courses in Copper-Catalyzed gamma-Selective Allyl-Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes
        Kazunori Nagao; Umi Yokobori; Yusuke Makida; Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2012, Peer-reviewed
      • Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed gamma-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes
        Kazunori Nagao; Hirohisa Ohmiya; Masaya Sawamura
        SYNTHESIS-STUTTGART, May 2012, Peer-reviewed
      • Efficient Preparation of beta-Branched gamma,delta-Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal
        Dong Li; Hirohisa Ohmiya; Masaya Sawamura
        SYNTHESIS-STUTTGART, May 2012, Peer-reviewed
      • Synthesis of Conjugated Allenes through Copper-Catalyzed gamma-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates
        Mingyu Yang; Natsumi Yokokawa; Hirohisa Ohmiya; Masaya Sawamura
        ORGANIC LETTERS, Feb. 2012, Peer-reviewed
      • Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation
        Yusuke Makida; Hirohisa Ohmiya; Masaya Sawamura
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, Peer-reviewed
      • Rh-Catalyzed Ortho-Selective C-H Borylatiob of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands
        Soichiro Kawamorita; Tatsuya Miyazaki; Hirohisa Ohmiya; Tomohiro Iwai; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2011, Peer-reviewed
      • General Approach to Allenes through Copper-Catalyzed gamma-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes
        Hirohisa Ohmiya; Umi Yokobori; Yusuke Makida; Masaya Sawamura
        ORGANIC LETTERS, Dec. 2011, Peer-reviewed
      • Copper-catalyzed Conjugate Additions of Alkylboranes to Aryl alpha,beta-Unsaturated Ketones
        Hirohisa Ohmiya; Yoshinori Shido; Mika Yoshida; Masaya Sawamura
        CHEMISTRY LETTERS, Sep. 2011, Peer-reviewed
      • Intramolecular hydroamination of alkynic sulfonamides catalyzed by a gold-triethynylphosphine complex: Construction of azepine frameworks by 7-exo-dig cyclization
        Hideto Ito; Tomoya Harada; Hirohisa Ohmiya; Masaya Sawamura
        BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, Jul. 2011, Peer-reviewed
      • Copper-Catalyzed gamma-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals
        Dong Li; Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2011, Peer-reviewed
      • Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes
        Hirohisa Ohmiya; Masahito Tanabe; Masaya Sawamura
        ORGANIC LETTERS, Mar. 2011, Peer-reviewed
      • Sulfonamidoquinoline/Palladium(II)-Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed gamma-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids
        Yusuke Makida; Hirohisa Ohmiya; Masaya Sawamura
        CHEMISTRY-AN ASIAN JOURNAL, Feb. 2011, Peer-reviewed
      • Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl alpha,beta-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes
        Hirohisa Ohmiya; Mika Yoshida; Masaya Sawamura
        ORGANIC LETTERS, Feb. 2011, Peer-reviewed
      • Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with a Silica-Supported Compact Phosphane Ligand
        Soichiro Kawamorita; Hirohisa Ohmiya; Tomohiro Iwai; Masaya Sawamura
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, Peer-reviewed
      • Construction of Methylenecycloheptane Frameworks through 7-Exo-Dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex
        Hideto Ito; Hirohisa Ohmiya; Masaya Sawamura
        ORGANIC LETTERS, Oct. 2010, Peer-reviewed
      • Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes
        Hirohisa Ohmiya; Mika Yoshida; Masaya Sawamura
        SYNLETT, Sep. 2010, Peer-reviewed
      • Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex
        Kenji Yamazaki; Soichiro Kawamorita; Hirohisa Ohmiya; Masaya Sawamura
        ORGANIC LETTERS, Sep. 2010, Peer-reviewed
      • Synthesis of alpha-Arylated Allylsilanes through Palladium-Catalyzed gamma-Selective Allyl-Aryl Coupling
        Dong Li; Tatsunori Tanaka; Hirohisa Ohmiya; Masaya Sawamura
        ORGANIC LETTERS, Aug. 2010, Peer-reviewed
      • Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex
        Soichiro Kawamorita; Hirohisa Ohmiya; Masaya Sawamura
        JOURNAL OF ORGANIC CHEMISTRY, Jun. 2010, Peer-reviewed
      • Copper-Catalyzed gamma-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates
        Hirohisa Ohmiya; Natsumi Yokokawa; Masaya Sawamura
        ORGANIC LETTERS, May 2010, Peer-reviewed
      • Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates
        Hirohisa Ohmiya; Mingyu Yang; Yoshihiro Yamauchi; Yuhki Ohtsuka; Masaya Sawamura
        ORGANIC LETTERS, Apr. 2010, Peer-reviewed
      • Copper-Catalyzed gamma-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes
        Hirohisa Ohmiya; Umi Yokobori; Yusuke Makida; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2010, Peer-reviewed
      • Palladium-Catalyzed gamma-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids
        Hirohisa Ohmiya; Yusuke Makida; Dong Li; Masahito Tanabe; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jan. 2010, Peer-reviewed
      • General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate
        Hirohisa Ohmiya; Hideto Ito; Masaya Sawamura
        ORGANIC LETTERS, Dec. 2009, Peer-reviewed
      • Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents
        Hirohisa Ohmiya; Toshimitsu Moriya; Masaya Sawamura
        ORGANIC LETTERS, May 2009, Peer-reviewed
      • Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System
        Soichiro Kawamorita; Hirohisa Ohmiya; Kenji Hara; Atsushi Fukuoka; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2009, Peer-reviewed
      • Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes
