Basic Information

Affiliated programs (koza)

• Graduate School of Engineering, 物質エネルギー化学専攻 物質変換科学講座, 准教授

Faculty

• Faculty of Engineering

Professional Memberships

• From Jan. 2022, To Present

  有機合成化学協会
• From Sep. 2019, To Present

  KINKA CHEMICAL SOCIETY
• From Sep. 2019, To Present

  The Society of Physical Organic Chemistry, Japan
• From Aug. 2016, To Present

  THE JAPANESE PHOTOCHEMISTRY ASSOCIATION
• From Mar. 2005, To Present

  THE CHEMICAL SOCIETY OF JAPAN

Academic Degree

• 修士（工学）(九州大学)
• 博士（工学）(九州大学)

Research History

• From Nov. 2018, To Present

  Kyoto University, Division of Synthetic Chemistry, Institute for Chemical Research, Associate Professor
• From Nov. 2011, To Oct. 2018

  Kyoto University, Department of Synthetic Chemistry and Biological Chemistry, Assistant Professor
• From May 2010, To Oct. 2011

  Eindhoven University of Technology (TU/e), Department of Chemical Engineering and Chemistry, Visiting Researcher
• From Apr. 2010, To Oct. 2011

  The University of Tokyo, Department of Applied Chemistry, JSPS Postdoctoral Research Fellow (PD)
• From Apr. 2007, To Mar. 2010

  Kyushu University, Department of Applied Chemistry, JSPS Research Fellow for Young Scientists (DC1)

Language of Instruction

• English

ID,URL

• ORCID ID

  0000-0002-5351-2101

• J-Global ID

  201401086132742278

• Researcher ID

  M-9764-2014

researchmap URL

• https://researchmap.jp/7000009163

Research

Research Topics, Overview of the research

• Research Topics

  1. Synthesis and Characterization of π-Extended Helical Aromatic Compounds
  2. Molecular Design of Helicene Derivatives showing Excellent Chiroptical Properties

• Overview of the research

  My research interest includes the development of synthetic approaches for the aromatic compounds with helical chirality and investigation of their novel molecular functions through spectroscopic measurements. More specifically, I aim at the systematic molecular design of helical aromatic compounds with uniformly extended pi conjugation systems to realize (1) an ideal response to circularly polarized lights (chiroptical properties), (2) molecular solenoid properties at the single-molecule level, (3) electronic spin selective conductance behavior in aromatic molecules with helical chirality, and (4) the development of tough and flexible polymer materials based on molecular spring properties.

Research Interests

• Organic Chemistry
• Molecular Springs
• Chirality
• Physical Organic Chemistry
• Photophysical Chemistry
• Quantum Chemical Calculation
• Photochemistry
• Photochromism
• Cooperative Assembly
• Scanning Tunneling Microscopy
• Diarylethene
• Supramolecular Chemistry

Research Areas

• Nanotechnology/Materials, Functional solid-state chemistry
• Nanotechnology/Materials, Basic physical chemistry, Physical Chemistry
• Life sciences, Bioorganic chemistry, Organic Chemistry
• Nanotechnology/Materials, Structural/physical organic chemistry, Organic Chemistry

Papers

• Nonplanar Nanographene with a Large Conjugated π-Surface

  Zongchi Zhang; Han Zhu; Jiajian Gu; Haonan Shi; Takashi Hirose; Long Jiang; Yanpeng Zhu; Dingyong Zhong; Jiaobing Wang

  Journal of the American Chemical Society, 21 Aug. 2024, Peer-reviewed

  
• Synthesis and Characterization of a Cyclic Trimer of a Chiral Spirosilabifluorene

  Rina Nakazono; Weizhe Hu; Takashi Hirose; Toru Amaya

  Chemistry – A European Journal, 27 Apr. 2024, Peer-reviewed

  
• Completely solvent-free synthesis of double heterohelicenes and their further ring fusion using mechanochemical reaction

  Honoka Sada; Daisuke Sakamaki; Masayuki Gon; Kazuo Tanaka; Takashi Hirose; Hideki Fujiwara

  RSC Mechanochemistry, 2024, Peer-reviewed

  
• Theoretical Investigation on Electron Transport Capabilities of Helically Twisted Molecules Based on Decay Constants of Exchange Interaction

  Yusuke Nakakuki; Takshi Hirose; Kenji Matsuda

  Chemistry Letters, 05 Mar. 2022, Peer-reviewed, Corresponding author

  
• Cover Picture: Investigation on the Surface-Confined Self-Assembly Stabilized by Hydrogen Bonds of Urea and Amide Groups: Quantitative Analysis of Concentration Dependence of Surface Coverage (Chem. Asian J. 9/2015).

  Nishitani, Nobuhiko; Hirose, Takashi; Matsuda, Kenji

  Chemistry, an Asian journal, 2015, Peer-reviewed

  
• Circularly polarized luminescence of Hetero[n]helicenes with 2,1,3-thiadiazole rings at both ends: Design of magnetically-allowed electronic transitions via heteroatom embedding

  Zheng Zhang; Yasujiro Murata; Takashi Hirose

  Tetrahedron, Aug. 2023, Peer-reviewed, Last author, Corresponding author

  
• CH₃CN@open‐C₆₀: An Effective Inner‐Space Modification and Isotope Effect Inside a Nano‐Sized Flask

  Guanglin Huang; Yuki Ide; Yoshifumi Hashikawa; Takashi Hirose; Yasujiro Murata

  Chemistry – A European Journal, 13 Jul. 2023, Peer-reviewed

  
• Logical Design of Small HOMO–LUMO Gap: Tetrabenzo[f,jk,mn,r][7]helicene as a Small-Molecule Near-Infrared Emitter

  Nakakuki, Y.; Hirose, T.; Matsuda, K.

  Organic Letters, 21 Jan. 2022, Peer-reviewed, Corresponding author

  
• Double Heterohelicenes Composed of Benzo[ b]- And Dibenzo[ b, i]phenoxazine: A Comprehensive Comparison of Their Electronic and Chiroptical Properties

  Sakamaki, D.; Tanaka, S.; Tanaka, K.; Takino, M.; Gon, M.; Tanaka, K.; Hirose, T.; Hirobe, D.; Yamamoto, H.M.; Fujiwara, H.

  Journal of Physical Chemistry Letters, 30 Sep. 2021, Peer-reviewed

  
• An H ₂ O ₂ Molecule Stabilized inside Open‐Cage C ₆₀ Derivatives by a Hydroxy Stopper

  Guanglin Huang; Shota Hasegawa; Yoshifumi Hashikawa; Yuki Ide; Takashi Hirose; Yasujiro Murata

  Chemistry – A European Journal, 10 Jan. 2022, Peer-reviewed

  
• All-Visible (>500 nm)-Light-Induced Diarylethene Photochromism Based on Multiplicity Conversion via Intramolecular Energy Transfer.

