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Shimizu, Daiki

Graduate School of Engineering, Division of Synthetic Chemistry and Biological Chemistry Assistant Professor

Shimizu, Daiki
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    Last Updated :2022/05/14

    Basic Information

    Faculty

    • 工学部

    Academic Degree

    • M.S.(Kyoto University)
    • Ph.D.(Kyoto University)

    Academic Resume (Graduate Schools)

    • Kyoto University, Department of Chemistry, Graduate School of Science, Chemistry, 修了
    • Kyoto University, Department of Chemistry, Graduate School of Science, Chemistry, 修了

    Academic Resume (Undergraduate School/Majors)

    • Kyoto University, Faculty of Science, 卒業

    High School

    • High School

      愛知県立刈谷高等学校

    Research History

    • From Apr. 2019, To Present
      Kyoto University, Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Assistant Professor
    • From Oct. 2016, To Present
      Otsu Academy Award Fellow
    • From Apr. 2016, To Mar. 2019
      Kyoto University, Department of Chemistry, Graduate School of Science, JSPS Fellowship for Young Scientists (DC1)

    Language of Instruction

    • Japanese
    • English

    ID,URL

    Website(s) (URL(s))

    researchmap URL

    list
      Last Updated :2022/05/14

      Research

      Research Topics, Overview of the research

      • Research Topics

        Development of genuinely novel π-electronic systems by utilizing electronic spin and topology.
      • Overview of the research

        My studies focus on electronic structure of organic π-systems, especially from the viewpoints of "spin".

      Research Interests

      • Electronic Spin
      • Organic Chemistry
      • Electron Paramagnetic Resonance (EPR)
      • Stable Radical
      • Physical Organic Chemistry

      Research Areas

      • Nanotechnology/Materials, Organic functional materials
      • Nanotechnology/Materials, Functional solid-state chemistry
      • Life sciences, Bioorganic chemistry
      • Nanotechnology/Materials, Structural/physical organic chemistry