        Go Hamasaka; Soichiro Kawamorita; Atsuko Ochida; Ryuto Akiyama; Kenji Hara; Atsushi Fukuoka; Kiyotaka Asakura; Wang Jae Chun; Hirohisa Ohmiya; Masaya Sawamura
        ORGANOMETALLICS, Dec. 2008, Peer-reviewed
      • Palladium-Catalyzed gamma-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids
        Hirohisa Ohmiya; Yusuke Makida; Tatsunori Tanaka; Masaya Sawamura
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2008, Peer-reviewed
      • Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
        Atsuko Ochida; Go Hamasaka; Yoshihiro Yamauchi; Soichiro Kawamorita; Naoya Oshima; Kenji Hara; Hirohisa Ohmiya; Masaya Sawamura
        ORGANOMETALLICS, Nov. 2008, Peer-reviewed
      • Cyclization of Nonterminal Alkynic beta-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand
        Hideto Ito; Yusuke Makida; Atsuko Ochida; Hirohisa Ohmiya; Masaya Sawamura
        ORGANIC LETTERS, Nov. 2008, Peer-reviewed
      • Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System
        Soichiro Kawamorita; Go Hamasaka; Hirohisa Ohmiya; Kenji Hara; Atsushi Fukuoka; Masaya Sawamura
        ORGANIC LETTERS, Oct. 2008, Peer-reviewed
      • Cobalt-catalyzed regioselective dehydrohalogenation of alkyl halides with dimethylphenylsilylmethylmagnesium chloride
        Tsuneyuki Kobayashi; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2008, Peer-reviewed
      • Generation of rhodium enolates via retro-aldol reaction and its application to regioselective aldol reaction
        Kei Murakami; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        TETRAHEDRON LETTERS, Apr. 2008, Peer-reviewed
      • Silver-catalyzed benzylation and allylation reactions of tertiary and secondary alkyl halides with Grignard reagents
        Hidenori Someya; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        ORGANIC LETTERS, Mar. 2008, Peer-reviewed
      • alpha-Olefins as alkenylmetal equivalents in catalytic conjugate addition reactions
        Chun-Yu Ho; Hirohisa Ohmiya; Timothy F. Jamison
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, Peer-reviewed
      • Nickel-catalyzed carbometalation reactions of [2-(1-propynyl)phenyl]methanol with 1-alkenylmagnesium reagents
        Kei Murakami; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        CHEMISTRY LETTERS, Aug. 2007, Peer-reviewed
      • Cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents and their application to the synthesis of 1,3-diols
        Hidenori Someya; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        TETRAHEDRON, Aug. 2007, Peer-reviewed
      • N-heterocyclic carbene ligands in cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents
        Hidenori Someya; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        ORGANIC LETTERS, Apr. 2007, Peer-reviewed
      • Chromium-catalyzed arylmagnesiation of alkynes
        Kei Murakami; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        ORGANIC LETTERS, Apr. 2007, Peer-reviewed
      • A new approach to 4-aryl-1,3-butanediols by cobalt-catalyzed sequential radical cyclization-arylation reaction of silicon-tethered 6-iodo-1-hexene derivatives
        Hidenori Someya; Azusa Kondoh; Akinori Sato; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        SYNLETT, Nov. 2006, Peer-reviewed
      • Cobalt-mediated cross-coupling reactions of primary and secondary alkyl halides with 1-(trimethylsilyl)ethenyl- and 2-trimethylsilylethynylmagnesium reagents
        Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima
        ORGANIC LETTERS, Jul. 2006, Peer-reviewed
      • Cobalt-catalyzed trimethylsilylmethylmagnesium-promoted radical alkenylation of alkyl halides: A complement to the heck reaction
        Walter Affo; Hirohisa Ohmiya; Takuma Fujioka; Yousuke Ikeda; Tomoaki Nakamura; Hideki Yorimitsu; Koichiro Oshima; Yuki Imamura; Tsutomu Mizuta; Katsuhiko Miyoshi
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jun. 2006, Peer-reviewed
      • Cobalt-catalyzed cross-coupling reactions of alkyl halides with aryl Grignard reagents and their application to sequential radical cyclization/cross-coupling reactions
        H Ohmiya; K Wakabayashi; H Yorimitsu; K Oshima
        TETRAHEDRON, Mar. 2006, Peer-reviewed
      • Cobalt(diamine)-catalyzed cross-coupling reaction of alkyl halides with arylmagnesium reagents: Stereoselective constructions of arylated asymmetric carbons and application to total synthesis of AH13205
        H Ohmiya; H Yorimitsu; K Oshima
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2006, Peer-reviewed
      • Regio- and stereoselective approach to 1,2-di- and 1,1,2-trisilylethenes by cobalt-mediated reaction of silyl-substituted dibromomethanes with silylmethylmagnesium reagents
        H Ohmiya; H Yorimitsu; K Oshima
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, Peer-reviewed
      • Cobalt-catalyzed syn hydrophosphination of alkynes
        H Ohmiya; H Yorimitsu; K Oshima
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, Peer-reviewed
      • Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic grignard reagents and their application to tandem radical cyclization/cross-coupling reactions
        H Ohmiya; T Tsuji; H Yorimitsu; K Oshima
        CHEMISTRY-A EUROPEAN JOURNAL, Nov. 2004, Peer-reviewed
      • Cobalt-catalyzed cross-coupling reaction of chloropyridines with Grignard reagents
        H Ohmiya; H Yorimitsu; K Oshima
        CHEMISTRY LETTERS, Oct. 2004, Peer-reviewed
      • Novel synthesis of 5-thio-hexopyranoside: preparation of 5-thio-D- and L-glucose and 1,6-anhydro-5-thio-L- and D-altrose
        J Uenishi; H Ohmiya
        TETRAHEDRON, Aug. 2003, Peer-reviewed
      • Studies on stereoselective Sonogashira coupling of 1,1-dibromo-1-alkene
        J Uenishi; K Matsui; H Ohmiya
        JOURNAL OF ORGANOMETALLIC CHEMISTRY, Jul. 2002, Peer-reviewed

