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Ohki, Yasuhiro

Institute for Chemical Research (ICR) Professor

Ohki, Yasuhiro
list
    Last Updated :2025/04/23

    Basic Information

    Affiliated programs (koza)

    • Graduate School of Engineering, 物質エネルギー化学専攻 物質変換科学講座, 教授

    Professional Memberships

    • The American Chemical Society
    • 近畿化学協会
    • 触媒学会
    • Japan Society of Coordination Chemistry
    • Chemical Society of Japan

    Academic Degree

    • Master's Degree (Engineering)(Tokyo Institute of Technology)
    • Ph.D Degree (Engineering)(Tokyo Institute of Technology)

    Research History

    • From Jan. 2021, To Present
      Kyoto University, Institute for Chemical Research, professor
    • From May 2008, To Dec. 2020
      Nagoya University, Graduate School of Science Division of Material Science, Associate professor
    • From 01 Apr. 2007, To 30 Apr. 2008
      Nagoya University, Graduate School of Science Division of Material Science, Assistant Professor
    • From Sep. 2000, To Mar. 2007
      Nagoya University, Graduate School of Science Division of Material Science, Assistant

    Language of Instruction

    • Japanese
    • English

    ID,URL

    researchmap URL

    list
      Last Updated :2025/04/23

      Research

      Research Topics, Overview of the research

      • Research Topics

        Design, synthesis, and reaction studies of molecular compounds with multiple transition metal atoms, Bio-inorganic chemistry of sulfur-supported transition metals, Development of molecular catalysts for energy conversion

      • Overview of the research

        Development of efficient processes for energy conversion and material synthesis is one of the key issues to be solved for sustainable societies. An innovative approach is to seek the frontier of materials with full of potentials, which may be discovered in between typical small molecular materials and nano materials. Our study starts from the synthesis of sophisticated “clusters”, which stand for molecules with multiple transition metal atoms. Their sizes are around 1 nm, the range of which has not been explored in molecular chemistry of transition and main-group elements, particularly those with iron-group metals. These cluster molecules are then applied as catalysts or functional materials, for instance in the catalytic reduction of nitrogen molecule or carbon dioxide, or they contribute to uncover the secrets of complicated metal centers in biology.

