Basic Information

Affiliated programs (koza)

• Graduate School of Pharmaceutical Sciences, 薬科学専攻 精密有機合成化学講座, 教授

Professional Memberships

• THE PHARMACEUTICAL SOCIETY OF JAPAN
• KINKI CHEMICAL SOCIETY, JAPAN
• THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN
• THE CHEMICAL SOCIETY OF JAPAN

Academic Degree

• 13 Mar. 2004

  京都薬科大学修士（薬学）
• 23 Mar. 2007

  京都大学博士（工学）

Academic Resume (Graduate Schools)

• 京都大学, 大学院工学研究科博士後期課程材料化学専攻, 修了
• 京都薬科大学, 大学院薬学研究科修士課程薬学専攻, 修了

Academic Resume (Undergraduate School/Majors)

• 京都薬科大学, 薬学部薬学科, 卒業

High School

• High School

  Takatsuki Senior High School

Research History

• From Apr. 2022, To Present

  Kyoto University, Institute for Chemical Research, Professor
• From Apr. 2022, To Mar. 2023

  Kanazawa University, 医薬保健研究域 薬学系, 客員教授
• From Oct. 2019, To Mar. 2023

  Japan Science and Technology Agency, さきがけ研究員（兼任）
• From Apr. 2017, To Mar. 2022

  Kanazawa University, 医薬保健研究域 薬学系, 教授
• From Dec. 2010, To Mar. 2017

  Hokkaido University, 大学院理学研究院 化学部門, 准教授
• From Apr. 2008, To Dec. 2010

  Hokkaido University, 大学院理学研究院 化学部門, 助教
• From Apr. 2007, To Mar. 2008

  Kyoto University, 大学院工学研究科 材料化学専攻, 博士研究員

ID,URL

• ORCID ID

  0000-0002-1374-1137

• J-Global ID

  201301056650433170

• Researcher number

  40508876

• External link

  https://www.fos.kuicr.kyoto-u.ac.jp/eng/

researchmap URL

• https://researchmap.jp/ohmiya

Research

Research Interests

• 有機合成化学

Research Areas

• Nanotechnology/Materials, Synthetic organic chemistry
• Life sciences, Bioorganic chemistry

Papers

• Biomimetic design of an α-ketoacylphosphonium-based light-activated oxygenation auxiliary.

  Ryoto Oya; Kenji Ota; Masaaki Fuki; Yasuhiro Kobori; Masahiro Higashi; Kazunori Nagao; Hirohisa Ohmiya

  Chemical science, 04 Oct. 2023

  
• Diastereoselective congested β-amido ketone synthesis via NHC-catalyzed radical-radical coupling

  Yukiya Sato; Yusuke Miyamoto; Takanori Matsui; Yuto Sumida; Hirohisa Ohmiya

  Chem Catalysis, Aug. 2023

  
• N-heterocyclic carbene- and organic photoredox-catalysed meta-selective acylation of electron-rich arenes

  Yamato Goto; Masaki Sano; Yuto Sumida; Hirohisa Ohmiya

  Nature Synthesis, 03 Aug. 2023

  
• Radical Caging Strategy for Cholinergic Optopharmacology.

  Rikako Nakamura; Takeru Yamazaki; Yui Kondo; Miho Tsukada; Yusuke Miyamoto; Nozomi Arakawa; Yuto Sumida; Taketoshi Kiya; Satoshi Arai; Hirohisa Ohmiya

  Journal of the American Chemical Society, 04 May 2023

  
• Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate

  Naho Takemura; Yuto Sumida; Hirohisa Ohmiya

  ACS CATALYSIS, Jun. 2022

  
• Organophotoredox-catalyzed semipinacol rearrangement via radical-polar crossover

  Taiga Kodo; Kazunori Nagao; Hirohisa Ohmiya

  Nature Communications, Dec. 2022

  
• Direct photoexcitable iodomethylborate enabling cyclopropanation of reactive alkenes

  Rikako Nakamura; Yuto Sumida; Hirohisa Ohmiya

  Bulletin of the Chemical Society of Japan, 27 May 2022

  
• Carbocation Generation by Organophotoredox Catalysis

  Kazunori Nagao; Hirohisa Ohmiya

  Journal of Synthetic Organic Chemistry, Japan, 01 Nov. 2021

  
• A Triple Photoredox/Cobalt/Brønsted Acid Catalysis Enabling Markovnikov Hydroalkoxylation of Unactivated Alkenes

  Masanari Nakagawa; Yuki Matsuki; Kazunori Nagao; Hirohisa Ohmiya

  Journal of the American Chemical Society, 27 Apr. 2022

  
• Reductive Cross‐Coupling between Arylaldehydes and (Hetero)aryl Electrophiles Using Silylboronate Reductant

  Koh Watanabe; Mitsutaka Takeda; Kazunori Nagao; Hirohisa Ohmiya

  European Journal of Organic Chemistry, 24 Feb. 2022

  
• Direct Photoexcitation of Borate Enabling Minisci Reaction

  Marin Kemmochi; Yusuke Miyamoto; Yuto Sumida; Hirohisa Ohmiya

  Asian Journal of Organic Chemistry, Jan. 2022

  
• Aryl radical-mediated N-heterocyclic carbene catalysis

  Yuki Matsuki; Nagisa Ohnishi; Yuki Kakeno; Shunsuke Takemoto; Takuya Ishii; Kazunori Nagao; Hirohisa Ohmiya