      Awards

      • 15 Sep. 2021
        Mukaiyama Award(公益社団法人 有機合成化学協会)
      • 29 Sep. 2019
        Asian Core Program Lectureship Award Singapore(ICCEOCA-14)
      • 04 Nov. 2018
        Asian Core Program Lectureship Award Korea(ICCEOCA-13)
      • 15 Apr. 2015
        平成27年度科学技術分野の文部科学大臣表彰 若手科学者賞
      • 11 Mar. 2015
        平成26年度北海道大学 研究総長賞 奨励賞
      • 11 Mar. 2015
        平成26年度北海道大学 教育総長賞 奨励賞
      • 19 Feb. 2015
        2014年度有機合成化学協会「中外製薬」研究企画賞
      • 12 Jan. 2015
        Thieme Chemistry Journal Award 2015
      • 06 Dec. 2014
        Banyu Chemist Award “BCA 2014”
      • 05 Aug. 2014
        平成25年度全学教育「北海道大学エクセレント・ティーチャーズ」
      • 28 Mar. 2014
        第63回日本化学会進歩賞
      • 06 Mar. 2012
        平成23年度北海道大学研究総長賞
      • 01 Feb. 2012
        第9回日本化学会北海道支部奨励賞
      • 28 Mar. 2011
        第25回日本化学会若い世代の特別講演会

