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Semba, Kazuhiko

Graduate School of Engineering, Division of Material Chemistry Assistant Professor

Semba, Kazuhiko
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    Last Updated :2022/05/14

    Basic Information

    Faculty

    • 工学部

    Concurrent Affiliation

    • Center for the Promotion of Interdisciplinary Education and Research (C-PiER), スーパーグローバルコース 化学系ユニット

    Academic Degree

    • 修士(工学)(京都大学)
    • 博士(工学)(京都大学)

    Language of Instruction

    • English

    ID,URL

    researchmap URL

    list
      Last Updated :2022/05/14

      Research

      Research Topics, Overview of the research

      • Research Topics

        Development of organic transformations catalyzed by dual catalysis
      • Overview of the research

        Transition-metal catalyzed reaction is a powerful tool in synthetic chemistry. Most of previous reactions were catalyzed by a single catalysis. Therefore, I am trying to develop new reactions which are catalyzed by dual catalysis.

      Research Areas

      • Nanotechnology/Materials, Synthetic organic chemistry

      Papers

      • 1,2-Arylboration of aliphatic alkenes by cooperative palladium/copper catalysis
        Kazuhiko Semba; Yasuhiro Ohtagaki; Yoshiaki Nakao
        TETRAHEDRON LETTERS, May 2021
      • Merging Pd-0/Pd-II Redox and Pd-II/Pd-II Non-redox Catalytic Cycles for the Allylarylation of Electron-Deficient Alkenes
        Kazuhiko Semba; Naoki Ohta; Fritz Paulus; Masaki Ohata; Yoshiaki Nakao
        CHEMISTRY-A EUROPEAN JOURNAL, Mar. 2021
      • Magnesiation of Aryl Fluorides Catalyzed by a Rhodium-Aluminum Complex
        Ikuya Fujii; Kazuhiko Semba; Qiao-Zhi Li; Shigeyoshi Sakaki; Yoshiaki Nakao
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2020
      • Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions
        Noam I. Saper; Akito Ohgi; David W. Small; Kazuhiko Semba; Yoshiaki Nakao; John F. Hartwig
        Nature Chemistry, 01 Mar. 2020, Peer-reviewed
      • A PA1P pincer ligand bearing a 2-Diphenylphosphinophenoxy backbone
        Kazuhiko Semba; Ikuya Fujii; Yoshiaki Nakao
        Inorganics, 01 Dec. 2019, Peer-reviewed
      • Carboallylation of Electron-Deficient Alkenes with Organoboron Compounds and Allylic Carbonates by Cooperative Palladium/Copper Catalysis
        Kazuhiko Semba; Naoki Ohta; Yoshiaki Nakao
        Organic Letters, 21 Jun. 2019, Peer-reviewed
      • Cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on the catalytic generation of organocopper nucleophiles
        Kazuhiko Semba; Yoshiaki Nakao
        Tetrahedron, 08 Feb. 2019
      • Pd/NHC-catalyzed cross-coupling reactions of nitroarenes
        Myuto Kashihara; Rong Lin Zhong; Kazuhiko Semba; Shigeyoshi Sakaki; Yoshiaki Nakao
        Chemical Communications, 2019, Peer-reviewed
      • Synthesis of N-heterocyclic carbene ligands for site-selective C-H alkylation by cooperative nickel/aluminum catalysis
        Shogo Okumura; Tomohiro Ebara; Kazuhiko Semba; Yoshiaki Nakao
        Heterocycles, 2019, Peer-reviewed
      • Rhodium Complexes Bearing PAlP Pincer Ligands
        Naofumi Hara; Teruhiko Saito; Kazuhiko Semba; Nishamol Kuriakose; Hong Zheng; Shigeyoshi Sakaki; Yoshiaki Nakao
        Journal of the American Chemical Society, 13 Jun. 2018, Peer-reviewed
      • Site-Selective Linear Alkylation of Anilides by Cooperative Nickel/Aluminum Catalysis
        Shogo Okumura; Takuya Komine; Erika Shigeki; Kazuhiko Semba; Yoshiaki Nakao
        Angewandte Chemie - International Edition, 22 Jan. 2018, Peer-reviewed
      • Hydrogenative cross-coupling of internal alkynes and aryl iodides by palladium/copper cooperative catalysis
        Kazuhiko Semba; Ryohei Kameyama; Yoshiaki Nakao
        Chemistry Letters, 2018, Peer-reviewed
      • Carboallylation of electron-deficient alkenes by palladium/copper catalysis
        Kazuhiko Semba; Naoki Ohta; Yuko Yano; Yoshiaki Nakao
        Chemical Communications, 2018, Peer-reviewed
      • Cross-Coupling Reactions by Cooperative Metal Catalysis
        Kazuhiko Semba; Yoshiaki Nakao
        JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Nov. 2017, Peer-reviewed
      • How to Control Inversion vs Retention Transmetalation between PdII-Phenyl and CuI-Alkyl Complexes: Theoretical Insight
        Hong Zheng; Kazuhiko Semba; Yoshiaki Nakao; Shigeyoshi Sakaki
        Journal of the American Chemical Society, 11 Oct. 2017, Peer-reviewed
      • Cross-coupling reactions by cooperative metal catalysis
        Kazuhiko Semba; Yoshiaki Nakao
        Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 2017, Peer-reviewed
      • C3-Selective alkenylation of N-acylindoles with unactivated internal alkynes by cooperative nickel/aluminium catalysis
