Basic Information

Professional Memberships

• From Oct. 2018, To Present

  The Japan Petroleum Institute
• From May 2018, To Present

  CATALYSIS SOCIETY OF JAPAN
• From Apr. 2010, To Present

  YOUNG COORDINATION CHEMISTS ASSOCIATION OF JAPAN
• From Apr. 2010, To Present

  JAPAN SOCIETY OF COORDINATION CHEMISTRY
• From Jan. 2010, To Present

  THE CHEMICAL SOCIETY OF JAPAN

Academic Degree

• 博士（工学）(京都大学)
• 修士（工学）(京都大学)

Academic Resume (Graduate Schools)

• 京都大学, 大学院工学研究科修士課程合成・生物化学専攻, 修了
• 京都大学, 大学院工学研究科博士後期課程合成・生物化学専攻, 修了

Academic Resume (Undergraduate School/Majors)

• 京都大学, 工学部工業化学科, 卒業

High School

• High School

  大阪府立三国丘高等学校

Research History

• From Jul. 2021, To Present

  Kyoto University, KUIAS-iCeMS, 特定講師
• From Apr. 2020, To Jun. 2021

  Osaka City University, Research Center for Artificial Photoshynthesis, 特定講師
• From Jan. 2019, To Mar. 2020

  Osaka City University, OCARINA, 特任講師
• From Apr. 2017, To Dec. 2018

  Osaka City University, Graduate School of Engineering, 特任助教
• From Apr. 2015, To Mar. 2017

  Kansai Technology Licensing Organization Co., Ltd.
• From Apr. 2012, To Mar. 2015

  Research Fellow, Japan Society for the Promotion of Science

Language of Instruction

• English
• Japanese

ID,URL

• J-Global ID

  201701008171263605

• External link

  https://www.horike.icems.kyoto-u.ac.jp/

Website(s) (URL(s))

• https://www.horike.icems.kyoto-u.ac.jp/members/hiroyasu-tabe

researchmap URL

• https://researchmap.jp/htabe

Research

Research Topics, Overview of the research

• Research Topics

  Coordination polymer, metal-organic framework, glass, heterogeneous catalysis, CO2 recycle

• Overview of the research

  My interest is (1) heterogeneous catalysis of coordination polymers (CPs)/metal-organic frameworks (MOFs) involving catalysts to convert CO2 into carbon monoxide and formic acid, (2) development of photo/electrocatalytic devices using CP/MOFs with proton (H+)-condictivity at high temperature and low humidification where conventional polymer electrolytes are not available, and (3) creation of multiple CP/MOF hybrids available as bimetallic alloy catalysts.

Research Interests

• Catalyst immobilization
• Metal-organic framework
• Heterogeneous catalysis
• Coordination polymer

Research Areas

• Nanotechnology/Materials, Biochemistry
• Nanotechnology/Materials, Inorganic and coordination chemistry

Papers

• Selective Crystallization of Linkage Isomers, [Rh^III(NCS)(SCN)₅]^3– and [Rh^III(SCN)₆]^3–, to Investigate Structural Trans Influence and Thermal Stability

  Miki Mukai; Seiya Hagiwara; Rika Tanaka; Hiroyasu Tabe; Takashi Nakazono; Yusuke Yamada

  Inorganic chemistry, 20 Oct. 2023, Peer-reviewed

  
• Nanocatalysis of prussian blue analogues related to h ₂ o ₂ production and utilization

  Yusuke Yamada; Hiroyasu Tabe

  Heterogeneous nanocatalysis for energy and environmental sustainability, 29 Nov. 2022, Invited

  
• Heterogenous CO₂ reduction photocatalysis of transparent coordination polymer glass membranes containing metalloporphyrins

  Hitoshi Izu; Hiroyasu Tabe; Yuji Namiki; Hiroki Yamada; Satoshi Horike

  Inorganic chemistry, 11 Jul. 2023, Peer-reviewed, Corresponding author

  
• Bismuth substitution in HSbOI with positively-charged oxide clusters

  Yuki Watanabe; Tatsuhiko Goto; Jingxin Xia; Naoki Ogiwara; Hiroyasu Tabe; Satoshi Horike; Yasuto Noda; Sayaka Uchida; Hiroshi Kageyama

