Basic Information

Faculty

• Faculty of Engineering

Concurrent Affiliation

• Center for the Promotion of Interdisciplinary Education and Research (C-PiER), スーパーグローバルコース 化学系ユニット

Professional Memberships

• the Society of Polymer Science, Japan
• the American Chemical Society
• the Society of Silicon Chemistry, Japan
• the Society of Synthetic Organic Chemistry, Japan
• the Chemical Society of Japan
• KINKA Chemical Society

Academic Degree

• 工学修士(京都大学)
• 博士（工学）(京都大学)

Academic Resume (Graduate Schools)

• 京都大学, 大学院工学研究科博士後期課程合成化学専攻, 修了
• 京都大学, 大学院工学研究科修士課程合成化学専攻, 修了

Academic Resume (Undergraduate School/Majors)

• 京都大学, 工学部合成化学科, 卒業

High School

• High School

  北海道立　札幌南高校

Research History

• From 2004, To Present

  Kyoto University, Graduate School of Engineering Department of Synthetic Chemistry and Biological Chemistry, Professor
• From 2001, To 2005

  Japan Science and Technology Corporation, PRESTO Researcher
• From 2002, To 2004

  Kyoto University, Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Associate Professor
• From 1993, To 2002

  Kyoto University, Graduate School of Engineering, Assistant Professor
• From Apr. 1993, To Apr. 1993

  Kyoto University, Postdoctoral Researcher

Language of Instruction

• English

ID,URL

• ORCID ID

  0000-0003-3023-2219

• J-Global ID

  200901008477302032

• External link

  http://www.sbchem.kyoto-u.ac.jp/suginome-lab/

Website(s) (URL(s))

• http://www.sbchem.kyoto-u.ac.jp/suginome-lab/

researchmap URL

• https://researchmap.jp/read0042669

Research

Research Topics, Overview of the research

• Research Topics

  Organic Chemistry, Organic Synthesis, Organometallic Chemistry, Macromolecular Chemistry

• Overview of the research

  A variety of research projects are pursued on the basis of synthetic organic chemistry, organometallic chemistry, main group metal chemistry, transition metal chemistry, polymer chemistry, asymmetric synthesis, etc. We always try to pursue innovative molecular and reaction design for establishing new synthetic methods, new molecular functions, new concept, new phenomena, new principles, etc.

Research Interests

• 有機元素化学
• 高分子合成
• 不斉合成
• 有機合成化学
• Organoelement Chmistry
• Polymer Synthesis
• Asymmetric Synthesis
• Organic Synthesis

Research Areas

• Nanotechnology/Materials, Synthetic organic chemistry

Papers

• In Situ Dehydrogenative Generation of Vinyl Groups Bound to Heteroatoms by the Use of Ethyl Groups as Surrogates in Iridium-Catalyzed Intramolecular C-H/C-H Coupling

  K Yagi; T Ohmura; M Suginome

  ACS CATALYSIS, Jan. 2024, Peer-reviewed

  
• C-E bond formation through element-element addition to carbon-carbon multiple bonds

  M. Suginome; T. Matsuda; T. Ohmura; A. Seki; M. Murakami

  Comprehensive Organometallic Chemistry III, 2007

  
• Asymmetric living polymerization of 1,2-diisocyanobenzenes using chiral arylnickel initiators

  Tetsuya Yamada; Michinori Suginome

  Polymer Preprints, Japan, 2006

  
• Dynamics of side chains in poly(quinoxaline-2,3-diyl)s studied via quasielastic neutron scattering

  R. Inoue; Y. Nagata; T. Tominaga; S. Sato; Y. Kawakita; T. Yamawaki; K. Morishima; M. Suginome; M. Sugiyama

  The Journal of Chemical Physics, 02 Aug. 2024

  
• Controlling the chiral molecular space using helical polymers

  Yuuya Nagata; Michinori Suginome

  Designed Molecular Space in Material Science and Catalysis, 01 Jan. 2018

  
• A Traceless Chiral Shift Reagent Based on Nonbonding Interaction with Single-Handed Helical Poly(quinoxaline-2,3-diyl)

  T Fujie; T Yamamoto; M Suginome

  ANGEWANDTE CHEMIE INTERNATIONAL EDITION, Mar. 2023, Peer-reviewed

  
• Development of Dynamically Chiral Helical Polymer Catalysts Based on Post-Polymerization Modification of Boronyl Pendants

  Takeshi Yamamoto; Yukako Yoshinaga; Michinori Suginome

  Journal of Synthetic Organic Chemistry, Japan, 01 Apr. 2023

  
• PQXdpap: Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-(Dipropylamino)pyridin-3-yl Pendants as Chirality-Switchable Nucleophilic Catalysts for the Kinetic Resolution of Secondary Alcohols

  Takeshi Yamamoto; Michinori Suginome; Ryo Murakami

  ORGANIC LETTERS, Nov. 2021, Peer-reviewed

  
• Iridium-catalyzed Enantioselective Intramolecular Cross-dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans

  Satoshi Kusaka; Toshimichi Ohmura; Michinori Suginome

  Chemistry Letters, Jun. 2022

  
• Synthesis of Disilanes, Dihydrosiloles, and 1,4-Disilacyclohexa-2,5-dienes by Transition-Metal-Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters

  Ikuo Sasaki; Asahi Maebashi; Jiaying Li; Toshimichi Ohmura; Michinori Suginome

  EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Mar. 2022

  
• Iridium-catalyzed enantioselective intramolecular hydroarylation of allylic aryl ethers devoid of a directing group on the aryl group

  Toshimichi Ohmura; Satoshi Kusaka; Michinori Suginome

  CHEMICAL COMMUNICATIONS, Dec. 2021

  
• Asymmetric Cycloisomerization of o -Alkenyl-N -Methylanilines to Indolines by Iridium-Catalyzed C(sp3 )−H Addition to Carbon-Carbon Double Bonds

  Takeru Torigoe; Toshimichi Ohmura; Michinori Suginome

  Angewandte Chemie, Nov. 2017, Peer-reviewed

  
• Intramolecular Addition of a Dimethylamino C(sp ³)-H Bond across C-C Triple Bonds Using IrCl(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl- N -methylanilines

  Toshimichi Ohmura; Kaito Yagi; Takeru Torigoe; Michinori Suginome

  Synthesis (Germany), 01 Sep. 2021

  
• Mechanism of 2,6-dichloro-4,4'-bipyridine-catalyzed diboration of pyrazines involving a bipyridine-stabilized boryl radical

  Toshimichi Ohmura; Yohei Morimasa; Tomoya Ichino; Yusuke Miyake; Yasujiro Murata; Michinori Suginome; Kunihiko Tajima; Tetsuya Taketsugu; Satoshi Maeda

  Bulletin of the Chemical Society of Japan, Jul. 2021

  
• Copper-catalyzed regioselective: Trans -silaboration of internal arylalkynes with stereochemical switch to cis -addition mode

  Toshimichi Ohmura; Yuta Takaoka; Michinori Suginome

  Chemical Communications, 11 May 2021

  
• 座談会 2050年の化学

  上杉 志成; 小澤 岳昌; 陰山 洋; 杉野目 道紀; 山口 潤一郎

  現代化学 = Chemistry today, Apr. 2021

  
• Asymmetric O-to-C aryloxycarbonyl migration of indolyl carbonates using single-handed dynamic helical polyquinoxalines bearing 4-aminopyridyl groups as chiral nucleophilic catalysts

  Takeshi Yamamoto; Takuya Takahashi; Ryo Murakami; Naoto Ariki; Michinori Suginome