      Research Areas

      • Nanotechnology/Materials, Inorganic and coordination chemistry

      Papers

      • An Icosahedral 55-Atom Iron Hydride Cluster Protected by Tri-tert-butylphosphines
        Tatsuya Higaki; Kanata Tanaka; Hitoshi Izu; Shunya Oishi; Koki Kawamoto; Mizuki Tada; W. M. C. Sameera; Ryo Takahata; Toshiharu Teranishi; Soichi Kikkawa; Seiji Yamazoe; Takuya Shiga; Masayuki Nihei; Tatsuhisa Kato; Roger E. Cramer; Zihan Zhang; Karsten Meyer; Yasuhiro Ohki
        Journal of the American Chemical Society, 20 Jan. 2025
      • Synthesis of Cubic [Mo3S4M] (M = Rh, Ir) Clusters for the Borylation of C–H Bonds in Aromatic Compounds
        Hitoshi Izu; Sayaka Shimoyama; Kazuki Tanifuji; Yasuhiro Ohki
        Organometallics, 11 Sep. 2024
      • Silylation of N2 catalyzed by cubic [Mo3S4Ni] clusters bearing Mo-bound cyclopentadienyl ligands
        Yuto Matsuoka; Yuta Sakai; Hitoshi Izu; Sayaka Shimoyama; Mayu Fujisawa; Mizuki Tada; Nishshanka M. Lakshan; W.M.C. Sameera; Kazuki Tanifuji; Yasuhiro Ohki
        Coordination Chemistry Research, Aug. 2024
      • Biomimetic Transition Metal Cluster Complexes: Synthetic Studies and Applications in the Reduction of Inert Small Molecules
        Yasuhiro Ohki
        Bulletin of the Chemical Society of Japan, 17 Jun. 2023
      • Asymmetric Metathesis Dimerization/Kinetic Resolution of Racemic Planar-Chiral Vinylphosphaferrocenes
        Kakeru Masaoka; Haruka Taue; Masayuki Wakioka; Yasuhiro Ohki; Masamichi Ogasawara
        Organometallics, 30 May 2023
      • Synthesis, Characterizations, and Catalytic Activity of a Cubic [Mo3S4Pd] Cluster Bearing Bulky Cyclopentadienyl Ligands
        Hitoshi Izu; Devashish Girish Bhave; Yuto Matsuoka; W. M. C. Sameera; Kazuki Tanifuji; Yasuhiro Ohki
        European Journal of Inorganic Chemistry, 31 Jul. 2023
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      • Competitive Double Friedel-Crafts 2,5-and 1 ',2-Diacylation of Monophosphaferrocenes
        Kakeru Masaoka; Haruka Taue; Tatsuya Higaki; Yasuhiro Ohki; Masamichi Ogasawara
        ORGANOMETALLICS, Jun. 2023
      • Flow-Chemistry-Enabled Synthesis of 5-Diethylboryl-2,3′-bipyridine and Its Self-Assembly Dynamics
        Shigeharu Wakabayashi; Masahiro Takumi; Shintaro Kamio; Masayuki Wakioka; Yasuhiro Ohki; Aiichiro Nagaki
        Chemistry - A European Journal, 10 Feb. 2023
      • Activation of unsaturated small molecules by bio-relevant multinuclear metal-sulfur clusters
        Kazuki Tanifuji; Shun Ohta; Yasuhiro Ohki; Hidetake Seino
        Coordination Chemistry Reviews, Jan. 2023
      • Diastereo- and Enantioselective Metathesis Dimerization/Kinetic Resolution of Racemic Planar-Chiral Vinylferrocenes
        Koji Nishimoto; Haruka Taue; Takehito Ohji; Sayaka Funakoshi; Yasuhiro Ohki; Masamichi Ogasawara
        Organic Letters, 03 Oct. 2022
      • CO Binding onto Heterometals of [Mo3S4M] (M = Fe, Co, Ni) Cubes
        Kazuki Tanifuji; Yuta Sakai; Yuto Matsuoka; Mizuki Tada; W. M. C. Sameera; Yasuhiro Ohki
        Bulletin of the Chemical Society of Japan, 15 Aug. 2022
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      • Incorporation of an Asymmetric Mo-Fe-S Cluster as an Artificial Cofactor into Nitrogenase.
        Kazuki Tanifuji; Andrew Jasniewski; Chi Chung Lee; Joseph Solomon; Takayuki Nagasawa; Yasuhiro Ohki; Kazuyuki Tatsumi; Britt Hedman; Keith Hodgson; Yilin Hu; Markus Walter Ribbe
        Chembiochem : a European journal of chemical biology, 04 Aug. 2022
      • Nitrogen reduction by the Fe sites of synthetic [Mo3S4Fe] cubes
        Yasuhiro Ohki; Kenichiro Munakata; Yuto Matsuoka; Ryota Hara; Mami Kachi; Keisuke Uchida; Mizuki Tada; Roger E. Cramer; W. M. C. Sameera; Tsutomu Takayama; Yoichi Sakai; Shogo Kuriyama; Yoshiaki Nishibayashi; Kazuki Tanifuji
        Nature, 07 Jul. 2022
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      • Synthesis of Monophosphaferrocenes Revisited
        Kakeru Masaoka; Manami Ohkubo; Haruka Taue; Masayuki Wakioka; Yasuhiro Ohki; Masamichi Ogasawara
        ChemistrySelect, 21 Jan. 2022
      • Tracing the incorporation of the “ninth sulfur” into the nitrogenase cofactor precursor with selenite and tellurite
        Kazuki Tanifuji; Andrew J. Jasniewski; David Villarreal; Martin T. Stiebritz; Chi Chung Lee; Jarett Wilcoxen; Yasuhiro Okhi; Ruchira Chatterjee; Isabel Bogacz; Junko Yano; Jan Kern; Britt Hedman; Keith O. Hodgson; R. David Britt; Yilin Hu; Markus W. Ribbe
        Nature Chemistry, Dec. 2021
      • Four-Electron Reduction of Dioxygen on a Metal Surface: Models of Dissociative and Associative Mechanisms in a Homogeneous System
        Hajime Kameo; Shigeyoshi Sakaki; Yasuhiro Ohki; Naoki Uehara; Takuya Kosukegawa; Hiroharu Suzuki; Toshiro Takao
        Inorganic Chemistry, 01 Feb. 2021
      • Cationic Ru-Se Complexes for Cooperative Si-H Bond Activation
        Marvin Oberling; Elisabeth Irran; Yasuhiro Ohki; Hendrik F.T. Klare; Martin Oestreich
        Organometallics, 28 Dec. 2020
      • Synthesis of Dinuclear Mo−Fe Hydride Complexes and Catalytic Silylation of N2
        Kodai Ishihara; Yuna Araki; Mizuki Tada; Tsutomu Takayama; Yoichi Sakai; W. M.C. Sameera; Yasuhiro Ohki
        Chemistry - A European Journal, 03 Aug. 2020
      • A dinuclear Mo2H8complex supported by bulky C5H2: T Bu3ligands
        Yasuhiro Ohki; Kodai Ishihara; Moeko Yaoi; Mizuki Tada; W. M.C. Sameera; Roger E. Cramer
        Chemical Communications, 25 Jul. 2020
      • Metal-Sulfur Compounds in N2 Reduction and Nitrogenase-Related Chemistry.
        Kazuki Tanifuji; Yasuhiro Ohki
        Chemical reviews, 24 Jun. 2020
      • Synthesis, Characterization, and Application of Segphos Derivative Having Diferrocenylphosphino-Donor Moieties
        Hao Hu; Hiroki Ichiryu; Naoki Seki; Kiyohiko Nakajima; Yasuhiro Ohki; Masamichi Ogasawara
        Organometallics, 23 Mar. 2020
      • Synthesis of [Mo 3 S 4 ] Clusters from Half-Sandwich Molybdenum(V) Chlorides and Their Application as Platforms for [Mo 3 S 4 Fe] Cubes
        Yasuhiro Ohki; Ryota Hara; Kenichiro Munakata; Mizuki Tada; Tsutomu Takayama; Yoichi Sakai; Roger E. Cramer
        Inorganic Chemistry, Apr. 2019
      • 3-[4′-(Diethylboryl)phenyl]pyridine: Exclusive Crystallization of the Cyclic Tetramer
        Shigeharu Wakabayashi; Natsu Sugiyama; Yasuhiro Ohki; Takahito Itoh; Toshikazu Kitagawa
        Chemistry - An Asian Journal, 15 Feb. 2019, Peer-reviewed
      • Chemical synthesis of an asymmetric mimic of the nitrogenase active site
        Kazuki Tanifuji; Yasuhiro Ohki
        Methods in Molecular Biology, 2019
      • N2 activation on a molybdenum–titanium–sulfur cluster
        Yasuhiro Ohki; Keisuke Uchida; Mizuki Tada; Roger E. Cramer; Takashi Ogura; Takehiro Ohta
        Nature Communications, 01 Dec. 2018
      • Cubane-Type [Mo3S4M] Clusters with First-Row Groups 4–10 Transition-Metal Halides Supported by C5Me5 Ligands on Molybdenum
        Yasuhiro Ohki; Keisuke Uchida; Ryota Hara; Mami Kachi; Mayu Fujisawa; Mizuki Tada; Yoichi Sakai; W. M.C. Sameera
        Chemistry - A European Journal, 16 Nov. 2018
      • Ambient conversion of CO2 to hydrocarbons by biogenic and synthetic [Fe4S4] clusters