      External funds: Kakenhi

      • ラジカルが拓く有機触媒化学
        Grant-in-Aid for Scientific Research (A)
        Medium-sized Section 33:Organic chemistry and related fields
        Kyoto University;Kanazawa University
        大宮 寛久
        From 05 Apr. 2021, To 31 Mar. 2025, Granted
        有機合成化学;有機分子触媒
      • Development of novel reactions using carbonyls as latent nucleophiles
        Grant-in-Aid for Scientific Research (B)
        Basic Section 33020:Synthetic organic chemistry-related
        Kanazawa University
        Hirohisa Ohmiya
        From 01 Apr. 2018, To 31 Mar. 2021, Project Closed
        ラジカル反応;カルベン触媒;銅触媒;有機触媒;不斉触媒;触媒・化学反応プロセス;触媒・化学プロセス
      • 有機触媒と金属触媒のハイブリッドに基づく高次反応制御法の開発
        Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
        Science and Engineering
        Kanazawa University
        大宮 寛久
        From 30 Jun. 2017, To 31 Mar. 2022, Granted
        触媒・化学反応プロセス;触媒・化学プロセス
      • Development of asymmetric catalysis directed toward rare-metal-free organic synthesis
        Grant-in-Aid for Scientific Research (B)
        Kanazawa University;Hokkaido University
        Hirohisa Ohmiya
        From 01 Apr. 2015, To 31 Mar. 2018, Project Closed
        銅触媒;有機分子触媒;不斉反応;C-H官能基化;有機ホウ素化合物;選択的合成
      • Development of Environmentally-friendly Molecular Transformations of Unsaturated Compounds
        Grant-in-Aid for Challenging Exploratory Research
        Hokkaido University
        Ohmiya HIROHISA
        From 01 Apr. 2013, To 31 Mar. 2015, Project Closed
        不飽和化合物;銅触媒;カルボスタニル化;水素化;不飽和炭化水素;還元的炭素炭素結合形成
      • Development of Chemoselective Carbon-Carbon Bond Formation Reactions Directed toward Synthesis of Functional Molecules
        Grant-in-Aid for Young Scientists (A)
        Hokkaido University
        Hirohisa OHMIYA
        From 01 Apr. 2012, To 31 Mar. 2015, Project Closed
        銅触媒;不斉合成;有機ホウ素化合物;C-H官能基化;アリル化;有機分子触媒;不斉反応;機能分子合成;炭素-炭素結合形成;化学選択性;遷移金属触媒;アリル位置換反応;共役付加反応;光学活性化合物
      • Palladium-Catalyzed Highly Selective Transformation of Allylic Substrates
        Grant-in-Aid for Young Scientists (B)
        Hokkaido University
        Hirohisa OHMIYA
        From 01 Apr. 2009, To 31 Mar. 2012, Project Closed
        アリル化;位置選択性;パラジウム触媒;銅触媒;有機ホウ素化合物;有機ケイ素化合物;立体特異性;パラジウム;銅;立体選択性;C-H官能基化;アリルアルコール基質;クロスカップリング反応;アリールホウ酸;不斉転写;アニオン性配位子;アリル系基質;gem-ジアリールアルカン;(+)-sertraline
      • 低原子価コバルト錯体触媒を用いた新形式変換反応の開発
        Grant-in-Aid for Young Scientists (Start-up)
        Hokkaido University
        大宮 寛久
        From 01 Apr. 2008, To 31 Mar. 2010, Project Closed
        不斉転写;パラジウム触媒;カップリング反応;アリル位置換反応;位置選択性;酢酸アリル;ボロン酸;立体特異性
      list
        Last Updated :2022/11/23

        Education

        Part-time lecturer

        • From 08 Sep. 2022, To 09 Sep. 2022
          化学特殊講義Ⅱ
          期間中2回、集中講義15時間, 関西学院大学大学院, 理工学研究科

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