  Bulletin of the Chemical Society of Japan, Mar. 2021, Peer-reviewed

  
• Protected amino acids as a nonbonding source of chirality in induction of single-handed screw-sense to helical macromolecular catalysts

  Shoma Ikeda; Ryohei Takeda; Takaya Fujie; Naoto Ariki; Yuuya Nagata; Michinori Suginome

  Chemical Science, 2021

  
• Amphiphilic immobilized diphenylprolinol alkyl ether catalyst on PS-PEG resin

  Seitaro Koshino; Shusuke Hattori; Shota Hasegawa; Naoki Haraguchi; Takeshi Yamamoto; Michinori Suginome; Yasuhiro Uozumi; Yujiro Hayashi

  Bulletin of the Chemical Society of Japan, 2021, Peer-reviewed

  
• Enantioconvergent Cu-catalyzed intramolecular C-C coupling at boron-bound C(sp³) atoms of α-aminoalkylboronates using a C1-symmetrical 2,2′-bipyridyl ligand attached to a helically chiral macromolecular scaffold

  Yukako Yoshinaga; Takeshi Yamamoto; Michinori Suginome

  Journal of the American Chemical Society, 28 Oct. 2020, Peer-reviewed

  
• Holding of planar chirality of pillar[5]arene by kinetic trapping using host-guest interactions with achiral guest solvents

  Yuuya Nagata; Misaki Suzuki; Yasuo Shimada; Hiroki Sengoku; Shungo Nishida; Takahiro Kakuta; Tada Aki Yamagishi; Michinori Suginome; Tomoki Ogoshi

  Chemical Communications, 04 Aug. 2020, Peer-reviewed

  
• Stereoinvertive C–C Bond Formation at the Boron-Bound Stereogenic Centers through Copper-Bipyridine-Catalyzed Intramolecular Coupling of α-Aminobenzylboronic Esters

  Yukako Yoshinaga; Takeshi Yamamoto; Michinori Suginome

  Angewandte Chemie - International Edition, Apr. 2020, Peer-reviewed

  
• Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4 + 2 + 1] Cycloaddition through Rhodium Silylenoid

  Ikuo Sasaki; Toshimichi Ohmura; Michinori Suginome

  Organic Letters, Apr. 2020, Peer-reviewed

  
• Tandem C-H Transformations by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o-Alkyl-N-methylanilines

  Toshimichi Ohmura; Kaito Yagi; Satoshi Kusaka; Michinori Suginome

  ACS Catalysis, 06 Mar. 2020, Peer-reviewed

  
• 4,4′-Bipyridyl-Catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron

  Hiromu Hosoya; Luis C. Misal Castro; Ibrahim Sultan; Yumiko Nakajima; Toshimichi Ohmura; Kazuhiko Sato; Hayato Tsurugi; Michinori Suginome; Kazushi Mashima

  Organic Letters, 20 Dec. 2019, Peer-reviewed

  
• Iridium-Catalyzed C(sp³)−H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans

  Toshimichi Ohmura; Satoshi Kusaka; Takeru Torigoe; Michinori Suginome

  Advanced Synthesis and Catalysis, 08 Oct. 2019, Peer-reviewed

  
• Boryl-Directed, Ir-Catalyzed C(sp³)-H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes

  Takeshi Yamamoto; Aoi Ishibashi; Michinori Suginome

  Organic Letters, 16 Aug. 2019, Peer-reviewed

  
• Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold

  Yuuya Nagata; Ryohei Takeda; Michinori Suginome

  ACS Central Science, 24 Jul. 2019, Peer-reviewed

  
• Pyridine-Based Organocatalysts for Regioselective syn-1,2-Silaboration of Terminal Alkynes and Allenes

  Yohei Morimasa; Kosuke Kabasawa; Toshimichi Ohmura; Michinori Suginome

  Asian Journal of Organic Chemistry, Jul. 2019, Peer-reviewed

  
• Lyotropic Liquid Crystallinity of Linear and Star Poly(quinoxaline-2,3-diyl)s: Isotropic-Liquid Crystal Phase Equilibria in Tetrahydrofuran

  Hirokazu Hasegawa; Ken Terao; Takahiro Sato; Yuuya Nagata; Michinori Suginome

  Macromolecules, 14 May 2019, Peer-reviewed

  
• Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization

  Shogo Kuriyama; Yuuya Nagata; Michinori Suginome

  ACS Macro Letters, Apr. 2019, Peer-reviewed

  
• Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2 + 2 + 1] Cycloaddition

  Toshimichi Ohmura; Ikuo Sasaki; Michinori Suginome

  Organic Letters, 15 Mar. 2019, Peer-reviewed

  
• Molecular technology for switch and amplification of chirality in asymmetric catalysis using a helically dynamic macromolecular scaffold as a source of chirality

  Michinori Suginome

  Molecular Technology: Materials Innovation, 06 Feb. 2019, Invited

  
• A bidirectional screw-sense induction of poly(quinoxaline-2,3-diyl)s that depends on the degree of polymerization

  Yuuya Nagata; Tsuyoshi Nishikawa; Ken Terao; Hirokazu Hasegawa; Michinori Suginome

  Journal of Polymer Science, Part A: Polymer Chemistry, 01 Feb. 2019, Peer-reviewed

  
• Helical Poly(quinoxaline-2,3-diyl)s Bearing 1,2,3-Triazole Pendants: Synthesis by CuAAC and Use as Reusable Abnormal NHC Ligands in Gold Catalysis

  Pinglu Zhang; Takeshi Yamamoto; Michinori Suginome

  ChemCatChem, 09 Jan. 2019, Peer-reviewed

  
• A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis

  Yuuya Nagata; Yasuo Shimada; Tsuyoshi Nishikawa; Ryohei Takeda; Makoto Uno; Tomoki Ogoshi; Michinori Suginome

  Synlett, Oct. 2018, Peer-reviewed

  
• Enantiospecific Suzuki–Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives

  Toshimichi Ohmura; Kyoko Miwa; Tomotsugu Awano; Michinori Suginome

  Chemistry - An Asian Journal, 04 Sep. 2018, Peer-reviewed

  
• Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites

  Takeshi Yamamoto; Ryo Murakami; Satoko Komatsu; Michinori Suginome

  Journal of the American Chemical Society, 21 Mar. 2018, Peer-reviewed

  
• Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome; Sota Sato; Masaaki Sugiyama; Lionel Porcar; Anne Martel; Rintaro Inoue; Nobuhiro Sato

  Journal of the American Chemical Society, 28 Feb. 2018, Peer-reviewed

  
• Abnormal sergeants-and-soldiers effects of poly(quinoxaline-2,3-diyl)s enabling discrimination of one-carbon homologous: N -alkanes through a highly sensitive solvent-dependent helix inversion

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  Chemical Communications, 2018, Peer-reviewed

  
• 4,4 '-Bipyridine-catalyzed Stereoselective &ITtrans&IT-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates

  Toshimichi Ohmura; Yohei Morimasa; Michinori Suginome

  CHEMISTRY LETTERS, Dec. 2017, Peer-reviewed

  
• Asymmetric Cycloisomerization of o-Alkenyl-N-Methylanilines to Indolines by Iridium-Catalyzed C(sp(3))-H Addition to Carbon-Carbon Double Bonds

  Takeru Torigoe; Toshimichi Ohmura; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Nov. 2017, Peer-reviewed

  
• Palladium-Catalyzed beta-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers

  Toshimichi Ohmura; Hiroki Nishiura; Michinori Suginome

  ORGANOMETALLICS, Nov. 2017, Peer-reviewed

  
• Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)

  Hirokazu Hasegawa; Yuuya Nagata; Ken Terao; Michinori Suginome

  MACROMOLECULES, Oct. 2017, Peer-reviewed

  
• Rhodium-catalyzed C(sp(2))-H Addition of Arylboronic Acids to Alkynes Using a Boron-based, Convertible ortho-Directing Group

  Takeshi Yamamoto; Aoi Ishibashi; Michinori Suginome

  CHEMISTRY LETTERS, Aug. 2017, Peer-reviewed

  
• Chirality-Switchable 2,2 '-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes

  Yukako Yoshinaga; Takeshi Yamamoto; Michinori Suginome

  ACS MACRO LETTERS, Jul. 2017, Peer-reviewed

  
• Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations.