        Fumiyoshi Inoue; Teruhiko Saito; Kazuhiko Semba; Yoshiaki Nakao
        Chemical Communications, 2017, Peer-reviewed
      • para-Selective C−H Borylation of (Hetero)Arenes by Cooperative Iridium/Aluminum Catalysis
        Lichen Yang; Kazuhiko Semba; Yoshiaki Nakao
        Angewandte Chemie - International Edition, 2017, Peer-reviewed
      • Arylboration of internal alkynes by cooperative palladium/copper catalysis
        Kazuhiko Semba; Megumi Yoshizawa; Yasuhiro Ohtagaki; Yoshiaki Nakao
        Bulletin of the Chemical Society of Japan, 2017, Peer-reviewed
      • Para-Selective Alkylation of Benzamides and Aromatic Ketones by Cooperative Nickel/Aluminum Catalysis
        Shogo Okumura; Shuwei Tang; Teruhiko Saito; Kazuhiko Semba; Shigeyoshi Sakaki; Yoshiaki Nakao
        Journal of the American Chemical Society, 09 Nov. 2016, Peer-reviewed
      • Arylboration of 1-Arylalkenes by Cooperative Nickel/Copper Catalysis
        Kazuhiko Semba; Yasuhiro Ohtagaki; Yoshiaki Nakao
        Organic Letters, 19 Aug. 2016, Peer-reviewed
      • Reductive cross-coupling of conjugated arylalkenes and aryl bromides with hydrosilanes by cooperative palladium/copper catalysis
        Kazuhiko Semba; Kenta Ariyama; Hong Zheng; Ryohei Kameyama; Shigeyoshi Sakaki; Yoshiaki Nakao
        Angewandte Chemie - International Edition, 17 May 2016, Peer-reviewed
      • Silicon-based cross-coupling of aryl tosylates by cooperative palladium/copper catalysis
        Akito Ohgi; Kazuhiko Semba; Tamejiro Hiyama; Yoshiaki Nakao
        Chemistry Letters, 2016, Peer-reviewed
      • Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel-N-Heterocyclic Carbene System
        York Schramm; Makoto Takeuchi; Kazuhiko Semba; Yoshiaki Nakao; John F. Hartwig
        Journal of the American Chemical Society, 30 Sep. 2015, Peer-reviewed
      • Copper-catalyzed semihydrogenation of alkynes to Z -alkenes
        Kazuhiko Semba; Ryohei Kameyama; Yoshiaki Nakao
        Synlett, Feb. 2015, Peer-reviewed
      • Arylboration of alkenes by cooperative palladium/copper catalysis
        Kazuhiko Semba; Yoshiaki Nakao
        Journal of the American Chemical Society, 28 May 2014, Peer-reviewed
      • Intramolecular aminocyanation of alkenes by cooperative palladium/boron catalysis
        Yosuke Miyazaki; Naoki Ohta; Kazuhiko Semba; Yoshiaki Nakao
        Journal of the American Chemical Society, 12 Mar. 2014, Peer-reviewed
      • Copper-catalyzed borylation of α-alkoxy allenes with bis(pinacolato)diboron: Efficient synthesis of 2-boryl 1,3-butadienes
        Kazuhiko Semba; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji
        Angewandte Chemie - International Edition, 18 Nov. 2013, Peer-reviewed
      • Highly selective copper-catalyzed hydroboration of allenes and 1,3-dienes
        Kazuhiko Semba; Masataka Shinomiya; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji
        Chemistry - A European Journal, 27 May 2013, Peer-reviewed
      • Copper-catalyzed silacarboxylation of internal alkynes by employing carbon dioxide and silylboranes
        Tetsuaki Fujihara; Yosuke Tani; Kazuhiko Semba; Jun Terao; Yasushi Tsuji
        Angewandte Chemie - International Edition, 12 Nov. 2012, Peer-reviewed
      • Copper-catalyzed highly selective semihydrogenation of non-polar carbon-carbon multiple bonds using a silane and an alcohol
        Kazuhiko Semba; Tetsuaki Fujihara; Tinghua Xu; Jun Terao; Yasushi Tsuji
        Advanced Synthesis and Catalysis, 21 May 2012, Peer-reviewed
      • Copper-catalyzed highly regio- and stereoselective directed hydroboration of unsymmetrical internal alkynes: Controlling regioselectivity by choice of catalytic species
        Kazuhiko Semba; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji
        Chemistry - A European Journal, Apr. 2012, Peer-reviewed
      • Copper-catalyzed hydrocarboxylation of alkynes using carbon dioxide and hydrosilanes
        Tetsuaki Fujihara; Tinghua Xu; Kazuhiko Semba; Jun Terao; Yasushi Tsuji
        Angewandte Chemie - International Edition, 10 Jan. 2011, Peer-reviewed
      • Copper-catalyzed hydrosilylation with a bowl-shaped phosphane ligand: Preferential reduction of a bulky ketone in the presence of an aldehyde
        Tetsuaki Fujihara; Kazuhiko Semba; Jun Terao; Yasushi Tsuji
        Angewandte Chemie - International Edition, 15 Feb. 2010, Peer-reviewed
      • Copper-catalyzed semihydrogenation of internal alkynes to (Z)-alkenes
        Semba Kazuhiko; Fujihara Tetsuaki; Terao Jun; Tsuji Yasushi
        Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2010
      • Copper-catalyzed hydrocarboxylation of an alkyne using carbon dioxide
        Fujihara Tetsuaki; Xu Tinghua; Semba Kazuhiko; Terao Jun; Tsuji Yasushi
        Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2010

