Basic Information

Faculty

• Faculty of Engineering

Concurrent Affiliation

• Center for the Promotion of Interdisciplinary Education and Research (C-PiER), スーパーグローバルコース 化学系ユニット

Professional Memberships

• KINKI CHEMICAL SOCIETY, JAPAN
• Society of Silicon Chemistry
• CATALYSIS SOCIETY OF JAPAN
• THE JAPAN PETROLEUM INSTITUTE
• 有機合成化学協会
• 日本化学会
• 錯体化学会

Academic Degree

• 修士（理学）(北海道大学)
• 博士（理学）(北海道大学)

Academic Resume (Graduate Schools)

• 北海道大学, 大学院理学研究科化学専攻博士課程, 修了
• 北海道大学, 大学院理学研究科化学専攻修士課程, 修了

Academic Resume (Undergraduate School/Majors)

• 静岡大学, 理学部化学科, 卒業

Research History

• From Jun. 2022, To Present

  Kyoto University, Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Professor
• From Feb. 2017, To May 2022

  Kyoto University, Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Associate Professor
• From Apr. 2007, To Jan. 2017

  Kyoto University, Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Assistant Professor
• From Jun. 2006, To Mar. 2007

  Kyoto University, Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Assistant Professor
• From Apr. 2006, To May 2006

  科学技術振興機構 戦略的創造研究推進事業 (CREST), 博士研究員
• From May 2004, To Mar. 2006

  Hokkaido University, Catalysis Research Center, Postdoctral Researcher
• From Apr. 2001, To Apr. 2004

  JST CREST, Postdoctral Researcher

Language of Instruction

• Japanese

ID,URL

• ORCID ID

  0000-0002-6687-2528

• J-Global ID

  200901075451481850

Website(s) (URL(s))

• http://www.ehcc.kyoto-u.ac.jp/eh42/home/fujihara.html

researchmap URL

• https://researchmap.jp/read0080498

Research

Research Topics, Overview of the research

• Research Topics

  Development of transiton-metal catalyzed transformation utilizing carbon dioxide

Research Interests

• Homogeneous Catalysts
• Carbon Dioxide
• 有機金属化学
• 錯体化学
• Organometallic Chemistry
• Coordinatio Chemistry
• Homogenous Catalysis

Research Areas

• Nanotechnology/Materials, Functional solid-state chemistry
• Nanotechnology/Materials, Synthetic organic chemistry
• Nanotechnology/Materials, Inorganic and coordination chemistry

Papers

• Periphery-Arranged Bulky Phosphite Ligands: Synthesis and Steric Effect in Cu-Catalyzed Hydrosilylation of Ketones

  I Satoh; K Semba; JY Hasegawa; T Fujihara

  ORGANOMETALLICS, May 2025, Peer-reviewed

  
• 銅触媒による二酸化炭素を用いた1,2-ジエンのボラカルボキシル化反応

  藤原 哲晶

  京都大学化学研究所スーパーコンピュータシステム研究成果報告書, Mar. 2025

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• Regioselective α-Allylation of Cyclic Allylborates with Allylic Bromides

  G Yamagiwa; H Murata; K Semba; T Fujihara

  JOURNAL OF ORGANIC CHEMISTRY, Mar. 2025, Peer-reviewed

  
• 銅錯体触媒を用いた1,2-ジエンまたは1,3-ジエンへのケイ素官能基導入反応の開発

  藤原 哲晶

  ケイ素化学協会誌, 2024, Peer-reviewed

  
• Exploring Catalytic Intermediates in Pd-Catalyzed Aerobic Oxidative Amination of 1,3-Dienes: Multiple Metal Interactions of the Palladium Nanoclusters

  K Tabaru; T Fujihara; K Torii; T Suzuki; Y Jing; T Toyao; Z Maeno; KI Shimizu; T Watanabe; H Sogawa; F Sanda; JY Hasegawa; Y Obora

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2024, Peer-reviewed

  
• 二酸化炭素を炭素源とする触媒的な有機合成反応の開発 : 環境調和型反応を目指して

  藤原 哲晶

  有機合成化学協会誌 = Journal of synthetic organic chemistry, Japan, Jun. 2024, Peer-reviewed

  
• 亜鉛触媒によるシリルボランを用いたアルデヒドのシリル化反応

  藤原 哲晶

  京都大学化学研究所スーパーコンピュータシステム研究成果報告書, Mar. 2024

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• Efficient access to chiral organogermanes

  T Fujihara

  CHEM CATALYSIS, Jan. 2024, Peer-reviewed

  
• 遷移金属錯体触媒を活用する二酸化炭素を炭素源とした有機合成反応

  藤原 哲晶

  Organometallic news, Dec. 2023

  
• A Typical Metal‐Ion‐Responsive Color‐Tunable Emitting Insulated π‐Conjugated Polymer Film

  Takuro Hosomi; Hiroshi Masai; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  Angewandte Chemie, 07 Jul. 2016

  
• パラジウム錯体触媒を用いた分子内C(sp³)-H 結合アリール化反応による環状アミド合成

  藤原 哲晶

  京都大学化学研究所スーパーコンピュータシステム研究成果報告書, Mar. 2023

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• ロジウム触媒によるカルベン挿入反応におけるカルボキシラト配位子の立体効果

  藤原 哲晶

  京都大学化学研究所スーパーコンピュータシステム研究成果報告書, Mar. 2023

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• Dimethylacetamide-stabilized ruthenium nanoparticles for catalysing alpha-alkylations of amides with alcohols

  H Iguchi; N Katayama; T Suzuki; T Fujihara; Y Jing; T Toyao; Z Maeno; KI Shimizu; Y Obora

  CHEMICAL COMMUNICATIONS, Oct. 2022, Peer-reviewed

  
• 1,3-ジエン類 ウイルスベクター ELISAアッセイ Box型リガンド

  藤原 哲晶; 松田 真弥; 渡辺 賢二; 小林 健一; 大多和 正樹

  有機合成化学協会誌, Aug. 2022, Peer-reviewed

  
• Cu-Catalyzed Transformations of 1,3-Dienes: Use of Allyl Copper Intermediates in Functionalization

  藤原 哲晶

  有機合成化学協会誌, Aug. 2022, Peer-reviewed

  
• Borylative Difunctionalization of Unsaturated Hydrocarbons Using Borylcopper Species

  Tetsuaki Fujihara

  Synlett, 05 Jun. 2023

  
• Paddle‐Wheel Dirhodium Complexes Bearing Bulky Carboxylate Ligands: Synthesis and Catalysis in Carbene Insertion Reactions

  Kotaro Yamashita; Kota Sato; Yutaka Tanji; Jun‐ya Hasegawa; Tetsuaki Fujihara

  Chemistry – An Asian Journal, Jun. 2023

  
• 1.9 Base-Metal-Catalyzed Carboxylation Using Carbon Dioxide

  T. Fujihara

  2023

  
• Copper‐Catalyzed Simultaneous Installation of Boryl and Carbonyl Functionalities to Unsaturated Hydrocarbons

  Tetsuaki Fujihara

  Asian Journal of Organic Chemistry, Dec. 2022

  
• Complementary Color Tuning by HCl via Phosphorescence-to-Fluorescence Conversion on Insulated Metallopolymer Film and Its Light-Induced Acceleration

  Shunichi Kaneko; Hiroshi Masai; Takuya Yokoyama; Maning Liu; Yasuhiro Tachibana; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  POLYMERS, Jan. 2020, Peer-reviewed