  Franco King-Chi Leung; Fumitaka Ishiwari; Yoshiaki Shoji; Tsuyoshi Nishikawa; Ryohei Takeda; Yuuya Nagata; Michinori Suginome; Yasuhiro Uozumi; Yoichi M A Yamada; Takanori Fukushima

  ACS omega, 31 May 2017, Peer-reviewed

  
• C-H Activation-Based Transformation of Naphthalenes to 3-Iodo-2-naphthylboronic Acid Derivatives for Use in Iterative Coupling Synthesis of Helical Oligo(naphthalene-2,3-diyl)s

  Takeshi Yamamoto; Aoi Ishibashi; Masashi Koyanagi; Hideki Ihara; Nils Eichenauer; Michinori Suginome

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, May 2017, Peer-reviewed

  
• New Chiral Functions Based on the Dynamic Induction of Macromolecular Helical Chirality by Chiral Side Chains

  Michinori Suginome; Yuuya Nagata; Takeshi Yamamoto

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, May 2017, Peer-reviewed

  
• Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness

  Tsuyoshi Nishikawa; Yuuya Nagata; Michinori Suginome

  ACS MACRO LETTERS, Apr. 2017, Peer-reviewed

  
• Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp(3))-H Borylation at the Methyl Group on Silicon

  Takeru Torigoe; Toshimichi Ohmura; Michinori Suginome

  JOURNAL OF ORGANIC CHEMISTRY, Mar. 2017, Peer-reviewed

  
• Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C-H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group

  Takeshi Yamamoto; Aoi Ishibashi; Michinori Suginome

  ORGANIC LETTERS, Feb. 2017, Peer-reviewed

  
• Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction

  Takeshi Yamamoto; Ryo Murakami; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2017, Peer-reviewed

  
• Iridium-Catalyzed Intramolecular Methoxy C-H Addition to Carbon-Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes

  Takeru Torigoe; Toshimichi Ohmura; Michinori Suginome

  CHEMISTRY-A EUROPEAN JOURNAL, Jul. 2016, Peer-reviewed

  
• Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends

  Yuuya Nagata; Makoto Uno; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Jun. 2016, Peer-reviewed

  
• A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp(3))-H Borylation and Conversion to Functionalized Siloxanes

  Toshimichi Ohmura; Ikuo Sasaki; Takeru Torigoe; Michinori Suginome

  ORGANOMETALLICS, Jun. 2016, Peer-reviewed

  
• Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  ACS MACRO LETTERS, Apr. 2016, Peer-reviewed

  
• High-pressure circular dichroism spectroscopy up to 400 MPa using polycrystalline yttrium aluminum garnet (YAG) as pressure-resistant optical windows

  Yuuya Nagata; Ryohei Takeda; Michinori Suginome

  RSC ADVANCES, 2016, Peer-reviewed

  
• Main-Chain Stiffness and Helical Conformation of a Poly(quinoxaline-2,3-diyl) in Solution

  Yuuya Nagata; Hirokazu Hasegawa; Ken Terao; Michinori Suginome

  MACROMOLECULES, Nov. 2015, Peer-reviewed

  
• Poly(quinoxaline-2,3-diyl)s: A Fascinating Helical Macromolecular Scaffold for New Chiral Functions

  Michinori Suginome; Takeshi Yamamoto; Yuuya Nagata

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Nov. 2015, Peer-reviewed

  
• Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis

  Yuan-Zhen Ke; Yuuya Nagata; Tetsuya Yamada; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Aug. 2015, Peer-reviewed

  
• Site- and Regioselective Silaborative C-C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester

  Toshimichi Ohmura; Hiroki Taniguchi; Michinori Suginome

  ACS CATALYSIS, May 2015, Peer-reviewed

  
• Exerting Control over the Helical Chirality in the Main Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2015, Peer-reviewed

  
• Organocatalytic Diboration Involving "Reductive Addition" of a Boron-Boron sigma-Bond to 4,4 '-Bipyridine

  Toshimichi Ohmura; Yohei Morimasa; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2015, Peer-reviewed

  
• Facile Preparation of Poly(quinoxaline-2,3-diyl)s via Aromatizing Polymerization of 1,2-Diisocyanobenzenes Using Phosphine Complexes of Nickel(II) Salts

  Yuuya Nagata; Yuan-Zhen Ke; Michinori Suginome

  CHEMISTRY LETTERS, Jan. 2015, Peer-reviewed

  
• Pressure-dependent helix inversion of poly(quinoxaline-2,3-diyl)s containing chiral side chains in non-aqueous solvents

  Yuuya Nagata; Ryohei Takeda; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2015, Peer-reviewed

  
• Asymmetric Suzuki-Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos

  Yuto Akai; Laure Konnert; Takeshi Yamamoto; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2015, Peer-reviewed

  
• Chiral Palladacycle Catalysts Generated on a Single-Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalene

  Takeshi Yamamoto; Yuto Akai; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Nov. 2014, Peer-reviewed

  
• Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main-Chain Helical Chirality

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2014, Peer-reviewed

  
• Chirality-switchable circularly polarized luminescence in solution based on the solvent-dependent helix inversion of poly(quinoxaline-2,3-diyl)s

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  CHEMICAL COMMUNICATIONS, Sep. 2014, Peer-reviewed

  
• Solid Polymer Films Exhibiting Handedness-Switchable, Full-Color-Tunable Selective Reflection of Circularly Polarized Light

  Yuuya Nagata; Keisuke Takagi; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2014, Peer-reviewed

  
• Ether solvent-induced chirality inversion of helical poly(quinoxaline-2,3-diyl)s containing L-lactic acid derived side chains

  Yuuya Nagata; Takuma Kuroda; Keisuke Takagi; Michinori Suginome

  CHEMICAL SCIENCE, 2014, Peer-reviewed

  
• Iridium-catalysed borylation of sterically hindered C(sp(3))-H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide

  Toshimichi Ohmura; Takeru Torigoe; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2014, Peer-reviewed

  
• Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium-Catalyzed C(sp(3))-H Borylation

  Toshimichi Ohmura; Takeru Torigoe; Michinori Suginome

  ORGANOMETALLICS, Nov. 2013, Peer-reviewed

  
• Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (-)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s

  Takeshi Yamamoto; Takumi Adachi; Michinori Suginome

  ACS MACRO LETTERS, Sep. 2013, Peer-reviewed

  
• Solvent-Dependent Switch of Helical Main-Chain Chirality in Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s: Effect of the Position and Structures of the "Sergeant" Chiral Units on the Screw-Sense Induction

  Yuuya Nagata; Tetsuya Yamada; Takumi Adachi; Yuto Akai; Takeshi Yamamoto; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2013, Peer-reviewed