  Nature Communications, Dec. 2021

  
• Light-Driven N-Heterocyclic Carbene Catalysis Using Alkylborates

  Yukiya Sato; Yamato Goto; Kei Nakamura; Yusuke Miyamoto; Yuto Sumida; Hirohisa Ohmiya

  ACS Catalysis, 05 Nov. 2021

  
• Radical Relay Trichloromethylacylation of Alkenes through N-Heterocyclic Carbene Catalysis

  Mayu Kusakabe; Kazunori Nagao; Hirohisa Ohmiya

  Organic Letters, 17 Sep. 2021

  
• Organophotoredox‐Catalyzed Decarboxylative N‐Alkylation of Sulfonamides

  Masanari Nakagawa; Kazunori Nagao; Zenichi Ikeda; Matthew Reynolds; Ignacio Ibáñez; Junsi Wang; Norihito Tokunaga; Yusuke Sasaki; Hirohisa Ohmiya

  ChemCatChem, 17 Sep. 2021

  
• Molecular Field Analysis Using Computational-Screening Data in Asymmetric N-Heterocyclic Carbene-Copper Catalysis toward Data-driven in silico Catalyst Optimization

  Masakiyo Mukai; Kazunori Nagao; Shigeru Yamaguchi; Hirohisa Ohmiya

  04 Aug. 2021

  
• Generation of Functionalized Alkyl Radicals via the Direct Photoexcitation of 2,2′-(Pyridine-2,6-diyl)diphenol-Based Borates

  Yusuke Miyamoto; Yuto Sumida; Hirohisa Ohmiya

  Organic Letters, 08 Jul. 2021

  
• Radical N-heterocyclic carbene catalysis for β-ketocarbonyl synthesis

  Takuya Ishii; Kazunori Nagao; Hirohisa Ohmiya

  Tetrahedron, Jul. 2021

  
• Decarboxylative N-Alkylation of Azoles through Visible-Light-Mediated Organophotoredox Catalysis

  Rino Kobayashi; Shotaro Shibutani; Kazunori Nagao; Zenichi Ikeda; Junsi Wang; Ignacio Ibáñez; Matthew Reynolds; Yusuke Sasaki; Hirohisa Ohmiya

  Organic Letters, 17 Jun. 2021

  
• Synthesis of Sterically Hindered α-Hydroxycarbonyls through Radical–Radical Coupling

  Kenji Ota; Kazunori Nagao; Hirohisa Ohmiya

  Organic Letters, 04 Jun. 2021

  
• Fluorescent-Oxaboroles: Synthesis and Optical Property by Sugar Recognition

  Misaki Nakano; Rikako Nakamura; Yuto Sumida; Kazunori Nagao; Taniyuki Furuyama; Fuyuhiko Inagaki; Hirohisa Ohmiya

  Chemical and Pharmaceutical Bulletin, 01 Jun. 2021

  
• Catalytic Reductive Cross‐Coupling between Aromatic Aldehydes and Arylnitriles

  Atsuhisa Mitsui; Kazunori Nagao; Hirohisa Ohmiya

  Chemistry – A European Journal, 26 Apr. 2021

  
• Organophotoredox-Catalyzed Three-Component Coupling of Heteroatom Nucleophiles, Alkenes, and Aliphatic Redox Active Esters

  Shotaro Shibutani; Kazunori Nagao; Hirohisa Ohmiya

  Organic Letters, 05 Mar. 2021

  
• Copper-Catalyzed Reactions of Alkylboranes

  Hirohisa Ohmiya; Masaya Sawamura

  Bulletin of the Chemical Society of Japan, 15 Jan. 2021

  
• Direct excitation strategy for radical generation in organic synthesis

  Yuto Sumida; Hirohisa Ohmiya

  Chemical Society Reviews, 2021

  
• Transition‐Metal‐Free Cross‐Coupling by Using Tertiary Benzylic Organoboronates

  Mitsutaka Takeda; Kazunori Nagao; Hirohisa Ohmiya

  Angewandte Chemie International Edition, 13 Oct. 2020

  
• Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis

  Yuki Kakeno; Mayu Kusakabe; Kazunori Nagao; Hirohisa Ohmiya

  ACS Catalysis, 21 Jul. 2020, Peer-reviewed

  
• N-Heterocyclic Carbene-Based Catalysis Enabling Cross-Coupling Reactions

  Hirohisa Ohmiya

  ACS Catalysis, 19 Jun. 2020, Peer-reviewed

  
• Generation of Alkyl Radical through Direct Excitation of Boracene-Based Alkylborate

  Yukiya Sato; Kei Nakamura; Yuto Sumida; Daisuke Hashizume; Takamitsu Hosoya; Hirohisa Ohmiya

  Journal of the American Chemical Society, 03 Jun. 2020, Peer-reviewed

  
• N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls

  Kenji Ota; Kazunori Nagao; Hirohisa Ohmiya

  Organic Letters, 15 May 2020, Peer-reviewed

  
• Allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions

  Akihiro Yuasa; Kazunori Nagao; Hirohisa Ohmiya

  Beilstein Journal of Organic Chemistry, 07 Feb. 2020, Peer-reviewed

  
• Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines

  Atsuhisa Mitsui; Kazunori Nagao; Hirohisa Ohmiya

  Organic Letters, 07 Feb. 2020, Peer-reviewed

  
• Organophotoredox-Catalyzed Decarboxylative C(sp3)–O Bond Formation

  Shotaro Shibutani; Taiga Kodo; Mitsutaka Takeda; Kazunori Nagao; Norihito Tokunaga; Yusuke Sasaki; Hirohisa Ohmiya