  Chemistry Letters, 13 May 2023, Peer-reviewed

  
• Formation of porosity toward acetylene upon vitrification of non-porous photochromic coordination polymer crystals

  Zeyu Fan; Yong-Sheng Wei; Hiroyasu Tabe; Tomotaka Nakatani; Chinmoy Das; Hiroki Yamada; Satoshi Horike

  Chemistry of materials, 11 May 2023, Peer-reviewed

  
• Synergistic Effect of Fe^II and Mn^II Ions in Cyano-Bridged Heterometallic Coordination Polymers on Catalytic Selectivity of Benzene Oxygenation to Phenol

  Hiroyasu Tabe; Yusuke Seki; Mari Yamane; Takashi Nakazono; Yusuke Yamada

  The Journal of Physical Chemistry Letters, 12 Jan. 2023, Peer-reviewed, Lead author

  
• Single‐Crystal‐to‐Single‐Crystal Installation of Ln 4 (OH) 4 Cubanes in an Anionic Metallosupramolecular Framework

  Nobuto Yoshinari; Natthaya Meundaeng; Hiroyasu Tabe; Yusuke Yamada; Satoshi Yamashita; Yasuhiro Nakazawa; Takumi Konno

  Angewandte Chemie, 05 Oct. 2020, Peer-reviewed

  
• Coordination polymer-forming liquid Cu(2-isopropylimidazolate)

  Teerat Watcharatpong; Taweesak Pila; Thana Maihom; Tomohiro Ogawa; Takuya Kurihara; Koji Ohara; Tadashi Inoue; Hiroyasu Tabe; Yong-Sheng Wei; Kanokwan Kongpatpanich; Satoshi Horike

  Chemical Science, 2022, Peer-reviewed

  Access this paper :

  
• Heterogeneous catalysis of lanthanoid ions for the hydrolysis of p-Nitrophenyl phosphate enhanced by incorporation to cyano-bridged heterometallic coordination polymers

  Tabe, H.; Yorozu, S.; Yamada, Y.

  Journal of physical chemistry c, 10 Mar. 2022, Peer-reviewed, Lead author

  
• Cobalt hexacyanoferrate as an effective cocatalyst boosting water oxidation on oxynitride TaON photocatalyst under visible light

  Hikaru Matsuoka; Osamu Tomita; Hiroyasu Tabe; Hajime Suzuki; Yusuke Yamada; Ryu Abe

  Journal of Photochemistry and Photobiology A: Chemistry, Dec. 2021, Peer-reviewed

  
• RuO₂Nanoparticle-Embedded graphitic carbon nitride for efficient photocatalytic H₂Evolution

  Shimoyama, Y.; Koga, K.; Tabe, H.; Yamada, Y.; Kon, Y.; Hong, D.

  ACS applied nano materials, 26 Nov. 2021, Peer-reviewed

  
• Efficient capturing of hydrogen peroxide in dilute aqueous solution by co-crystallisation with amino acids

  Ryota Yamaguchi; Rika Tanaka; Mayu Maetani; Hiroyasu Tabe; Yusuke Yamada

  CrystEngComm, 2021, Peer-reviewed

  
• Enhanced catalytic stability of acid phosphatase immobilized in the mesospaces of a SiO2-nanoparticles assembly for catalytic hydrolysis of organophosphates

  Hiroyasu Tabe; Hiroyuki Oshima; Shusaku Ikeyama; Yutaka Amao; Yusuke Yamada

  Molecular catalysis, Jun. 2021, Peer-reviewed, Lead author

  
• Construction of Multistep Catalytic Systems in Protein Assemblies

  Hiroyasu Tabe; Takafumi Ueno

  Cell-Inspired Materials and Engineering, 2021, Peer-reviewed, Invited

  
• Single Open Sites on FeII Ions Stabilized by Coupled Metal Ions in CN-Deficient Prussian Blue Analogues for High Catalytic Activity in the Hydrolysis of Organophosphates

  Mari Yamane; Hiroyasu Tabe; Masami Kawakami; Hisashi Tanaka; Tohru Kawamoto; Yusuke Yamada