  
• Cycloaddition-based Formal C-H Alkynylation of Isoindoles Leading to the Synthesis of Air-stable Fluorescent 1,3-Dialkynylisoindoles

  Toshimichi Ohmura; Akihito Kijima; Yusuke Komori; Michinori Suginome

  ORGANIC LETTERS, Jul. 2013, Peer-reviewed

  
• Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron-Chlorine Bonds

  Kanayo Nakada; Masaki Daini; Michinori Suginome

  CHEMISTRY LETTERS, May 2013, Peer-reviewed

  
• Synthesis of Cyclic Alkenylborates via Silaboration of Alkynes Followed by Hydrolysis for Utilization in External-Base-Free Cross Coupling

  Toshimichi Ohmura; Kazuyuki Oshima; Michinori Suginome

  ORGANOMETALLICS, May 2013, Peer-reviewed

  
• Catalytic Asymmetric Synthesis with Chirality-Switchable Helical Polymer Ligands

  Takeshi Yamamoto; Yuuya Nagata; Michinori Suginome

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, May 2013, Peer-reviewed

  
• Anthranilamide-masked o-iodoarylboronic acids as coupling modules for iterative synthesis of ortho-linked oligoarenes

  Masashi Koyanagi; Nils Eichenauer; Hideki Ihara; Takeshi Yamamoto; Michinori Suginome

  Chemistry Letters, 2013, Peer-reviewed

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• Nickel-catalyzed cyclizative trans-carboboration of alkynes through activation of boron-chlorine bonds by using organometallic reagents as donors of organic groups

  Masaki Daini; Akihiko Yamamoto; Michinori Suginome

  Asian Journal of Organic Chemistry, 2013, Peer-reviewed

  
• Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp(3))-H Borylation of Methylchlorosilanes

  Toshimichi Ohmura; Takeru Torigoe; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Oct. 2012, Peer-reviewed

  
• Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes

  Yuto Akai; Takeshi Yamamoto; Yuuya Nagata; Toshimichi Ohmura; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 2012, Peer-reviewed

  
• Control of helical chirality of poly(quinoxaline-2,3-diyl)s based on postpolymerization modification of the terminal group by small chiral molecules

  Yuuya Nagata; Satoru Ohashi; Michinori Suginome

  JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, Apr. 2012, Peer-reviewed

  
• Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines

  Kazuyuki Oshima; Toshimichi Ohmura; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2012, Peer-reviewed

  
• Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants

  Yuuya Nagata; Tsuyoshi Nishikawa; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2012, Peer-reviewed

  
• Catalytic asymmetric synthesis using chirality-switchable helical polymer as a chiral ligand

  Michinori Suginome; Takeshi Yamamoto; Yuuya Nagata; Tetsuya Yamada; Yuto Akai

  PURE AND APPLIED CHEMISTRY, 2012, Peer-reviewed

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• Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

  Kazuyuki Oshima; Toshimichi Ohmura; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2012, Peer-reviewed

  
• Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki-Miyaura Coupling of alpha-(Acetylamino)benzylboronic Esters

  Tomotsugu Awano; Toshimichi Ohmura; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Dec. 2011, Peer-reviewed

  
• (E)- and (Z)-β-Borylallylsilanes by Alkyne Silaboration Followed by Regio- and Stereoselective Double-Bond Migration

  Toshimichi Ohmura; Kazuyuki Oshima; Michinori Suginome

  Angewandte Chemie, Nov. 2011, Peer-reviewed

  
• Synthesis of Poly(quinoxaline-2,3-diyl)s with Alkoxy Side Chains by Aromatizing Polymerization of 4,5-Dialkoxy-substituted 1,2-Diisocyanobenzenes

  Yuuya Negate; Michinori Suginome

  JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, Oct. 2011, Peer-reviewed

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• Transition Metal-Catalyzed Element-Boryl Additions to Unsaturated Organic Compounds

  M. Suginome; T. Ohmura

  Boronic Acids: Preparation and Applications in Organic Synthesis, Medicine and Materials (Volume 1 and 2), Oct. 2011, Peer-reviewed

  
• Ruthenium-catalyzed C-H Silylation of Methylboronic Acid Using a Removable alpha-Directing Modifier on the Boron Atom

  Hideki Ihara; Akinori Ueda; Michinori Suginome

  CHEMISTRY LETTERS, Sep. 2011, Peer-reviewed

  
• Dinuclear Palladium and Platinum Complexes with Bridging Silylene Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand Precursor and Their Reactions with Alkynes

  Tanabe, Makoto; Jiang, Jian; Yamazawa, Hideto; Osakada, Kohtaro; Ohmura, Toshimichi; Suginome, Michinori

  ORGANOMETALLICS, Aug. 2011, Peer-reviewed

  
• Poly(isocyanide)s, Poly(quinoxaline-2,3-diyl)s, and Related Helical Polymers Used as Chiral Polymer Catalysts in Asymmetric Synthesis

  Yuuya Nagata; Michinori Suginome

  Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis, 27 Jun. 2011, Peer-reviewed

  
• Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

  Kazuyuki Oshima; Toshimichi Ohmura; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2011, Peer-reviewed

  
• Anthranilamide: A Simple, Removable ortho-Directing Modifier for Arylboronic Acids Serving also as a Protecting Group in Cross-Coupling Reactions

  Hideki Ihara; Masashi Koyanagi; Michinori Suginome

  ORGANIC LETTERS, May 2011, Peer-reviewed

  
• Palladium-Catalyzed, Stereoselective, Cyclizative Alkenylboration of Carbon-Carbon Double Bonds through Activation of a Boron-Chlorine Bond

  Masaki Daini; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2011, Peer-reviewed

  
• 2-Vinylindoles As the Four-Atom Component in a Catalytic [4+1] Cycloaddition with a Silylene-Palladium Species Generated from (Aminosilyl)boronic Ester

  Kohei Masuda; Toshimichi Ohmura; Michinori Suginome

  ORGANOMETALLICS, Mar. 2011, Peer-reviewed

  
• Integrated Catalytic C-H Transformations for One-Pot Synthesis of 1-Arylisoindoles from Isoindolines via Palladium-Catalyzed Dehydrogenation Followed by C-H Arylation

  Toshimichi Ohmura; Akihito Kijima; Michinori Suginome

  ORGANIC LETTERS, Mar. 2011, Peer-reviewed

  
• Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki-Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines

  Takeshi Yamamoto; Yuto Akai; Yuuya Nagata; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, Peer-reviewed

  
• (E)- and (Z)-ss-Borylallylsilanes by Alkyne Silaboration Followed by Regio- and Stereoselective Double-Bond Migration

  Toshimichi Ohmura; Kazuyuki Oshima; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, Peer-reviewed

  
• Catalytic Carboborations

  Michinori Suginome

  CHEMICAL RECORD, Oct. 2010, Peer-reviewed

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• Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

  Toshimichi Ohmura; Kazuyuki Oshima; Hiroki Taniguchi; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 2010, Peer-reviewed

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• Stereospecific Suzuki-Miyaura Coupling of Chiral alpha-(Acylamino)benzylboronic Esters with Inversion of Configuration

  Toshimichi Ohmura; Tomotsugu Awano; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 2010, Peer-reviewed

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• Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked beta-Borylstyrenes as New Phenylene Vinylene Cross-coupling Modules

  Noriyuki Iwadate; Michinori Suginome

  CHEMISTRY LETTERS, Jun. 2010, Peer-reviewed

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• High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes

  Takeshi Yamamoto; Tetsuya Yamada; Yuuya Nagata; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jun. 2010, Peer-reviewed

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• Langmuir-Blodgett films of helical rigid-rod poly(quinoxaline-2,3-diyl)s

  Yoshihiko Ito; Toshiyuki Miyake; Michinori Suginome; Rie Katakura; Masaya Mitsuishi; Tokuji Miyashita

  POLYMER JOURNAL, May 2010, Peer-reviewed

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• Synthesis of Helical Rod-Coil Multiblock Copolymers by Living Block Copolymerization of Isocyanide and 1,2-Diisocyanobenzene Using Arylnickel Initiators

  Tetsuya Yamada; Michinori Suginome

  MACROMOLECULES, May 2010, Peer-reviewed

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• Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

  Noriyuki Iwadate; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2010, Peer-reviewed

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• Chiral Arylnickel Complexes as Highly Active Initiators for Screw-Sense Selective Living Polymerization of 1,2-Diisocyanobenzenes

  Tetsuya Yamada; Hiroyoshi Noguchi; Yuuya Nagata; Michinori Suginome

  JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, Feb. 2010, Peer-reviewed

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• Nickel-Catalyzed Asymmetric Addition of Alkyne C-H Bonds across 1,3-Dienes Using Taddol-Based Chiral Phosphoramidite Ligands

  Masamichi Shirakura; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, Peer-reviewed

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• Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains

  Tetsuya Yamada; Yuuya Nagata; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2010, Peer-reviewed

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• Palladium-Catalyzed Silylene-1,3-Diene [4+1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene

  Toshimichi Ohmura; Kohei Masuda; Ichiro Takase; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2009, Peer-reviewed

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• Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes: Synthesis of gamma,delta-Unsaturated Ketones from Aldehydes

  Hiroki Taniguchi; Toshimichi Ohmura; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2009, Peer-reviewed

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• Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of beta-cyanoallylboranes

  Akihiko Yamamoto; Yuto Ikeda; Michinori Suginome

  TETRAHEDRON LETTERS, Jul. 2009, Peer-reviewed

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• Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C-C Cleavage

  Toshimichi Ohmura; Hiroki Taniguchi; Michinori Suginome

  ORGANIC LETTERS, Jul. 2009, Peer-reviewed

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• alpha-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki-Miyaura Coupling with alpha-(Acylamino)benzylboronic Esters

  Toshimichi Ohmura; Tomotsugu Awano; Michinori Suginome

  CHEMISTRY LETTERS, Jul. 2009, Peer-reviewed

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• Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C-H Silylation

  Hideki Ihara; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jun. 2009, Peer-reviewed

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• Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C-H borylation with 1,8-naphthalenediaminatoborane (danBH)

  Noriyuki Iwadate; Michinori Suginome

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, May 2009, Peer-reviewed

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• Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C-H Borylation of Isoindolines

  Toshimichi Ohmura; Akihito Kijima; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2009, Peer-reviewed

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• Synthesis of B-Protected beta-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

  Noriyuki Iwadate; Michinori Suginome

  ORGANIC LETTERS, May 2009, Peer-reviewed

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• Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes

  Masamichi Shirakura; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2009, Peer-reviewed

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• B(OMe)(3) as a Nonacidic Iminium Ion Generator in Mannich- and Ugi-Type Reactions

  Yusuke Tanaka; Kousuke Hidaka; Tomoaki Hasui; Michinori Suginome

  EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Mar. 2009, Peer-reviewed

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• Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism

  Masamichi Shirakura; Michinori Suginome

  ORGANIC LETTERS, Feb. 2009, Peer-reviewed

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• Silylboranes as New Tools in Organic Synthesis

  Toshimichi Ohmura; Michinori Suginome

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Jan. 2009, Peer-reviewed

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• Stereoselective Synthesis of cis-beta-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation

  Toshimichi Ohmura; Yuta Takasaki; Hideki Furukawa; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, Peer-reviewed

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• Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis

  Takeshi Yamamoto; Michinori Suginome

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, Peer-reviewed

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• Diarylborinic acid derivatives as a catalytic iminium ion generator in the Mannich-type reaction using secondary amines, aldehydes, and ketene silyl acetals

  Yusuke Tanaka; Tomoaki Hasui; Michinori Suginome

  SYNLETT, May 2008, Peer-reviewed

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• Nickel-catalyzed addition of C-H bonds of terminal alkynes to 1,3-dienes and styrenes

  Masamichi Shirakura; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Apr. 2008, Peer-reviewed

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• A mechanism for the palladium-catalyzed regioselective silaboration of allene: A theoretical study

  Yoko Abe; Kei Kuramoto; Masahiro Ehara; Hiroshi Nakatsuji; Michinori Suginome; Masahiro Murakami; Yoshihiko Ito

  ORGANOMETALLICS, Apr. 2008, Peer-reviewed

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• Palladium-catalyzed trans- and cis-carboboration of Alkynes tethered to chloroborane with organozirconium reagents: Ligand-dependent complementary stereoselectivity

  Masaki Daini; Akihiko Yamamoto; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2008, Peer-reviewed

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• Synthetic application of intramolecular cyanoboration on the basis of removal and conversion of a tethering group by palladium-catalyzed retro-allylation

  Toshimichi Ohmura; Tomotsugu Awano; Michinori Suginome; Hideki Yorimitsu; Koichiro Oshima

  SYNLETT, Feb. 2008, Peer-reviewed

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• Differentially protected, benzenediboronic acids: Divalent cross-coupling modules for the efficient synthesis of boron-substituted oligoarenes

  Hiroyoshi Noguchi; Takayuki Shioda; Chih-Ming Chou; Michinori Suginome

  ORGANIC LETTERS, Feb. 2008, Peer-reviewed

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• Silylboranes bearing dialkylamino groups on silicon as silylene equivalents: Palladium-catalyzed regioselective synthesis of 2,4-disubstituted siloles

  Toshimichi Ohmura; Kohei Masuda; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 2008, Peer-reviewed

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• Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents

  Masaki Daini; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2008, Peer-reviewed

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• Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

  Toshimichi Ohmura; Kazuyuki Oshima; Michinori Suginome

  CHEMICAL COMMUNICATIONS, 2008, Peer-reviewed

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• “Synthetic Organic Chemistry” and “Polymer Science” of Isocyanide

  Michinori Suginome

  Kobunshi, 2008, Peer-reviewed

  
• Development of boron-based reactions and reagents for organic synthesis

  Michinori Suginome

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Nov. 2007

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• Acid-free, aminoborane-mediated Ugi-type reaction leading to general utilization of secondary Amines

  Yusuke Tanaka; Tomoaki Hasui; Michinori Suginome

  ORGANIC LETTERS, Oct. 2007

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• Synthesis and helical structure of oligo(quinoline-2,3-diyl)s

  Michinori Suginome; Hiroyoshi Noguchi; Masahiro Murakami

  CHEMISTRY LETTERS, Aug. 2007

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• Palladium-catalyzed asymmetric silaborative C-C cleavage of meso-methylenecyclopropanes

  Toshimichi Ohmura; Hiroki Taniguchi; Yoshiyuki Kondo; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 2007

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• Synthesis of silylboronic esters functionalized on silicon

  Toshimichi Ohmura; Kohei Masuda; Hideki Furukawa; Michinori Suginome

  ORGANOMETALLICS, Feb. 2007

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• Boron-masking strategy for the selective synthesis of oligoarenes via iterative Suzuki-Miyaura coupling

  Hiroyoshi Noguchi; Kosho Hojo; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jan. 2007