  Issei Ikariko; Sunnam Kim; Yae Hiroyasu; Kenji Higashiguchi; Kenji Matsuda; Takashi Hirose; Hikaru Sotome; Hiroshi Miyasaka; Satoshi Yokojima; Masahiro Irie; Seiji Kurihara; Tuyoshi Fukaminato

  The journal of physical chemistry letters, 05 Aug. 2022, Peer-reviewed

  
• Doubly linked chiral phenanthrene oligomers for homogeneously π-extended helicenes with large effective conjugation length

  Yusuke Nakakuki; Takashi Hirose; Hikaru Sotome; Min Gao; Daiki Shimizu; Ruiji Li; Jun-ya Hasegawa; Hiroshi Miyasaka; Kenji Matsuda

  Nature Communications, Dec. 2022, Peer-reviewed, Corresponding author

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• Diarylethene-Powered Light-Induced Folding of Supramolecular Polymers

  Takuya Fukushima; Kenta Tamaki; Atsushi Isobe; Takashi Hirose; Nobutaka Shimizu; Hideaki Takagi; Rie Haruki; Shin-ichi Adachi; Martin J. Hollamby; Shiki Yagai

  Journal of the American Chemical Society, 21 Apr. 2021, Peer-reviewed

  
• Donor-Acceptor Type [5]Helicene Derivative with Strong Circularly Polarized Luminescence

  Hiromu Kubo; Takashi Hirose; Daiki Shimizu; Kenji Matsuda

  Chemistry Letters, 05 Apr. 2021, Peer-reviewed, Corresponding author

  
• Tuning Transition Electric and Magnetic Dipole Moments: [7]Helicenes Showing Intense Circularly Polarized Luminescence

  Hiromu Kubo; Takashi Hirose; Takuya Nakashima; Tsuyoshi Kawai; Jun-ya Hasegawa; Kenji Matsuda

  The Journal of Physical Chemistry Letters, 14 Jan. 2021, Peer-reviewed, Corresponding author

  
• Arylene–hexaynylene and –octaynylene macrocycles: extending the polyyne chains drives self-association by enhanced dispersion force

  Shin-ichiro Kato; Ryo Kumagai; Tsukasa Abe; Chisa Higuchi; Yoshihito Shiota; Kazunari Yoshizawa; Nobutaka Takahashi; Koji Yamamoto; Md Zakir Hossain; Kazuhiro Hayashi; Takashi Hirose; Yosuke Nakamura

  Chemical Communications, 2021, Peer-reviewed

  
• HOMO–LUMO Energy-Gap Tuning of π-Conjugated Zwitterions Composed of Electron-Donating Anion and Electron-Accepting Cation

  Akihiro Shimizu; Yu Ishizaki; Shun Horiuchi; Takashi Hirose; Kenji Matsuda; Hiroyasu Sato; Jun-ichi Yoshida

  The Journal of Organic Chemistry, 01 Jan. 2021, Peer-reviewed

  
• Circularly Polarized Luminescence Designed from Molecular Orbitals: A Figure-Eight-Shaped [5]Helicene Dimer with D2 Symmetry

  Hiromu Kubo; Daiki Shimizu; Takashi Hirose; Kenji Matsuda

  Organic Letters, 04 Dec. 2020, Peer-reviewed, Corresponding author

  
• An orifice design: water insertion into C60

  Yoshifumi Hashikawa; Kazuro Kizaki; Takashi Hirose; Yasujiro Murata

  RSC Advances, Nov. 2020, Peer-reviewed

  
• The polymorphism of porphyrin 2D assemblies at the liquid-graphite interface: The effect of a polar solvent additive and a flexible spacer on the face-on and edge-on type molecular arrangements

  Adachi, K.; Hirose, T.; Matsuda, K.

  Chemical Communications, May 2019, Peer-reviewed, Corresponding author

  
• Fabrication of Robust Spatially Resolved Photochromic Patterns on Cellulose Papers by Covalent Printing for Anticounterfeiting Applications

  Bretel, G.; Le Grognec, E.; Jacquemin, D.; Hirose, T.; Matsuda, K.; Felpin, F.-X.

  ACS Applied Polymer Materials, Apr. 2019, Peer-reviewed

  
• Self-assembly of photochromic diarylethene–peptide conjugates stabilized by β-sheet formation at the liquid/graphite interface

  Nobuhiko Nishitani; Takashi Hirose; Kenji Matsuda

  Chemical Communications, Apr. 2019, Peer-reviewed

  
• 2-D self-assembly of alkyl-substituted oligophenylene derivatives at the liquid/solid interface: Influence of core size and hydrogen bonds on the nucleationelongation process

  Nishitani, N.; Hirose, T.; Matsuda, K.

  Chemistry Letters, Jan. 2019, Peer-reviewed

  
• Synthesis of a Helical Analogue of Kekulene: A Flexible π-Expanded Helicene with Large Helical Diameter Acting as a Soft Molecular Spring

  Yusuke Nakakuki; Takashi Hirose; Kenji Matsuda

  Journal of the American Chemical Society, 14 Nov. 2018, Peer-reviewed, Corresponding author

  
• Self-assembly of metal–organic polyhedra into supramolecular polymers with intrinsic microporosity

  Arnau Carné-Sánchez; Gavin A. Craig; Patrick Larpent; Takashi Hirose; Masakazu Higuchi; Susumu Kitagawa; Kenji Matsuda; Kenji Urayama; Shuhei Furukawa

  Nature Communications, 12 Jul. 2018, Peer-reviewed

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• Hexa- peri -hexabenzo[7]helicene: Homogeneously π-Extended Helicene as a Primary Substructure of Helically Twisted Chiral Graphenes

  Yusuke Nakakuki; Takashi Hirose; Hikaru Sotome; Hiroshi Miyasaka; Kenji Matsuda

  Journal of the American Chemical Society, 28 Mar. 2018, Peer-reviewed, Corresponding author

  
• Photoresponsive supramolecular self-assemblies at the liquid/solid interface

  Denis Frath; Soichi Yokoyama; Takashi Hirose; Kenji Matsuda

  Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 01 Mar. 2018, Peer-reviewed

  
• Influence of Multidirectional Interactions on Domain Size and Shape of 2-D Molecular Assemblies

  Nobuhiko Nishitani; Takashi Hirose; Kenji Matsuda

  LANGMUIR, Sep. 2017, Peer-reviewed

  
• Control over the Emission Properties of [5]Flelicenes Based on the Symmetry and Energy Levels of Their Molecular Orbitals

  Hiromu Kubo; Takashi Hirose; Kenji Matsuda

  ORGANIC LETTERS, Apr. 2017, Peer-reviewed

  
• Macrocyclic Oligothiophene with Stereogenic [2.2] Paracyclophane Scaffolds: Chiroptical Properties from pi-Transannular Interactions

  Masashi Hasegawa; Kosuke Kobayakawa; Hideyo Matsuzawa; Tohru Nishinaga; Takashi Hirose; Katsuya Sako; Yasuhiro Mazaki

  CHEMISTRY-A EUROPEAN JOURNAL, Mar. 2017, Peer-reviewed

  
• Discrimination between Conglomerates and Pseudoracemates Using Surface Coverage Plots in 2D Self-Assemblies at the Liquid-Graphite Interface

  Naoki Maeda; Takashi Hirose; Kenji Matsuda

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Feb. 2017, Peer-reviewed

  
• Aggregation of 4,8,12-Triazatriangulene Cation with Amphiphilic Side Chains: Emission Properties in Solution, in Aggregates, and in the Solid State

  Takashi Hirose; Kengo Sasatsuki; Hiromu Noguchi; Soichi Yokoyama; Kenji Matsuda

  CHEMISTRY LETTERS, Sep. 2016, Peer-reviewed, Lead author

  
• Synthesis and Photophysical Properties of a 13,13 '-Bibenzo[b]perylenyl Derivative as a pi-Extended 1,1 '-Binaphthyl Analog

  Yosuke Uchida; Takashi Hirose; Takuya Nakashima; Tsuyoshi Kawai; Kenji Matsuda

  ORGANIC LETTERS, May 2016, Peer-reviewed, Corresponding author

  
• Rational Design of Highly Photoresponsive Surface-Confined Self-Assembly of Diarylethenes: Reversible Three-State Photoswitching at the Liquid/Solid Interface

  Naoki Maeda; Takashi Hirose; Soichi Yokoyama; Kenji Matsuda

  JOURNAL OF PHYSICAL CHEMISTRY C, May 2016, Peer-reviewed

  
• Fluorescence behavior of 2,6,10-trisubstituted 4,8,12-triazatriangulene cations in solution and in the solid state

  Hiromu Noguchi; Takashi Hirose; Soichi Yokoyama; Kenji Matsuda

  CRYSTENGCOMM, 2016, Peer-reviewed

  
• Fluorescence behavior of 5,10-disubstituted [5] helicene derivatives in solution and the effect of self-assembly on their radiative and non-radiative rate constants