  Inorganic Chemistry, 02 Nov. 2020, Peer-reviewed

  
• Immobilization of ir(OH)3 nanoparticles in mesospaces of Al-SiO2 nanoparticles assembly to enhance stability for photocatalytic water oxidation

  Gentaro Sakamoto; Hiroyasu Tabe; Yusuke Yamada

  Catalysts, 03 Sep. 2020, Peer-reviewed

  
• 

  Single‐Crystal‐to‐Single‐Crystal Installation of Ln4(OH)4 Cubanes in an Anionic Metallosupramolecular Framework

  Nobuto Yoshinari; Natthaya Meundaeng; Hiroyasu Tabe; Yusuke Yamada; Satoshi Yamashita; Yasuhiro Nakazawa; Takumi Konno

  Angewandte Chemie International Edition, 13 Aug. 2020, Peer-reviewed

  
• Utilization of core-shell nanoparticles to evaluate subsurface contribution to water oxidation catalysis of [CoII(H2O)2]1.5[CoIII(CN)6] nanoparticles

  Hiroyasu Tabe: Akira Kitase; Yusuke Yamada

  Applied catalysis b: Environmental, Mar. 2020, Peer-reviewed

  
• Creation and stabilisation of tuneable open metal sites in thiocyanato-bridged heterometallic coordination polymers to be used as heterogeneous catalysts

  Hiroyasu Tabe; Masaaki Matsushima; Rika Tanaka; Yusuke Yamada

  DALTON TRANSACTIONS, Dec. 2019, Peer-reviewed

  
• 

  Effect of surface acidity of cyano-bridged polynuclear metal complexes on the catalytic activity for the hydrolysis of organophosphates

  Hiroyasu Tabe; Chihiro Terashima; Yusuke Yamada

  CATALYSIS SCIENCE & TECHNOLOGY, Oct. 2018, Peer-reviewed

  
• 

  Photocatalytic hydrogen evolution systems constructed in cross-linked porous protein crystals

  Hiroyasu Tabe; Hikaru Takahashi; Takuya Shimoi; Satoshi Abe; Takafumi Ueno; Yusuke Yamada

  Applied Catalysis B: Environmental, Feb. 2018, Peer-reviewed

  
• 

  Crystal Engineering of Self-Assembled Porous Protein Materials in Living Cells

  Satoshi Abe; Hiroyasu Tabe; Hiroshi Ijiri; Keitaro Yamashita; Kunio Hirata; Kohei Atsumi; Takuya Shimoi; Masaki Akai; Hajime Mori; Susumu Kitagawa; Takafumi Ueno

  ACS Nano, 09 Feb. 2017, Peer-reviewed

  
• Photoactivatable CO release from engineered protein crystals to modulate NF-κB activation

  Hiroyasu Tabe; Takuya Shimoi; Marion Boudes; Satoshi Abe; Fasséli Coulibaly; Susumu Kitagawa; Hajime Mori; Takafumi Ueno

  Chemical Communications, 2016, Peer-reviewed

  
• Design of a CO-releasing Extracellular Scaffold Using in Vivo Protein Crystals

  Hiroyasu Tabe; Takuya Shimoi; Kenta Fujita; Satoshi Abe; Hiroshi Ijiri; Masahiko Tsujimoto; Takahiro Kuchimaru; Shinae Kizaka-Kondo; Hajime Mori; Susumu Kitagawa; Takafumi Ueno

  Chemistry Letters, 05 Mar. 2015, Peer-reviewed

  
• Surface Functionalization of Protein Crystals with Carbohydrate Using Site-selective Bioconjugation

  Satoshi Abe; Yu Tokura; Rita Pal; Naoko Komura; Akihiro Imamura; Kaori Matsumoto; Hiroshi Ijiri; Nusrat J. M. Sanghamitra; Hiroyasu Tabe; Hiromune Ando; Makoto Kiso; Hajime Mori; Susumu Kitagawa; Takafumi Ueno

  Chemistry Letters, 05 Jan. 2015, Peer-reviewed

  
• Cover picture: Porous protein crystals as catalytic vessels for organometallic complexes (chem. asian j. 5/2014)