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• Nickel-catalyzed addition of alkynylboranes to alkynes

  Michinori Suginome; Masamichi Shirakura; Akihiko Yamamoto

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2006

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• Palladium-catalyzed asymmetric silaboration of allenes

  Toshimichi Ohmura; Hiroki Taniguchi; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Oct. 2006

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• Ligand-controlled, complementary stereoselectivity in the platinum-catalyzed intramolecular silaboration of alkenes

  Toshimichi Ohmura; Hideki Furukawa; Michinori Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Oct. 2006

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• Aminoboranes as new iminium ion generators in amination reactions

  Michinori Suginome

  PURE AND APPLIED CHEMISTRY, Jul. 2006

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• Reactions of cyanoboranes with a palladium-PMe3 complex: Mechanism for the catalytic cyanoboration of alkynes

  M Suginome; A Yamamoto; T Sasaki; M Murakami

  ORGANOMETALLICS, Jun. 2006

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• Asymmetric silaboration of terminal allenes bearing alpha-stereogenic centers: Stereoselection based on "reagent control"

  Toshimichi Ohmura; Michinori Suginome

  ORGANIC LETTERS, Jun. 2006

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• Reductive amination of aldehydes using aminoboranes as iminium ion generators

  Michinori Suginome; Yusuke Tanaka; Tomoaki Hasui

  SYNLETT, May 2006

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• Nickel-catalyzed trans-alkynylboration of alkynes via activation of a boron-chlorine bond

  A Yamamoto; M Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2005

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• Intramolecular cyanoboration of alkynes via activation of boron-cyanide bonds by transition metal catalysts

  M Suginome; A Yamamoto; M Murakami

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, Nov. 2005

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• Stereoselective synthesis of highly enantioenriched (E)-allylsilanes by palladium-catalyzed intramolecular bis-silylation: 1,3-chirality transfer and enantioenrichment via dimer formation

  M Suginome; T Iwanami; Y Ohmori; A Matsumoto; Y Ito

  CHEMISTRY-A EUROPEAN JOURNAL, May 2005

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• Synthesis and reactions of cyclic silylboranes

  M Suginome; H Noguchi; T Hasui; M Murakami

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Feb. 2005

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• Palladium-catalyzed addition of cyanoboranes to alkynes: Regio- and stereoselective synthesis of alpha,beta-unsaturated beta-boryl nitriles

  M Suginome; A Yamamoto; M Murakami

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005

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• Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s

  Motomura, T; Nakamura, H; Suginome, M; Murakami, M; Ito, Y

  Bull. Chem. Soc. Jpn., 2005, Peer-reviewed

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• A new look at boron enolate chemistry: Aminative C-C bond formation using diaminoboron enolate with aldehyde

  M Suginome; L Uehlin; A Yamamoto; M Murakami

  ORGANIC LETTERS, Apr. 2004

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• Transition metal-mediated polymerization of isocyanides

  M Suginome; Y Ito

  POLYMER SYNTHESIS, 2004

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• Aminoboranes as "Compatible" Iminium Ion Generators in Aminative C-C Bond Formations

  Suginome, M; Uhelin, L; Murakami, M

  Journal of the American Chemical Society, 2004, Peer-reviewed

  
• Stereoselective accesses to enantioenriched allyl-, allenyl-, and propargyl-silanes via Si-Si bond activation by palladium-isocyanide catalysts

  M Suginome; Y Ito

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, Nov. 2003

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• Enantioface-selective palladium-catalyzed silaboration of allenes via double asymmetric induction

  M Suginome; T Ohmura; Y Miyake; S Mitani; Y Ito; M Murakami

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 2003

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• Regio- and stereoselective synthesis of boryl-substituted allylsilanes via transition metal-catalyzed silaboration

  M Suginome; Y Ito

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, Aug. 2003

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• Palladium- and nickel-catalyzed intramolecular cyanoboration of alkynes

  M Suginome; A Yamamoto; M Murakami

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2003

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• Highly efficient strecker-type aminative cyanation of aldehydes and ketones using bis(dialkylamino)cyanoboranes.

  M Suginome; A Yamamoto; Y Ito

  ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2002

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• Nickel-catalyzed silaboration of small-ring vinylcycloalkanes: Regio- and stereoselective (E)-allylsilane formation via C-C bond cleavage

  M Suginome; T Matsuda; T Yoshimoto; Y Ito

  ORGANOMETALLICS, Apr. 2002

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• 1,2-Azaboretidine formation in the reactions of (boryl)(silyl)iminomethanes via possible generation of (amino) (boryl)carbene species

  M Suginome; T Fukuda; Y Ito

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, Feb. 2002

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• Highly effective, easily accessible screw-sense-determining end group in the asymmetric polymerization of 1,2-diisocyanobenzenes

  M Suginome; S Collet; Y Ito

  ORGANIC LETTERS, Feb. 2002

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• Bis(dialkylamino)cyanoboranes: highly efficient reagents for the Strecker-type aminative cyanation of aldehydes and ketones

  M Suginome; A Yamamoto; Y Ito

  CHEMICAL COMMUNICATIONS, 2002

  
• Stereoselective construction of trans-1,2-benzooxadecaline frameworks by three-component cascade reactions of an alpha-phenethyl-beta-borylallylsilane with aldehydes

  M Suginome; Y Ohmori; Y Ito

  CHEMICAL COMMUNICATIONS, Jun. 2001

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• beta-Borylallylsilanes as a new tool for convenient synthesis of alkenylboranes

  M Suginome; Y Ohmori; Y Ito

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2001

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• Solid-phase synthesis and asymmetric reactions of polymer-supported highly enantioenriched allylsilanes

  M Suginome; T Iwanami; Y Ito

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 2001

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• Asymmetric synthesis of cyclic alkenes via cyclization of enantioenriched allylsilanes

  M Suginome; T Iwanami; A Yamamoto; Y Ito

  SYNLETT, 2001

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• Palladium- and platinum-catalyzed silaboration of methylenecyclopropanes through selective proximal or distal C-C bond cleavage

  M Suginome; T Matsuda; Y Ito

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 2000

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• Palladium-catalyzed regioselective silaboration of 1,2-dienes

  M Suginome; Y Ohmori; Y Ito

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, Oct. 2000

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• Convenient preparation of silylboranes

  M Suginome; T Matsuda; Y Ito

  ORGANOMETALLICS, Oct. 2000

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• Transition-metal-catalyzed additions of silicon-silicon and silicon-heteroatom bonds to unsaturated organic molecules

  M Suginome; Y Ito

  CHEMICAL REVIEWS, Aug. 2000

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• Structural modification of living polymers: Synthesis of helical block copolymers from a single monomer via palladium-mediated aromatizing polymerization of 1,2-diisocyanobenzenes

  Y Ito; T Miyake; M Suginome

  MACROMOLECULES, May 2000

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• Synthesis of (boryl)(silyl)iminomethanes by insertion of isonitriles into silicon-boron bonds

  M Suginome; T Fukuda; H Nakamura; Y Ito

  ORGANOMETALLICS, Mar. 2000

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• First synthesis and resolution of a planar-chiral tetrahydroindolyl complex of iron: Electronic tuning of reactivity and enantioselective nucleophilic catalysis

  M Suginome; GC Fu

  CHIRALITY, 2000

  
• New access to 2,3-disubstituted quinolines through cyclization of o-alkynylisocyanobenzenes

  M Suginome; T Fukuda; Y Ito

  ORGANIC LETTERS, Dec. 1999

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• Stereoselective 1,4-silaboration of 1,3-dienes catalyzed by nickel complexes