        Martin T. Stiebritz; Caleb J. Hiller; Nathaniel S. Sickerman; Chi Chung Lee; Kazuki Tanifuji; Yasuhiro Ohki; Yilin Hu
        Nature Catalysis, 01 Jun. 2018
      • Tracing the 'ninth sulfur' of the nitrogenase cofactor via a semi-synthetic approach
        Kazuki Tanifuji; Chi Chung Lee; Nathaniel S. Sickerman; Kazuyuki Tatsumi; Yasuhiro Ohki; Yilin Hu; Markus W. Ribbe
        Nature Chemistry, 01 May 2018
      • Recent Advances in the Chemical Synthesis of Nitrogenase Model Clusters
        Kazuki Tanifuji; Yasuhiro Ohki
        Structure and Bonding, 2018
      • Synthesis and Characterization of Bioinspired [Mo2Fe2]–Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2
        Yasuhiro Ohki; Yuna Araki; Mizuki Tada; Yoichi Sakai
        Chemistry - A European Journal, 21 Sep. 2017
      • Impact of ligands and media on the structure and properties of biological and biomimetic iron-sulfur clusters
        Shun Ohta; Yasuhiro Ohki
        Coordination Chemistry Reviews, 01 May 2017
      • [Fe4] and [Fe6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N2 Reduction
        Ryoichi Araake; Kazuki Sakadani; Mizuki Tada; Yoichi Sakai; Yasuhiro Ohki
        Journal of the American Chemical Society, Apr. 2017
      • Reduction of C1, substrates to hydrocarbons by the homometallic precursor and synthetic mimic of the nitrogenase cofactor
        Nathaniel S. Sickerman; Kazuki Tanifuji; Chi Chung Lee; Yasuhiro Ohki; Kazuyuki Tatsumi; Markus W. Ribbe; Yilin Hu
        Journal of the American Chemical Society, 18 Jan. 2017
      • Co6H8(PiPr3)6: A Cobalt Octahedron with Face-Capping Hydrides
        Yasuhiro Ohki; Yuki Shimizu; Ryoichi Araake; Mizuki Tada; W. M.C. Sameera; Jun Ichi Ito; Hisao Nishiyama
        Angewandte Chemie - International Edition, 19 Dec. 2016
      • Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor
        Kazuki Tanifuji; Nathaniel Sickerman; Chi Chung Lee; Takayuki Nagasawa; Kosuke Miyazaki; Yasuhiro Ohki; Kazuyuki Tatsumi; Yilin Hu; Markus W. Ribbe
        Angewandte Chemie - International Edition, 12 Dec. 2016
      • N-Heterocyclic Carbene Complexes of Three-and Four-Coordinate Fe(I)
        Yasuhiro Ohki; Ryoko Hoshino; Kazuyuki Tatsumi
        Organometallics, 23 May 2016
      • Interconversion between [Fe4S4] and [Fe2S2] Clusters Bearing Amide Ligands
        Kazuki Tanifuji; Shunichi Tajima; Yasuhiro Ohki; Kazuyuki Tatsumi
        Inorganic Chemistry, 02 May 2016
      • Self-Assembly of 4-(Diethylboryl)pyridine: Crystal Structures of the Cyclic Pentamer and Hexamer and Their Solvent-Dependent Selective Crystallization
        Shigeharu Wakabayashi; Yuka Hori; Seiji Komeda; Yuki Shimizu; Yasuhiro Ohki; Misaki Horiuchi; Takahito Itoh; Yoshikazu Sugihara; Kazuyuki Tatsumi
        Journal of Organic Chemistry, 18 Mar. 2016
      • N-Heterocyclic carbenes as supporting ligands in transition metal complexes of N2
        Yasuhiro Ohki; Hidetake Seino
        Dalton Transactions, 21 Jan. 2016
      • Synthesis of dimethylmanganese(II) complexes bearing N-heterocyclic carbenes and nucleophilic substitution reaction of tetraalkoxysilanes by diorganomanganese(II) complexes
        Takayoshi Hashimoto; Yuko Kawato; Yumiko Nakajima; Yasuhiro Ohki; Kazuyuki Tatsumi; Wataru Ando; Kazuhiko Sato; Shigeru Shimada
        Journal of Organometallic Chemistry, 2016
      • Combining a Nitrogenase Scaffold and a Synthetic Compound into an Artificial Enzyme
        Kazuki Tanifuji; Chi Chung Lee; Yasuhiro Ohki; Kazuyuki Tatsumi; Yilin Hu; Markus W. Ribbe
        Angewandte Chemie - International Edition, 16 Nov. 2015
      • Synthesis and Protonation of N-Heterocyclic-Carbene-Supported Dinitrogen Complexes of Molybdenum(0)
        Yasuhiro Ohki; Keiya Aoyagi; Hidetake Seino
        Organometallics, 13 Jul. 2015
      • Mechanism of the cooperative Si-H bond activation at Ru-S bonds
        Timo Stahl; Peter Hrobárik; C. David F. Königs; Yasuhiro Ohki; Kazuyuki Tatsumi; Sebastian Kemper; Martin Kaupp; Hendrik F.T. Klare; Martin Oestreich
        Chemical Science, 01 Jul. 2015
      • Synthesis of V/Fe/S clusters using vanadium(III) thiolate complexes bearing a phenoxide-based tridentate ligand
        Nobuhiro Taniyama; Yasuhiro Ohki; Kazuyuki Tatsumi
        Inorganic Chemistry, 02 Jun. 2014
      • A convenient route to synthetic analogues of the oxidized form of high-potential iron-sulfur proteins
        Kazuki Tanifuji; Norihiro Yamada; Tomoyuki Tajima; Takahiro Sasamori; Norihiro Tokitoh; Tsukasa Matsuo; Kohei Tamao; Yasuhiro Ohki; Kazuyuki Tatsumi
        Inorganic Chemistry, Apr. 2014
      • Coupling of an N-heterocyclic carbene on iron with alkynes to form η5-cyclopentadienyl-diimine ligands
        Tsubasa Hatanaka; Yasuhiro Ohki; Kazuyuki Tatsumi
        Angewandte Chemie - International Edition, 03 Mar. 2014
      • Dinuclear iron(0) complexes of N-heterocyclic carbenes
        Takayoshi Hashimoto; Ryoko Hoshino; Tsubasa Hatanaka; Yasuhiro Ohki; Kazuyuki Tatsumi
        Organometallics, 24 Feb. 2014
      • Synthetic analogues of the active sites of nitrogenase and [NiFe] hydrogenase
        Yasuhiro Ohki
        Bulletin of the Chemical Society of Japan, 2014
      • Catalytic generation of borenium ions by cooperative B-H bond activation: The elusive direct electrophilic borylation of nitrogen heterocycles with pinacolborane
        Timo Stahl; Kristine Müther; Yasuhiro Ohki; Kazuyuki Tatsumi; Martin Oestreich
        Journal of the American Chemical Society, 31 Jul. 2013
      • Catalytic Generation of Borenium Ions by Cooperative B-H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane
        Timo Stahl; Kristine Muether; Yasuhiro Ohki; Kazuyuki Tatsumi; Martin Oestreich
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2013
      • New synthetic routes to metal-sulfur clusters relevant to the nitrogenase metallo-clusters
        Yasuhiro Ohki; Kazuyuki Tatsumi
        Zeitschrift fur Anorganische und Allgemeine Chemie, Jul. 2013
      • Synthesis of coordinatively unsaturated half-sandwich iron-silyl complexes with an N-heterocyclic carbene ligand and their reactions with H2
        Tsubasa Hatanaka; Yasuhiro Ohki; Kazuyuki Tatsumi
        European Journal of Inorganic Chemistry, 2013
      • An iron(II) complex of a diamine-bridged bis-N-heterocyclic carbene
        Christoph Grohmann; Takayoshi Hashimoto; Roland Fröhlich; Yasuhiro Ohki; Kazuyuki Tatsumi; Frank Glorius
        Organometallics, 10 Dec. 2012
      • A nitrogenase cluster model [Fe8S6O] with an oxygen unsymmetrically bridging two proto-Fe4s3 cubes: Relevancy to the substrate binding mode of the femo cofactor
        Shun Ohta; Yasuhiro Ohki; Takayoshi Hashimoto; Roger E. Cramer; Kazuyuki Tatsumi
        Inorganic Chemistry, 05 Nov. 2012
      • Formation of a nitrogenase P-cluster [Fe 8S 7] core via reductive fusion of two all-ferric [Fe 4S 4] clusters
        Yasuhiro Ohki; Kazuki Tanifuji; Norihiro Yamada; Roger E. Cramer; Kazuyuki Tatsumi
        Chemistry - An Asian Journal, Oct. 2012
      • Synthesis of bis(N-heterocyclic carbene) complexes of iron(II) and their application in hydrosilylation and transfer hydrogenation
        Takayoshi Hashimoto; Slawomir Urban; Ryoko Hoshino; Yasuhiro Ohki; Kazuyuki Tatsumi; Frank Glorius
