Basic Information

Academic Degree

• 修士（工学）(京都大学)
• 博士（工学）(京都大学)

ID,URL

• J-Global ID

  201401090009460311

researchmap URL

• https://researchmap.jp/7000009009

Research

Research Topics, Overview of the research

• Research Topics

  Development of Porous Coordination Polymers toward Catalysis

Papers

• High CO2/N-2/O-2/CO separation in a chemically robust porous coordination polymer with low binding energy

  Jingui Duan; Masakazu Higuchi; Rajamani Krishna; Tomokazu Kiyonaga; Yosuke Tsutsumi; Yohei Sato; Yoshiki Kubota; Masaki Takata; Susumu Kitagawa

  CHEMICAL SCIENCE, 2014, Peer-reviewed

  
• High CO2/CH4 and C-2 Hydrocarbons/CH4 Selectivity in a Chemically Robust Porous Coordination Polymer

  Jingui Duan; Masakazu Higuchi; Satoshi Horike; Maw Lin Foo; Koya Prabhakara Rao; Yasutaka Inubushi; Tomohiro Fukushima; Susumu Kitagawa

  ADVANCED FUNCTIONAL MATERIALS, Jul. 2013, Peer-reviewed

  
• A Family of Rare Earth Porous Coordination Polymers with Different Flexibility for CO2/C2H4 and CO2/C2H6 Separation

  Jingui Duan; Masakazu Higuchi; Maw Lin Foo; Satoshi Horike; Koya Prabhakara Rao; Susumu Kitagawa

  INORGANIC CHEMISTRY, Jul. 2013, Peer-reviewed

  
• pH-Dependent Interpenetrated, Polymorphic, Cd2+- and BTB-based Porous Coordination Polymers with Open Metal Sites

  Koya Prabhakara Rao; Masakazu Higuchi; Jingui Duan; Susumu Kitagawa

  CRYSTAL GROWTH & DESIGN, Mar. 2013, Peer-reviewed

  
• Highly Selective CO2 Adsorption Accompanied with Low-Energy Regeneration in a Two-Dimensional Cu(II) Porous Coordination Polymer with Inorganic Fluorinated PF6- Anions

  Shin-ichiro Noro; Yuh Hijikata; Munehiro Inukai; Tomohiro Fukushima; Satoshi Horike; Masakazu Higuchi; Susumu Kitagawa; Tomoyuki Akutagawa; Takayoshi Nakamura

  INORGANIC CHEMISTRY, Jan. 2013, Peer-reviewed

  
• One-dimensional alignment of strong Lewis acid sites in a porous coordination polymer

  Takashi Kajiwara; Masakazu Higuchi; Akihiro Yuasa; Hideyuki Higashimura; Susumu Kitagawa

  CHEMICAL COMMUNICATIONS, 2013, Peer-reviewed

  
• Design of Flexible Lewis Acidic Sites in Porous Coordination Polymers by using the Viologen Moiety

  Masakazu Higuchi; Kohei Nakamura; Satoshi Horike; Yuh Hijikata; Nobuhiro Yanai; Tomohiro Fukushima; Jungeun Kim; Kenichi Kato; Masaki Takata; Daisuke Watanabe; Shinji Oshima; Susumu Kitagawa

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, Peer-reviewed

  
• Effects of Unsaturated Metal Sites on Radical Vinyl Polymerization in Coordination Nanochannels

  Takashi Uemura; Noriyuki Uchida; Masakazu Higuchi; Susumu Kitagawa

  MACROMOLECULES, Apr. 2011, Peer-reviewed

  
• Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymer

  Satoru Shimomura; Masakazu Higuchi; Ryotaro Matsuda; Ko Yoneda; Yuh Hijikata; Yoshiki Kubota; Yoshimi Mita; Jungeun Kim; Masaki Takata; Susumu Kitagawa

  NATURE CHEMISTRY, Aug. 2010, Peer-reviewed

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• Enhanced selectivity of CO2 from a ternary gas mixture in an interdigitated porous framework