  Takashi Hirose; Natsuki Ito; Hiromu Kubo; Tohru Sato; Kenji Matsuda

  JOURNAL OF MATERIALS CHEMISTRY C, 2016, Peer-reviewed, Invited, Lead author

  
• Photochemical Cleavage of Axial Group Attached to the Central Carbon Atom of Triangulene Leuco Derivatives at the Ethanol/Au(111) Substrate

  Soichi Yokoyama; Takashi Hirose; Kenji Matsuda

  CHEMISTRY LETTERS, Nov. 2015, Peer-reviewed

  
• Effects of Alkyl Chain Length and Hydrogen Bonds on the Cooperative Self-Assembly of 2-Thienyl-Type Diarylethenes at a Liquid/Highly Oriented Pyrolytic Graphite (HOPG) Interface

  Soichi Yokoyama; Takashi Hirose; Kenji Matsuda

  CHEMISTRY-A EUROPEAN JOURNAL, Sep. 2015, Peer-reviewed

  
• Investigation on the Surface-Confined Self-Assembly Stabilized by Hydrogen Bonds of Urea and Amide Groups: Quantitative Analysis of Concentration Dependence of Surface Coverage

  Nobuhiko Nishitani; Takashi Hirose; Kenji Matsuda

  CHEMISTRY-AN ASIAN JOURNAL, Sep. 2015, Peer-reviewed

  
• Diarylethene Self-Assembled Monolayers: Cocrystallization and Mixing-Induced Cooperativity Highlighted by Scanning Tunneling Microscopy at the Liquid/Solid Interface

  Denis Frath; Takeshi Sakano; Yohei Imaizumi; Soichi Yokoyama; Takashi Hirose; Kenji Matsuda

  CHEMISTRY-A EUROPEAN JOURNAL, Aug. 2015, Peer-reviewed

  
• Photoinduced Four-State Three-Step Ordering Transformation of Photochromic Terthiophene at a Liquid/Solid Interface Based on Two Principles: Photochromism and Polymorphism

  Soichi Yokoyama; Takashi Hirose; Kenji Matsuda

  LANGMUIR, Jun. 2015, Peer-reviewed

  
• Photoinduced Macroscopic Morphological Transformation of an Amphiphilic Diarylethene Assembly: Reversible Dynamic Motion

  Kenji Higashiguchi; Genki Taira; Jun-ichiro Kitai; Takashi Hirose; Kenji Matsuda

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2015, Peer-reviewed

  
• Fluorescence Enhancement of Covalently Linked 1-Cyano-1,2-diphenylethene Chromophores with Naphthalene-1,8-diyl Linker Units: Analysis Based on Kinetic Constants

  Takashi Hirose; Yohei Tsunoi; Yuya Fujimori; Kenji Matsuda

  CHEMISTRY-A EUROPEAN JOURNAL, Jan. 2015, Peer-reviewed, Lead author

  
• Photochemical Cleavage of the Axial Group Attached to the Central Carbon Atom of Triazatriangulene

  Soichi Yokoyama; Takashi Hirose; Kenji Matsuda

  CHEMISTRY LETTERS, Jan. 2015, Peer-reviewed

  
• Molecular Design Strategy toward Diarylethenes That Photoswitch with Visible Light

  Tuyoshi Fukaminato; Takashi Hirose; Takao Doi; Masaki Hazama; Kenji Matsuda; Masahiro Irie

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2014, Peer-reviewed

  
• Facile Photochemical Synthesis of 5,10-Disubstituted [5]Helicenes by Removing Molecular Orbital Degeneracy

  Natsuki Ito; Takashi Hirose; Kenji Matsuda

  ORGANIC LETTERS, May 2014, Peer-reviewed

  
• Investigation on CD Inversion at Visible Region Caused by a Tilt of the pi-Conjugated Substituent: Theoretical and Experimental Approaches by Using an Asymmetric Framework of Diarylethene Annulated Isomer

  Takashi Hirose; Yuki Inoue; Jun-ya Hasegawa; Kenji Higashiguchi; Kenji Matsuda

  JOURNAL OF PHYSICAL CHEMISTRY A, Feb. 2014, Peer-reviewed, Lead author

  
• Phototriggered formation and disappearance of surface-confined self-assembly composed of photochromic 2-thienyl-type diarylethene: a cooperative model at the liquid/solid interface

  Soichi Yokoyama; Takashi Hirose; Kenji Matsuda

  CHEMICAL COMMUNICATIONS, 2014, Peer-reviewed

  
• Formation of two-dimensionally ordered diarylethene annulated isomer at the liquid/hopg interface upon in situ UV irradiation

  Takeshi Sakano; Yohei Imaizumi; Takashi Hirose; Kenji Matsuda

  Chemistry Letters, 2013, Peer-reviewed

  
• Photocontrol over Cooperative Porphyrin Self-Assembly with Phenylazopyridine Ligands

  Takashi Hirose; Floris Helmich; E. W. Meijer

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, Peer-reviewed, Lead author

  
• Conformational analysis of supramolecular polymerization processes of disc-like molecules

  Yoko Nakano; Takashi Hirose; Patrick J. M. Stals; E. W. Meijer; Anja R. A. Palmans

  CHEMICAL SCIENCE, 2012, Peer-reviewed

  
• Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the Solid State

  Takashi Hirose; Kenji Higashiguchi; Kenji Matsuda

  CHEMISTRY-AN ASIAN JOURNAL, Apr. 2011, Peer-reviewed, Lead author

  
• Theoretical investigation on the origin of the CD signal reversal for the closed-ring isomer of diarylethene with peripherical π-conjugated substituents

  Takashi Hirose; Jun-Ya Hasegawa; Kenji Matsuda

  Chemistry Letters, 2010, Peer-reviewed, Lead author

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• Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Core-Chain Ratio Dependence on Supramolecular Structures

  Takashi Hirose; Masahiro Irie; Kenji Matsuda

  CHEMISTRY-AN ASIAN JOURNAL, 2009, Peer-reviewed, Lead author

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• Self-assembly of amphiphilic fluorescent dyes showing aggregate-induced enhanced emission: temperature dependence of molecular alignment and intermolecular interaction in aqueous environment

  Takashi Hirose; Kenji Matsuda

  CHEMICAL COMMUNICATIONS, 2009, Peer-reviewed, Lead author

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• The photochromic and self-assembling properties of diarylethenes having chiral amphiphilic chains at the reactive carbon atoms

  Takashi Hirose; Masahiro Irie; Kenji Matsuda

  NEW JOURNAL OF CHEMISTRY, 2009, Peer-reviewed, Lead author

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• Temperature-light dual control of clouding behavior of an oligo(ethylene glycol)-diarylethene hybrid system

  Takashi Hirose; Masahiro Irie; Kenji Matsuda

  ADVANCED MATERIALS, Jun. 2008, Peer-reviewed, Lead author

  
• Self-assembly of photochromic diarylethenes with amphiphilic side chains: reversible thermal and photochemical control

  Takashi Hirose; Kenji Matsuda; Masahiro Irie

  JOURNAL OF ORGANIC CHEMISTRY, Sep. 2006, Peer-reviewed, Lead author

  

Misc.