        Organometallics, 25 Jun. 2012
      • Naphthalene and anthracene complexes sandwiched by two {(Cp*)Fe I} fragments: Strong electronic coupling between the Fe I centers
        Tsubasa Hatanaka; Yasuhiro Ohki; Takashi Kamachi; Tomonori Nakayama; Kazunari Yoshizawa; Motomi Katada; Kazuyuki Tatsumi
        Chemistry - An Asian Journal, Jun. 2012
      • Base-free dehydrogenative coupling of enolizable carbonyl compounds with silanes
        C. David F. Königs; Hendrik F.T. Klare; Yasuhiro Ohki; Kazuyuki Tatsumi; Martin Oestreich
        Organic Letters, 01 Jun. 2012
      • Non-centrosymmetric coordination polymer with a highly hindered octahedral copper center bridged by mandelate
        Makoto Moriya; Shingo Tominaga; Takayoshi Hashimoto; Kazuki Tanifuji; Tsuyoshi Matsumoto; Yasuhiro Ohki; Kazuyuki Tatsumi; Junichi Kaneshiro; Yoshiaki Uesu; Wataru Sakamoto; Toshinobu Yogo
        Inorganic Chemistry, Apr. 2012
      • Oxido-bridged di-, tri-, and tetra-nuclear iron complexes bearing bis(trimethylsilyl)amide and thiolate ligands
        Shun Ohta; Saori Yokozawa; Yasuhiro Ohki; Kazuyuki Tatsumi
        Inorganic Chemistry, 20 Feb. 2012
      • Synthetic analogues of [Fe 4S 4(Cys) 3(His)] in hydrogenases and [Fe 4S 4(Cys) 4] in HiPIP derived from all-ferric [Fe 4S 4{N(SiMe 3) 2} 4]
        Yasuhiro Ohki; Kazuki Tanifuji; Norihiro Yamada; Motosuke Imada; Tomoyuki Tajima; Kazuyuki Tatsumi
        Proceedings of the National Academy of Sciences of the United States of America, 02 Aug. 2011
      • Synthetic analogues of [Fe4S4(Cys)(3)(His)] in hydrogenases and [Fe4S4(Cys)(4)] in HiPIP derived from all-ferric [Fe4S4{N(SiMe3)(2)}(4)]
        Yasuhiro Ohki; Kazuki Tanifuji; Norihiro Yamada; Motosuke Imada; Tomoyuki Tajima; Kazuyuki Tatsumi
        PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, Aug. 2011, Peer-reviewed
      • Cooperative catalytic activation of Si-H bonds by a polar Ru-S bond: Regioselective low-temperature c-h silylation of indoles under neutral conditions by a Friedel-crafts mechanism
        Hendrik F.T. Klare; Martin Oestreich; Jun Ichi Ito; Hisao Nishiyama; Yasuhiro Ohki; Kazuyuki Tatsumi
        Journal of the American Chemical Society, 16 Mar. 2011, Peer-reviewed
      • Thiolate-bridged iron-nickel models for the active site of [NiFe] hydrogenase
        Yasuhiro Ohki; Kazuyuki Tatsumi
        European Journal of Inorganic Chemistry, Mar. 2011
      • Cooperative Catalytic Activation of Si-H Bonds by a Polar Ru-S Bond: Regioselective Low-Temperature C-H Silylation of Indoles under Neutral Conditions by a Friedel-Crafts Mechanism
        Hendrik F. T. Klare; Martin Oestreich; Jun-ichi Ito; Hisao Nishiyama; Yasuhiro Ohki; Kazuyuki Tatsumi
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2011
      • Exploring the limits of frustrated Lewis pair chemistry with alkynes: Detection of a system that favors 1,1-carboboration over cooperative 1,2-P/B-addition
        Chao Chen; Florian Eweiner; Birgit Wibbeling; Roland Fröhlich; Shunsuke Senda; Yasuhiro Ohki; Kazuyuki Tatsumi; Stefan Grimme; Gerald Kehr; Gerhard Erker
        Chemistry - An Asian Journal, 04 Oct. 2010
      • Bio-Inspired Iron and Nickel Complexes: Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates
        Yasuhiro Ohki; Shun Ohta; Kazuyuki Tatsumi; Luke M. Davis; Gregory S. Girolami; Aaron M. Royer; Thomas B. Rauchfuss
        Inorganic Syntheses, 08 Sep. 2010
      • Bio-Inspired Iron and Nickel Complexes: (1,3-Propanedithiolato)-Hexacarbonyldiiron and Cyanide Derivatives
        Amanda E. Mack; Thomas B. Rauchfuss; Koshi Ohnishi; Yasuhiro Ohki; Kazuyuki Tatsumi
        Inorganic Syntheses, 08 Sep. 2010
      • An iron(II) carbonyl thiolato complex bearing 2-methoxy-pyridine: A structural model of the active site of [Fe] hydrogenase
        Soichiro Tanino; Yasuhiro Ohki; Kazuyuki Tatsumi
        Chemistry - An Asian Journal, 03 Sep. 2010
      • C-H bond activation/borylation of furans and thiophenes catalyzed by a half-sandwich iron N-heterocyclic carbene complex
        Tsubasa Hatanaka; Yasuhiro Ohki; Kazuyuki Tatsumi
        Chemistry - An Asian Journal, 05 Jul. 2010
      • Synthesis of coordinatively unsaturated mesityliron thiolate complexes and their reactions with elemental sulfur
        Takayoshi Hashimoto; Yasuhiro Ohki; Kazuyuki Tatsumi
        Inorganic Chemistry, 05 Jul. 2010
      • Synthesis and reactions of coordinatively unsaturated half-sandwich rhodium and iridium complexes having a 2,6-dimesitylbenzenethiolate ligand
        Mayumi Sakamoto; Yasuhiro Ohki; Kazuyuki Tatsumi
        Organometallics, Apr. 2010
      • A model for the CO-inhibited form of [NiFe] hydrogenase: Synthesis of (CO)3Fe(μ-StBu)3Ni{SC6H 3-2, 6-(mesityl)2} and reversible CO addition at the Ni site
        Yasuhiro Ohki; Kazunari Yasumura; Masaru Ando; Satoko Shimokata; Kazuyuki Tatsumi
        Proceedings of the National Academy of Sciences of the United States of America, 02 Mar. 2010
      • Methodology for phase selection of a weak basic drug candidate, utilizing kinetic solubility profiles in bio-relevant media
        Furukawa Shuntaro; Zhao Chenhua; Ohki Yasuhiro
        EUROPEAN JOURNAL OF PHARMACEUTICS AND BIOPHARMACEUTICS, Feb. 2010
      • Evidence for a rapid degenerate hetero-cope-type rearrangement in [Cp*W(S) 2S-CH2-CH=CH2]
        Florian Eweiner; Shunsuke Senda; Klaus Bergander; Christian Mück-Lichtenfeld; Stefan Grimme; Roland Fröhlich; Michiko Aoyama; Hiroyuki Kawaguchi; Yasuhiro Ohki; Tsuyoshi Matsumoto; Gerald Kehr; Kazuyuki Tatsumi; Gerhard Erker
        Chemistry - An Asian Journal, 01 Dec. 2009
      • Synthesis, structures, and electronic properties of [8Fe-7S] cluster complexes modeling the nitrogenase P-cluster
        Yasuhiro Ohki; Motosuke Imada; Ayuro Murata; Yusuke Sunada; Shun Ohta; Masaru Honda; Takahiro Sasamori; Norihiro Tokitoh; Motomi Katada; Kazuyuki Tatsumi
        Journal of the American Chemical Society, 16 Sep. 2009
      • Catalytic hydrogenation of C{double bond, long}O and C{double bond, long}N bonds via heterolysis of H2 mediated by metal-sulfur bonds of rhodium and iridium thiolate complexes
        Mayumi Sakamoto; Yasuhiro Ohki; Gerald Kehr; Gerhard Erker; Kazuyuki Tatsumi
        Journal of Organometallic Chemistry, 01 Aug. 2009
      • Dithiolate-bridged Fe-Ni-Fe trinuclear complexes consisting of Fe(CO) 3-n(CN)n(n=0, 1) components relevant to the active site of [NiFe] hydrogenase
        Satyanarayan Pal; Yasuhiro Ohki; Teppei Yoshikawa; Katsuaki Kuge; Kazuyuki Tatsumi
        Chemistry - An Asian Journal, 02 Jun. 2009
      • C-H bond activation of decamethylcobaltocene mediated by a nitrogenase Fe8S7 P-cluster model
        Yasuhiro Ohki; Ayuro Murata; Motosuke Imada; Kazuyuki Tatsumi
        Inorganic Chemistry, 18 May 2009
      • Organometallic chemistry in [NiFe] hydrogenases: Synthesis of the structural and functional models
        Tsuyoshi Matsumoto; Yasuhiro Ohki; Kazuyuki Tatsumi
        Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, May 2009
      • A dithiolate-bridged (CN)2(CO)Fe-Ni complex reproducing the IR bands of [NiFe] hydrogenase
        Soichiro Tanino; Zilong Li; Yasuhiro Ohki; Kazuyuki Tatsumi
        Inorganic Chemistry, 16 Mar. 2009