      Papers

      • Donor-Acceptor Type [5]Helicene Derivative with Strong Circularly Polarized Luminescence
        Hiromu Kubo; Takashi Hirose; Daiki Shimizu; Kenji Matsuda
        Chemistry Letters, 14 Jan. 2021
      • Circularly Polarized Luminescence Designed from Molecular Orbitals: A Figure-Eight-Shaped [5]Helicene Dimer with D2 Symmetry
        Hiromu Kubo; Daiki Shimizu; Takashi Hirose; Kenji Matsuda
        Organic Letters, 04 Dec. 2020
      • Balancing Charge Transfer and Frenkel Exciton Coupling Leads to Excimer Formation in Molecular Dimers: Implications for Singlet Fission
        Youn Jue Bae; Daiki Shimizu; Jonathan D. Schultz; Gyeongwon Kang; Jiawang Zhou; George C. Schatz; Atsuhiro Osuka; Michael R. Wasielewski
        The Journal of Physical Chemistry A, 15 Oct. 2020
      • Stable meso – meso ‐Linked 2NH ‐Corrole Radical Dimers as a Key Intermediate to Corrole Tape
        Shota Ooi; B. Adinarayana; Daiki Shimizu; Takayuki Tanaka; Atsuhiro Osuka
        Angewandte Chemie, 08 Jun. 2020
      • Stable meso – meso ‐Linked 2NH ‐Corrole Radical Dimers as a Key Intermediate to Corrole Tape
        Shota Ooi; B. Adinarayana; Daiki Shimizu; Takayuki Tanaka; Atsuhiro Osuka
        Angewandte Chemie International Edition, 08 Jun. 2020, Peer-reviewed
      • Figure‐eight Octaphyrin Bis‐Ge(IV) Complexes: Synthesis, Structures, Aromaticity, and Chiroptical Properties
        Mondo Izawa; Taisuke Suito; Shin‐ichiro Ishida; Daiki Shimizu; Takayuki Tanaka; Tadashi Mori; Atsuhiro Osuka
        Chemistry – An Asian Journal, 04 May 2020, Peer-reviewed
      • Cyclophane-Type Chlorin Dimers from Dynamic Covalent Chemistry of 2,18-Porphyrinyl Dicyanomethyl Diradicals
        B. Adinarayana; Kenichi Kato; Daiki Shimizu; Takayuki Tanaka; Ko Furukawa; Atsuhiro Osuka
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Mar. 2020, Peer-reviewed
      • meso ‐(2‐Pyridyl)‐boron(III)‐subporphyrin: Perimeter Iridium(III) Coordination
        Giulia Lavarda; Daiki Shimizu; Tomás Torres; Atsuhiro Osuka
        Angewandte Chemie, 17 Feb. 2020
      • meso ‐(2‐Pyridyl)‐boron(III)‐subporphyrin: Perimeter Iridium(III) Coordination
        Giulia Lavarda; Daiki Shimizu; Tomás Torres; Atsuhiro Osuka
        Angewandte Chemie International Edition, 17 Feb. 2020, Peer-reviewed
      • STM apparent height measurements of molecular wires with different physical length attached on 2-D phase separated templates for evaluation of single molecular conductance
        Tomoya Iizuka; Daiki Shimizu; Kenji Matsuda
        RSC Advances, 2020, Peer-reviewed
      • Phenylene‐bridged Porphyrin meso ‐Oxy Radical Dimers
        Takayuki Yamamoto; Kenichi Kato; Daiki Shimizu; Takayuki Tanaka; Atsuhiro Osuka
        Chemistry – An Asian Journal, 18 Nov. 2019, Peer-reviewed
      • Quadrupolar Cyclopenta[hi]aceanthrylene-Based Electron Donor-Acceptor-Donor Conjugates: Charge Transfer versus Charge Separation
        Christoph Schierl; Wiebke Alex; Luis M. Mateo; Beatriz Ballesteros; Daiki Shimizu; Atsuhiro Osuka; Tomas Torres; Dirk M. Guldi; Giovanni Bottari
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Oct. 2019, Peer-reviewed
      • Cover Feature: Bis‐copper(II) Complex of Triply‐linked Corrole Dimer and Its Dication (Chem. Asian J. 10/2019)
        Shota Ooi; Takayuki Tanaka; Takahisa Ikeue; Kazuhisa Yamasumi; Kento Ueta; Daiki Shimizu; Masatoshi Ishida; Hiroyuki Furuta; Atsuhiro Osuka
        Chemistry – An Asian Journal, 15 May 2019, Peer-reviewed
      • Coordination‐Induced Spin‐State Switching of an Aminyl‐Radical‐Bridged Nickel(II) Porphyrin Dimer between Doublet and Sextet States