      Misc.

      • Copper-catalyzed borylative transformations of non-polar carbon-carbon unsaturated compounds employing borylcopper as an active catalyst species
        Kazuhiko Semba; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji
        Tetrahedron, Apr. 2015
      • Copper-catalyzed borylative allyl-allyl coupling reaction
        Kazuhiko Semba; Naoto Bessho; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji
        Angewandte Chemie - International Edition, 18 Aug. 2014, Peer-reviewed
      • Regioselective transformation of alkynes catalyzed by a copper hydride or boryl copper species
        Tetsuaki Fujihara; Kazuhiko Semba; Jun Terao; Yasushi Tsuji
        Catalysis Science and Technology, Jun. 2014
      • Dual-catalyzed transformations combining palladium/gold co-catalysis
        Kazuhiko Semba
        Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 2014

      External funds: Kakenhi

      • Carboboration of Alkenes Based on New Mechanisms
        Grant-in-Aid for Early-Career Scientists
        Basic Section 33020:Synthetic organic chemistry-related
        Kyoto University
        仙波 一彦
        From 01 Apr. 2018, To 31 Mar. 2021, Granted
        アリルアリール化;アルケン;協働触媒作用;カルボホウ素化;ニッケル;パラジウム;銅;カルボホウ素化反応;有機ホウ素化合物;遷移金属触媒
      • Development of Reactions by Cooperative Transition-Metal Catalysis Based on Controlling Transition State of Transmetallations
        Grant-in-Aid for Scientific Research (C)
        Kyoto University
        Kazuhiko Semba
        From 18 Jul. 2017, To 31 Mar. 2020, Project Closed
        トランスメタル化;協働触媒;クロスカップリング;パラジウム;コバルト;アルケン;水素化カップリング;銅;トランスメタル化反応;金属協働触媒
      • Cross-Coupling Reactions Based on Catalytically Generated Organometallics via Addition of Metal Species
        Grant-in-Aid for Young Scientists (B)
        Kyoto University
        Kazuhiko Semba
        From 01 Apr. 2014, To 31 Mar. 2017, Project Closed
        クロスカップリング反応;金属協働触媒;クロスカップリング;パラジウム;銅;ヒドロアリール化;カルボホウ素化;アリールホウ素化;アルキン;アルケン;交差カップリング反応
      • Functionalization of Unactivated Bonds by Cooperative Metal Catalysis
        Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
        Science and Engineering
        Kyoto University
        Yoshiaki NAKAO
        From 01 Apr. 2010, To 31 Mar. 2015, Project Closed
        協働金属触媒;遷移金属;ルイス酸;不活性結合;不活性結合活性化;炭素ー水素結合活性化;炭素ー炭素結合活性化;炭素ー酸素結合活性化;炭素ー窒素結合活性化;炭素-水素結合活性化;炭素-炭素結合活性化;炭素-炭素結合活性
      list
        Last Updated :2022/05/14

        Administration

        Faculty management (title, position)

        • From 01 Apr. 2017, To 31 Mar. 2018
          桂事業場環境安全衛生委員会 委員
        • From 01 Apr. 2018, To 31 Mar. 2020
          桂事業場環境安全衛生委員会 委員
        • From 01 Apr. 2021, To 31 Mar. 2023
          桂事業場環境安全衛生委員会 委員

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