      • C-H bond activation of heteroarenes mediated by a half-sandwich iron complex of N-heterocyclic carbene
        Yasuhiro Ohki; Tsubasa Hatanaka; Kazuyuki Tatsumi
        Journal of the American Chemical Society, 17 Dec. 2008
      • Heterolytic cleavage of dihydrogen by frustrated Lewis Pairs derived from α-(dimesitylphosphino)ferrocenes and B(C6F5) 3
        Dominique P. Huber; Gerald Kehr; Klaus Bergander; Roland Fröhlich; Gerhard Erker; Soichiro Tanino; Yasuhiro Ohki; Kazuyuki Tatsumi
        Organometallics, 27 Oct. 2008
      • Reversible heterolysis of H2 mediated by an M-S(Thiolate) bond (M = Ir, Rh): A mechanistic implication for [NiFe] hydrogenase
        Yasuhiro Ohki; Mayumi Sakamoto; Kazuyuki Tatsumi
        Journal of the American Chemical Society, 03 Sep. 2008
      • Reactions at the Ru-S bonds of coordinatively unsaturated ruthenium complexes with tethered 2,6-dimesitylphenyl thiolate
        Yasuhiro Ohki; Yuko Takikawa; Hitomi Sadohara; Christian Kesenheimer; Barthel Engendahl; Elissavet Kapatina; Kazuyuki Tatsumi
        Chemistry - An Asian Journal, 01 Sep. 2008
      • Thiolate-bridged dinuclear iron(tris-carbonyl)-nickel complexes relevant to the active site of [NiFe] hydrogenase
        Yasuhiro Ohki; Kazunari Yasumura; Katsuaki Kuge; Soichiro Tanino; Masaru Ando; Zilong Li; Kazuyuki Tatsumi
        Proceedings of the National Academy of Sciences of the United States of America, 03 Jun. 2008
      • Trithio-chloro molybdate [MoClS3]-: A versatile precursor for molybdenum trisulfido complexes
        Jun Ichi Ito; Yasuhiro Ohki; Masatoshi Iwata; Kazuyuki Tatsumi
        Inorganic Chemistry, 05 May 2008
      • 3-(Dimethylboryl)pyridine: Synthesis, structure, and remarkable steric effects in scrambling reactions
        Shigeharu Wakabayashi; Saori Imamura; Yoshikazu Sugihara; Makoto Shimizu; Toshikazu Kitagawa; Yasuhiro Ohki; Kazuyuki Tatsumi
        Journal of Organic Chemistry, 04 Jan. 2008
      • Synthesis and dehydrogenation of M(AlH4)2 (M = Mg, Ca)
        K. Komiya; N. Morisaku; Y. Shinzato; K. Ikeda; S. Orimo; Y. Ohki; K. Tatsumi; H. Yukawa; M. Morinaga
        Journal of Alloys and Compounds, 31 Oct. 2007
      • Synthesis and characterization of heteroleptic iron(II) thiolate complexes with weak iron-arene interactions
        Shun Ohta; Yasuhiro Ohki; Yohei Ikagawa; Rie Suizu; Kazuyuki Tatsumi
        Journal of Organometallic Chemistry, 01 Oct. 2007
      • Synthesis of new [8Fe-7S] clusters: A topological link between the core structures of P-cluster, FeMo-co, and FeFe-co of nitrogenases
        Yasuhlro Ohki; Yohei Ikagawa; Kazuyuki Tatsumi
        Journal of the American Chemical Society, 29 Aug. 2007
      • Dinitrogen activation by group 4 metal complexes
        Yasuhiro Ohki; Michael D. Fryzuk
        Angewandte Chemie - International Edition, 2007
      • Theory of chemical bonds in metalloenzymes V: Hybrid-DFT studies of the inorganic [8Fe-7S] core
        M. Shoji; K. Koizumi; Y. Kitagawa; S. Yamanaka; M. Okumura; K. Yamaguchi; Y. Ohki; Y. Sunada; M. Honda; K. Tatsumi
        International Journal of Quantum Chemistry, Dec. 2006
      • Mono{hydrotris(mercaptoimidazolyl)borato} complexes of manganese(II), iron(II), cobalt(II), and nickel(II) halides
        Shunsuke Senda; Yasuhiro Ohki; Tomoko Hirayama; Daisuke Toda; Jing Lin Chen; Tsuyoshi Matsumoto; Hiroyuki Kawaguchi; Kazuyuki Tatsumi
        Inorganic Chemistry, 27 Nov. 2006
      • Reductive N-N bond cleavage of diphenylhydrazine and azobenzene induced by coordinatively unsaturated Cp*Fe{N(SiMe3)2}
        Yasuhiro Ohki; Yuko Takikawa; Tsubasa Hatanaka; Kazuyuki Tatsumi
        Organometallics, 19 Jun. 2006
      • Sulfido-bridged dinuclear molybdenum-copper complexes related to the active site of CO dehydrogenase: [(dithiolate)Mo(O)S2Cu(SAr)] 2-(dithiolate = 1,2-S2C6H4, 1,2-S2C6H2-3,6-Cl2, 1,2-S 2C2H4)
        Motoki Takuma; Yasuhiro Ohki; Kazuyuki Tatsumi
        Inorganic Chemistry, 22 Aug. 2005
      • Dithiolato-bridged dinuclear iron-nickel complexes [Fe(CO) 2(CN)2(μ-SCH2CH2CH 2S)Ni(S2CNR2)]- modeling the active site of [NiFe] hydrogenase
        Zilong Li; Yasuhiro Ohki; Kazuyuki Tatsumi
        Journal of the American Chemical Society, 29 Jun. 2005
      • A facile method for synthesis of (R)-(-)- and (S)-(+)-homocitric acid lactones and related α-hydroxy dicarboxylic acids from D- or L-malic acid
        Peng Fei Xu; Tsuyoshi Matsumoto; Yasuhiro Ohki; Kazuyuki Tatsumi
        Tetrahedron Letters, 30 May 2005
      • Molybdenum carbonyl complexes with citrate and its relevant carboxylates
        Motoki Takuma; Yasuhiro Ohki; Kazuyuki Tatsumi
        Organometallics, 14 Mar. 2005
      • Synthesis of [2Fe-2S] and [4Fe-4S] clusters having terminal amide ligands from an iron(II) amide complex
        Yasuhiro Ohki; Yusuke Sunada; Kazuyuki Tatsumi
        Chemistry Letters, 05 Feb. 2005
      • Elimination-addition mechanism for nucleophilic substitution reaction of cyclohexenyl iodonium salts and regioselectivity of nucleophilic addition to the cyclohexyne intermediate
        Morifumi Fujita; Wan Hyeok Kim; Yuichi Sakanishi; Koji Fujiwara; Sayaka Hirayama; Tadashi Okuyama; Yasuhiro Ohki; Kazuyuki Tatsumi; Yasunori Yoshioka
        Journal of the American Chemical Society, 23 Jun. 2004
      • A half-sandwich ruthenium(II) complex containing a coordinatively unsaturated 2,6-dimesitylphenyl thiolate ligand
        Yasuhiro Ohki; Hitomi Sadohara; Yuko Takikawa; Kazuyuki Tatsumi
        Angewandte Chemie - International Edition, Apr. 2004
      • Heterolytic cleavage of dihydrogen promoted by sulfido-bridged tungsten-ruthenium dinuclear complexes
        Yasuhiro Ohki; Nobuo Matsuura; Tadashi Marumoto; Hiroyuki Kawaguchi; Kazuyuki Tatsumi
        Journal of the American Chemical Society, 02 Jul. 2003
      • Synthesis of the P-cluster inorganic core of nitrogenases
        Yasuhiro Ohki; Yusuke Sunada; Masaru Honda; Motomi Katada; Kazuyuki Tatsumi
        Journal of the American Chemical Society, Apr. 2003
      • Pentanuclear polyhydride cluster of ruthenium with trigonal-bipyramidal geometry. Synthesis and fluxional behavior
        Yasuhiro Ohki; Naoki Uehara; Hiroharu Suzuki
        Organometallics, 06 Jan. 2003
      • Rational synthesis of tetranuclear ruthenium polyhydride clusters and their mixed-ligand analogues
        Yasuhiro Ohki; Naoki Uehara; Hiroharu Suzuki
        Angewandte Chemie - International Edition, 04 Nov. 2002
      • Migration of a phosphane ligand between the two metal centers in diruthenium hydrido complexes
        Yasuhiro Ohki; Hiroharu Suzuki
        Angewandte Chemie - International Edition, 16 Aug. 2002
      • {(η5-C5Me5)Fe}2 (μ-H)2(μ-η2:η2-H2 SitBu2), a versatile precursor for bimetallic active species
        Yasuhiro Ohki; Takahiro Kojima; Masato Oshima; Hiroharu Suzuki
        Organometallics, 25 Jun. 2001
      • Novel mode of C-C bond cleavage of norbornadiene on a dinuclear ruthenium complex
        Yasuhiro Ohki; Hiroharu Suzuki
        Angewandte Chemie - International Edition, 02 Oct. 2000
      • [{(η5-C5Me5)Fe}2(μ-H)4]: A novel dinuclear iron tetrahydrido complex
        Yasuhiro Ohki; Hiroharu Suzuki
        Angewandte Chemie - International Edition, 01 Sep. 2000