• Control of the Emission and Chiroptical Properties of Helicene Derivatives

  Kenji Matsuda; Hiromu Kubo; Takashi Hirose

  Chiral Luminescence: From Molecules to Materials and Devices, 28 May 2024, Last author

  
• 5,10-二置換[5]ヘリセン誘導体の光化学反応を用いた合成

  伊藤夏輝; 廣瀬崇至; 松田建児

  日本化学会講演予稿集, 2014

  
• 5,10-二置換[5]ヘリセン誘導体の光化学反応を用いた合成と疎水性相互作用による自己集合

  伊藤夏輝; 廣瀬崇至; 松田建児

  基礎有機化学討論会要旨集, 2014

  
• 疎水性相互作用を用いたヘリセン誘導体の自己集合

  伊藤夏輝; 廣瀬崇至; 松田建児

  基礎有機化学討論会要旨集, 2013

  
• Highly Sensitive Photoresponsive System Using Cooperative Assembly at Solid/Liquid interface

  横山 創一; 廣瀬 崇至; 松田 建児

  化學工業, Jul. 2015

  
• Tuning Transition Electric and Magnetic Dipole Moments: [7]Helicenes Showing Intense Circularly Polarized Luminescence (vol 12, pg 686, 2021)

  Hiromu Kubo; Takashi Hirose; Takuya Nakashima; Tsuyoshi Kawai; Jun-ya Hasegawa; Kenji Matsuda

  JOURNAL OF PHYSICAL CHEMISTRY LETTERS, Feb. 2021

  
• Difference in Reactivity of Open-Cage C₆₀ Derivatives Bearing a C=C or C=N Moiety on Their Openings

  木崎和郎; KIM Kyusun; 橋川祥史; 廣瀬崇至; 村田靖次郎

  日本化学会春季年会講演予稿集(CD-ROM), 2020

  
• トリアジン誘導体を用いたH₂O@C₆₀の大量合成法の開発

  木崎和郎; KIM Kyusun; 橋川祥史; 廣瀬崇至; 村田靖次郎

  基礎有機化学討論会要旨集, 2019

  
• Photochemical manipulation of two-dimensional self-assembly

  Hirose, T.; Matsuda, K.

  Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Apr. 2018, Peer-reviewed, Invited

  
• Strategic Design of Highly Emissive Organic Molecules Based on Interchromophoric Interactions and Control of Molecular Orbitals

  Takashi Hirose

  Journal of the Japan Society of Colour Material, Jan. 2018, Peer-reviewed, Invited

  
• Cooperativity in Self-Assemblies and Dynamic Response to External Stimuli

  Takashi Hirose; Kenji Matsuda

  Polymers, Dec. 2017, Peer-reviewed

  
• 二次元界面での超分子化学—協同的組織化を用いた高感度光応答性分子配列の設計

  廣瀬 崇至

  化学と工業, Nov. 2017, Peer-reviewed, Invited

  
• 協同的組織化を用いた光応答性二次元分子配列の設計

  Takashi Hirose

  日本化学会研究会「低次元系光機能材料研究会」ニュースレター, Jul. 2017, Peer-reviewed, Invited

  
• Cooperative self-assembly of photochromie diarylethenes at liquid/solid interface and highly sensitive photoinduced transformation of the ordering

  Kenji Matsuda; Takashi Hirose; Soichi Yokoyama; Denis Frath

  Photon-Working Switches, 29 May 2017

  
• 固液界面での協同的組織化を用いた高感度光配列制御

  横山 創一; 廣瀬 崇至; 松田 建児

  化学工業, Jul. 2015

  
• Photoswitching of chiral supramolecular environments and photoinduced lower critical solution temperature transitions in aqueous media following a supramolecular approach

  Takashi Hirose; Kenji Matsuda

  ORGANIC & BIOMOLECULAR CHEMISTRY, 2013, Peer-reviewed

  
• Supramolecular porphyrin systems chemistry

  Floris Helmich; Marko M. L. Nieuwenhuizen; Takashi Hirose; Cameron C. Lee; Albert P. H. J. Schenning; E. W. Meijer

  ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2011

  
• 水中で組織化する両親媒性ジアリールエテンによる光誘起超分子環境変化とLCST転移挙動

  T. Hirose; K. Matsuda

  Photochemistry, Aug. 2008, Peer-reviewed

  

Presentations

• Rational Design of Helically Twisted Chiral Molecular Wires based on Homogeneously π-Extended Helicenes

  Takashi Hirose

  20th International Symposium on Novel Aromatic Compounds (ISNA-20), 15 Aug. 2024

  
• らせん状π共役分子を用いた未来材料の開発

  廣瀬 崇至

  JSTさきがけ「未来材料」領域 第15回未来材料セミナー, 14 Dec. 2023, Invited

  
• らせん状化合物の機能開拓と着想の経緯

  廣瀬崇至

  第１回メゾヒエラルキー若手会, 11 Nov. 2023, Invited

  
• Photochemical Synthesis and Emission Properties of Pyrene Dimers Covalently Linked to a Helical π-Conjugated System

  Takashi Hirose

  10th International Symposium on Photochromism (ISOP 2023), 08 Nov. 2023

  
• Homogeneously π-Extended Helicenes as Helically Twisted Chiral Molecular Wires

  Takashi Hirose

  The 15th Asian Conference on Organic Electronics (A-COE 2023), 01 Nov. 2023, Invited

  
• Terminal Functionalization of Helical Molecules and Their Properties

  Takashi Hirose

  The 2nd Seminar on International Core-to-Core Project on Nano Carbon Device Science at Kyoto, 06 Oct. 2023, Invited

  
• Synthesis of π-Extended Helicenes and Their Properties as Helical Molecular Wires

  Takashi Hirose

  CEMS Topical Meeting on Chemistry of π-Conjugated Materials, 31 Jul. 2023, Invited

  
• らせん状化合物の合成と分子機能の開拓

  廣瀬崇至

  第３回 岡山理科大学プロジェクト研究推進事業 学術講演会, 27 Feb. 2023, Invited

  
• Synthesis and Molecular Function of π-Extended Helicenes as Ladder-Shaped Molecules

  Takashi Hirose

  The 2nd Workshop on Ladder Polymer Science at OIST, 21 Nov. 2022, Invited

  
• Doubly Linked Chiral Phenanthrene Oligomers for Homogeneously π-Extended Helicenes with Large Effective Conjugation Length

  Takashi Hirose

  The 4th International Symposium on the Synthesis and Applications of Curved Organic pi-Molecules and Materials (Curo-π4), 28 Sep. 2022, Invited

  
• Synthesis of π-Extended Helicenes and Their Molecular Functions

  Takashi Hirose

  The Kick-off Meeting for International Core-to-Core Project on Nano Carbon Devices, 16 Sep. 2022, Invited

  
• らせんπ共役化合物の合成と物性開拓

  廣瀬崇至

  京都大学大学院工学研究科分子工学専攻 第310回分子工学コロキウム, 25 Apr. 2022, Invited

  
• Doubly Linked Chiral Phenanthrene Oligomers for Homogeneously π-Extended Helicenes with Large Effective Conjugation Length

  Takashi Hirose

  NanoSynergetics monthly web seminar organized by French-Japanese International Associate Laboratory, 15 Apr. 2022, Invited

  
• Development of Circularly Polarized Luminescence (CPL) Properties Using Helical Aromatic Compounds

  Takashi Hirose

  International CREST-CPL Conference in Awaji, Japan (ICCC-2022), 04 Mar. 2022, Invited

  
• らせん状芳香族化合物を用いた円偏光物性の開拓

  廣瀬崇至

  第9回IROASTシンポジウム ~Nano-organics and Nano-hybrids~, 21 Jan. 2022, Invited

  
• π拡張型ヘリセン誘導体の合成とらせん構造に由来する分子機能

  廣瀬崇至

  大阪府立大学理学系研究科 分子科学特別講義B/F, 09 Nov. 2021, Invited

  
• Development of Highly Efficient Photophysical and Photoresponsive Functions Based on Rational Designs of π-Conjugated Compounds

  Takashi Hirose

  Annual Meeting on Photochemistry 2021, 14 Sep. 2021, Invited

  
• π拡張型ヘリセン誘導体の合成と分子機能の開拓

  廣瀬崇至

  錯体化学若手研究会「錯体化学若手の会夏の学校2021」, 03 Aug. 2021, Invited

  
• Tuning the Transition Electric and Magnetic Dipole Moments: [7]Helicenes Showing Intense Circularly Polarized Luminescence