  Journal of the American Chemical Society, 22 Jan. 2020, Peer-reviewed

  
• 5 anti Boron Addition to Alkynes

  M. Sawamura; H. Ohmiya

  Advances in Organoboron Chemistry towards Organic Synthesis, 2020

  
• Boracene-Based Alkylborate Enabling Ni/Ir Hybrid Catalysis

  Yukiya Sato; Yusuke Miyamoto; Yuto Sumida; Takamitsu Hosoya; Hirohisa Ohmiya

  Organic & Biomolecular Chemistry, 2020, Peer-reviewed

  
• Reductive umpolung for asymmetric synthesis of chiral α-allenic alcohols

  Yui Kondo; Kazunori Nagao; Hirohisa Ohmiya

  Chemical Communications, 2020, Peer-reviewed

  
• Recent advances in N-heterocyclic carbene-based radical catalysis

  Takuya Ishii; Kazunori Nagao; Hirohisa Ohmiya

  Chemical Science, 2020, Peer-reviewed

  
• Aliphatic Oxaboroles Enabling Remarkable Recognition of Diols

  Arakawa N; Nagao K; Murakami R; Sumida Y; Arakawa H; Inagaki F; Ohmiya H

  Bulletin of the Chemical Society of Japan, 2020, Peer-reviewed

  
• N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis

  Kazunori Nagao; Hirohisa Ohmiya

  Topics in Current Chemistry, Dec. 2019, Peer-reviewed

  
• N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes

  Takuya Ishii; Kenji Ota; Kazunori Nagao; Hirohisa Ohmiya

  Journal of the American Chemical Society, Sep. 2019, Peer-reviewed

  
• Synergistic N‐Heterocyclic Carbene/Palladium‐Catalyzed Aldehyde Acylation of Allylic Amines

  Nagisa Ohnishi; Shigeo Yasuda; Kazunori Nagao; Hirohisa Ohmiya

  Asian Journal of Organic Chemistry, Jul. 2019, Peer-reviewed

  
• Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand

  Koji Imai; Yurie Takayama; Hiroaki Murayama; Hirohisa Ohmiya; Yohei Shimizu; Masaya Sawamura

  Organic Letters, Mar. 2019, Peer-reviewed

  
• N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes

  Takuya Ishii; Yuki Kakeno; Kazunori Nagao; Hirohisa Ohmiya

  Journal of the American Chemical Society, Mar. 2019, Peer-reviewed

  
• Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis

  Mitsutaka Takeda; Atsuhisa Mitsui; Kazunori Nagao; Hirohisa Ohmiya

  Journal of the American Chemical Society, Jan. 2019, Peer-reviewed

  
• Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis

  Hiroki Haruki; Shigeo Yasuda; Kazunori Nagao; Hirohisa Ohmiya

  Chemistry - A European Journal, Jan. 2019, Peer-reviewed

  
• Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions

  Kenya Yabushita; Akihiro Yuasa; Kazunori Nagao; Hirohisa Ohmiya

  Journal of the American Chemical Society, Jan. 2019, Peer-reviewed

  
• Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis

  Hiroki Haruki; Shigeo Yasuda; Kazunori Nagao; Hirohisa Ohmiya

  Chemistry - A European Journal, Jan. 2019, Peer-reviewed

  
• Front Cover: Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis (Chem. Eur. J. 3/2019)

  Hiroki Haruki; Shigeo Yasuda; Kazunori Nagao; Hirohisa Ohmiya

  Chemistry - A European Journal, Jan. 2019, Peer-reviewed

  
• Copper-Catalyzed Enantioselective Coupling between Allyl-boronates and Phosphates Using a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes

  Yuto Yasuda; Hirohisa Ohmiya; Masaya Sawamura

  Synthesis (Germany), 01 Jun. 2018, Peer-reviewed

  
• Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates

  Shigeo Yasuda; Takuya Ishii; Shunsuke Takemoto; Hiroki Haruki; Hirohisa Ohmiya

  Angewandte Chemie - International Edition, 05 Mar. 2018, Peer-reviewed

  
• Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates

  Shigeo Yasuda; Takuya Ishii; Shunsuke Takemoto; Hiroki Haruki; Hirohisa Ohmiya

  Angewandte Chemie, Mar. 2018, Peer-reviewed

  
• Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of α-ketoesters with terminal alkynes: OH⋯O/sp3-CH⋯O two-point hydrogen bonding combined with dispersive attractions

  Martin C. Schwarzer; Akane Fujioka; Takaoki Ishii; Hirohisa Ohmiya; Seiji Mori; Masaya Sawamura

  Chemical Science, 2018, Peer-reviewed

  
• Phosphine-Catalyzed Anti -Hydroboration of Internal Alkynes

  Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.

  Organic Letters, 2018, Peer-reviewed

  
• Synergistic palladium/copper-catalyzed Csp3-Csp2 cross-couplings using aldehydes as latent α-alkoxyalkyl anion equivalents

  Mitsutaka Takeda; Kenya Yabushita; Shigeo Yasuda; Hirohisa Ohmiya

  Chemical Communications, 2018, Peer-reviewed

  
• Phosphine-Catalyzed anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multisubstituted γ-Borylallylboranes

  Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.