      Misc.

      • 高電位鉄硫黄タンパク(HiPIP)を模倣する[Fe4S4]クラスターの合成と構造
        谷藤一樹; 山田昇広; 田嶋智之; 大木靖弘; 巽和行
        日本化学会講演予稿集, 2013
      • アミド配位子を持つ高酸化型[4Fe-4S]クラスターの配位子置換反応と[Fe-4Fe-4S]クラスター化反応
        谷藤一樹; 山田昇広; 田嶋智之; 大木靖弘; 巽和行
        日本化学会講演予稿集, 2012
      • かさ高いチオラート配位子を有する高酸化型[4Fe-4S]クラスターおよび[Fe-4Fe-4S]クラスターの合成
        谷藤一樹; 山田昇広; 田嶋智之; 大木靖弘; 巽和行
        錯体化学会討論会講演要旨集, 2011
      • かさ高いチオラート配位子を持つ高酸化型[4Fe-4S]クラスターの合成と配位子置換反応
        谷藤一樹; 山田昇広; 田嶋智之; 大木靖弘; 笹森貴裕; 時任宣博; 巽和行
        日本化学会講演予稿集, 2010
      • 高酸化型[Fe4S4]クラスターの配位子置換反応と[Fe-Fe4S4]クラスター化反応
        谷藤一樹; 山田昇広; 田嶋智之; 大木靖弘; 巽和行
        錯体化学討論会講演要旨集, 2010
      • 高電位鉄硫黄タンパク(HiPIP)を模倣する[4Fe-4S]クラスターの合成と配位子置換反応
        谷藤一樹; 山田昇広; 田嶋智之; 大木靖弘; 巽和行
        錯体化学討論会講演要旨集, 2009
      • Synthesis of [4Fe-4S] Clusters Relevant to the Active Centers of HiPIP and Aconitase
        谷藤一樹; 山田昇広; 田嶋智之; 大木靖弘; 巽和行
        日本化学会講演予稿集, 2009
      • 酵素ニトロゲナーゼを模した合成金属錯体による窒素分子の還元
        谷藤 一樹; 大木 靖弘
        バイオサイエンスとインダストリー, Jan. 2023
      • 酵素を模倣した金属-硫黄化合物による窒素の還元
        大木 靖弘; 谷藤 一樹
        クリーンエネルギー, Dec. 2022
      • 有機金属化学に関わる金属-硫黄クラスターによる小分子の活性化および変換反応—Metal-Sulfur Clusters with Relevance to Organometallic Chemistry for Small Molecule Activation and Transformation
        谷藤 一樹; 大木 靖弘; 清野 秀岳
        有機合成化学協会誌 = Journal of synthetic organic chemistry, Japan, Sep. 2022
      • アンモニア合成の最新動向 自然界におけるアンモニア合成(窒素固定化)の化学的理解に向けて
        大木靖弘
        月刊ファインケミカル, 2016
      • Recent Progress in Research on the Structures and Functions of Nitrogenase Active Sites
        大木靖弘
        Bulletin of Japan Society of Coordination Chemistry, 2015
      • [NiFe]ヒドロゲナーゼ活性中心のモデル研究における潮流と展望—特集 生物無機化学のこれから
        大木 靖弘
        Bulletin of Japan Society of Coordination Chemistry, Nov. 2013
      • 多核金属錯体の生体機能—有機金属化学の最前線--多様な元素を使いこなす ; 高周期金属化合物の化学
        大木 靖弘
        現代化学 : 増刊, Mar. 2011
      • 硫酸還元菌は水素燃料電池のお手本? 反応の鍵を握る酵素〔NiFe〕ヒドロゲナーゼの無機化学—Inorganic chemistry of 〔Nipe〕 hydrogenase: a key element to future fuel cell technology learning from sulfate-reducing bacteria
        大木 靖弘
        硫酸と工業, Jan. 2010
      • Syntheses of Metal-Sulfur Complexes Modeling the Active Sites of Nitrogenase and [NiFe] Hydrogenase
        OHKI YASUHIRO; TATSUMI KAZUYUKI
        觸媒 = Catalyst, 10 Dec. 2009