  Takashi Hirose

  The 101st CSJ Annual Meeting (2021), 20 Mar. 2021, Invited

  
• π拡張型らせん状化合物の合成と物性開拓

  廣瀬崇至

  第五回 "光"機到来！ Qコロキウム, 17 Aug. 2020, Invited

  
• Management of Chiroptical Properties using Helicene-Based Molecules

  Takashi Hirose

  Online seminar at Guido Clever’s research group, Technische Universität Dortmund, 26 Jun. 2020, Invited

  
• Rational Design of Highly Emissive Molecules Based on Molecular Orbitals and Intermolecular Interactions

  Takashi Hirose

  The 100th CSJ Annual Meeting (Abstracts), 05 Mar. 2020, Invited

  
• Photophysical and Mechanical Properties of π-Extended Helicenes

  Takashi Hirose

  TU/e Meijer Symposium 2020, 27 Feb. 2020, Invited

  
• Photochemical and Photophysical Functions of Molecular Assemblies with Chirality

  Takashi Hirose

  第2回令和元年度化学研究所イブニングセミナー, 13 Nov. 2019, Invited

  
• pi-Expansion of Helically Twisted pi-Conjugated compounds and Their Properties

  Takashi Hirose

  第40回光化学若手の会, 14 Jun. 2019, Invited

  
• Synthesis of pi-Extended Helical Aromatic Compounds and Molecular Functions

  Takashi Hirose

  第7回慶應有機化学若手シンポジウム, 11 May 2019, Invited

  
• Development of Molecular Functions Based on Helically Twisted Polycyclic Aromatic Hydrocarbons

  Takashi Hirose

  IRCCS The 2nd International Symposium "New Future by Chemical Synthesis and Energy Materials", 25 Jan. 2019, Invited

  
• π拡張型らせん状分子のキラル分光特性と分子バネ特性

  廣瀬 崇至

  研究室講演会 (千葉大学グローバルプロミネント研究基幹 矢貝史樹研究室), 12 Dec. 2018, Invited

  
• π拡張型らせん状芳香族化合物の合成と物性評価

  廣瀬 崇至

  物質科学セミナー (筑波大学数理物質系 山本洋平研究室), 11 Dec. 2018, Invited

  
• キラリティーを持つ多環芳香族化合物の合成と分子機能

  廣瀬 崇至

  化学科講演会 (静岡大学理学部 山中正道研究室), 30 Nov. 2018, Invited

  
• π-Extended Polycyclic Aromatic Hydrocarbons Having Axial or Helical Chirality

  Takashi Hirose

  International Congress on Pure & Applied Chemistry Langkawi 2018 (ICPAC Langkawi), 30 Oct. 2018, Invited

  
• キラリティーを持つ大きなπ共役系分子の合成と分光特性評価

  廣瀬 崇至

  第5回π造形科学若手研究会, 05 Oct. 2018, Invited

  
• π拡張型キラル化合物の合成と分光特性

  廣瀬 崇至

  第7回化学フロンティア研究会, 02 Sep. 2018, Invited

  
• 走査型トンネル顕微鏡 (STM) を用いた光応答性分子配列の観測

  廣瀬 崇至

  第48回国際化学オリンピック (IChO48) 日本代表生徒特別訓練京都大学合宿, 25 Jun. 2016, Invited

  
• Design of Highly Photoresponsive 2-D Molecular Orderings Based on Cooperative Assembly at the Liquid/Graphite Interface

  Takashi Hirose

  Workshop on Control and Functions of Two-Dimensional Materials, 06 Jun. 2016, Invited

  
• Highly Photoresponsive –D Assembly at the Liquid/Graphite Interface

  T. Hirose; S. Yokoyama; N. Maeda; K. Matsuda

  The 2nd International Symposium on Synthetic Two-Dimensional Polymers (S2DP-2), 03 Jun. 2016

  
• STM Investigation on Highly Photoresponsive Surface-Confined Self-Assembly of Photochromic Diarylethenes

  Takashi Hirose

  Multi-Responsive Photochromes (MRP) Conference in Nantes, 27 Apr. 2016

  
• 走査型トンネル顕微鏡 (STM) を用いた光応答性分子配列の観測：協同的組織化モデルを用いた配列形成プロセスの解析

  Takashi Hirose

  第61回超分子創製化学セミナー (立命館大学 薬学部), 19 Jan. 2016, Invited

  
• Photoresponsive Supramolecular Assemblies Composed of Photochromic Diarylethenes: Investigation of Concentration Dependence of Surface Coverage at a Liquid/Solid Interface Using a Nucleation–Growth Model

  T. Hirose; S. Yokoyama; D. Frath; T. Sakano; K. Matsuda

  The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015), Dec. 2015

  
• Fluorescence Enhancement of Covalently Linked Fluorescent Chromophores with Naphthalene-1,8-diyl Linker Units: Analysis Based on Kinetic Constants

  T. Hirose; Y. Tsunoi; Y. Fujimori; K. Matsuda

  The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015), Dec. 2015

  
• Photocontrol over Surface-Confined Self-Assembly Composed of Photochromic Diarylethenes: Cooperative Model at the Liquid/Solid Interface

  T. Hirose; S. Yokoyama; D. Frath; T. Sakano; K. Matsuda

  16th International Symposium on Novel Aromatic Compounds (ISNA-16), PSB-128, Jul. 2015

  
• ナフタレン-1,8-ジイル基で連結した蛍光色素の発光特性とその温度依存性：速度定数および量子化学計算を用いた解析

  廣瀬崇至; 角井洋平; 藤森裕也; 松田建児

  新学術領域研究「高次複合光応答」第１回領域会議・第２回若手セミナー, 05 Jun. 2015

  
• ウレア基とアミド基の水素結合に由来する協同的組織化挙動の固液界面におけるSTM観察

  西谷暢彦; 廣瀬崇至; 松田建児

  日本化学会第95春季年会, 4D3-04, Mar. 2015

  
• ジアリールエテンが形成する光応答性分子配列のSTM観察とチエニル基の置換位置依存性

  前田尚生; 廣瀬崇至; 松田建児

  日本化学会第95春季年会, 4D3-03, Mar. 2015

  
• "Mixing-Induced Cooperativity" Highlighted by Scanning Tunneling Microscopy at the Liquid/Solid Interface

  F. Denis; T. Sakano; Y. Imaizumi; S. Yokoyama; T. Hirose; K. Matsuda

  The 95th CSJ annual meeting, 3D3-17, Mar. 2015

  
• Photoresponsive 2-D Orderings of Diarylethenes at the Liquid/HOPG Interface: Correlation between Molecular Structure and Cooperative Parameter

  S. Yokoyama; T. Hirose; K. Matsuda

  The 95th CSJ annual meeting, 3D3-15, Mar. 2015

  
• Temperature Effect on Fluorescence Enhancement of Covalently-Linked Fluorescent Chromophores with Naphthalene-1,8-diyl Linker Units

  T. Hirose; Y. Tsunoi; Y. Fujimori; K. Matsuda

  The 95th CSJ annual meeting, 2D4-35, Mar. 2015

  
• Reversible Photocontrol over Axial Coordination of Diarylethene-Based Pyridine Ligands to Zinc-Porphyrin Using Substituents Effect

  C. Lu; T. Hirose; K. Matsuda

  The 95th CSJ annual meeting, 2A7-34, Mar. 2015

  
• 可視光で可逆的なフォトクロミズムを示すジアリールエテンのための分子設計指針

  深港豪; 廣瀬崇至; 松田建児; 入江正浩

  日本化学会第95春季年会, 1A7-43, Mar. 2015

  
• ナフタレン-1,8-ジイル基で連結した蛍光色素の発光増強特性とその温度依存性：速度定数を用いた解析

  廣瀬崇至; 角井洋平; 藤森裕也; 松田建児

  高次複合光応答第2回公開シンポジウム, P18, Jan. 2015

  
• STM Observation of Phototriggered Formation and Disappearance of Molecular Orderings: A Cooperative Model on 2-D Surface