  Hiroyasu Tabe; Satoshi Abe; Tatsuo Hikage; Susumu Kitagawa; Takafumi Ueno

  Chemistry - an asian journal, Apr. 2014, Peer-reviewed

  
• Porous Protein Crystals as Catalytic Vessels for Organometallic Complexes

  Hiroyasu Tabe; Satoshi Abe; Tatsuo Hikage; Susumu Kitagawa; Takafumi Ueno

  Chemistry - An Asian Journal, Feb. 2014, Peer-reviewed

  
• Preparation of a Cross-Linked Porous Protein Crystal Containing Ru Carbonyl Complexes as a CO-Releasing Extracellular Scaffold

  Hiroyasu Tabe; Kenta Fujita; Satoshi Abe; Masahiko Tsujimoto; Takahiro Kuchimaru; Shinae Kizaka-Kondoh; Mikio Takano; Susumu Kitagawa; Takafumi Ueno

  Inorganic Chemistry, 2014, Peer-reviewed

  
• ChemInform abstract: Artificial metalloenzymes constructed from hierarchically-assembled proteins

  Takafumi Ueno; Hiroyasu Tabe; Yuya Tanaka

  ChemInform, 01 Oct. 2013, Peer-reviewed

  
• Artificial Metalloenzymes Constructed From Hierarchically-Assembled Proteins

  Takafumi Ueno; Hiroyasu Tabe; Yuya Tanaka

  Chemistry - An Asian Journal, May 2013, Peer-reviewed

  
• Post-crystal engineering of zinc-substituted myoglobin to construct a long-lived photoinduced charge-separation system

  Tomomi Koshiyama; Masanobu Shirai; Tatsuo Hikage; Hiroyasu Tabe; Koichiro Tanaka; Susumu Kitagawa; Takafumi Ueno

  Angewandte chemie, Apr. 2011, Peer-reviewed

  
• Post-Crystal Engineering of Zinc-Substituted Myoglobin to Construct a Long-Lived Photoinduced Charge-Separation System

  Tomomi Koshiyama; Masanobu Shirai; Tatsuo Hikage; Hiroyasu Tabe; Koichiro Tanaka; Susumu Kitagawa; Takafumi Ueno

  Angewandte Chemie International Edition, Apr. 2011, Peer-reviewed

  
• Mechanism for catalytic stability enhancement of Fe^III[Co^III(CN)₆] by doping divalent ions for organophosphate hydrolysis

  Seki, Y.; Tabe, H.; Yamada, Y.

  Journal of physical chemistry C, 31 Mar. 2022, Peer-reviewed

  
• Kinetic Analysis of Nitrite Reduction Reactions by Nitrite Reductase Derived from Spinach in the Presence of One-Electron Reduced Riboflavin

  Shusaku Ikeyama; Hiroyasu Tabe

  Sci, 15 Mar. 2022, Peer-reviewed

  

Misc.

• Heterogeneous catalysis by coordination polymers with intentionally introduced monodentate ligands

  Petrotech, Aug. 2022

  
• Catalysis in living cells

  Hiroyasu Tabe

  Jan. 2021

  
• Construction of composite photocatalytic hydrogen generation systems on various supports

  Yusuke Yamada; Hiroyasu Tabe

  JXTG Technical Review, Oct. 2018

  
• Solid Artificial Metalloenzymes by Post-Engineering of Porous Protein Crystals

  T. Ueno; S. Abe; H. Tabe

  JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, Mar. 2014

  
• Protein Crystals as Porous Supports for Catalyst Immobilization

  田部 博康

  触媒, Aug. 2021

  
• Creation of Open Metal Sites in Coordination Polymers for Catalytic Applications

  Bulletin of Japan Society of Coordination Chemistry (BJSCC), Nov. 2020

  
• 規則的構造を有する金属錯体の構造情報に基づいた固体触媒の調製

  OCARINA通信, Mar. 2019

  
• Functionalization of porous protein crystals by the accumulation of metal complexes

  Hiroyasu Tabe

  Bulletin of Japan Society of Coordination Chemistry (BJSCC), May 2011

  

Books and Other Publications

• CO2の有効利用技術の開発

  橋﨑, 克雄; 技術情報協会, Joint work, 酵素を利用した二酸化炭素資源化反応（田部 博康）

  技術情報協会, Jul. 2023

  Find Kyoto University's collection of books :