  M Suginome; T Matsuda; T Yoshimoto; Y Ito

  ORGANIC LETTERS, Nov. 1999, Peer-reviewed

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• Highly regioselective silaboration of 3-substituted 1,2-dienes catalyzed by palladium/2,6-xylyl isocyanide

  M Suginome; Y Ohmori; Y Ito

  SYNLETT, Oct. 1999

  
• Regio- and stereoselective synthesis of (Z)-beta-silylalkenylboranes by silaboration of alkynes catalyzed by palladium and platinum complexes

  M Suginome; T Matsuda; H Nakamura; Y Ito

  TETRAHEDRON, Jul. 1999

  
• Asymmetric synthesis of 2,3-disubstituted oxepanes via acetalization-cyclization of an enantioenriched functionalized allylsilane with aldehydes

  M Suginome; T Iwanami; Y Ito

  CHEMICAL COMMUNICATIONS, 1999

  
• Nickel-catalyzed silaborative dimerization of alkynes

  M Suginome; T Matsuda; Y Ito

  ORGANOMETALLICS, Nov. 1998

  
• Asymmetric synthesis of helical poly(quinoxaline-2,3-diyl)s by palladium-mediated polymerization of 1,2-diisocyanobenzenes: Effective control of the screw-sense by a binaphthyl group at the chain-end

  Y Ito; T Miyake; S Hatano; R Shima; T Ohara; M Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 1998

  
• Stereoselective cyclization of highly enantioenriched allylsilanes with aldehydes via acetal formation: New asymmetric access to tetrahydropyrans and piperidines

  M Suginome; T Iwanami; Y Ito

  JOURNAL OF ORGANIC CHEMISTRY, Sep. 1998

  
• Activation of silicon-silicon sigma bonds by transition-metal complexes: synthesis and catalysis of new organosilyl transition-metal complexes

  M Suginome; Y Ito

  JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, Jun. 1998

  
• Platinum-catalyzed silaborative coupling of 1,3-dienes to aldehydes: Regio- and stereoselective allylation with dienes through allylic platinum intermediates

  M Suginome; H Nakamura; T Matsuda; Y Ito

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 1998

  
• Stereospecific cationic [1,2] silyl shift with retention of configuration at the migrating terminus

  M Suginome; A Takama; Y Ito

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 1998

  
• Asymmetric synthesis of helically stable poly(quinoxaline-2,3-diyl)s having hydrophilic and/or hydrophobic side chains

  Y Ito; T Miyake; T Ohara; M Suginome

  MACROMOLECULES, Mar. 1998

  
• Reactions of a spiro trisilane with palladium complexes: Synthesis and structure of tris(organosilyl)CpPdIV and Bis(organosilyl)(mu-organosilylene)Pd-2(II) complexes

  M Suginome; Y Kato; N Takeda; H Oike; Y Ito

  ORGANOMETALLICS, Feb. 1998

  
• Platinum-catalyzed regioselective silaboration of alkenes

  M Suginome; H Nakamura; Y Ito

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, Dec. 1997, Peer-reviewed

  
• Racemization and deracemization of poly(quinoxaline-2,3-diyl)s

  Y Ito; Y Kojima; M Murakami; M Suginome

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Nov. 1997

  
• Synthesis of highly enantio-enriched allylsilanes via palladium-catalyzed intramolecular bis-silylation. Determination of the enantiomeric excesses through regio- and stereoselective hydroboration with 9-BBN

  M Suginome; T Iwanami; A Matsumoto; Y Ito

  TETRAHEDRON-ASYMMETRY, Mar. 1997, Peer-reviewed

  
• Optically active isonitrile ligand for palladium-catalyzed enantioselective bis-silylation of carbon-carbon double bonds

  M Suginome; H Nakamura; Y Ito

  TETRAHEDRON LETTERS, Jan. 1997, Peer-reviewed

  
• New synthetic access to 1,3-diaza-5-sila-2-boracyclohexane frameworks by the reaction of borane with bis[(N-arylimino)organosilylmethyl]silanes

  M Suginome; M Murakami; Y Ito

  HETEROCYCLES, Jan. 1997

  
• Regio- and stereo-selective silaboration of alkynes catalysed by palladium and platinum complexes

  M Suginome; H Nakamura; Y Ito

  CHEMICAL COMMUNICATIONS, Dec. 1996

  
• Palladium-catalyzed intramolecular addition of trisilanes to carbon-carbon double bonds. Polyol synthesis by use of a disilanyl group as a hydroxyl equivalent.

  M Suginome; S Matsunaga; T Iwanami; A Matsumoto; Y Ito

  TETRAHEDRON LETTERS, Dec. 1996

  
• Highly screw-sense selective polymerization of 1,2-diisocyano-3,6-di-p-tolylbenzene initiated by optically active binaphthylpalladium(II) complexes

  Y Ito; T Ohara; R Shima; M Suginome

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 1996

  
• Double oxidative addition of the Si-Si and Si-Ge bonds onto isonitrile-platinum(0) complexes leading to the formation of tetrakis(organosilyl)- and bis(organogermyl) bis(organosilyl)platinum(IV) complexes

  M Suginome; H Oike; PH Shuff; Y Ito

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, Aug. 1996

  
• Palladium-catalyzed intramolecular bis-silylation of propargylic alcohols: A new stereospecific access to chiral allenylsilanes

  M Suginome; A Matsumoto; Y Ito

  JOURNAL OF ORGANIC CHEMISTRY, Jul. 1996

  
• Synthesis of organosilicon macrocycles. Palladium-catalyzed ring-enlargement oligomerization of cyclic disilanes via Si-Si sigma-bond metathesis

  M Suginome; H Oike; PH Shuff; Y Ito

  ORGANOMETALLICS, Apr. 1996

  
• New synthesis of (E)-allylsilanes with high enantiopurity via diastereoselective intramolecular bis-silylation of chiral allylic alcohols

  M Suginome; A Matsumoto; Y Ito

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Mar. 1996

  
• Intramolecular bis-silylation of alkenes catalyzed by palladium(0) tert-alkyl isocyanide complex. Stereoselective synthesis of polyols

  Y Ito; M Suginome

  PURE AND APPLIED CHEMISTRY, Mar. 1996, Peer-reviewed

  
• Reactions of Si-Si sigma-bonds with bis(t-alkyl isocyanide)palladium(0) complexes. Synthesis and reactions of cyclic bis(organosilyl)palladium complexes

  M Suginome; H Oike; SS Park; Y Ito

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Feb. 1996, Peer-reviewed

  
• New synthesis of quinoxaline derivatives based on palladium catalyzed oligomerization of 1-diisocyano-arenes

  Y Ito; Y Kojima; M Suginome; M Murakami

  HETEROCYCLES, Jan. 1996

  
• PALLADIUM-TERT-ALKYL ISOCYANIDE CATALYZED INTRAMOLECULAR BIS-SILYLATION OF VICINALLY DISUBSTITUTED ALKENES

  M SUGINOME; A MATSUMOTO; K NAGATA; Y ITO

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, Sep. 1995

  
• DISILANYL GROUP AS A SYNTHETIC EQUIVALENT OF THE HYDROXYL GROUP

  M SUGINOME; S MATSUNAGA; Y ITO

  SYNLETT, Sep. 1995

  
• DIASTEREOSELECTIVE INTRAMOLECULAR BIS-SILYLATION OF A CARBON-CARBON DOUBLE-BOND - A HIGHLY STEREOCONTROLLED SYNTHESIS OF (-)-AVENACIOLIDE