  Takashi Hirose

  The 4th International Kyoto Symposium on Organic Nanostructures, 06 Nov. 2014, Invited

  
• トリアザトリアンギュレン誘導体の中心炭素に導入した軸置換基の光解離挙動

  廣瀬崇至; 横山創一; 松田建児

  2014年光化学討論会, 1P023, Oct. 2014

  
• ジアリールエテン超分子構造体の光誘起形態変化

  東口顕士; 平元輝; 北井淳一郎; 廣瀬崇至; 松田建児

  2014年光化学討論会, 1P012, Oct. 2014

  
• 固液界面におけるジアリールエテンの協同的分子配列形成の評価と配列形成・崩壊挙動の光制御

  横山創一; 廣瀬崇至; 松田建児

  2014年光化学討論会, 1P005, Oct. 2014

  
• 中心炭素に軸置換基を有するトリアザトリアンギュレン誘導体の光解離挙動における置換基および溶媒効果

  横山創一; 廣瀬崇至; 松田建児

  第25回基礎有機化学討論会, 1P039, Sep. 2014

  
• π共役の繋がりの変化を利用したジアリールエテン配位子の光応答性錯形成挙動

  呂澄; 廣瀬崇至; 松田建児

  第25回基礎有機化学討論会, 1P039, Sep. 2014

  
• ウレア基を介した水素結合ネットワークを有する2次元配列のSTM観察と協同的組織化挙動

  西谷暢彦; 廣瀬崇至; 松田建児

  第25回基礎有機化学討論会, 1P037, Sep. 2014

  
• 5,10-二置換[5]ヘリセン誘導体の光化学反応を用いた合成と疎水性相互作用による自己集合

  伊藤夏輝; 廣瀬崇至; 松田建児

  第25回基礎有機化学討論会, 1P029, Sep. 2014

  
• 固液界面におけるジアリールエテンの協同的組織化と配列形成・消失の光制御

  横山創一; 廣瀬崇至; 松田建児

  第25回基礎有機化学討論会, 1C07, Sep. 2014

  
• Phototriggered formation and disappearance of surface confined self-assembly of photochromic diarylethene: a cooperative model at the liquid/solid interface

  Yokoyama; T. Sakano; Y. Imaizumi; T. Hirose; K. Matsuda

  9th Phenics International Network Symposium, Jul. 2014

  
• 5,10-二置換[5]ヘリセン誘導体の光化学反応による合成

  伊藤夏輝; 廣瀬崇至; 松田建児

  日本化学会第94春季年会, 1A1-13, Mar. 2014

  
• 固液界面におけるジアリールエテンの光応答性二次元配列形成と協同性モデルによる解析

  横山創一; 廣瀬崇至; 松田建児

  日本化学会第94春季年会, 1A5-06, Mar. 2014

  
• らせん状多環芳香族化合物の合成と物性評価

  内田洋介; 廣瀬崇至; 松田建児

  日本化学会第94春季年会, 1PC-024, Mar. 2014

  
• 会合誘起増強発光色素の空間的配置が及ぼす発光特性への影響

  角井洋平; 廣瀬崇至; 松田建児

  日本化学会第94春季年会, 1PC-060, Mar. 2014

  
• ウレア基を導入したジアリールエテンの協同的組織化挙動と光応答性

  西谷暢彦; 廣瀬崇至; 松田建児

  日本化学会第94春季年会, 1PC-137, Mar. 2014

  
• 両親媒性側鎖を有するジアリールエテンが作る会合様式と光反応性その

  平元輝; 東口顕士; 廣瀬崇至; 松田建児

  日本化学会第94春季年会, 2E5-03, Mar. 2014

  
• 疎水性相互作用を用いたヘリセン誘導体の自己集合

  伊藤夏輝; 廣瀬崇至; 松田建児

  第24回基礎有機化学討論会, 1P036, Sep. 2013

  
• 会合誘起増強発光を示す色素の空間的配置が失活速度定数に及ぼす影響

  角井洋平; 廣瀬崇至; 松田建児

  第24回基礎有機化学討論会, 1P123, Sep. 2013

  
• アミド基を介して二次元配列した2-チエニル型ジアリールエテンのSTM観察

  横山創一; 廣瀬崇至; 松田建児

  第24回基礎有機化学討論会, 2P013, Sep. 2013

  
• ジアリールエテン超分子構造体の光誘起形態変化

  東口顕士; 平元輝; 廣瀬崇至; 松田建児

  第24回基礎有機化学討論会, 3C11, Sep. 2013

  
• 中心炭素に置換基を有するTriazatriangulene誘導体の光解離挙動

  横山創一; 廣瀬崇至; 松田建児

  2013年光化学討論会, 1P052, Sep. 2013

  
• 種々の幾何構造を有する両親媒性ジアリールエテン会合体の光誘起変化特性

  北井淳一郎; 東口顕士; 平元輝; 廣瀬崇至; 松田建児

  2013年光化学討論会, 1P064, Sep. 2013

  
• 両親媒性側鎖を有するジアリールエテンが作る会合様式と光反応性

  平元輝; 東口顕士; 廣瀬崇至; 松田建児

  2013年光化学討論会, 1P066, Sep. 2013

  
• 電子的効果を利用した光応答性ジアリールエテン配位子の会合挙動の光制御

  呂澄; 廣瀬崇至; 松田建児

  2013年光化学討論会, 1P067, Sep. 2013

  
• ナフタレン骨格で連結した蛍光性色素の発光増強特性と速度定数を用いた解析

  廣瀬崇至; 角井洋平; 松田建児

  2013年光化学討論会, 2C05, Sep. 2013

  
• Photo-Control of Binding Affinity at Pyridyl Group Based on Steric and Electronic Effect

  Takashi Hirose

  第7回スマート分子材料研究分野セミナー, 16 Apr. 2013, Invited

  
• 水素結合ネットワークを有するフォトクロミック化合物の二次元配列のSTM制御

  今泉洋平; 廣瀬崇至; 坂野豪; 松田建児

  日本化学会第93春季年会, 1A4-46, Mar. 2013

  
• 両親媒性側鎖を持つジアリールエテンの会合様式と光反応性

  平元輝; 東口顕士; 廣瀬崇至; 松田建児

  日本化学会第93春季年会, 1C2-51, Mar. 2013

  
• PTCDI-Melamineネットワーク内に閉じ込めた光機能性分子のSTM観察

  横山創一; 廣瀬崇至; 松田建児

  日本化学会第93春季年会, 3PC-035, Mar. 2013

  
• 空間的に位置を固定した色素の速度定数による発光挙動の解析

  角井洋平; 廣瀬崇至; 藤森裕也; 松田建児

  日本化学会第93春季年会, 4A5-19, Mar. 2013

  
• ジアリールエテンベシクルの光誘起形態変化

  東口顕士; 平元輝; 佐藤洋介; 西村一樹; 廣瀬崇至; 松田建児

  2012年光化学討論会, 2B08, Sep. 2012

  
• 両親媒性側鎖を持つジアリールエテンが作る会合様式と光反応性

  平元輝; 東口顕士; 廣瀬崇至; 松田建児

  2012年光化学討論会, 2P052, Sep. 2012

  
• 空間的に位置を固定した色素の発光挙動

  角井洋平; 廣瀬崇至; 藤森裕也; 松田建児

  2012年光化学討論会, 1P086, Sep. 2012

  
• -共役長伸長および置換基の立体構造によるCDスペクトルへの影響

  廣瀬崇至; 井上友喜; 長谷川淳也; 東口顕士; 松田建児

  2012年光化学討論会, 1P054, Sep. 2012

  
• 両親媒性側鎖を持つジアリールエテンが作る会合様式とその光反応性

  平元輝; 東口顕士; 廣瀬崇至; 松田建児

  第23回基礎有機化学討論会, 2P019, Sep. 2012

  
• 特定の空間的配置に固定された色素が示す発光挙動の解析

  角井洋平; 廣瀬崇至; 藤森裕也; 松田建児

  第23回基礎有機化学討論会, 3P071, Sep. 2012

  
• キラルなコアを有するジアリールエテン縮環体のCDスペクトル反転現象

  井上友喜; 廣瀬崇至; 東口顕士; 長谷川淳也; 松田建児

  日本化学会第92春季年会, 1M3-48, Mar. 2012

  
• 光応答性配位子を用いた協同的ポルフィリン会合体の外部光制御

  廣瀬崇至; Floris Helmich; E. W. Meijer

  日本化学会第92春季年会, 1M4-52, Mar. 2012

  
• Photo-Control of Cooperative Porphyrin Fibrous Aggregates with Photoresponsive Phenylazopyridine Ligand