        Daiki Shimizu; Yuki Ide; Takahisa Ikeue; Atsuhiro Osuka
        Angewandte Chemie International Edition, 01 Apr. 2019, Peer-reviewed
      • Coordination‐Induced Spin‐State Switching of an Aminyl‐Radical‐Bridged Nickel(II) Porphyrin Dimer between Doublet and Sextet States
        Daiki Shimizu; Yuki Ide; Takahisa Ikeue; Atsuhiro Osuka
        Angewandte Chemie, 01 Apr. 2019, Peer-reviewed
      • Selective Formation of Helical Tetrapyrrin‐Fused Porphyrins by Oxidation of β‐to‐β Linked meso‐Aminoporphyrin Dimers
        Daiki Shimizu
        Chem. Eur. J., 01 Feb. 2019, Peer-reviewed
      • Stable (BIII‐Subporphyrin‐5‐yl)dicyanomethyl Radicals
        Daiki Shimizu
        Chem. Eur. J., 01 Feb. 2019, Peer-reviewed
      • Porphyrin‐Stabilized Nitrenium Dication
        Daiki Shimizu
        Chem. Eur. J., 07 Jan. 2019, Peer-reviewed
      • Stable radical versus reversible σ-bond formation of (porphyrinyl)dicyanomethyl radicals
        B. Adinarayana; Daiki Shimizu; Ko Furukawa; Atsuhiro Osuka
        Chemical Science, 2019, Peer-reviewed
      • Aminyl Radical Bridged NiII-Porphyrin Dimer: Coordination-Induced Spin-State Switching between Doublet and Sextet States
        D. Shimizu; Y. Ide; T. Ikeue; A. Osuka
        Angew. Chem. Int. Ed., 2019, Peer-reviewed
      • Stable Face-to-Face Singlet Diradicaloids: Triply Linked Corrole Dimer Gallium(III) Complexes with Two μ -Hydroxo-Bridges
        Shota Ooi; Daiki Shimizu; Ko Furukawa; Takayuki Tanaka; Atsuhiro Osuka
        Angewandte Chemie, 05 Nov. 2018, Peer-reviewed
      • Stable Face-to-Face Singlet Diradicaloids: Triply Linked Corrole Dimer Gallium(III) Complexes with Two μ -Hydroxo-Bridges
        Shota Ooi; Daiki Shimizu; Ko Furukawa; Takayuki Tanaka; Atsuhiro Osuka
        Angewandte Chemie International Edition, 05 Nov. 2018, Peer-reviewed
      • meso -Functionalization of Boron(III) Subporphyrin with Boron(III) meso -Lithiosubporphyrin
        Yosuke Bekki; Daiki Shimizu; Keisuke Fujimoto; Atsuhiro Osuka
        Chemistry - A European Journal, Aug. 2018, Peer-reviewed
      • Stable Diporphyrinylaminyl Radical and Nitrenium Ion
        Daiki Shimizu; Keisuke Fujimoto; Atsuhiro Osuka
        Angewandte Chemie, Jul. 2018, Peer-reviewed
      • Stable Diporphyrinylaminyl Radical and Nitrenium Ion
        Daiki Shimizu; Keisuke Fujimoto; Atsuhiro Osuka
        Angewandte Chemie International Edition, Jul. 2018, Peer-reviewed
      • Diarylamine-Fused Subporphyrins: Proof of Twisted Intramolecular Charge Transfer (TICT) Mechanism
        Koki Kise; Yongseok Hong; Norihito Fukui; Daiki Shimizu; Dongho Kim; Atsuhiro Osuka
        Chemistry - A European Journal, 12 Jun. 2018, Peer-reviewed
      • Synthesis of (bis)Silicon Complexes of [38], [37], and [36]Octaphyrins: Aromaticity Switch and Stable Radical Cation
        Shin-Ichiro Ishida; Jinseok Kim; Daiki Shimizu; Dongho Kim; Atsuhiro Osuka
        Angewandte Chemie - International Edition, 14 May 2018, Peer-reviewed
      • BIII 5‐Arylsubporphyrins and BIII Subporphine
        Chem. Eur. J., Apr. 2018, Peer-reviewed
      • A Benzene-1,3,5-Triaminyl Radical Fused with ZnII-Porphyrins: Remarkable Stability and a High-Spin Quartet Ground State
        Daiki Shimizu; Atsuhiro Osuka
        Angewandte Chemie - International Edition, 26 Mar. 2018, Peer-reviewed
      • Porphyrinoids as a platform of stable radicals
        Daiki Shimizu; Atsuhiro Osuka
        Chemical Science, 2018, Peer-reviewed
      • Thienylquinonoidal Porphyrins and Hexaphyrins with Singlet Diradical Ground States
        Koji Naoda; Daiki Shimizu; Jun Oh Kim; Ko Furukawa; Dongho Kim; Atsuhiro Osuka