  
• Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material

  Hiroshi Masai; Takuya Yokoyama; Hiromichi V. Miyagishi; Maning Liu; Yasuhiro Tachibana; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  NATURE COMMUNICATIONS, Jan. 2020, Peer-reviewed

  
• Synthesis of Cyclic Allylborates from 1,3-Dienes and a Diboron Reagent

  Seiya Sakuragi; Tomofumi Akiba; Takumi Tanahashi; Tetsuaki Fujihara

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Apr. 2022, Peer-reviewed

  
• ロジウム触媒によるカルベン挿入反応におけるカルボキシラート配位子の立体効果

  藤原 哲晶

  京都大学化学研究所スーパーコンピュータシステム研究成果報告書, Mar. 2022

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• Copper-Catalyzed Regioselective Sila-acylation and Sila-imination of Allenes Using Esters and Nitriles

  Katsushi Suda; Yuki Matsuda; Tatsuya Yamaguchi; Tetsuaki Fujihara

  SYNTHESIS-STUTTGART, Feb. 2022, Peer-reviewed

  
• Copper-Catalyzed Regioselective Sila-Acylation and Silaformylation of 1,3-Dienes Using Esters

  Kazutaka Kanayama; Ayumi Sawada; Katsushi Suda; Tetsuaki Fujihara

  JOURNAL OF ORGANIC CHEMISTRY, Jul. 2021, Peer-reviewed

  
• パラジウム触媒による分子間炭素-水素結合アリール化反応におけるカルボキシラト配位子の立体効果

  藤原 哲晶

  京都大学化学研究所スーパーコンピュータシステム研究成果報告書, Mar. 2021

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• Palladium-Catalyzed Difunctionalization of 1,3-Diene with Amine and Disilane under a Mild Re-oxidation System

  Kazuyuki Torii; Atsushi Kawakubo; Xianjin Lin; Tetsuaki Fujihara; Tatsuo Yajima; Yasushi Obora

  CHEMISTRY-A EUROPEAN JOURNAL, Mar. 2021, Peer-reviewed

  
• Synthesis of Tetrasilatetrathia[8]circulenes through C-I and C-H Silylation

  Shuhei Akahori; Tetsuaki Fujihara; Yasushi Tsuji; Hiroshi Shinokubo; Yoshihiro Miyake

  SYNTHESIS-STUTTGART, Mar. 2021, Peer-reviewed

  
• Palladium-Catalyzed Synthesis of Fluorenes by Intramolecular C(sp(2))-H Activation at Room Temperature

  Yutaka Tanji; Yasushi Tsuji; Tetsuaki Fujihara

  SYNLETT, May 2020, Peer-reviewed

  
• Pyridines Bearing Poly(ethylene glycol) Chains: Synthesis and Use as Ligands

  Motoi Satou; Arata Kiyooka; Yasushi Tsuji; Tetsuaki Fujihara

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, May 2020, Peer-reviewed

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• Cu-Catalyzed three-component coupling reactions using nitriles, 1,3-dienes and silylboranes

  Yuki Matsuda; Yasushi Tsuji; Tetsuaki Fujihara

  CHEMICAL COMMUNICATIONS, Apr. 2020, Peer-reviewed

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• Pd-Catalyzed intermolecular C-H bond arylation reactions: effect of bulkiness of carboxylate ligands

  Yutaka Tanji; Ryo Hamaguchi; Yasushi Tsuji; Tetsuaki Fujihara

  CHEMICAL COMMUNICATIONS, Apr. 2020, Peer-reviewed

  
• ポリエチレングリコールで修飾したピリジン配位子の開発

  藤原 哲晶

  京都大学化学研究所スーパーコンピュータシステム研究成果報告書, Mar. 2020

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• Zinc-Catalyzed Synthesis of Acylsilanes Using Carboxylic Acids and a. Silylborane in the Presence of Pivalic Anhydride

  Kenta Tatsumi; Sae Tanabe; Yasushi Tsuji; Tetsuaki Fujihara

  ORGANIC LETTERS, Dec. 2019, Peer-reviewed

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• Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates

  Tetsuaki Fujihara; Yasushi Tsuji

  FRONTIERS IN CHEMISTRY, Jun. 2019, Peer-reviewed

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• Two-step template method for synthesis of axis-length-controlled porphyrin-containing hollow structures

  Yusuke Chiba; Yuki Oka; Hiroshi Masai; Wakana Matsuda; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  Chemical Communications, 2019, Peer-reviewed

  
• 二酸化炭素の炭素資源再生を指向した遷移金属錯体触媒の開発

  藤原 哲晶

  旭硝子財団助成研究成果報告 Reports of research assisted by the Asahi Glass Foundation, 2019

  
• Cobalt-Catalyzed Reductive Coupling of Alkynes and Acrylates Bearing a Leaving Group: Construction of Cyclobutene Rings

  Tetsuaki Fujihara; Susumu Kukita; Yuki Yagi; Maho Kirihara; Keisuke Nogi; Yasushi Tsuji

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, Dec. 2018, Peer-reviewed

  
• Copper-Catalyzed [4+2] Cycloaddition Using N-(2-Pyridyl)ketimines and Terminal Alkynes

  Kenta Tatsumi; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  Advanced Synthesis and Catalysis, 03 Sep. 2018, Peer-reviewed

  
• Cobalt- and rhodium-catalyzed carboxylation using carbon dioxide as the C1 source

  Tetsuaki Fujihara; Yasushi Tsuji

  BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, Sep. 2018, Peer-reviewed

  
• Steric Effect of Carboxylate Ligands on Pd-Catalyzed Intramolecular C(sp(2))-H and C(sp(3))-H Arylation Reactions

  Yutaka Tanji; Naoya Mitsutake; Tetsuaki Fujihara; Yasushi Tsuji

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Aug. 2018, Peer-reviewed

  
• Copper-Catalyzed Bora-Acylation and Bora-Alkoxyoxalylation of Allenes

  Ayumi Sawada; Tetsuaki Fujihara; Yasushi Tsuji

  ADVANCED SYNTHESIS & CATALYSIS, Jul. 2018, Peer-reviewed

  
• Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis

  Tetsuaki Fujihara; Yasushi Tsuji

  Synthesis (Germany), 02 May 2018, Peer-reviewed

  
• Cu-catalyzed Transformations of Allenes: Use of in-situ Generated Allyl Copper Intermediates in Organic Synthesis

  Tetsuaki Fujihara; Yasushi Tsuji

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Apr. 2018, Peer-reviewed

  
• Synthesis and Characterization of Carboxylic Acids Bearing Poly(ethylene glycol) Chains

  Motoi Satou; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  Synlett, 15 Mar. 2018, Peer-reviewed

  
• 銅錯体触媒を用いた二酸化炭素を炭素源とする有機合成反応の開発 (特集 次世代型エネルギー利活用の展望)

  藤原 哲晶

  ケミカルエンジニヤリング = Chemical engineering, Jan. 2018

  
• 遷移金属錯体触媒を活用するギ酸エステルまたはホルムアミドを原料としたカルボニル化合物の合成反応

  藤原 哲晶; 辻 康之

  Ｊｏｕｒｎａｌ ｏｆ ｔｈｅ Ｊａｐａｎ Ｐｅｔｒｏｌｅｕｍ Ｉｎｓｔｉｔｕｔｅ, Jan. 2018, Peer-reviewed

  
• 銅触媒によるアレンの変換反応：触媒的に生成したアリル銅中間体を利用する有機合成反応

  藤原 哲晶; 辻 康之

  有機合成化学協会誌, Jan. 2018, Peer-reviewed

  
• 均一系錯体触媒を活用する二酸化炭素を用いたカルボン酸合成 (特集 二酸化炭素からの有用化学品合成)