      Awards

      • 23 Mar. 2023
        公益社団法人日本化学会, 学術賞(公益社団法人日本化学会)
      • 13 Apr. 2009
        Ministry of Education, Culture, Sports, Science and Technology, The Young Scientists' Prize (The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology)
      • 25 Mar. 2009
        Japanese Chemical Society, Chemical Society of Japan Award for Young Chemists
      • 22 Sep. 2004
        Japan Society of Coordination Chemistry, Japan Society of Coordination Chemistry Award for Young Chemists

      External funds: Kakenhi

      • Synthesis and Reactions of Bio-inspired Molecular Metal-Hydride Compounds
        Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
        Science and Engineering
        Kyoto University
        大木 靖弘
        From 01 Apr. 2021, To 31 Mar. 2023, Project Closed
        多座配位子;ヒドリド;架橋配位子;分子触媒
        https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-21H00021/
      • Synthesis of Metal-Nanoclusters of Iron Group Metals
        Grant-in-Aid for Challenging Research (Exploratory)
        Medium-sized Section 34:Inorganic/coordination chemistry, analytical chemistry, and related fields
        Kyoto University
        Yasuhiro Ohki
        From 30 Jul. 2020, To 31 Mar. 2023, Project Closed
        鉄;ホスフィン;ホウ素;アミド;コバルト;ニッケル;クラスター;ヒドリド
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20K21207/
      • Synthesis and Reactions of Mo-Fe-S Clusters Toward Understanding of the Mechanism of Nitrogenase
        Grant-in-Aid for Scientific Research (B)
        Basic Section 34010:Inorganic/coordination chemistry-related
        Kyoto University;Nagoya University
        Yasuhiro Ohki
        From 01 Apr. 2019, To 31 Mar. 2022, Project Closed
        鉄;モリブデン;硫黄;ニトロゲナーゼ;窒素固定;窒素
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19H02733/
      • Precise Formation of Dinuclear Organometallic Reaction Sites and their Application in Difficult Substrate Reductions
        Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
        Nagoya University
        大木 靖弘
        From 01 Apr. 2018, To 31 Mar. 2020, Project Closed
        モリブデン;鉄;ヒドリド;二核錯体;還元反応;窒素;シリル化;有機金属錯体
        https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-18H04246/
      • Synthesis of Cp*-supported metal-sulfur clusters as functional analogues of the active site of nitrogenase
        Grant-in-Aid for Scientific Research (B)
        Nagoya University
        Yasuhiro Ohki
        From 01 Apr. 2016, To 31 Mar. 2019, Project Closed
        窒素固定化;ニトロゲナーゼ;金属-硫黄クラスター;モリブデン;チタン;窒素;硫黄;クラスター;鉄;窒素活性化;金属;酵素モデル
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16H04116/
      • Synthesis of Well-Defined Subnano-Sized Metal Cluster Molecules
        Grant-in-Aid for Challenging Exploratory Research
        Nagoya University
        Yasuhiro Ohki
        From 01 Apr. 2015, To 31 Mar. 2017, Project Closed
        クラスター;鉄;コバルト;ヒドリド;ホスフィン
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K13655/
      • 非在来型-金属硫黄クラスターの構造モデル創製と性質
        Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
        Science and Engineering
        Nagoya University
        大木 靖弘
        From 01 Apr. 2015, To 31 Mar. 2017, Project Closed
        クラスター;金属;硫黄;酵素;活性中心;鉄
        https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-15H00936/
      • [NiFe]ヒドロゲナーゼに学ぶ感応性モデル錯体の合成と水素分子代謝
        Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
        Science and Engineering
        Nagoya University
        大木 靖弘
        From 01 Apr. 2013, To 31 Mar. 2015, Project Closed
        ヒドロゲナーゼ;鉄;ニッケル;チオラート;水素
        https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-25109522/
      • 遷移金属と硫黄がともに関わる結合活性化反応と分子変換
        Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
        Science and Engineering
        Nagoya University
        大木 靖弘
        From 01 Apr. 2013, To 31 Mar. 2015, Project Closed
        ルテニウム;チオラート;ヘテロリシス;ヒドロシラン;配位不飽和錯体;硫黄;ヒドロボラン
        https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-25105725/
      • Synthesis and Properties of Metal-Sulfur Clusters Consisting of Multiple Components
        Grant-in-Aid for Young Scientists (A)
        Nagoya University
        Yasuhiro OHKI
        From 01 Apr. 2011, To 31 Mar. 2014, Project Closed
        鉄;硫黄;クラスター;ニトロゲナーゼ;一酸化炭素デヒドロゲナーゼ;金属-硫黄クラスター;COデヒドロゲナーゼ
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23685015/
      • Bioinorganic Chemistry of Oxidoreductases having Unique Active Site Clusters
        Grant-in-Aid for Specially Promoted Research
        Science and Engineering
        Nagoya University
        Kazuyuki TATSUMI
        From 01 Apr. 2011, To 31 Mar. 2016, Project Closed
        酸化還元金属酵素;金属クラスター;ニトロゲナーゼ;ヒドロゲナーゼ;アセチルCoA 合成酵素;光化学系II酸素発生中心;プロトクロロフィリド還元酵素;クラスター;酸化還元酵素;COデヒドロゲナーゼ;プロトクロコフィリド還元酵素;COヒドロゲナーゼ;活性中心モデル;酸素発生中心
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23000007/
      • Synthesis of Coordinatively Unsaturated Iron Complexes and C-H Bond Activation
        Grant-in-Aid for Scientific Research (C)
        Nagoya University
        Yasuhiro OHKI
        From 01 Apr. 2008, To 31 Mar. 2011, Project Closed
        鉄;C-H結合活性化;配位不飽和;有機金属;触媒;有機金属錯体;N-ヘテロ環カルベン
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20613004/
      • Organometallic and Cluster Chemistry in M+I40etalloenzymes with Reducing Activities
        Grant-in-Aid for Creative Scientific Research
        Nagoya University
        Kazuyuki TATSUMI
        From 01 Apr. 2006, To 31 Mar. 2011, Project Closed
        金属-硫黄クラスター;ニトロゲナーゼ;ヒドロゲナーゼ;還元系金属酵素;金属硫黄クラスター;小分子活性化;アセチルCoA合成酵素;COデヒドロゲナーゼ;有機金属化学;金属酵素
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18GS0207/
      • 活性化フェレドキシン型金属錯体の創出と触媒機能の開拓
        Grant-in-Aid for Young Scientists (B)
        Nagoya University
        大木 靖弘
        From 01 Apr. 2006, To 31 Mar. 2008, Project Closed
        フェレドキシン;鉄;硫黄;クラスター;アコニターゼ;窒素活性化;触媒;アミド
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18750045/
      • Design and Synthesis of Transition Metal-Chalcogen Compounds
        Grant-in-Aid for Scientific Research on Priority Areas
        Science and Engineering
        Nagoya University
        Ohki YASUHIRO;Yasuhiro OHKI
        From 01 Apr. 2006, To 31 Mar. 2010, Project Closed
        遷移金属;硫黄;クラスター;集積化;カルコゲン;金属-硫黄クラスター;ニトロゲナーゼ;ヒドロゲナーゼ;小分子活性化;C-H結合活性化;鉄;チオラート;自己集積化;錯体
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18064009/
      • 金属-硫黄部位を有する酵素活性中心のモデル化研究
        Grant-in-Aid for Scientific Research on Priority Areas
        Science and Engineering
        Nagoya University
        大木 靖弘
        From 01 Apr. 2005, To 31 Mar. 2006, Project Closed
        ニトロゲナーゼ;チオラート;鉄硫黄クラスター;FeMo-cofactor;ヒドロゲナーゼ;ニッケル;鉄;アミド錯体
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17036020/
      • Reproduction of the Structure and the Function of Hydrogenase Active Sites
        Grant-in-Aid for Scientific Research (B)
        Nagoya University
        Kazuyuki TATSUMI
        From 01 Apr. 2004, To 31 Mar. 2006, Project Closed
        ヒドロゲナーゼ;鉄;ニッケル;チオラート;シアノ基;カルボニル基;水素活性化;二核錯体;水素;一酸化炭素;多核錯体;金属酵素, hydrogenase;iron;nickel;thiolate;cyanide;carbonyl;activation of hydrogen molecule;dinuclear complex
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16350031/
      • ニトロゲナーゼ活性部位のモデル構築と機能
        Grant-in-Aid for Young Scientists (B)
        Nagoya University
        大木 靖弘
        From 01 Apr. 2003, To 31 Mar. 2005, Project Closed
        鉄-硫黄クラスター;ニトロゲナーゼ;チオラート;P-cluster;ルテニウム;タングステン;アミド錯体;水素活性化;鉄(II)アミド錯体;硫黄;チオ尿素
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15750047/
      • Rational Synthesis of Dynamic Complexes of Mezzoscopic-size
        Grant-in-Aid for Scientific Research on Priority Areas
        Science and Engineering
        Nagoya University
        Kazuyuki TATSUMI
        From 01 Apr. 2002, To 31 Mar. 2006, Project Closed
        動的錯体;自在構築;メゾスコピック;金属チオラート;金属クラスター;金属酵素モデル;ニトロゲナーゼ;ヒドロゲナーゼ;鉄硫黄クラスター;P-クラスター;FeMo-co;チオラート;スルフィド;鉄;モリブデン;タングステン;金属酵素;チオラート錯体;ニッケル;無機ポリマー;クラスター;環状クラスター錯体, Dynamic Complexes;Rational Synthesis;Mezzoscopic;Thiolate Complexes;Metal Cluster;Metalloenzymes Model;Nitrogenase;Hydrogenase
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-14078211/
      • 遷移金属カルコゲニド錯体の特性を利用した新規メタラサイクルの合成と機能解明
        Grant-in-Aid for Scientific Research on Priority Areas
        Science and Engineering
        Nagoya University
        松本 剛
        From 01 Apr. 2002, To 31 Mar. 2004, Project Closed
        カルコゲン;ヒドロゲナーゼ;水素分子活性化;架橋ヒドロキシル基;ゲルマニウム;ルテニウム;ヒドリド錯体;メタラサイクル;付加環化;アルキンチオラート;ロジウム;イリジウム;ベンゾチオフェン;カップリング
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-14044037/
      • Construction of Transition Metal Chalcogenide Clusters and Their Functions
        Grant-in-Aid for Scientific Research (A)
        Nagoya University
        Kazuyuki TATSUMI
        From 01 Apr. 2001, To 31 Mar. 2004, Project Closed
        遷移金属チオラート錯体;遷移金属スルフィド錯体;遷移金属チアリル錯体;アルキンチオラート;ジインチオラート;無機ポリマー;水素分子活性化;金属クラスター;クラスター;チオラート;シリルチオラート;シリル-硫黄結合切断;鉄;銅;チタン;モリブデン;カルコゲン;イオウ;ゲルマニウム;ルテニウム;ニッケル, Transition Metal Thiolato Complex;Transition Metal Sulfido Complex;Transition Metal Thiallyl Complex;Alkynethiolate;Diynethiolate;Inorganic Polymer;Activation of Hydrogen Molecule;Metal Cluster
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13304052/
      • 遷移金属カルコゲニド錯体の特性を利用した新規メタラサイクルの合成と機能解明
        Grant-in-Aid for Scientific Research on Priority Areas (A)
        Science and Engineering
        Nagoya University
        巽 和行
        From 01 Apr. 2001, To 31 Mar. 2002, Project Closed
        カルコゲン;メタラサイクル;硫黄;付加環化;末端カルコゲニド;アルキンカルコゲノラート;ニッケル
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13029043/
      • Study on Fuel Regeneration from CO2 by Biomimetic Catalysts on Functionalized Silica
        Grant-in-Aid for JSPS Fellows
        Basic Section 34010:Inorganic/coordination chemistry-related
        Kyoto University
        From 16 Nov. 2022, To 31 Mar. 2025, Granted
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22F22342/
      • Synthesis of Iron-Containing Cluster Complexes and Reducing Reactions with Multiple Metals
        Grant-in-Aid for Scientific Research (B)
        Basic Section 34010:Inorganic/coordination chemistry-related
        Kyoto University
        大木 靖弘
        From 01 Apr. 2023, To 31 Mar. 2026, Granted
        鉄;クラスター;錯体;還元反応
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23H01974/
      • Fuel Regeneration from CO2 by Grid-Aligned Biomimetic Catalysts on Functionalized Silica
        Grant-in-Aid for JSPS Fellows
        Basic Section 34010:Inorganic/coordination chemistry-related
        Kyoto University
        大木 靖弘
        From 08 Mar. 2023, To 31 Mar. 2025, Granted
        鉄;硫黄;クラスター;錯体;一酸化炭素
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22KF0217/
      • Synthesis of Iron-Containing Cluster Complexes and Reducing Reactions with Multiple Metals
        Grant-in-Aid for Scientific Research (B)
        Basic Section 34010:Inorganic/coordination chemistry-related
        Kyoto University
        大木 靖弘
        From 01 Apr. 2023, To 31 Mar. 2026, Granted
        鉄;クラスター;錯体;還元反応
        https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23K26667/