  
• 触媒総合事典

  触媒学会; 山下, 弘巳; 福岡, 淳; 田中, 庸裕; 関根, 泰, 生体触媒の固定化技術（田部 博康）

  朝倉書店, Feb. 2023

  Find Kyoto University's collection of books :

  
• Cell-inspired materials and engineering

  Wang, Dan Ohtan; Packwood, Daniel, Joint work, Construction of Multistep Catalytic Systems in Protein Assemblies (Hiroyasu Tabe and Takafumi Ueno)

  Springer International Publishing, Aug. 2021

  Find Kyoto University's collection of books :

  
• New Developments in Molecular Catalysis for Photoenergy Conversion

  日本化学会, Joint work, Integrated Catalysis Using Protein Crystals

  化学同人, Sep. 2020

  Find Kyoto University's collection of books :

  

External funds: Kakenhi

• Proximity Effect of Enzymes and Metal Complex Catalysts on Selective Oxidation

  Grant-in-Aid for Early-Career Scientists

  Basic Section 34010:Inorganic/coordination chemistry-related

  Kyoto University;Osaka City University

  Hiroyasu Tabe

  From 01 Apr. 2021, To 31 Mar. 2024, Project Closed

  固定化触媒;酸化還元;光触媒;配位高分子;多段階反応;人工酵素;不安定生成物;活性点;固定化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K14648/
• Photocatalytic water splitting by a MOF-modified semiconductor photocatalyst

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Complex systems

  Osaka City University

  田部 博康

  From 01 Apr. 2020, To 31 Mar. 2022, Granted

  光触媒;水分解;複合型触媒;配位高分子;プルシアンブルー;リンカー分子;表面修飾;コアシェル型微粒子;プルシアンブルー型錯体

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-20H05110/
• Joint international research on development of hybrid materials composed of photo and biocatalysts for carbon dioxide utilization

  Fund for the Promotion of Joint International Research (Fostering Joint International Research (B))

  Medium-sized Section 36:Inorganic materials chemistry, energy-related chemistry, and related fields

  Osaka Metropolitan University;Osaka City University

  Yutaka Amao

  From 07 Oct. 2019, To 31 Mar. 2024, Project Closed

  二酸化炭素還元;生体触媒;人工補酵素;半導体光触媒;多孔質材料

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19KK0144/
• Hierarchically Assembled Coordination Polymers for Sequential Release of Small Molecules

  Grant-in-Aid for Early-Career Scientists

  Basic Section 34010:Inorganic/coordination chemistry-related

  Osaka City University

  Hiroyasu Tabe

  From 01 Apr. 2019, To 31 Mar. 2021, Project Closed

  プルシアンブルー;配位高分子;ナノ粒子;コアシェル構造;配位子交換反応;コアシェル;金属錯体;シアノ架橋金属錯体ポリマー;吸脱着;配位不飽和サイト;シアノ架橋錯体ポリマー;コアシェル微粒子;小分子;吸着

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K15591/
• Storage and Release of Small Molecules with a Cyano-Bridged Polynuclear Metal Complex

  Grant-in-Aid for Research Activity Start-up

  Osaka City University

  Hiroyasu Tabe

  From 25 Aug. 2017, To 31 Mar. 2019, Project Closed

  シアノ架橋錯体ポリマー;プルシアンブルー;アンモニア;一酸化窒素;放出;シグナル分子;ガス分子;吸脱着;配位高分子;多核錯体;小分子

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H07020/

Administration

School management (title, position)

• From 01 Apr. 2024

  ASEAN拠点情報連絡会構成員

Academic, Social Contribution

Committee Memberships

• From Apr. 2020, To Present

  Committee Member, The Japan Petroleum Institute young Society
• From Sep. 2018, To Present

  世話人, 錯体化学若手の会
• From Sep. 2021

  実行委員, 第71回錯体討論会討論会
• From Mar. 2019

  実行委員, 第123回触媒討論会
• From Apr. 2022, To Mar. 2024

  幹事, 触媒学会 会誌編集委員会
• From Apr. 2021, To Mar. 2024

  編集委員, 触媒学会 会誌編集委員会
• From Apr. 2020, To Present

  世話人代表, 錯体化学若手の会近畿支部