  藤原 哲晶; 辻 康之

  触媒 = Catalysts & catalysis, Jan. 2018, Peer-reviewed

  
• 脱フッ素水素化反応 キラルリン酸 アリル銅（錯体） ニトロゲナーゼ

  松並 明日香; 高須 清誠; 藤原 哲晶; 桑田 繁樹; 干鯛 眞信

  有機合成化学協会誌, Jan. 2018, Peer-reviewed

  
• Kinetic stabilization of a Ni(II) bis(dithiobenzoate)-type complex achieved using three-dimensional insulation by a [1]rotaxane structure

  Takuro Hosomi; Ryosuke Harada; Hiroshi Masai; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  Chemical Communications, 2018, Peer-reviewed

  
• Programmed Synthesis of Molecular Wires with Fixed Insulation and Defined Length Based on Oligo(phenylene ethynylene) and Permethylated -Cyclodextrins

  Hiroshi Masai; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  CHEMISTRY-A EUROPEAN JOURNAL, Oct. 2017, Peer-reviewed

  
• Thieme Chemistry Journals Awardees - Where Are They Now? Synthesis of a Dinuclear Copper NHC Complex Bearing a Rigid -Conjugated Cyclic Framework

  Daiki Inamori; Takuya Miwa; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  SYNLETT, Sep. 2017, Peer-reviewed

  
• Hetero Face-to-Face Porphyrin Array with Cooperative Effects of Coordination and Host-Guest Complexation

  Yusuke Chiba; Maning Liu; Yasuhiro Tachibana; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  CHEMISTRY-AN ASIAN JOURNAL, Aug. 2017, Peer-reviewed

  
• Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide Catalyzed by MgCl2

  Tetsuaki Fujihara; Masaki Inokuchi; Taiga Mizoe; Keisuke Nogi; Jun Terao; Yasushi Tsuji

  CHEMISTRY LETTERS, Jul. 2017, Peer-reviewed

  
• Copper-catalyzed hydroallylation of allenes employing hydrosilanes and allyl chlorides

  Tetsuaki Fujihara; Ken Yokota; Jun Terao; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, Jul. 2017, Peer-reviewed

  
• Regio- and Stereoselective Synthesis of Triarylalkene-Capped Rotaxanes via Palladium-Catalyzed Tandem Sonogashira/Hydroaryl Reaction of Terminal Alkynes

  Hiroshi Masai; Wakana Matsuda; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  JOURNAL OF ORGANIC CHEMISTRY, May 2017, Peer-reviewed

  
• Boraformylation and Silaformylation of Allenes

  Tetsuaki Fujihara; Ayumi Sawada; Tatsuya Yamaguchi; Yosuke Tani; Jun Terao; Yasushi Tsuji

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Feb. 2017, Peer-reviewed

  
• Copper-Catalyzed Transformations Using Cu-H, Cu-B, and Cu-Si as Active Catalyst Species

  Yasushi Tsuji; Tetsuaki Fujihara

  CHEMICAL RECORD, Oct. 2016, Peer-reviewed

  
• A Typical Metal-Ion-Responsive Color-Tunable Emitting Insulated -Conjugated Polymer Film

  Takuro Hosomi; Hiroshi Masai; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Oct. 2016, Peer-reviewed

  
• Steric effect of carboxylic acid ligands on Pd-catalyzed C-H activation reactions

  Tetsuaki Fujihara; Atsushi Yoshida; Motoi Satou; Yutaka Tanji; Jun Terao; Yasushi Tsuji

  CATALYSIS COMMUNICATIONS, Sep. 2016, Peer-reviewed

  
• Synthesis of Highly Insulated Conjugated Metallopolymers Containing Terpyridine-Metal Complexes

  Takuro Hosomi; Hiroshi Masai; Wakana Matsuda; Shu Seki; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

  CHEMISTRY LETTERS, Aug. 2016, Peer-reviewed

  
• Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes

  Keisuke Nogi; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2016, Peer-reviewed

  
• Rational Design for Rotaxane Synthesis through Intramolecular Slippage: Control of Activation Energy by Rigid Axle Length

  Hiroshi Masai; Jun Terao; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMISTRY-A EUROPEAN JOURNAL, May 2016, Peer-reviewed

  
• Cobalt-catalyzed three component coupling reaction providing cyclobutene structure

  Kukita Susumu; Nogi Keisuke; Fujihara Tetsuaki; Terao Jun; Tsuji Yasushi

  Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, Jan. 2016

  
• 遷移金属錯体触媒を用いた炭素–炭素結合形成を経る二酸化炭素固定化反応

  藤原 哲晶; 辻 康之

  Journal of the Japan Petroleum Institute, Jan. 2016, Peer-reviewed

  
• Reductive cross-coupling reaction of allenes and allyl chlorides via catalytic allyl copper species

  Yokota Ken; Fujihara Tetsuaki; Terao Jun; Tsuji Yasushi

  Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, Jan. 2016

  
• Copper-based Catalysts

  Yasushi Tsuji; Tetsuaki Fujihara

  SUSTAINABLE CATALYSIS: WITH NON-ENDANGERED METALS, PT 2, 2016, Peer-reviewed

  
• Cobalt- and Nickel-Catalyzed Carboxylation of Alkenyl and Sterically Hindered Aryl Triflates Utilizing CO2

  Keisuke Nogi; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  JOURNAL OF ORGANIC CHEMISTRY, Nov. 2015, Peer-reviewed

  
• Synthesis of Molecular Wires Strapped by pi-Conjugated Side Chains: Integration of Dehydrobenzo[20]annulene Units

  Jun Terao; Masami Ohsawa; Hiroshi Masai; Yuki Kurashige; Tetsuaki Fujihara; Yasushi Tsuji

  JOURNAL OF ORGANIC CHEMISTRY, Sep. 2015, Peer-reviewed

  
• Palladium-catalyzed formal hydroacylation of allenes employing carboxylic anhydrides and hydrosilanes

  Tetsuaki Fujihara; Takuro Hosomi; Cong Cong; Tomoya Hosoki; Jun Terao; Yasushi Tsuji

  TETRAHEDRON, Jul. 2015

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• Copper-catalyzed borylative transformations of non-polar carbon-carbon unsaturated compounds employing borylcopper as an active catalyst species

  Kazuhiko Semba; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  TETRAHEDRON, Apr. 2015

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• Copper-catalyzed Silylative Allylation of Ketones and Aldehydes Employing Allenes and Silylboranes

  Yosuke Tani; Tatsuya Yamaguchi; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  CHEMISTRY LETTERS, Mar. 2015, Peer-reviewed

  
• Synthesis and Functionalities of Insulated Conjugated Metallowire

  正井 宏; 寺尾 潤; 藤原 哲晶

  化學工業, Jan. 2015, Peer-reviewed

  
• N-Heterocyclic carbene ligands bearing poly(ethylene glycol) chains: effect of the chain length on palladium-catalyzed coupling reactions employing aryl chlorides

  Tetsuaki Fujihara; Takahiro Yoshikawa; Motoi Satou; Hidetoshi Ohta; Jun Terao; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2015, Peer-reviewed

  
• Copper-catalyzed C-C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes

  Yosuke Tani; Kazunari Kuga; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2015, Peer-reviewed

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• Copper-Catalyzed Regiodivergent Silacarboxylation of Allenes with Carbon Dioxide and a Silylborane