      External funds: others

      • Electron Transfer Networks of Transition Metal Cluster Complexes for Catalytic Applications
        CREST
        From 01 Oct. 2021, To 31 Mar. 2027
        大木靖弘
      list
        Last Updated :2025/04/23

        Education

        Teaching subject(s)

        • From 01 Apr. 2024, To 31 Mar. 2025
          Inorganic Chemistry II (Advanced Chemistry)
          7415, Spring, Faculty of Engineering, 2
        • From 01 Apr. 2024, To 31 Mar. 2025
          Dimensional Control and Micro-Nano Systems
          H403, Fall, Graduate School of Engineering, 1.5
        • From 01 Apr. 2024, To 31 Mar. 2025
          Chemistry of Well-Defined Catalysts
          H226, Fall, Graduate School of Engineering, 1.5
        • From 01 Apr. 2023, To 31 Mar. 2024
          Inorganic Chemistry II (Advanced Chemistry)
          7415, Spring, Faculty of Engineering, 2
        • From 01 Apr. 2023, To 31 Mar. 2024
          Organotransition Metal Chemistry 2
          H042, Spring, Graduate School of Engineering, 1.5
        • From 01 Apr. 2023, To 31 Mar. 2024
          Chemistry of Well-Defined Catalysts
          H226, Fall, Graduate School of Engineering, 1.5
        • From 01 Apr. 2022, To 31 Mar. 2023
          Inorganic Chemistry II (Advanced Chemistry)
          7415, Spring, Faculty of Engineering, 2
        • From 01 Apr. 2022, To 31 Mar. 2023
          Chemistry of Well-Defined Catalysts
          H226, Fall, Graduate School of Engineering, 1.5
        • From 01 Apr. 2022, To 31 Mar. 2023
          Organotransition Metal Chemistry 1
          H041, Spring, Graduate School of Engineering, 1.5
        • From 01 Apr. 2022, To 31 Mar. 2023
          Dimensional Control and Micro-Nano Systems
          H403, Fall, Graduate School of Engineering, 1.5
        • From Apr. 2021, To Mar. 2022
          Organotransition Metal Chemistry 2
          Spring, 工学研究科
        • From Apr. 2021, To Mar. 2022
          Inorganic Chemistry II (Advanced Chemistry)
          Spring, 工学部
        • From Apr. 2021, To Mar. 2022
          Inorganic Chemistry II (Advanced Chemistry)
          Spring, 工学部
        • From Apr. 2021, To Mar. 2022
          Chemistry of Well-Defined Catalysts
          Fall, 工学研究科

        Part-time lecturer

        • From 01 Apr. 2024, To 31 Mar. 2025
          無機化学Ⅱ（先端化学）、特別研究
          前期16時間 通年52時間, 京都大学, 工学部
        • From 10 Apr. 2024, To 31 Mar. 2025
          総時間数20時間 , 名古屋大学, 大学院理学研究科
        • From 01 Apr. 2023, To 30 Sep. 2023
          期間中7回、1回　2時間, （国大）大阪大学
        • From 01 Apr. 2023, To 31 Mar. 2024
          無機化学Ⅱ（先端化学）、特別研究
          前期16時間、通年52時間, 京都大学, 工学部
        • From 01 Apr. 2022, To 31 Mar. 2023
          無機化学Ⅱ（先端化学）、特別研究
          前期16時間、通年52時間, 工学部
        list
          Last Updated :2025/04/23

          Administration

          School management (title, position)

          • From 01 Jan. 2022, To 31 Dec. 2022
            国際教育委員会国際学生交流委員会アムジェン・スカラーズ・プログラム小委員会 委員

          Faculty management (title, position)

          • From 01 Apr. 2024, To 31 Mar. 2025
            化学研究所広報委員会委員長
          • From 01 Jan. 2024, To 31 Dec. 2024
            大学院教育支援機構グローバル展開オフィスアムジェン・スカラーズ・プログラムタスクフォース 委員
          • From 01 Apr. 2024, To 31 Mar. 2025
            化学研究所研究活性化委員会委員
          • From 01 Apr. 2024, To 31 Mar. 2025
            化学研究所自己点検評価委員会委員
          • From 01 Apr. 2023, To 31 Mar. 2024
            化学研究所将来問題・研究活性化委員会
          • From 01 Apr. 2023, To 31 Mar. 2024
            化学研究所広報委員会
          • From 01 Apr. 2023, To 31 Mar. 2024
            化学研究所ゲノムネット推進室運営委員会
          • From 01 Apr. 2023, To Present
            京都大学宇治地区化学物質・実験排水系管理委員会 委員
          • From 01 Apr. 2022, To 31 Mar. 2023
            化学研究所産学連携委員会委員
          • From 01 Apr. 2022, To 31 Mar. 2023
            化学研究所将来問題・研究活性化委員会 委員
          • From 01 Apr. 2022, To 31 Mar. 2023
            化学研究所総務・教務委員会委員長
          • From 01 Apr. 2021, To 31 Mar. 2023
            宇治地区実験系廃棄物処理委員会
          • From 01 Apr. 2021, To 31 Mar. 2023
            宇治地区総合環境安全管理センター運営委員会
          • From 01 Apr. 2021, To 31 Mar. 2022
            化学研究所将来問題・研究活性化委員会委員
          • From 01 Apr. 2021, To 31 Mar. 2022
            化学研究所総務・教務委員会副委員長
          • From 01 Apr. 2021, To 31 Mar. 2022
            化学研究所産学連携委員会委員

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