  Keiji Nakagawa; Daisuke Tanaka; Satoshi Horike; Satoru Shimomura; Masakazu Higuchi; Susumu Kitagawa

  CHEMICAL COMMUNICATIONS, 2010, Peer-reviewed

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• New Interpenetrated Copper Coordination Polymer Frameworks having Porous Properties

  Prakash Kanoo; Ryotaro Matsuda; Masakazu Higuchi; Susumu Kitagawa; Tapas Kumar Maji

  CHEMISTRY OF MATERIALS, Dec. 2009, Peer-reviewed

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• One-dimensional imidazole aggregate in aluminium porous coordination polymers with high proton conductivity

  Sareeya Bureekaew; Satoshi Horike; Masakazu Higuchi; Motohiro Mizuno; Takashi Kawamura; Daisuke Tanaka; Nobuhiro Yanai; Susumu Kitagawa

  NATURE MATERIALS, Oct. 2009, Peer-reviewed

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• Porous Coordination Polymer with Pyridinium Cationic Surface, [Zn-2(tpa)(2)(Cpb)]

  Masakazu Higuchi; Daisuke Tanaka; Satoshi Horike; Hirotoshi Sakamoto; Kohei Nakamura; Yohei Takashima; Yuh Hijikata; Nobuhiro Yanai; Jungeun Kim; Kenichi Kato; Yoshiki Kubota; Masaki Takata; Susumu Kitagawa

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2009, Peer-reviewed

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• Charge-Polarized Coordination Space for H-2 Adsorption

  Jun-ya Hasegawa; Masakazu Higuchi; Yuh Hijikata; Susumu Kitagawa

  CHEMISTRY OF MATERIALS, May 2009, Peer-reviewed

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• Alkane hydroxylation catalyzed by a series of mononuclear nonheme iron complexes containing 4-nitropyridine ligands

  Yutaka Hitomi; Shinya Furukawa; Masakazu Higuchi; Tetsuya Shishido; Tsunehiro Tanaka

  JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, Jun. 2008, Peer-reviewed

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• Kinetic gate-opening process in a flexible porous coordination polymer

  Daisuke Tanaka; Keiji Nakagawa; Masakazu Higuchi; Satoshi Horike; Yoshiki Kubota; Latsuo C. Kobayashi; Masaki Takata; Susumu Kitagawa

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, Peer-reviewed

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• Storage and sorption properties of acetylene in jungle-gym-like open frameworks

  Daisuke Tanaka; Masakazu Higuchi; Satoshi Horike; Ryotaro Matsuda; Yoshinori Kinoshita; Nobuhiro Yanai; Susumu Kitagawa

  CHEMISTRY-AN ASIAN JOURNAL, 2008, Peer-reviewed

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• Kagome type extra-large microporous solid based on a paddle-wheel Cu(2+) dimer

  Satoshi Horike; Shinpei Hasegawa; Daisuke Tanaka; Masakazu Higuchi; Susumu Kitagawa

  CHEMICAL COMMUNICATIONS, 2008, Peer-reviewed

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• Spatial and surface design of porous coordination polymers

  Masakazu Higuchi; Satoshi Horike; Susumu Kitagawa

  SUPRAMOLECULAR CHEMISTRY, 2007, Peer-reviewed

  
• Correlation of spin states and spin delocalization with the dioxygen reactivity of catecholatoiron(III) complexes

  M Higuchi; Y Hitomi; H Minami; T Tanaka; T Funabiki

  INORGANIC CHEMISTRY, Nov. 2005, Peer-reviewed

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• Catalytic oxygenative degradation of 4-chlorocatechol by a nonheme iron(III) complex - Mechanism and prevention of catechol ester formation

  Y Hitomi; M Higuchi; T Tanaka; T Funabiki

  JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, Oct. 2005, Peer-reviewed

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• Electron spray ionization mass study on dioxygenation process in the reaction of catecholatoiron(III) complexes with molecular oxygen