  Yosuke Tani; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2014, Peer-reviewed

  
• Synthesis of an organic-soluble pi-conjugated [3]rotaxane via rotation of glucopyranose units in permethylated beta-cyclodextrin

  Jun Terao; Yohei Konoshima; Akitoshi Matono; Hiroshi Masai; Tetsuaki Fujihara; Yasushi Tsuji

  BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, Nov. 2014, Peer-reviewed

  
• Enhancement of Phosphorescence and Unimolecular Behavior in the Solid State by Perfect Insulation of Platinum-Acetylide Polymers

  Hiroshi Masai; Jun Terao; Satoshi Makuta; Yasuhiro Tachibana; Tetsuaki Fujihara; Yasushi Tsuji

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Oct. 2014, Peer-reviewed

  
• Nickel-Catalyzed Double Carboxylation of Alkynes Employing Carbon Dioxide

  Tetsuaki Fujihara; Yuichiro Horimoto; Taiga Mizoe; Fareed Bhasha Sayyed; Yosuke Tani; Jun Terao; Shigeyoshi Sakaki; Yasushi Tsuji

  ORGANIC LETTERS, Sep. 2014, Peer-reviewed

  
• Encapsulation by Cyclic Porphyrin Dimers Using Various Interaction Modes

  Jun Terao; Yusuke Chiba; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMISTRY LETTERS, Aug. 2014, Peer-reviewed

  
• Palladium-catalyzed formal arylacylation of allenes employing acid chlorides and arylboronic acids

  Kenta Tatsumi; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, Aug. 2014, Peer-reviewed

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• Molecular Wiring Method Based on Polymerization or Copolymerization of an Insulated pi-Conjugated Monomer

  Jun Terao; Kyohei Homma; Yohei Konoshima; Masateru Taniguchi; Manabu Kiguchi; Yuuki Komoto; Masayo Horikawa; Yasuhisa Naito; Tetsuaki Fujihara; Yasushi Tsuji

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Aug. 2014, Peer-reviewed

  
• Synthesis and Redox Response of Insulated Molecular Wire Elongated through Iron Terpyridine Coordination Bonds

  Jun Terao; Takuro Hosomi; Hiroshi Masai; Wakana Matsuda; Shu Seki; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMISTRY LETTERS, Aug. 2014, Peer-reviewed

  
• TRANSITION METAL-CATALYZED SYNTHESIS OF pi-CONJUGATED CYCLIC ESTERS AND AMIDES FROM ALKYNES AND CARBONYL REAGENTS

  Tetsuaki Fujihara; Yasushi Tsuji

  HETEROCYCLES, Jun. 2014, Peer-reviewed

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• Iron oxide catalyzed reduction of acid chlorides to aldehydes with hydrosilanes

  Cong Cong; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  CATALYSIS COMMUNICATIONS, May 2014, Peer-reviewed

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• Synthesis of One-Dimensional Metal-Containing Insulated Molecular Wire with Versatile Properties Directed toward Molecular Electronics Materials

  Hiroshi Masai; Jun Terao; Shu Seki; Shigeto Nakashima; Manabu Kiguchi; Kento Okoshi; Tetsuaki Fujihara; Yasushi Tsuji

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2014, Peer-reviewed

  
• Synthesis and characterization of ruthenium(II) complexes with dendritic N-heterocyclic carbene ligands

  Tetsuaki Fujihara; Takeru Nishida; Jun Terao; Yasushi Tsuji

  INORGANICA CHIMICA ACTA, Jan. 2014, Peer-reviewed

  
• Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide

  Keisuke Nogi; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2014, Peer-reviewed

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• Synthesis of functionalized insulated molecular wires by polymerization of an insulated pi-conjugated monomer

  Jun Terao; Kyohei Homma; Yohei Konoshima; Rika Imoto; Hiroshi Masai; Wakana Matsuda; Shu Seki; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2014, Peer-reviewed

  
• Palladium-catalyzed reduction of carboxylic acids to aldehydes with hydrosilanes in the presence of pivalic anhydride

  Tetsuaki Fujihara; Cong Cong; Jun Terao; Yasushi Tsuji

  Advanced Synthesis and Catalysis, 25 Nov. 2013, Peer-reviewed

  
• Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

  Kazuhiko Semba; Masataka Shinomiya; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  CHEMISTRY-A EUROPEAN JOURNAL, May 2013, Peer-reviewed

  
• Palladium-Catalyzed Formal Hydroacylation of Allenes Employing Acid Chlorides and Hydrosilanes

  Tetsuaki Fujihara; Kenta Tatsumi; Jun Terao; Yasushi Tsuji

  ORGANIC LETTERS, May 2013, Peer-reviewed

  
• Design principle for increasing charge mobility of pi-conjugated polymers using regularly localized molecular orbitals

  Jun Terao; Akihisa Wadahama; Akitoshi Matono; Tomofumi Tada; Satoshi Watanabe; Shu Seki; Tetsuaki Fujihara; Yasushi Tsuji

  NATURE COMMUNICATIONS, Apr. 2013, Peer-reviewed

  
• Palladium-Catalyzed Reduction of Acid Chlorides to Aldehydes with Hydrosilanes

  Tetsuaki Fujihara; Cong Cong; Tomohiro Iwai; Jun Terao; Yasushi Tsuji

  SYNLETT, Oct. 2012, Peer-reviewed

  
• Synthesis of Insulated Pt-Alkynyl Complex Polymer

  Jun Terao; Hiroshi Masai; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMISTRY LETTERS, Jun. 2012, Peer-reviewed

  
• Copper-Catalyzed Highly Selective Semihydrogenation of Non-Polar Carbon-Carbon Multiple Bonds using a Silane and an Alcohol

  Kazuhiko Semba; Tetsuaki Fujihara; Tinghua Xu; Jun Terao; Yasushi Tsuji

  ADVANCED SYNTHESIS & CATALYSIS, May 2012, Peer-reviewed

  
• Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes: Controlling Regioselectivity by Choice of Catalytic Species

  Kazuhiko Semba; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  CHEMISTRY-A EUROPEAN JOURNAL, Apr. 2012, Peer-reviewed

  
• 平成23年度研究助成報告書 二酸化炭素を高付加価値化学物質へと変換する銅錯体触媒の開発

  藤原 哲晶

  ペトロテック, Jan. 2012

  
• Iridium-Catalyzed Addition of Aroyl Chlorides and Aliphatic Acid Chlorides to Terminal Alkynes

  Tomohiro Iwai; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jan. 2012, Peer-reviewed

  
• 二酸化炭素を高付加価値化学物質へと変換する銅錯体触媒の開発

  藤原 哲晶

  ペトロテック = Petrotech, Jan. 2012

  
• 配位子周辺部の修飾による新しい遷移金属錯体触媒の開発と触媒反応への応用

  藤原 哲晶

  有機合成化学協会誌, Jan. 2012

  
• Copper-Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes

  Tetsuaki Fujihara; Yosuke Tani; Kazuhiko Semba; Jun Terao; Yasushi Tsuji

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, Peer-reviewed

  
• Synthesis of an insulated molecular wire by click polymerization

  Jun Terao; Kazuya Kimura; Shu Seki; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2012, Peer-reviewed

  
• Carbon dioxide as a carbon source in organic transformation: carbon-carbon bond forming reactions by transition-metal catalysts

  Yasushi Tsuji; Tetsuaki Fujihara

  CHEMICAL COMMUNICATIONS, 2012, Peer-reviewed

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• Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide

  Tetsuaki Fujihara; Tomoya Hosoki; Yuko Katafuchi; Tomohiro Iwai; Jun Terao; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2012, Peer-reviewed

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• Nickel-​Catalyzed Carboxylation of Aryl and Vinyl Chlorides Employing Carbon Dioxide

  Tetsuaki Fujihara; Keisuke Nogi; Tinghua Xu; Jun Terao; Yasushi Tsuji

  Journal of the American Chemical Socie, 2012, Peer-reviewed

  
• Transition-Metal-Catalyzed Addition Reactions of Carbonyl Functionalities to Alkynes

  Yasushi Tsuji; Tetsuaki Fujihara

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Dec. 2011, Peer-reviewed

  
• Palladium(II) complexes bearing a salicylaldiminato ligand with a hydroxyl group: Synthesis , structures, deprotonation, and catalysis

  Yusuke Murata; Hiroyuki Ohgi; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  INORGANICA CHIMICA ACTA, Mar. 2011, Peer-reviewed

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• Palladium-Catalyzed Hydroesterification of Alkynes Employing Aryl Formates without the Use of External Carbon Monoxide

  Yuko Katafuchi; Tetsuaki Fujihara; Tomohiro Iwai; Jun Terao; Yasushi Tsuji

  ADVANCED SYNTHESIS & CATALYSIS, Feb. 2011, Peer-reviewed

  
• 遷移金属錯体によるカルボニル官能基のアルキンへの付加反応

  辻 康之; 藤原 哲晶

  有機合成化学協会誌, Jan. 2011

  
• Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes

  Tetsuaki Fujihara; Tinghua Xu; Kazuhiko Semba; Jun Terao; Yasushi Tsuji

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, Peer-reviewed

  
• Synthesis of a head-to-tail-type cyclodextrin-based insulated molecular wire

  Jun Terao; Kazuhiro Ikai; Nobuaki Kambe; Shu Seki; Akinori Saeki; Kento Ohkoshi; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2011, Peer-reviewed

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• Ruthenium-catalyzed ring-closing metathesis accelerated by long-range steric effect

  Tetsuaki Fujihara; Yoshikazu Tomike; Toshiyuki Ohtake; Jun Terao; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2011, Peer-reviewed

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• Transition-Metal-Catalyzed Additions of Carbonyl Functionalities to Alkynes

  Tetsuaki Fujihara; Tomohiro Iwai; Jun Terao; Yasushi Tsuji

  SYNLETT, Oct. 2010, Peer-reviewed

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• 配位子周辺部の修飾により発現する錯体触媒の特異な機能

  藤原 哲晶

  化学と工業 = Chemistry and chemical industry, Oct. 2010

  
• Iridium-Catalyzed Annulation of N-Arylcarbamoyl Chlorides with Internal Alkynes

  Tomohiro Iwai; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2010, Peer-reviewed

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• Synthesis of Linked Symmetric [3]Rotaxane Having an Oligomeric Phenylene-Ethynylene Unit as a pi Guest via Double Sonogashira Cross-coupling

  Jun Terao; Akihisa Wadahama; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMISTRY LETTERS, May 2010, Peer-reviewed

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• Palladium-Catalyzed Intermolecular Addition of Formamides to Alkynes

  Tetsuaki Fujihara; Yuko Katafuchi; Tomohiro Iwai; Jun Terao; Yasushi Tsuji

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2010, Peer-reviewed

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• Copper-Catalyzed Hydrosilylation with a Bowl-Shaped Phosphane Ligand: Preferential Reduction of a Bulky Ketone in the Presence of an Aldehyde

  Tetsuaki Fujihara; Kazuhiko Semba; Jun Terao; Yasushi Tsuji

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, Peer-reviewed

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• Synthesis of Organic-Soluble Conjugated Polyrotaxanes by Polymerization of Linked Rotaxanes

  Jun Terao; Susumu Tsuda; Yuji Tanaka; Kento Okoshi; Tetsuaki Fujihara; Yasushi Tsuji; Nobuaki Kambe

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2009, Peer-reviewed

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• Synthesis and Structural Characterization of a Series of Mono-O-(diphenylphosphinobenzyl)calix[6]arenes with and without tert-Butyl Moieties at the Upper Rim

  Tetsuaki Fujihara; Sho Kubouchi; Yasushi Obora; Makoto Tokunaga; Kazuhiro Takenaka; Yasushi Tsuji

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Sep. 2009, Peer-reviewed

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• A Triarylphosphine Ligand Bearing Dodeca(ethylene glycol) Chains: Enhanced Efficiency in the Palladium-Catalyzed Suzuki-Miyaura Coupling Reaction

  Tetsuaki Fujihara; Shohei Yoshida; Jun Terao; Yasushi Tsuji

  ORGANIC LETTERS, May 2009, Peer-reviewed

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• Iridium-Catalyzed Addition of Acid Chlorides to Terminal Alkynes

  Tomohiro Iwai; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2009, Peer-reviewed

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• The iridium-catalyzed decarbonylation of aldehydes under mild conditions

  Tomohiro Iwai; Tetsuaki Fujihara; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2008, Peer-reviewed

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• Triarylphosphanes with Dendritically Arranged Tetraethylene Glycol Moieties at the Periphery: An Efficient Ligand for the Palladium-Catalyzed Suzuki-Miyaura Coupling Reaction

  Tetsuaki Fujihara; Shohei Yoshida; Hidetoshi Ohta; Yasushi Tsuji

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, Peer-reviewed

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• N-heterocyclic carbene ligands bearing hydrophilic and/or hydrophobic chains: Rh(I) and Pd(II) complexes and their catalytic activity

  Hidetoshi Ohta; Tetsuaki Fujihara; Yasushi Tsuji

  DALTON TRANSACTIONS, 2008

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• New design in homogeneous palladium catalysis: Study of transformation of group 14 element compounds and development of nanosize palladium catalysts

  Yasushi Tsuji; Tetsuaki Fujihara

  BULLETIN OF THE KOREAN CHEMICAL SOCIETY, Nov. 2007

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• New design in homogeneous palladium catalysis: Study of transformation of group 14 element compounds and development of nanosize palladium catalysts

  Yasushi Tsuji; Tetsuaki Fujihara

  BULLETIN OF THE KOREAN CHEMICAL SOCIETY, Nov. 2007, Peer-reviewed

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• Recent development of homogeneous transition metal catalysts with nanosize ligands

  Yasushi Tsuji; Tetsuaki Fujihara

  CHEMISTRY LETTERS, Nov. 2007

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• Homogeneous nanosize palladium catalysts

  Yasushi Tsuji; Tetsuaki Fujihara

  INORGANIC CHEMISTRY, Mar. 2007

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• A bowl-shaped phosphine as a ligand in palladium-catalyzed Suzuki-Miyaura coupling of aryl chlorides: Effect of the depth of the bowl

  Hidetoshi Ohta; Makoto Tokunaga; Yasushi Obora; Tomohiro Iwai; Tetsuo Iwasawa; Tetsuaki Fujihara; Yasushi Tsuji

  ORGANIC LETTERS, Jan. 2007

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• Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks

  Hiromichi Sato; Tetsuaki Fujihara; Yasushi Obora; Makoto Tokunaga; Junya Kiyosu; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2007

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• Rhodium(III) complexes with a bidentate N-heterocyclic carbene ligand bearing flexible dendritic frameworks

  Tetsuaki Fujihara; Yasushi Obora; Makoto Tokunaga; Yasushi Tsuji

  DALTON TRANSACTIONS, 2007

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• Phosphines having a 2,3,4,5-tetraphenylphenyl moiety: Effective ligands in palladium-catalyzed transformations of aryl chlorides

  Tetsuo Iwasawa; Tomoko Komano; Atsunori Tajima; Makoto Tokunaga; Yasushi Obora; Tetsuaki Fujihara; Yasushi Tsuji

  ORGANOMETALLICS, Sep. 2006

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Misc.