  Angewandte Chemie - International Edition, 2018, Peer-reviewed

  
• Phosphine-Catalyzed anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multisubstituted γ-Borylallylboranes

  Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.

  Angewandte Chemie - International Edition, 2018, Peer-reviewed

  
• Copper-catalyzed enantioselective intramolecular alkylboron allylic alkylation

  Kentaro Hojoh; Yoshinori Shido; Hirohisa Ohmiya; Masaya Sawamura

  Chemistry Letters, 2018, Peer-reviewed

  
• Asymmetric Synthesis of beta-Lactams through Copper-Catalyzed Alkyne-Nitrone Coupling with a Prolinol-Phosphine Chiral Ligand

  Yurie Takayama; Takaoki Ishii; Hirohisa Ohmiya; Tomohiro Iwai; Martin C. Schwarzer; Seiji Mori; Tohru Taniguchi; Kenji Monde; Masaya Sawamura

  CHEMISTRY-A EUROPEAN JOURNAL, Jun. 2017, Peer-reviewed

  
• Synthesis of alpha-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides

  Kentaro Hojoh; Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2017, Peer-reviewed

  
• Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand

  Yuto Yasuda; Hirohisa Ohmiya; Masaya Sawamura

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Aug. 2016, Peer-reviewed

  
• Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles

  Hirohisa Ohmiya; Heng Zhang; Saori Shibata; Ayumi Harada; Masaya Sawamura

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Apr. 2016, Peer-reviewed

  
• Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates

  Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.

  Organic Letters, 2016, Peer-reviewed

  
• Copper-catalyzed semihydrogenation of internal alkynes with molecular hydrogen

  Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.

  Organometallics, 2016, Peer-reviewed

  
• Silica-Supported Triptycene-Type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki-Miyaura Cross-Coupling of Chloroarenes

  Tomohiro Iwai; Shota Konishi; Tatsuya Miyazaki; Soichiro Kawamorita; Natsumi Yokokawa; Hirohisa Ohmiya; Masaya Sawamura

  ACS CATALYSIS, Dec. 2015, Peer-reviewed

  
• Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

  Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.

  Angewandte Chemie - International Edition, 2015, Peer-reviewed

  
• Copper-catalyzed stereoselective conjugate addition of alkylboranes to alkynoates

  Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.

  Beilstein Journal of Organic Chemistry, 2015, Peer-reviewed

  
• Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes

  Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M.

  Chemistry - A European Journal, 2015, Peer-reviewed

  
• Copper-catalyzed enantioselective allylic cross-coupling with alkylboranes

  Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.

  Tetrahedron, 2015, Peer-reviewed

  
• Copper(I)-catalyzed intramolecular hydroalkoxylation of unactivated alkenes

  Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.

  Organic Letters, 2015, Peer-reviewed

  
• Anti-selective vicinal silaboration and diboration of alkynoates through phosphine organocatalysis

  Nagao, K.; Ohmiya, H.; Sawamura, M.

  Organic Letters, 2015, Peer-reviewed

  
• Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes

  Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Nov. 2014, Peer-reviewed

  
• Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles

  Ayumi Harada; Yusuke Makida; Tatsunori Sato; Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Oct. 2014, Peer-reviewed

  
• Construction of Quaternary Stereogenic Carbon Centers through Copper- Catalyzed Enantioselective Allylic Cross- Coupling with Alkylboranes**

  Kentaro Hojoh; Yoshinori Shido; Hirohisa Ohmiya; Masaya Sawamura

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, May 2014, Peer-reviewed

  
• Phosphine-catalyzed anti-carboboration of alkynoates with alkyl-, alkenyl-, and arylboranes

  Nagao, K.; Ohmiya, H.; Sawamura, M.

  Journal of the American Chemical Society, 2014, Peer-reviewed

  
• Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling of Alkylboranes, Alkynoates, and Tributyltin Methoxide

  Takamichi Wakamatsu; Kazunori Nagao; Hirohisa Ohmiya; Masaya Sawamura

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Oct. 2013, Peer-reviewed

  
• Cooperative Catalysis of Metal and O-H center dot center dot center dot O/sp(3)-C-H center dot center dot center dot O Two-Point Hydrogen Bonds in Alcoholic Solvents: Cu-Catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes

  Takaoki Ishii; Ryo Watanabe; Toshimitsu Moriya; Hirohisa Ohmiya; Seiji Mori; Masaya Sawamura

  CHEMISTRY-A EUROPEAN JOURNAL, Sep. 2013, Peer-reviewed

  
• Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters

  Hideto Ito; Ayumi Harada; Hirohisa Ohmiya; Masaya Sawamura

  ADVANCED SYNTHESIS & CATALYSIS, Mar. 2013, Peer-reviewed

  
• Copper-Catalyzed gamma-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes

  Yusuke Makida; Yurie Takayama; Hirohisa Ohmiya; Masaya Sawamura

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, Peer-reviewed

  
• Conjugate Reduction of alpha,beta-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane-Copper Complex

  Soichiro Kawamorita; Kenji Yamazaki; Hirohisa Ohmiya; Tomohiro Iwai; Masaya Sawamura