  Takashi Hirose

  The 16th International Workshop at Kyushu University, 12 Jan. 2012, G-COE program, Kyushu University

  
• 協同的組織化挙動を示すポルフィリン会合体の光制御

  廣瀬崇至; Floris Helmich; E. W. Meijer

  日本化学会第91春季年会 (講演予稿集), 3D6-49, 11 Mar. 2011

  
• Photo-Switching of Cooperative Porphyrin Aggregation

  T. Hirose; F. A. Helmich; E. W. Meijer

  NWO meeting Ontwerp & Synthese, Structuur en Reactiviteit en Biomoleculaire Chemie, Oct. 2010

  
• 会合誘起増強発光特性を示す蛍光性色素の超分子組織化と速度定数の解析

  廣瀬崇至; 松田建児

  日本化学会講演予稿集, 2E3-32, Mar. 2010

  
• 水溶液中における会合誘起発光特性を示す蛍光色素の組織化と熱応答挙動

  廣瀬崇至; 松田建児

  2009年光化学討論会, 3P034, 18 Sep. 2009

  
• Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission:

  T. Hirose; K. Matsuda

  13th International Symposium on Novel Aromatic Compounds (ISNA-13), AE014, Jul. 2009

  
• 疎水性相互作用による蛍光性色素の組織化と会合誘起発光挙動

  廣瀬崇至; 松田建児

  日本化学会講演予稿集, 4E2-05, Mar. 2009

  
• ジアリールエテンの組織化とフォトクロミズム

  廣瀬崇至; 新居遼太; 入江正浩; 松田建児

  第１回有機フォトクロミズムシンポジウム, Nov. 2008

  
• 両親媒性側鎖を有する蛍光色素の組織化と会合誘起発光挙動

  廣瀬崇至; 松田建児

  第19回基礎有機化学連合討論会, C03, Oct. 2008

  
• Temperature Light Dual Control of Supramolecular Structures Composed by Amphiphilic

  T. Hirose; K. Matsuda

  Kyushu Univ. Global COE Program: Prof. Jean-Marie Lehn Symposium III, P31, Oct. 2008

  
• 両親媒性側鎖を有する蛍光性色素の組織化と会合誘起発光挙動

  廣瀬崇至; 松田建児; 松田建児

  基礎有機化学討論会要旨集, 26 Sep. 2008

  
• 両親媒性側鎖を有する蛍光性色素の組織化とLCST挙動

  廣瀬崇至; 松田建児

  日本化学会第88春季年会, 2K1-40, Mar. 2008

  
• Temperature-Light Dual Control of Supramolecular Structures Composed by Photochromic Dyes Having PEG Side Chains

  T. Hirose; K. Matsuda

  The 1st Kyushu University Global COE/Yonsei University BK21 Joint Symposium on ‘Future Molecular Systems’, SP7, Feb. 2008

  
• アミド結合を有する両親媒性ジアリールエテンの組織化と光誘起白濁転移

  廣瀬崇至; 入江正浩; 松田建児

  第37回構造有機化学討論会, 1B-04, Oct. 2007

  
• Supramolecular Assembly of Photochromic Diarylethene Having Amphiphilic Side Chains: LCST Control by Photoisomerization

  T. Hirose; M. Irie; K. Matsuda

  ISOP-07 International Symposium on Photochromism, Oct. 2007

  
• Self-Assembly and Photochromism of Diarylethenes Having Amphiphilic Groups

  T. Hirose; M. Irie; K. Matsuda

  12th International Symposium on Novel Aromatic Compounds (ISNA-12), PP-059, Jul. 2007

  
• Temperature-Light Dual Control of Clouding Behavior of Oligo-(ethylene glycol)-Diarylethene Hybrid System

  T. Hirose; M. Irie; K. Matsuda

  The Post ISNA-12 Symposium on Physical Organic Chemistry in Fukuoka, I-B7, Jul. 2007

  
• アミド結合を有する両親媒性ジアリールエテンの組織化と光・熱応答挙動

  廣瀬崇至; 松田建児; 入江正浩

  日本化学会第87春季年会, 2G7-47, Mar. 2007

  
• 疎水性相互作用によるジアリールエテンの組織化と光・熱応答挙動

  廣瀬崇至; 松田建児; 入江正浩

  第18回基礎有機化学連合討論会, C14, Oct. 2006

  
• Self-Assembly and Photochromism of Diarylethenes Having Amphiphilic Groups

  T. Hirose; K. Matsuda; M. Irie

  XXIst IUPAC SYMPOSIUM ON PHOTOCHEMISTRY, P219, Apr. 2006

  
• 両親媒性基を有するジアリールエテンの組織化とフォトクロミズム

  廣瀬崇至; 松田建児; 入江正浩

  2005年光化学討論会, 3P034, Sep. 2005

  
• 両親媒性基を持つジアリールエテンの組織化とフォトクロミズム

  廣瀬崇至; 松田建児; 入江正浩

  日本化学会第85春季年会, 2H7-09, Mar. 2005

  

Industrial Property Rights

• 特許特許第4558542号, フォトクロミック材料

  独立行政法人科学技術振興機構

  

Awards

• 08 Apr. 2022

  The Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan, The Young Scientists’ Award, The Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan

  Studies on Photophysical Functions and Mechanical Properties of Helical Molecules, Japan, Others

  Takashi Hirose
• 27 Jul. 2007

  12th International Symposium on Novel Aromatic Compounds, Best Poster Presentation Award at ISNA-12
• 12 May 2009

  The Chemical Society of Japan, CSJ Student Presentation Award 2008
• 10 Jul. 2015

  16th International Symposium on Novel Aromatic Compounds, J. Mater. Chem. C Poster Prize at ISNA-16
• 01 Feb. 2017

  26th Annual Meeting of MRS-J (2016), Award for Encouragement of Research in the 26th Annual Meeting of MRS-J
• 24 Feb. 2017

  The Royal Society of Chemistry, Outstanding Reviewer for Chemical Communications in 2016
• 17 Mar. 2017

  The Chemical Society of Japan, CSJ Young Scholar Lecuture Award 2017
• 12 Sep. 2018

  Publons, Publons Peer Review Awards 2018
• 20 Mar. 2019

  The Royal Society of Chemistry, Outstanding Reviewer for Chemical Communications in 2018
• 17 Sep. 2019

  Publons, Publons Peer Review Awards 2019
• 14 Jan. 2020

  Thieme Chemistry, Thieme Chemistry Journals Award 2020
• 10 Sep. 2020

  The Japanese Photochemistry Association (JPA), The Japanese Photochemistry Association (JPA) Award for Young Scientist 2020
• 26 May 2021

  The Royal Society of Chemistry, Outstanding Reviewer for Chemical Communications in 2020

External funds: Kakenhi

• Creation of Multi-Dimensional Chiral Assemblies Based on pi-Expanded Helical Aromatic Ligands

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  廣瀬 崇至

  From 01 Apr. 2019, To 31 Mar. 2021, Project Closed

  ヘリセン;キラリティー;円偏光発光;遷移双極子モーメント;量子化学計算;分子らせん;キラル配位子;円二色性;自己集合;ピレン;ソルバトクロミズム;エキシマー発光;非対称因子;遷移磁気双極子モーメント