        CHEMISTRY-A EUROPEAN JOURNAL, Jul. 2017, Peer-reviewed
      • Stable Subporphyrin meso-Aminyl Radicals without Resonance Stabilization by a Neighboring Heteroatom
        Daiki Shimizu; Ko Furukawa; Atsuhiro Osuka
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Jun. 2017, Peer-reviewed
      • Stable Ni-II Porphyrin meso-Oxy Radical with a Quartet Ground State
        Cosima Staehler; Daiki Shimizu; Kota Yoshida; Ko Furukawa; Rainer Herges; Atsuhiro Osuka
        CHEMISTRY-A EUROPEAN JOURNAL, May 2017, Peer-reviewed
      • Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations
        Norihito Fukui; Wonhee Cha; Daiki Shimizu; Juwon Oh; Ko Furukawa; Hideki Yorimitsu; Dongho Kim; Atsuhiro Osuka
        CHEMICAL SCIENCE, Jan. 2017, Peer-reviewed
      • meso-Nitro- and meso-Aminosubporphyrinatoboron(III)s and meso-to-meso Azosubporphyrinatoboron(III)s
        Daiki Shimizu; Seung-Kyu Lee; Dongho Kim; Atsuhiro Osuka
        CHEMISTRY-AN ASIAN JOURNAL, Oct. 2016, Peer-reviewed
      • Effect of bulky meso-substituents on photoinduced twisted intramolecular charge transfer processes in meso-diarylamino subporphyrins
        Seung-Kyu Lee; Jun Oh Kim; Daiki Shimizu; Atsuhiro Osuka; Dongho Kim
        JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, Jun. 2016, Peer-reviewed
      • meso-to-meso Sulfide- and Disulfide-Bridged Subporphyrin Dimers
        Graeme Copley; Daiki Shimizu; Juwon Oh; Jooyoung Sung; Ko Furukawa; Dongho Kim; Atsuhiro Osuka
        EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Apr. 2016, Peer-reviewed
      • Intramolecular electron transfer reactions in meso-(4-nitrophenyl)-substituted subporphyrins
        Graeme Copley; Juwon Oh; Kota Yoshida; Daiki Shimizu; Dongho Kim; Atsuhiro Osuka
        CHEMICAL COMMUNICATIONS, 2016, Peer-reviewed
      • Regioselective phenylene-fusion reactions of Ni(II)-porphyrins controlled by an electron-withdrawing meso-substituent
        Norihito Fukui; Seung-Kyu Lee; Kenichi Kato; Daiki Shimizu; Takayuki Tanaka; Sangsu Lee; Hideki Yorimitsu; Dongho Kim; Atsuhiro Osuka
        CHEMICAL SCIENCE, 2016, Peer-reviewed
      • Triarylporphyrin meso-Oxy Radicals: Remarkable Chemical Stabilities and Oxidation to Oxophlorin pi-Cations
        Daiki Shimizu; Juwon Oh; Ko Furukawa; Dongho Kim; Atsuhiro Osuka
        JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2015, Peer-reviewed
      • meso-Hydroxysubporphyrins: A Cyclic Trimeric Assembly and a Stable meso-Oxy Radical
        Daiki Shimizu; Juwon Oh; Ko Furukawa; Dongho Kim; Atsuhiro Osuka
        ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, May 2015, Peer-reviewed
      • CCDC 1006032: Experimental Crystal Structure Determination
        Kitano Masaaki; Shimizu Daiki; Tanaka Takayuki; Yorimitsu Hideki; Osuka Atsuhiro
        Cambridge Structural Database, 2015, Peer-reviewed
      • Nucleophilic Aromatic Substitution Reactions of meso-Bromosubporphyrin: Synthesis of a Thiopyrane-Fused Subporphyrin
        Daiki Shimizu; Hirotaka Mori; Masaaki Kitano; Won-Young Cha; Juwon Oh; Takayuki Tanaka; Dongho Kim; Atsuhiro Osuka
        CHEMISTRY-A EUROPEAN JOURNAL, Dec. 2014, Peer-reviewed
      • Synthesis of meso-heteroatom-substituted subporphyrins
        Masaaki Kitano; Daiki Shimizu; Takayuki Tanaka; Hideki Yorimitsu; Atsuhiro Osuka
        JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, Aug. 2014, Peer-reviewed
      • Unusual carbon-sulfur bond cleavage in the reaction of a new type of bulky hexathioether with a zerovalent palladium complex
        D Shimizu; N Takeda; N Tokitoh
        CHEMICAL COMMUNICATIONS, 2006, Peer-reviewed