  ADVANCED SYNTHESIS & CATALYSIS, Dec. 2012, Peer-reviewed

  
• Synthesis of Allenylsilanes through Copper-Catalyzed gamma-Selective Coupling between gamma-Silylated Propargylic Phosphates and Alkylboranes

  Umi Yokobori; Hirohisa Ohmiya; Masaya Sawamura

  ORGANOMETALLICS, Nov. 2012, Peer-reviewed

  
• Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex

  Masaya Sawamura; Hirohisa Ohmiya; Mika Yoshida

  SYNTHESIS-STUTTGART, Nov. 2012, Peer-reviewed

  
• Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes

  Yoshinori Shido; Mika Yoshida; Masahito Tanabe; Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2012, Peer-reviewed

  
• Rh-Catalyzed Borylation of N-Adjacent C(sp(3))-H Bonds with a Silica-Supported Triarylphosphine Ligand

  Soichiro Kawamorita; Tatsuya Miyazaki; Tomohiro Iwai; Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2012, Peer-reviewed

  
• Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex

  Mika Yoshida; Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2012, Peer-reviewed

  
• Reversible 1,3-anti/syn-Stereochemical Courses in Copper-Catalyzed gamma-Selective Allyl-Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes

  Kazunori Nagao; Umi Yokobori; Yusuke Makida; Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2012, Peer-reviewed

  
• Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed gamma-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes

  Kazunori Nagao; Hirohisa Ohmiya; Masaya Sawamura

  SYNTHESIS-STUTTGART, May 2012, Peer-reviewed

  
• Efficient Preparation of beta-Branched gamma,delta-Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal

  Dong Li; Hirohisa Ohmiya; Masaya Sawamura

  SYNTHESIS-STUTTGART, May 2012, Peer-reviewed

  
• Synthesis of Conjugated Allenes through Copper-Catalyzed gamma-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates

  Mingyu Yang; Natsumi Yokokawa; Hirohisa Ohmiya; Masaya Sawamura

  ORGANIC LETTERS, Feb. 2012, Peer-reviewed

  
• Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation

  Yusuke Makida; Hirohisa Ohmiya; Masaya Sawamura

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, Peer-reviewed

  
• Rh-Catalyzed Ortho-Selective C-H Borylatiob of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands

  Soichiro Kawamorita; Tatsuya Miyazaki; Hirohisa Ohmiya; Tomohiro Iwai; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2011, Peer-reviewed

  
• General Approach to Allenes through Copper-Catalyzed gamma-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes

  Hirohisa Ohmiya; Umi Yokobori; Yusuke Makida; Masaya Sawamura

  ORGANIC LETTERS, Dec. 2011, Peer-reviewed

  
• Copper-catalyzed Conjugate Additions of Alkylboranes to Aryl alpha,beta-Unsaturated Ketones

  Hirohisa Ohmiya; Yoshinori Shido; Mika Yoshida; Masaya Sawamura

  CHEMISTRY LETTERS, Sep. 2011, Peer-reviewed

  
• Intramolecular hydroamination of alkynic sulfonamides catalyzed by a gold-triethynylphosphine complex: Construction of azepine frameworks by 7-exo-dig cyclization

  Hideto Ito; Tomoya Harada; Hirohisa Ohmiya; Masaya Sawamura

  BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, Jul. 2011, Peer-reviewed

  
• Copper-Catalyzed gamma-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals

  Dong Li; Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2011, Peer-reviewed

  
• Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes

  Hirohisa Ohmiya; Masahito Tanabe; Masaya Sawamura

  ORGANIC LETTERS, Mar. 2011, Peer-reviewed

  
• Sulfonamidoquinoline/Palladium(II)-Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed gamma-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids

  Yusuke Makida; Hirohisa Ohmiya; Masaya Sawamura

  CHEMISTRY-AN ASIAN JOURNAL, Feb. 2011, Peer-reviewed

  
• Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl alpha,beta-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes

  Hirohisa Ohmiya; Mika Yoshida; Masaya Sawamura

  ORGANIC LETTERS, Feb. 2011, Peer-reviewed

  
• Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with a Silica-Supported Compact Phosphane Ligand

  Soichiro Kawamorita; Hirohisa Ohmiya; Tomohiro Iwai; Masaya Sawamura

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, Peer-reviewed

  
• Construction of Methylenecycloheptane Frameworks through 7-Exo-Dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex

  Hideto Ito; Hirohisa Ohmiya; Masaya Sawamura

  ORGANIC LETTERS, Oct. 2010, Peer-reviewed

  
• Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes

  Hirohisa Ohmiya; Mika Yoshida; Masaya Sawamura

  SYNLETT, Sep. 2010, Peer-reviewed

  
• Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex

  Kenji Yamazaki; Soichiro Kawamorita; Hirohisa Ohmiya; Masaya Sawamura

  ORGANIC LETTERS, Sep. 2010, Peer-reviewed

  
• Synthesis of alpha-Arylated Allylsilanes through Palladium-Catalyzed gamma-Selective Allyl-Aryl Coupling

  Dong Li; Tatsunori Tanaka; Hirohisa Ohmiya; Masaya Sawamura

  ORGANIC LETTERS, Aug. 2010, Peer-reviewed

  
• Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex

  Soichiro Kawamorita; Hirohisa Ohmiya; Masaya Sawamura

  JOURNAL OF ORGANIC CHEMISTRY, Jun. 2010, Peer-reviewed

  
• Copper-Catalyzed gamma-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates

  Hirohisa Ohmiya; Natsumi Yokokawa; Masaya Sawamura

  ORGANIC LETTERS, May 2010, Peer-reviewed

  
• Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates

  Hirohisa Ohmiya; Mingyu Yang; Yoshihiro Yamauchi; Yuhki Ohtsuka; Masaya Sawamura

  ORGANIC LETTERS, Apr. 2010, Peer-reviewed

  
• Copper-Catalyzed gamma-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes

  Hirohisa Ohmiya; Umi Yokobori; Yusuke Makida; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2010, Peer-reviewed

  
• Palladium-Catalyzed gamma-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids

  Hirohisa Ohmiya; Yusuke Makida; Dong Li; Masahito Tanabe; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jan. 2010, Peer-reviewed

  
• General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate

  Hirohisa Ohmiya; Hideto Ito; Masaya Sawamura

  ORGANIC LETTERS, Dec. 2009, Peer-reviewed

  
• Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents

  Hirohisa Ohmiya; Toshimitsu Moriya; Masaya Sawamura

  ORGANIC LETTERS, May 2009, Peer-reviewed

  
• Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System

  Soichiro Kawamorita; Hirohisa Ohmiya; Kenji Hara; Atsushi Fukuoka; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2009, Peer-reviewed

  
• Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes

  Go Hamasaka; Soichiro Kawamorita; Atsuko Ochida; Ryuto Akiyama; Kenji Hara; Atsushi Fukuoka; Kiyotaka Asakura; Wang Jae Chun; Hirohisa Ohmiya; Masaya Sawamura

  ORGANOMETALLICS, Dec. 2008, Peer-reviewed

  
• Palladium-Catalyzed gamma-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids

  Hirohisa Ohmiya; Yusuke Makida; Tatsunori Tanaka; Masaya Sawamura

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2008, Peer-reviewed

  
• Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane

  Atsuko Ochida; Go Hamasaka; Yoshihiro Yamauchi; Soichiro Kawamorita; Naoya Oshima; Kenji Hara; Hirohisa Ohmiya; Masaya Sawamura

  ORGANOMETALLICS, Nov. 2008, Peer-reviewed

  
• Cyclization of Nonterminal Alkynic beta-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand

  Hideto Ito; Yusuke Makida; Atsuko Ochida; Hirohisa Ohmiya; Masaya Sawamura

  ORGANIC LETTERS, Nov. 2008, Peer-reviewed

  
• Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System

  Soichiro Kawamorita; Go Hamasaka; Hirohisa Ohmiya; Kenji Hara; Atsushi Fukuoka; Masaya Sawamura

  ORGANIC LETTERS, Oct. 2008, Peer-reviewed

  
• Cobalt-catalyzed regioselective dehydrohalogenation of alkyl halides with dimethylphenylsilylmethylmagnesium chloride

  Tsuneyuki Kobayashi; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2008, Peer-reviewed

  
• Generation of rhodium enolates via retro-aldol reaction and its application to regioselective aldol reaction

  Kei Murakami; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  TETRAHEDRON LETTERS, Apr. 2008, Peer-reviewed

  
• Silver-catalyzed benzylation and allylation reactions of tertiary and secondary alkyl halides with Grignard reagents

  Hidenori Someya; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  ORGANIC LETTERS, Mar. 2008, Peer-reviewed

  
• alpha-Olefins as alkenylmetal equivalents in catalytic conjugate addition reactions

  Chun-Yu Ho; Hirohisa Ohmiya; Timothy F. Jamison

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, Peer-reviewed

  
• Nickel-catalyzed carbometalation reactions of [2-(1-propynyl)phenyl]methanol with 1-alkenylmagnesium reagents

  Kei Murakami; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  CHEMISTRY LETTERS, Aug. 2007, Peer-reviewed

  
• Cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents and their application to the synthesis of 1,3-diols

  Hidenori Someya; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  TETRAHEDRON, Aug. 2007, Peer-reviewed

  
• N-heterocyclic carbene ligands in cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents

  Hidenori Someya; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  ORGANIC LETTERS, Apr. 2007, Peer-reviewed

  
• Chromium-catalyzed arylmagnesiation of alkynes

  Kei Murakami; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  ORGANIC LETTERS, Apr. 2007, Peer-reviewed

  
• A new approach to 4-aryl-1,3-butanediols by cobalt-catalyzed sequential radical cyclization-arylation reaction of silicon-tethered 6-iodo-1-hexene derivatives

  Hidenori Someya; Azusa Kondoh; Akinori Sato; Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  SYNLETT, Nov. 2006, Peer-reviewed

  
• Cobalt-mediated cross-coupling reactions of primary and secondary alkyl halides with 1-(trimethylsilyl)ethenyl- and 2-trimethylsilylethynylmagnesium reagents

  Hirohisa Ohmiya; Hideki Yorimitsu; Koichiro Oshima

  ORGANIC LETTERS, Jul. 2006, Peer-reviewed

  
• Cobalt-catalyzed trimethylsilylmethylmagnesium-promoted radical alkenylation of alkyl halides: A complement to the heck reaction

  Walter Affo; Hirohisa Ohmiya; Takuma Fujioka; Yousuke Ikeda; Tomoaki Nakamura; Hideki Yorimitsu; Koichiro Oshima; Yuki Imamura; Tsutomu Mizuta; Katsuhiko Miyoshi