• ロタキサン構造により被覆された金属-ジチオベンゾエート錯体の合成

  原田涼佑; 細見拓郎; 寺尾潤; 藤原哲晶; 辻康之

  日本化学会春季年会講演予稿集(CD-ROM), 2017

  
• ロタキサン構造により被覆されたπ共役分子のAu基板への接合挙動

  細見拓郎; 寺尾潤; 藤原哲晶; 辻康之

  基礎有機化学討論会要旨集, 2016

  
• パラジウム触媒を用いた酸無水物とヒドロシランによるアレンのヒドロアシル化

  細見拓郎; 巽謙太; CONG Cong; 藤原哲晶; 寺尾潤; 辻康之

  日本化学会講演予稿集, 2013

  
• 分子周辺部にエチレングリコール鎖を有する含窒素複素環カルベン配位子の開発とパラジウム錯体の触媒反応への応用

  吉川貴裕; 太田英俊; 藤原哲晶; 寺尾潤; 辻康之

  錯体化学討論会講演要旨集, 2010

  
• 長鎖疎水基及び長鎖親水基を有する新規デンドリマーモノホスフィン配位子の合成

  吉田昌平; 太田英俊; 藤原哲晶; 辻康之

  錯体化学討論会講演要旨集, 2007

  
• 疎水性・親水性部位を有する含窒素ヘテロ環カルベン配位子の合成と触媒反応への応用

  太田英俊; 藤原哲晶; 辻康之

  日本化学会講演予稿集, 2007

  
• 被覆による金属ビスジチオベンゾエート錯体の選択的合成と速度論的安定化

  原田涼佑; 細見拓郎; 正井宏; 藤原哲晶; 辻康之; 寺尾潤

  基礎有機化学討論会要旨集, 07 Sep. 2017

  
• 被覆型共役メタロワイヤを用いた燐光ガスセンサ材料の開発

  横山琢矢; 正井宏; 藤原哲晶; 辻康之; 寺尾潤

  基礎有機化学討論会要旨集, 07 Sep. 2017

  
• メチル化シクロデキストリンを用いた被覆による不安定錯体の合成と速度論的安定化

  原田涼佑; 細見拓郎; 正井宏; 藤原哲晶; 辻康之; 寺尾潤

  シクロデキストリンシンポジウム講演要旨集, 07 Aug. 2017

  
• 銅触媒による二酸化炭素とシリルボランを用いた不飽和化合物のシラカルボキシル化反応

  藤原哲晶; 谷洋介; 寺尾潤; 辻康之

  有機合成シンポジウム講演要旨集, 23 Oct. 2015

  
• 遷移金属含有被覆型分子ワイヤの合成と環状被覆効果

  正井宏; 寺尾潤; 藤原哲晶; 辻康之

  基礎有機化学討論会要旨集, 24 Sep. 2015

  
• 共役鎖上および鎖中に多座ピリジル系遷移金属錯体を含むメチル化CD被覆型分子ワイヤの合成およびその物性

  細見拓郎; 正井宏; 寺尾潤; 藤原哲晶; 辻康之

  シクロデキストリンシンポジウム講演要旨集, 01 Sep. 2014

  
• Copper-catalyzed borylative allyl-allyl coupling reaction

  Kazuhiko Semba; Kazuhiko Semba; Naoto Bessho; Tetsuaki Fujihara; Jun Terao; Yasushi Tsuji

  Angewandte Chemie - International Edition, 18 Aug. 2014

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• 被覆型架橋配位子を用いた高分子錯体の合成と物性

  正井宏; 寺尾潤; 藤原哲晶; 辻康之

  日本化学会講演予稿集, 09 Mar. 2012

  
• ナノサイズ分子触媒を用いる高効率変換反応の開発 (特集/グリーンケミストリー最前線)

  辻 康之; 藤原 哲晶

  化学工業, Jun. 2006

  
• Preparation of molybdenum porphyrin dioxygen complexes without bulky substituents

  T Fujihara; Y Sasaki; T Imamura

  CHEMISTRY LETTERS, May 1999

  
• Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks

  Hiromichi Sato; Tetsuaki Fujihara; Yasushi Obora; Makoto Tokunaga; Junya Kiyosu; Yasushi Tsuji

  CHEMICAL COMMUNICATIONS, 2007

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• Experimental and theoretical evaluation of the charge distribution over the ruthenium and dioxolene framework of [Ru(OAc)(dioxolene)(terpy)] (terpy) 2,2 ': 6 ', 2 ''-terpyridine) depending on the substituents

  Tohru Wada; Masahiro Yamanaka; Tetsuaki Fujihara; Yuji Miyazato; Koji Tanaka

  INORGANIC CHEMISTRY, Oct. 2006

  
• Dendrimer N-heterocyclic carbene complexes with rhodium(I) at the core

  T Fujihara; Y Obora; M Tokunaga; H Sato; Y Tsuji

  CHEMICAL COMMUNICATIONS, 2005

  
• Strong interaction between carbonyl and dioxolene ligands caused by charge distribution of ruthenium-dioxolene frameworks of mono- and dicarbonylruthenium complexes

  T Wada; T Fujihara; M Tomori; D Ooyama; K Tanaka

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Apr. 2004

  
• Syntheses and electrochemical properties of ruthenium(II) complexes with 4,4 '-bipyrimidine and 4,4 '-bipyrimidinium ligands

  T Fujihara; T Wada; K Tanaka

  INORGANICA CHIMICA ACTA, Mar. 2004

  
• Syntheses and electrochemical properties of ruthenium(II) complexes with 4,4 '-bipyrimidine and 4,4 '-bipyrimidinium ligands

  T Fujihara; T Wada; K Tanaka

  INORGANICA CHIMICA ACTA, Mar. 2004

  
• Acid-base equilibria of various oxidation states of aqua-ruthenium complexes with 1,10-phenanthroline-5,6-dione in aqueous media

  T Fujihara; T Wada; K Tanaka

  DALTON TRANSACTIONS, 2004

  
• Coordination ability of 1,10-phenanthroline-5,6-dione: syntheses and redox behavior of a Ru(II) complex with an o-quinoid moiety and of bridged Ru(II)-M(II) complexes (M = Pd, Pt)

  T Fujihara; R Okamura; T Wada; K Tanaka

  DALTON TRANSACTIONS, Aug. 2003

  
• Synthesis and properties of rhodium(III) porphyrin cyclic tetramer and cofacial dimer

  K Fukushima; K Funatsu; A Ichimura; Y Sasaki; M Suzuki; T Fujihara; K Tsuge; T Imamura

  INORGANIC CHEMISTRY, May 2003

  
• Synthesis, Properties and Crystal Structure of a Novel Anthracene-Bridged Mo-Zn Porphyrin Dimer

  Inorg. Chem., 2002

  
• Synthesis, Properties and Crystal Structure of a Novel Anthracene-Bridged Mo-Zn Porphyrin Dimer

  Inorg. Chem., 2002

  
• Unusual Oxidation of Oxo-peroxomolybdenum(VI) Tetramesitylporphyrin Giving Molybdenum(V) Porphyrin and Dioxygen