      Presentations

      • ジポルフィリニルアミニルラジカル−ニッケル二核錯体とその配位誘起スピンクロスオーバー挙動
        清水大貴; 大須賀篤弘
        日本化学会第99春季年会, Mar. 2019
      • A Benzene-1,3,5-Triaminyl Radical Fused with Zn(II)-Porphyrins: Remarkable Stability and High Spin Quartet Ground State
        Daiki Shimizu; Atsuhiro Osuka
        SICC10, Dec. 2018
      • 安定ラジカルの基盤としてのポルフィリン類縁体
        清水 大貴
        2018 年度 高分子・ハイブリッド材料研究センター(PHyM)若手フォーラム, 19 Nov. 2018, Invited
      • ポルフィリンによって安定化されたアミニルラジカルの合成と物性
        清水大貴; 大須賀篤弘
        第29回基礎有機化学討論会, Sep. 2018
      • A Benzene-1,3,5-Triaminyl Radical Fused with Zn(II)-Porphyrins: Remarkable Stability and High Spin Quartet Ground State
        Daiki Shimizu; Atsuhiro Osuka
        ICPP10, Jun. 2018
      • ポルフィリンによって安定化されたアミニルラジカル及びナイトレニウムイオンの合成と物性
        清水大貴; 大須賀篤弘
        日本化学会第98春季年会, Mar. 2018
      • Stable meso-Aminyl Radicals stabilized by Porphyrinoids
        Daiki Shimizu; Atsuhiro Osuka
        International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC) in conjunction with ISACS: Challenges in Organic Materials & Supramolecular Chemistry, Jul. 2017
      • Stable Aminyl Radicals of a Triaminobenzene-fused Porphyrin Trimer
        Daiki Shimizu; Atsuhiro Osuka
        日本化学会第97春季年会, Mar. 2017
      • ポルフィリノイドによって安定化されたアミニルラジカルの合成と物性
        清水大貴; 古川貢; 大須賀篤弘
        第27回基礎有機化学討論会, Sep. 2016
      • 化学的に安定なポルフィリンメゾオキシラジカルの合成と物性
        清水大貴; 大須賀篤弘
        第36回有機合成若手セミナー, 09 Aug. 2016
      • Triarylporphyrin meso-Oxy Radical: Remarkable Stabilities, Properties, and Oxidation to Oxophlorin π-Cations
        Daiki Shimizu; Atsuhiro Osuka
        International Conference on Porphyrins and Phthalocyanines (ICPP-9), Jul. 2016
      • ポルフィリンおよびサブポルフィリンによって安定化された中性窒素ラジカルの合成と物性
        清水大貴; 古川貢; 大須賀 篤弘
        日本化学会第96春季年会, Mar. 2016
      • 化学的に安定なメゾオキシポルフィリンラジカルの合成と物性
        清水大貴; 大須賀篤弘
        第26回基礎有機化学討論会, Sep. 2015
      • meso-Hydroxysubporphyrin: A Cyclic Trimeric Assembly and Stable meso-Oxy Radical
        Daiki Shimizu; Atsuhiro Osuka
        16th International Symposium on novel aromatic compunds (ISNA16), Jul. 2015
      • Stable Oxophlorin Radical and Its Metal Complexes
        Daiki Shimizu; Atsuhiro Osuka
        The 10th Organoelement Chemistry Seminar, 08 Jun. 2015
      • 非常に安定なサブポルフィリンメゾオキシラジカルの合成
        清水大貴; 大須賀 篤弘
        日本化学会第95春季年会, Mar. 2015
      • サブポルフィリンのメゾ位における芳香族求核置換反応
        清水大貴; 大須賀篤弘
        第25回基礎有機化学討論会, Sep. 2014
      • Synthesis and Properties of Fused Subporphyrin
        Daiki Shimizu; Hirotaka Mori; Takayuki Tanaka; Atsuhiro Osuka
        Eighth International Conference on Porphyrins and Phthalocyanines (ICPP-8), Jun. 2014
      • SNAr Reaction at meso-Position of Subporphyrin
        Daiki Shimizu; Atsuhiro Osuka
        Tenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP14), May 2014
      • 縮環サブポルフィリンの合成と物性
        清水大貴; 森裕貴; 田中隆行; 大須賀敦弘
        日本化学会第94春季年会, Mar. 2014

      Awards

      • 30 Mar. 2017
        Chemical Society of Japan, CSJ Student Presentation Award
      • 08 Sep. 2018
        The Society of Physical Organic Chemistry, Japan, RSC Advances Award
      • 19 Dec. 2018
        10th Singapore International Chemistry Conference, Chemical Reviews Poster Prize
      • 04 Feb. 2020
        Inoue Foundation for Science, The 36th Inoue Research Award for Young Scientists

      External funds: Kakenhi

      • 非ケクレ型メソイオン共役系化学の開拓
        Grant-in-Aid for Early-Career Scientists
        Basic Section 33010:Structural organic chemistry and physical organic chemistry-related
        Kyoto University
        清水 大貴
        From 01 Apr. 2020, To 31 Mar. 2023, Granted
        非ケクレ分子;メソイオン性;芳香族性;π共役系
      • 直交型分散力を用いた分子間高密度共役の実現
        Grant-in-Aid for Transformative Research Areas (A)
        Transformative Research Areas, Section (II)
        Osaka Prefecture University
        酒巻 大輔
        From 19 Nov. 2020, To 31 Mar. 2025, Granted
        分子間力;分散力;πスタック;フタロシアニン;アザアセン;高密度共役;分子会合体;有機固体化学
      • Spin-state control of 4n[pi]-systems by introducing spin perturbation
        Grant-in-Aid for Research Activity Start-up
        0501:Physical chemistry, functional solid state chemistry, organic chemistry, polymers, organic materials, biomolecular chemistry, and related fields
        Kyoto University
        Daiki Shimizu
        From 30 Aug. 2019, To 31 Mar. 2021, Project Closed
        ラジカル;芳香族性;反芳香族性;電子スピン;安定ラジカル;スピン

      External funds: others

      • 非ケクレ型メソイオン共役系を有するジアザペンタレンの創製と機能探索
        京都技術科学センター 研究開発助成
        From 01 Apr. 2020, To 31 Mar. 2021
        清水 大貴

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