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jun. 2006, Peer-reviewed

  
• Cobalt-catalyzed cross-coupling reactions of alkyl halides with aryl Grignard reagents and their application to sequential radical cyclization/cross-coupling reactions

  H Ohmiya; K Wakabayashi; H Yorimitsu; K Oshima

  TETRAHEDRON, Mar. 2006, Peer-reviewed

  
• Cobalt(diamine)-catalyzed cross-coupling reaction of alkyl halides with arylmagnesium reagents: Stereoselective constructions of arylated asymmetric carbons and application to total synthesis of AH13205

  H Ohmiya; H Yorimitsu; K Oshima

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2006, Peer-reviewed

  
• Regio- and stereoselective approach to 1,2-di- and 1,1,2-trisilylethenes by cobalt-mediated reaction of silyl-substituted dibromomethanes with silylmethylmagnesium reagents

  H Ohmiya; H Yorimitsu; K Oshima

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, Peer-reviewed

  
• Cobalt-catalyzed syn hydrophosphination of alkynes

  H Ohmiya; H Yorimitsu; K Oshima

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, Peer-reviewed

  
• Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic grignard reagents and their application to tandem radical cyclization/cross-coupling reactions

  H Ohmiya; T Tsuji; H Yorimitsu; K Oshima

  CHEMISTRY-A EUROPEAN JOURNAL, Nov. 2004, Peer-reviewed

  
• Cobalt-catalyzed cross-coupling reaction of chloropyridines with Grignard reagents

  H Ohmiya; H Yorimitsu; K Oshima

  CHEMISTRY LETTERS, Oct. 2004, Peer-reviewed

  
• Novel synthesis of 5-thio-hexopyranoside: preparation of 5-thio-D- and L-glucose and 1,6-anhydro-5-thio-L- and D-altrose

  J Uenishi; H Ohmiya

  TETRAHEDRON, Aug. 2003, Peer-reviewed

  
• Studies on stereoselective Sonogashira coupling of 1,1-dibromo-1-alkene

  J Uenishi; K Matsui; H Ohmiya

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, Jul. 2002, Peer-reviewed

  

Awards

• 15 Sep. 2021

  Mukaiyama Award(公益社団法人　有機合成化学協会）
• 29 Sep. 2019

  Asian Core Program Lectureship Award Singapore(ICCEOCA-14)
• 04 Nov. 2018

  Asian Core Program Lectureship Award Korea(ICCEOCA-13)
• 15 Apr. 2015

  平成27年度科学技術分野の文部科学大臣表彰 若手科学者賞
• 11 Mar. 2015

  平成26年度北海道大学 研究総長賞 奨励賞
• 11 Mar. 2015

  平成26年度北海道大学 教育総長賞 奨励賞
• 19 Feb. 2015

  2014年度有機合成化学協会「中外製薬」研究企画賞
• 12 Jan. 2015

  Thieme Chemistry Journal Award 2015
• 06 Dec. 2014

  Banyu Chemist Award “BCA 2014”
• 05 Aug. 2014

  平成25年度全学教育「北海道大学エクセレント・ティーチャーズ」
• 28 Mar. 2014

  第63回日本化学会進歩賞
• 06 Mar. 2012

  平成23年度北海道大学研究総長賞
• 01 Feb. 2012

  第9回日本化学会北海道支部奨励賞
• 28 Mar. 2011

  第25回日本化学会若い世代の特別講演会

External funds: Kakenhi

• ラジカルが拓く有機触媒化学

  Grant-in-Aid for Scientific Research (A)

  Medium-sized Section 33:Organic chemistry and related fields

  Kyoto University;Kanazawa University

  大宮 寛久

  From 05 Apr. 2021, To 31 Mar. 2025, Granted

  有機触媒;有機合成化学;有機分子触媒

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21H04681/
• Development of novel reactions using carbonyls as latent nucleophiles

  Grant-in-Aid for Scientific Research (B)

  Basic Section 33020:Synthetic organic chemistry-related

  Kanazawa University

  Hirohisa Ohmiya

  From 01 Apr. 2018, To 31 Mar. 2021, Project Closed

  ラジカル反応;カルベン触媒;銅触媒;有機触媒;不斉触媒;触媒・化学反応プロセス;触媒・化学プロセス

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18H01971/
• Development of novel reactions through organo/metal hybrid catalysis

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kanazawa University

  Hirohisa Ohmiya

  From 30 Jun. 2017, To 31 Mar. 2022, Project Closed

  触媒・化学反応プロセス;触媒・化学プロセス

  https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-17H06449/
• Development of asymmetric catalysis directed toward rare-metal-free organic synthesis

  Grant-in-Aid for Scientific Research (B)

  Kanazawa University;Hokkaido University

  Hirohisa Ohmiya

  From 01 Apr. 2015, To 31 Mar. 2018, Project Closed

  銅触媒;有機分子触媒;不斉反応;C-H官能基化;有機ホウ素化合物;選択的合成

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15H03803/
• Development of Environmentally-friendly Molecular Transformations of Unsaturated Compounds

  Grant-in-Aid for Challenging Exploratory Research

  Hokkaido University

  Ohmiya HIROHISA

  From 01 Apr. 2013, To 31 Mar. 2015, Project Closed

  不飽和化合物;銅触媒;カルボスタニル化;水素化;不飽和炭化水素;還元的炭素炭素結合形成

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25620072/
• Development of Chemoselective Carbon-Carbon Bond Formation Reactions Directed toward Synthesis of Functional Molecules