  Chem. Lett., 2001

  

Awards

• Feb. 2010

  The Society of Synthetic Organic Chemistry, Japan, Incentive Award in Synthetic Organic Chemistry, Japan
• 19 Feb. 2010

  有機合成化学協会, 有機合成化学奨励賞
• 01 Dec. 2014

  Thieme , Thieme Chemistry Journal Award 2015

External funds: Kakenhi

• Carbon-Hydrogen bond activation reactions realized by long-range steric effect of ligands

  Grant-in-Aid for Scientific Research (B)

  Basic Section 33020:Synthetic organic chemistry-related

  Kyoto University

  Fujihara Tetsuaki

  From 01 Apr. 2020, To 31 Mar. 2024, Project Closed

  炭素－水素結合;パラジウム;ロジウム;カルボン酸;コバルト;炭素ー水素結合活性化;DFT計算;炭素－水素結合活性化反応;炭素－水素結合活性化;分子内カルベン挿入反応;分子間 C-H 結合アリール化;炭素-水素結合活性化反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20H02738/
• Development of Periphery-functionalized Carboxylic Acid Ligands and Their Use in Transition-metal-catalyzed Transformations

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Kyoto University

  藤原 哲晶

  From 01 Apr. 2018, To 31 Mar. 2020, Project Closed

  カルボン酸;パラジウム触媒;炭素－水素結合活性化;パラジウム;炭素-水素結合活性化反応;配位子;炭素ー水素結合活性化反応;炭素ー水素結合活性化

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-18H04257/
• Development of Periphery-Functionalized Gigantic Ligands and Their Application to Transition-Metal Catalyzed Reactions

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  藤原 哲晶

  From 01 Apr. 2016, To 31 Mar. 2018, Project Closed

  カルボン酸配位子;ポリエチレングリコール;パラジウム;銅;配位子;カルボン酸;二酸化炭素;銅触媒;アレン;ジボロン;シリルボラン;エチレングリコール

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-16H01020/
• Development of carbon dioxide fixation methods by using heterogeneous and homogeneous catalysts

  Grant-in-Aid for Challenging Exploratory Research

  Kyoto University

  Tetsuaki Fujihara

  From 01 Apr. 2015, To 31 Mar. 2017, Project Closed

  二酸化炭素;均一系触媒;不均一系触媒;コバルト;マグネシウム;エポキシド;環状炭酸エステル;ニッケル;アリールトリフラート;アルケニルトリフラート

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K13755/
• Development of transition-metal catalyzed fixation of carbon dioxide via carbon-carbon bond formation

  Grant-in-Aid for Young Scientists (A)

  Kyoto University

  Tetsuaki Fujihara

  From 01 Apr. 2013, To 31 Mar. 2017, Project Closed

  二酸化炭素;銅;ニッケル;コバルト;アルキン;アレン;亜鉛;コバルト触媒;アクリル酸エステル;ヒドロシラン;アルコール;カルボン酸;シリルボラン

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25708017/
• 柔軟なナノサイズ反応場を提供する配位子の開発と遷移金属触媒反応への応用

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  藤原 哲晶

  From 01 Apr. 2013, To 31 Mar. 2015, Project Closed

  配位子制御;銅触媒;アレン;シリルボラン;反応場;パラジウム;含窒素複素環カルベン;ポリエチレングリコール

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-25105731/
• Catalytic Fixation of Carbon Dioxide Driven by Photoenergy

  Grant-in-Aid for Challenging Exploratory Research

  Kyoto University

  Tetsuaki FUJIHARA

  From 01 Apr. 2012, To 31 Mar. 2014, Project Closed

  二酸化炭素;カルボキシル化反応;ニッケル;コバルト;光エネルギー;銅

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24655139/
• Development of highly atom-efficient addition reactions with catalytic functionalizations

  Grant-in-Aid for Scientific Research (A)

  Kyoto University

  Yasushi TSUJI

  From 31 May 2012, To 31 Mar. 2015, Project Closed

  カルボニル化合物;遷移金属触媒;官能基化;パラジウム触媒;銅触媒;高選択的反応;カルボニル基;付加反応;イリジウム触媒;酸塩化物;高選択的;アルキン;脱カルボニル化反応;立体選択的;位置選択的

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24245021/
• 配位子周辺部の修飾による特異な反応場の構築と高機能触媒開発

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  藤原 哲晶

  From 01 Apr. 2011, To 31 Mar. 2013, Project Closed

  デンドリマー;ルテニウム;メタセシス;均一系触媒;配位子;ポリフェニレン;触媒環境;オレフィンメタセシス;エチレングリコール

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-23105523/
• 樹木状分子の特性を活かした協奏機能錯体触媒の開発

  Grant-in-Aid for Scientific Research on Priority Areas

  Science and Engineering

  Kyoto University

  藤原 哲晶

  From 01 Apr. 2008, To 31 Mar. 2010, Project Closed

  ホスフィン配位子;含窒素複素環カルベン配位子;ポリエチレングリコール;鈴木-宮浦反応;パラジウム;イリジウム;アルキン;付加反応;デンドリマー;協奏機能

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20037030/
• デンドリマー構造の内と外に協奏的な機能を付与した分子触媒の開発

  Grant-in-Aid for Scientific Research on Priority Areas

  Science and Engineering

  Kyoto University

  藤原 哲晶

  From 01 Apr. 2007, To 31 Mar. 2008, Project Closed

  デンドリマー;カルベン配位子;協奏機能;ロジウム;パラジウム;長鎖置換基

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19028025/
• デンドリマーの構造特性を活かした均一系分子触媒の合成と機能開発

  Grant-in-Aid for Young Scientists (B)

  Kyoto University

  藤原 哲晶

  From 01 Apr. 2006, To 31 Mar. 2008, Project Closed

  デンドリマー;均一系触媒;カルベン配位子;ロジウム;X線構造解析;ヒドロシリル化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18750074/
• Development of Zinc-catalyzed Silylative Transformation

  Grant-in-Aid for Scientific Research (C)

  Basic Section 33020:Synthetic organic chemistry-related

  Kyoto University

  藤原 哲晶

  From 01 Apr. 2024, To 31 Mar. 2027, Granted

  亜鉛;ケイ素;アルデヒド;ジエン

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24K08409/

External funds: others

• 二酸化炭素を炭素源とする触媒的なカルボン酸誘導体合成法の開拓

  ゼネラル石油研究奨励財団　研究助成

  From 2010, To 2010

  藤原哲晶
• 銅ヒドリド種の反応性を活かした分子変換反応の開拓

  三菱化学研究奨励基金

  From 2010, To 2010

  藤原哲晶
• 高い原子効率を達成するカルボニル化合物の炭素－炭素不飽和結合への付加反応の開拓

  住友財団　基礎科学研究助成

  From 2010, To 2011

  藤原哲晶
• 原子効率・環境調和・実用性を兼ね備えた遷移金属触媒反応の開発

  内藤記念科学奨励金（研究助成）

  From 2010, To 2011

  藤原哲晶
• 二酸化炭素を高付加価値化学物質へと変換する銅錯体触媒の開発

  石油学会　研究助成

  From 2010, To 2011

  藤原哲晶

Education

Teaching subject(s)