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-19H04573/
• Synthesis of pi-Extended Helical Aromatic Compounds and Investigation on Their Chiral Molecular Functions

  Grant-in-Aid for Scientific Research (C)

  Basic Section 33010:Structural organic chemistry and physical organic chemistry-related

  Kyoto University

  Takashi Hirose

  From 01 Apr. 2018, To 31 Mar. 2021, Project Closed

  ヘリセン;π拡張;キラリティー;円二色性;分子バネ;単結晶構造解析;量子化学計算;単結晶構造;分子ワイヤー;励起状態ダイナミクス;中性ラジカル;エナンチオマー分離型;カラムナー構造;らせん反転;分子ばね定数;芳香族性;過渡吸収分光;芳香族化合物;らせん構造;π共役

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K05077/
• Rational design and synthesis of pi-conjugated wire which shows high efficiency and low attenuation of electron tunneling

  Grant-in-Aid for Scientific Research (B)

  Kyoto University

  Kenji MATSUDA

  From 01 Apr. 2015, To 31 Mar. 2018, Project Closed

  分子コンダクタンス;電子トンネリング;分子ワイヤ;交換相互作用;π共役系

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15H03794/
• Control of adsorption/desorption dynamics at the liquid/solid interface towards self-repairing molecular devices

  Grant-in-Aid for Young Scientists (B)

  Kyoto University

  Takashi Hirose

  From 01 Apr. 2013, To 31 Mar. 2016, Project Closed

  協同的組織化;光応答性;走査型トンネル顕微鏡;固液界面;ジアリールエテン;走査トンネル顕微鏡

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25810048/
• Coherent control of excitons in chiral molecular systems throught interactions with helical light fields

  Grant-in-Aid for Transformative Research Areas (A)

  Transformative Research Areas, Section (II)

  Osaka Metropolitan University

  中嶋 琢也

  From 16 Jun. 2022, To 31 Mar. 2027, Granted

  自己組織化;円二色性;円偏光発光;キラリティー;超螺旋光

  https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-22H05134/
• Investigation on Chiral Molecular Wire Properties Based on pi-Extended Helical Molecules

  Grant-in-Aid for Scientific Research (B)

  Basic Section 33010:Structural organic chemistry and physical organic chemistry-related

  Kyoto University

  廣瀬 崇至

  From 01 Apr. 2023, To 31 Mar. 2026, Granted

  らせん状分子ワイヤー;ヘリセン;キラリティー;分子間相互作用

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23H01949/
• Creation of Meso-Hierarchy Materials Based on Helical pi-Conjugated Compounds

  Grant-in-Aid for Transformative Research Areas (A)

  Transformative Research Areas, Section (II)

  Kyoto University

  廣瀬 崇至

  From 01 Apr. 2024, To 31 Mar. 2026, Granted

  らせん状化合物;超分子組織化;キラリティー;分子間相互作用;分子ばね

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-24H01713/
• Investigation on Chiral Molecular Wire Properties Based on pi-Extended Helical Molecules

  Grant-in-Aid for Scientific Research (B)

  Basic Section 33010:Structural organic chemistry and physical organic chemistry-related

  Kyoto University

  廣瀬 崇至

  From 01 Apr. 2023, To 31 Mar. 2026, Granted

  らせん状分子ワイヤー;ヘリセン;キラリティー;分子間相互作用

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23K26642/

External funds: others

• Investigation on photoresponsive intermolecular interactions based on a topological change of molecular orbital

  平成24年度京都大学若手研究者スタートアップ研究費

  From 15 Oct. 2012, To 31 Mar. 2014

  廣瀬崇至
• Synthesis and Chiroptical Properties of Chiral Polycyclic Aromatic Hydrocarbons: π-Extension of 1,1′-Binaphtyl and [7]helicene

  矢崎科学技術振興記念財団 2017年度国際交流援助（前期）

  From 23 Jul. 2017, To 28 Jul. 2017

  代表
• Creation of Asymmetric Molecular Functions Based on the Precise Molecular Arrangements of Helical pi-Conjugated Compounds

  戦略的創造研究推進事業 個人型研究（さきがけ）

  From 01 Dec. 2020, To 31 Mar. 2023

  代表

Education

Teaching subject(s)

• From 01 Apr. 2024, To 31 Mar. 2025

  Physical Chemistry: Fundamentals and Exercises

  7102, Spring, Faculty of Engineering, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Spectroscopy for Organic Compounds

  7059, Spring, Faculty of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Physical Chemistry: Fundamentals and Exercises

  7102, Spring, Faculty of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Spectroscopy for Organic Compounds

  7059, Spring, Faculty of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Structural Organic Chemistry

  H219, Fall, Graduate School of Engineering, 1.5
• From 01 Apr. 2023, To 31 Mar. 2024

  Advanced Organic Chemistry

  H818, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2022, To 31 Mar. 2023

  Advanced Organic Chemistry

  H818, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2022, To 31 Mar. 2023

  Spectroscopy for Organic Compounds

  7059, Spring, Faculty of Engineering, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Structural Organic Chemistry

  H219, Fall, Graduate School of Engineering, 1.5
• From Apr. 2019, To Mar. 2020

  Structural Organic Chemistry

  Fall, 工学研究科
• From Apr. 2020, To Mar. 2021

  Spectroscopy for Organic Compounds

  Spring, 工学部
• From Apr. 2020, To Mar. 2021

  Structural Organic Chemistry

  Fall, 工学研究科
• From Apr. 2020, To Mar. 2021

  Energy and Hydrocarbon Chemistry, Adv. III

  Spring, 工学研究科
• From Apr. 2021, To Mar. 2022

  Spectroscopy for Organic Compounds

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Structural Organic Chemistry

  Fall, 工学研究科

Student achievements: Awards

• Poster Prize on the 32nd Symposium on Physical Organic Chemistry

  Zheng ZHANG, The Society of Physical Organic Chemistry, 22 Sep. 2022
• Student Poster Prize on the 31st Symposium on Physical Organic Chemistry

  Yusuke Nakakuki, The Society of Physical Organic Chemistry, Japan, 23 Sep. 2021
• Oral Presentation Awards on the 101st CSJ Annual Meeting (2021)

  Yusuke Nakakuki, The Chemical Society of Japan (CSJ), 28 Apr. 2021

Part-time lecturer

• From 01 Apr. 2024, To 31 Mar. 2025

  物理化学基礎及び演習、有機分光学、先端化学実験Ⅰ・Ⅱ（先端化学）

  前期10時間、前期8時間、通年144時間 , 京都大学, 工学部
• From 01 Apr. 2023, To 31 Mar. 2024

  物理化学基礎及び演習、有機分光学、先端化学実験Ⅰ・Ⅱ（先端化学）

  前期16時間、前期8時間、通年144時間, 京都大学, 工学部
• From 01 Apr. 2022, To 31 Mar. 2023

  有機分光学、先端化学実験Ⅰ・Ⅱ

  前期8時間、通年144時間, 工学部

Administration

Faculty management (title, position)

• From 01 Apr. 2024, To 31 Mar. 2025

  化学研究所総務・教務委員会委員
• From 01 Apr. 2023, To 31 Mar. 2024

  化学研究所図書委員会
• From 01 Apr. 2022, To 31 Mar. 2023

  化学研究所広報委員会委員
• From 01 Apr. 2019, To 31 Mar. 2020

  化学研究所講演委員会 委員
• From 01 Apr. 2020, To 31 Mar. 2021

  化学研究所広報委員会委員
• From 01 Apr. 2020, To 31 Mar. 2022

  京都大学宇治事業場衛生委員会
• From 01 Apr. 2020, To 31 Mar. 2022

  京都大学宇治地区化学物質管理委員会
• From 01 Apr. 2021, To 31 Mar. 2022

  化学研究所総務・教務委員会委員