  Y Hitomi; M Higuchi; T Tanaka; T Funabiki

  INORGANICA CHIMICA ACTA, Aug. 2005, Peer-reviewed

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• A linear correlation between energy of LMCT band and oxygenation reaction rate of a series of catecholatoiron(III) complexes: initial oxygen binding during intradiol catechol oxygenation

  Y Hitomi; M Yoshida; M Higuchi; H Minami; T Tanaka; T Funabiki

  JOURNAL OF INORGANIC BIOCHEMISTRY, Mar. 2005, Peer-reviewed

  
• Tuning of spin crossover equilibrium in catecholatoiron(III) complexes by supporting ligands

  Y Hitomi; M Higuchi; H Minami; T Tanaka; T Funabiki

  CHEMICAL COMMUNICATIONS, 2005, Peer-reviewed

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• A reaction intermediate involved in oxygenation of catecholatoiron(III) complexes with molecular oxygen - Relevance to catechol dioxygenases

  Y Hitomi; Y Tase; M Higuchi; T Tanaka; T Funabiki

  CHEMISTRY LETTERS, Mar. 2004, Peer-reviewed

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• Structures and electronic properties of the catecholatoiron complexes in relation to catechol dioxygenases: chlorocatecholatoiron complexes are compared to the 3,5-di-tert-butylcatecholatoiron complex in the solid state and in solution

  T Funabiki; A Fukui; Y Hitomi; M Higuchi; T Yamamoto; T Tanaka; F Tani; Y Naruta

  JOURNAL OF INORGANIC BIOCHEMISTRY, Jul. 2002, Peer-reviewed

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Misc.

• The RIKEN materials science beamline at SPring-8: Towards visualization of electrostatic interaction

  K. Kato; R. Hirose; M. Takemoto; S. Ha; J. Kim; M. Higuchi; R. Matsuda; S. Kitagawa; M. Takata

  AIP Conference Proceedings, 2010, Peer-reviewed

  

External funds: Kakenhi

• Development of non-fluorinated superhydrophobic porous material

  Grant-in-Aid for Young Scientists (B)

  Kyoto University

  Masakazu Hiugchi

  From 01 Apr. 2015, To 31 Mar. 2017, Project Closed

  超撥水;複合化;多孔性材料;複合化技術;複合材料;多孔性;超撥水性

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K17910/

Education

Teaching subject(s)

• From 01 Apr. 2024, To 31 Mar. 2025

  ILAS Seminar

  Z001, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Molecular assembly in chemistry and biology

  N930, Fall, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  ILAS Seminar

  Z001, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Molecular assembly in chemistry and biology

  N930, Fall, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  ILAS Seminar

  Z001, Spring, Institute for Liberal Arts and Sciences, 2
• From Apr. 2014, To Mar. 2015

  Integrated Cell-Material Sciences

  Fall, 全学共通科目
• From Apr. 2015, To Mar. 2016

  When chemistry meets cell biology

  Spring, 全学共通科目
• From Apr. 2015, To Mar. 2016

  Integrated Cell-Material Sciences

  Fall, 全学共通科目
• From Apr. 2016, To Mar. 2017

  ILAS Seminar

  Spring, 全学共通科目
• From Apr. 2017, To Mar. 2018

  ILAS Seminar

  Spring, 全学共通科目
• From Apr. 2018, To Mar. 2019

  ILAS Seminar

  Spring, 全学共通科目
• From Apr. 2019, To Mar. 2020

  ILAS Seminar

  Spring, 全学共通科目
• From Apr. 2020, To Mar. 2021

  ILAS Seminar :Lonely Planet - Across Multidisciplinary Science

  Spring, 全学共通科目
• From Apr. 2021, To Mar. 2022

  ILAS Seminar :Lonely Planet - Across Multidisciplinary Science

  Spring, 全学共通科目