  Grant-in-Aid for Young Scientists (A)

  Hokkaido University

  Hirohisa OHMIYA

  From 01 Apr. 2012, To 31 Mar. 2015, Project Closed

  銅触媒;不斉合成;有機ホウ素化合物;C-H官能基化;アリル化;有機分子触媒;不斉反応;機能分子合成;炭素-炭素結合形成;化学選択性;遷移金属触媒;アリル位置換反応;共役付加反応;光学活性化合物

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24685015/
• Palladium-Catalyzed Highly Selective Transformation of Allylic Substrates

  Grant-in-Aid for Young Scientists (B)

  Hokkaido University

  Hirohisa OHMIYA

  From 01 Apr. 2009, To 31 Mar. 2012, Project Closed

  アリル化;位置選択性;パラジウム触媒;銅触媒;有機ホウ素化合物;有機ケイ素化合物;立体特異性;パラジウム;銅;立体選択性;C-H官能基化;アリルアルコール基質;クロスカップリング反応;アリールホウ酸;不斉転写;アニオン性配位子;アリル系基質;gem-ジアリールアルカン;(+)-sertraline

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21750086/
• 低原子価コバルト錯体触媒を用いた新形式変換反応の開発

  Grant-in-Aid for Young Scientists (Start-up)

  Hokkaido University

  大宮 寛久

  From 01 Apr. 2008, To 31 Mar. 2010, Project Closed

  不斉転写;パラジウム触媒;カップリング反応;アリル位置換反応;位置選択性;酢酸アリル;ボロン酸;立体特異性

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20850002/
• 光エネルギーを利用した複雑かつ嵩高い分子の自在変換

  Grant-in-Aid for Transformative Research Areas (A)

  Transformative Research Areas, Section (II)

  Kyoto University

  大宮 寛久

  From 01 Apr. 2023, To 31 Mar. 2028, Granted

  光エネルギー;有機合成;ラジカル

  https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-23H04912/

Education

Teaching subject(s)

• From 01 Apr. 2023, To 31 Mar. 2024

  Laboratory Practice in Basic Fine Organic Synthesis

  4209, Year-long, Graduate School of Pharmaceutical Sciences, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Research Training(Fine Organic Synthesis)

  D149, Year-long, Faculty of Pharmaceutical Sciences, 10
• From 01 Apr. 2023, To 31 Mar. 2024

  Research in Basic Fine Organic Synthesis

  3209, Year-long, Graduate School of Pharmaceutical Sciences, 4
• From 01 Apr. 2023, To 31 Mar. 2024

  Organic Chemistry III

  C005, Spring, Faculty of Pharmaceutical Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Organic Chemistry 5

  A015, Spring, Faculty of Pharmaceutical Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Introduction to Clinical Pharmacy

  6001, Spring, Graduate School of Pharmaceutical Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Basic Organic Chemistry Seminar

  2309, Year-long, Graduate School of Pharmaceutical Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Basic Laboratory Techniques in Organic Chemistry

  1205, Spring, Graduate School of Pharmaceutical Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Introduction to Organic Chemistry for Drug Discovery

  8102, Spring, Graduate School of Pharmaceutical Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Introduction to Pharmaceutical Sciences

  6002, Spring, Graduate School of Pharmaceutical Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Introduction to Organic Chemistry for Drug Discovery

  1026, Spring, Graduate School of Pharmaceutical Sciences, 2

Participation in PhD Defense

• 新規ケミカルスペースの開拓を指向した八員環縮環インドール及びスピロ環状ペプチドの合成研究

  YAMAGUCHI AYUTA, Graduate School of Pharmaceutical Sciences, Sub-chief Examiner

  23 Mar. 2023
• Gold(I)-Catalyzed Reaction of Azido Alkynes for the Synthesis of Indole-Based Polycycles

  Luca Can Greiner, Graduate School of Pharmaceutical Sciences, Sub-chief Examiner

  23 Mar. 2023
• Synthetic Utility of Fused-Cyclobutenes:Synthesis of Medium-Sized Cycloalkenes

  ITO TOMOHIRO, Graduate School of Pharmaceutical Sciences, Sub-chief Examiner

  23 Mar. 2023
• Mannich反応を利用したβ-アミノ-α-ケト酸誘導体の触媒的不斉合成法の開発とペプチドへの合成展開

  TOKUHIRO YUSUKE, Graduate School of Pharmaceutical Sciences, Sub-chief Examiner

  23 Mar. 2023

Part-time lecturer

• From 11 Apr. 2023, To 30 Sep. 2023

  化学生命工学特別講義

  期間中1回、1回　5時間, 名古屋大学, 工学部
• From 08 Sep. 2022, To 09 Sep. 2022

  化学特殊講義Ⅱ

  期間中2回、集中講義15時間, 関西学院大学大学院, 理工学研究科

Administration

Faculty management (title, position)

• From 01 Apr. 2023, To 31 Mar. 2024

  化学研究所運営委員会
• From 01 Apr. 2023, To 31 Mar. 2024

  化学研究所将来問題・研究活性化委員会
• From 01 Apr. 2023, To 31 Mar. 2024

  化学研究所総務・教務委員会
• From 01 Apr. 2023, To 31 Mar. 2024

  化学研究所建物管理委員会