• From 01 Apr. 2025, To 31 Mar. 2026

  Introduction to Chemical Science and Technology

  7501, Spring, Faculty of Engineering, 2
• From 01 Apr. 2025, To 31 Mar. 2026

  Exercises in Basic Organic Chemistry

  7103, Spring, Faculty of Engineering, 2
• From 01 Apr. 2025, To 31 Mar. 2026

  Catalyst Chemistry

  7061, Spring, Faculty of Engineering, 2
• From 01 Apr. 2025, To 31 Mar. 2026

  Industrial Organic Chemistry

  7028, Fall, Faculty of Engineering, 2
• From 01 Apr. 2025, To 31 Mar. 2026

  ILAS Seminar

  Z001, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2025, To 31 Mar. 2026

  Energy and Hydrocarbon Chemistry, Adv.V

  H232, Fall, Graduate School of Engineering, 1.5
• From 01 Apr. 2025, To 31 Mar. 2026

  Advanced Organic Chemistry

  H818, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2024, To 31 Mar. 2025

  Catalyst Chemistry

  7061, Spring, Faculty of Engineering, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Industrial Organic Chemistry

  7028, Fall, Faculty of Engineering, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Exercises in Basic Organic Chemistry

  7103, Spring, Faculty of Engineering, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  ILAS Seminar

  Z001, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Chemistry of Organometallic Complexes

  H210, Fall, Graduate School of Engineering, 1.5
• From 01 Apr. 2024, To 31 Mar. 2025

  Organotransition Metal Chemistry 1

  H041, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2024, To 31 Mar. 2025

  Advanced Organic Chemistry

  H818, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2024, To 31 Mar. 2025

  Energy and Hydrocarbon Chemistry, Adv.V

  H232, Fall, Graduate School of Engineering, 1.5
• From 01 Apr. 2024, To 31 Mar. 2025

  Chemical Conversion of Carbon Resources

  H217, Fall, Graduate School of Engineering, 1.5
• From 01 Apr. 2023, To 31 Mar. 2024

  Exercises in Basic Organic Chemistry

  7103, Spring, Faculty of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Organic Chemistry II (Advanced Chemistry)

  7414, Spring, Faculty of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Introduction to Industrial Chemistry

  7405, Spring, Faculty of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Energy and Hydrocarbon Chemistry Special Seminar 3

  S206, Fall, Graduate School of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Energy and Hydrocarbon Chemistry Special Seminar 2

  S205, Fall, Graduate School of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Energy and Hydrocarbon Chemistry Special Seminar 1

  S204, Spring, Graduate School of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  ILAS Seminar

  Z001, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Master's Thesis

  D299, Year-long, Graduate School of Engineering, 0
• From 01 Apr. 2023, To 31 Mar. 2024

  Energy and Hydrocarbon Chemistry, Adv.VII

  D235, Spring, Graduate School of Engineering, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Energy and Hydrocarbon Chemistry, Adv.VIII

  D236, Fall, Graduate School of Engineering, 1
• From 01 Apr. 2023, To 31 Mar. 2024

  Advanced Organic Chemistry

  H818, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2023, To 31 Mar. 2024

  Energy and Hydrocarbon Chemistry, Adv.V

  H232, Fall, Graduate School of Engineering, 1.5
• From 01 Apr. 2023, To 31 Mar. 2024

  Seminar on Energy & Hydrocarbon Chemistry (A)

  H208, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2023, To 31 Mar. 2024

  Experiments & Exercises in Energy and Hydrocarbon Chemistry, Adv.

  D234, Year-long, Graduate School of Engineering, 8
• From 01 Apr. 2022, To 31 Mar. 2023

  Organic Chemistry II (Advanced Chemistry)

  7414, Spring, Faculty of Engineering, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Chemistry of Organometallic Complexes

  H210, Fall, Graduate School of Engineering, 1.5
• From 01 Apr. 2022, To 31 Mar. 2023

  Chemical Conversion of Carbon Resources

  H217, Fall, Graduate School of Engineering, 1.5
• From 01 Apr. 2022, To 31 Mar. 2023

  ILAS Seminar

  Z001, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Exercises in Basic Organic Chemistry

  7103, Spring, Faculty of Engineering, 2
• From Apr. 2012, To Mar. 2013

  Energy and Hydrocarbon Chemistry, Adv. III

  Spring, 工学研究科
• From Apr. 2012, To Mar. 2013

  Energy and Hydrocarbon Chemistry, Adv. IV

  Spring, 工学研究科
• From Apr. 2017, To Mar. 2018

  Advanced Organic Chemistry

  Spring, 工学研究科
• From Apr. 2018, To Mar. 2019

  Advanced Organic Chemistry

  Spring, 工学研究科
• From Apr. 2018, To Mar. 2019

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2018, To Mar. 2019

  Chemistry of Organometallic Complexes

  Spring, 工学研究科
• From Apr. 2018, To Mar. 2019

  Energy and Hydrocarbon Chemistry, Adv. III

  Spring, 工学研究科
• From Apr. 2018, To Mar. 2019

  Energy and Hydrocarbon Chemistry, Adv. IV

  Spring, 工学研究科
• From Apr. 2019, To Mar. 2020

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2019, To Mar. 2020

  Organotransition Metal Chemistry 2

  Spring, 工学研究科
• From Apr. 2019, To Mar. 2020

  Energy and Hydrocarbon Chemistry, Adv.VIII

  Fall, 工学研究科
• From Apr. 2020, To Mar. 2021

  ILAS Seminar :Organic chemistry for sustainable society - Synthesizing valuable molecules

  Spring, 全学共通科目
• From Apr. 2020, To Mar. 2021

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2020, To Mar. 2021

  Chemistry of Organometallic Complexes

  Spring, 工学研究科
• From Apr. 2021, To Mar. 2022

  ILAS Seminar :Organic chemistry for sustainable society - Synthesizing valuable molecules

  Spring, 全学共通科目
• From Apr. 2021, To Mar. 2022

  Organic Chemistry II (Advanced Chemistry)

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Exercises in Basic Organic Chemistry

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Organotransition Metal Chemistry 2

  Spring, 工学研究科

Participation in PhD Defense

• Leveraging Photo-induced Isomerization of π-Conjugated Molecules for Bioimaging and Drug Delivery

  HUO WENTING, Graduate School of Engineering, Sub-chief Examiner

  25 Nov. 2024
• Iron-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions Toward Selective Synthesis of Alkynes and Allenes via Propargylic/Allenylic Radical Species

  LU SIMING, Graduate School of Engineering, Sub-chief Examiner

  25 Nov. 2024
• New Synthetic Approaches to Heterocyclic Compounds Based on Iridium-Catalyzed Transformations of C(sp3)-H Bonds

  YAGI KAITO, Graduate School of Engineering, Sub-chief Examiner

  23 Mar. 2023
• Development of Early Transition Metal Hydride Catalysts for Ammonia Synthesis

  Yu Cao, Graduate School of Engineering, Sub-chief Examiner

  23 Mar. 2023

Part-time lecturer

• From 01 Oct. 2019, To 31 Mar. 2020

  国立大学法人豊橋技術科学大学
• From 01 Apr. 2018, To 31 Mar. 2019

  国立大学法人九州大学, 先導物質化学研究所
• From 01 Oct. 2019, To 31 Mar. 2020

  国立大学法人豊橋技術科学大学

Administration

Faculty management (title, position)

• From 01 Apr. 2014, To 31 Mar. 2016

  桂事業場環境安全衛生委員会　委員

Academic, Social Contribution

Committee Memberships

• From Mar. 2020, To Feb. 2022

  近畿支部幹事, 日本化学会
• From Apr. 2015, To Mar. 2017

  OM News編集委員, 近畿化学協会有機金属部会
• From Apr. 2013, To Mar. 2015

  関西支部庶務幹事, 石油学会