  M SUGINOME; Y YAMAMOTO; K FUJII; Y ITO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Sep. 1995

  
• INTRAMOLECULAR BIS-SILYLATION CATALYZED BY PALLADIUM-ISOCYANIDE

  M MURAKAMI; M SUGINOME; Y ITO

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Jun. 1995, Peer-reviewed

  
• MACROCYCLES WITH REGULARLY ARRANGED SI-SI BONDS - RING-ENLARGEMENT OLIGOMERIZATION OF CYCLIC DISILANES VIA PALLADIUM-CATALYZED SI-SI SIGMA-BOND METATHESIS

  M SUGINOME; H OIKE; Y ITO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Feb. 1995

  
• PALLADIUM-CATALYZED INTRAMOLECULAR CYANOSILYLATION OF ALKYNES LEADING TO STEREOSELECTIVE SYNTHESIS OF ALPHA,BETA-UNSATURATED NITRILES

  M SUGINOME; H KINUGASA; Y ITO

  TETRAHEDRON LETTERS, Nov. 1994

  
• NOVEL ACTIVATION OF 2 SI-SI SIGMA-BONDS IN A MOLECULE BY TERT-ALKYL ISOCYANIDE-PALLADIUM COMPLEXES

  M SUGINOME; H OIKE; Y ITO

  ORGANOMETALLICS, Nov. 1994

  
• Nontwisted Tetrakis(organosilyl)ethenes

  M MURAKAMI; M SUGINOME; K FUJIMOTO; Y ITO

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, Oct. 1993

  
• STEREOSELECTIVE INTRAMOLECULAR BIS-SILYLATION OF ALKENES PROMOTED BY A PALLADIUM ISOCYANIDE CATALYST LEADING TO POLYOL SYNTHESIS

  M MURAKAMI; M SUGINOME; K FUJIMOTO; H NAKAMURA; PG ANDERSSON; Y ITO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Jul. 1993

  
• Stereoselective Synthesis of 1,2,4-Triols via Intramolecular Bis-Silylation of Carbon-Carbon Triple Bonds Followed by Hydrogenation

  M. Murakami; H. Oike; M. Sugawara; M. Suginome; Y. Ito

  Tetrahedron, 1993, Peer-reviewed

  
• PALLADIUM-CATALYZED INSERTION OF ISOCYANIDES INTO THE SILICON-SILICON LINKAGES OF OLIGOSILANES

  Y ITO; M SUGINOME; T MATSUURA; M MURAKAMI

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Nov. 1991

  
• INTRAMOLECULAR BIS-SILYLATION OF CARBON-CARBON DOUBLE BONDS LEADING TO STEREOSELECTIVE SYNTHESIS OF 1,2,4-TRIOLS

  M MURAKAMI; PG ANDERSSON; M SUGINOME; Y ITO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, May 1991

  
• PALLADIUM(II) ACETATE TERT-ALKYL ISOCYANIDE AS A HIGHLY EFFICIENT CATALYST FOR THE INTERMOLECULAR AND INTRAMOLECULAR BIS-SILYLATION OF CARBON-CARBON TRIPLE BONDS

  Y ITO; M SUGINOME; M MURAKAMI

  JOURNAL OF ORGANIC CHEMISTRY, Mar. 1991

  
• NOVEL SKELETAL REARRANGEMENT REACTION OF TETRASILANES WITH ARYL ISOCYANIDES

  Y ITO; M SUGINOME; M MURAKAMI; M SHIRO

  JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, Oct. 1989

  
• REACTIONS OF (TRIPHENYLPHOSPHINE)GOLD(I) ENOLATES AND HOMOENOLATES

  M MURAKAMI; M INOUYE; M SUGINOME; Y ITO

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Oct. 1988, Peer-reviewed

  
• Convenient preparative method and crystal structures of (tripenylphosphine)gold(I) enolate and homoenolate complexes

  Y. Ito; M. Inouye; M. Suginome; M. Murakami

  Journal of Organometallic Chemistry, 1988, Peer-reviewed

  

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• Iridium-Catalyzed Intramolecular Silylene Transfer Leading to Silylene Insertion into sp³ Carbon-Oxygen Bond

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• Functionalized Disilanylboronic Esters: Synthesis and Transition-Metal-Catalyzed Reaction

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• Iridium-Catalyzed Annulative Coupling: C(sp³)-H Addition in Preference to O-H Addition of Phenol

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• Catalytic Construction of Silicon-Containing Rings Based on a Rhodium Silylenoid Formed from Chlorodisilane

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• Direct Synthesis of 2-Methylbenzofurans from o-Cresols with Ethylene by Iridium-Catalyzed Annulative Coupling

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• Iridium-Catalyzed Tandem Dehydrogenation-Intramolecular C-H/C-H Coupling of 2-(Pyrrolidin-1-yl)alkylbenzenes

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• Iridium-Catalyzed C-H/C-H Coupling. Part 3. Synthesis of π-Conjugated Molecules by Reaction of Ethylarenes with Benzofuran

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• Iridium-Catalyzed C-H/C-H Coupling. Part 2. Synthesis of Benzofuran Derivatives through Cyclization of 2-Alkylphenyl Methyl Ethers

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• Copper-Catalyzed Regioselective Stereodivergent Silaboration of Internal Alkynes

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• Iridium-Catalyzed Enantioselective Cycloisomerization of Allylic Aryl Ethers

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• Formation of Oligosilanes via Transition-Metal-Free Sequential Silylene Insertion into Silicon-Oxygen Bond

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• 分子内ビスシリル化を用いた1,2,5-トリオールの立体選択的合成

  伊藤嘉彦; 杉野目道紀; 藤本健造; 村上正浩

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• ホウ素で炭素を組み立てる : 機能性ホウ素反応剤のデザイン・創製・新反応

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  化学と工業 = Chemistry and chemical industry, 01 Aug. 2005

  
• Iterative Suzuki-Miyaura Cross-Coupling Reaction for the Selective Synthesis of Oligoarenes

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  Journal of the Japanese Liquid Crystal Society, 25 Oct. 2008

  
• Development of new chirality-switchable polymeric materials based on the solvent-dependent helix inversion of the macromolecular helicity

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  ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2018

  
• Elucidation of the mechanism of the solvent-dependent helix inversion of polymer backbones by using quasielastic neutron scattering and light scattering measurements

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• Synthesis of Poly(quinoxaline-2,3-diyl)s with Polar Terminal Groups and Their Screw-sense Induction by the Addition of Chiral Additives

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• Synthesis and Helical Chirality Induction of Poly(quinoxaline-2,3-diyl)s Bearing Hydroxymethyl Groups at 5,8-Positions

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• Asymmetric Suzuki-Miyaura Coupling of 1-bromo-2-naphtoates in Water with Water-Soluble Helical Polymer Ligands

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• Rhodium-Catalyzed Reaction Using a Borylsilane as a Synthetic Equivalent of Silylene: [2+2+1] Cycloaddition with Ketone as a Two Atom Component

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• Iridium-Catalyzed Tandem CH Transformations: 1: Synthesis of 2-Methylbenzofurans through Cyclization of Ethyl 2-Methylphenyl Ethers

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• Iridium-Catalyzed Tandem CH Transformations: 2: Synthesis of 2,3-Dihydrobenzofuran Derivatives through Cyclization of Phenyl 2-Siloxypropyl Ethers

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• アキラルカルボン酸側鎖を有するポリ(キノキサリン-2,3-ジイル)のキラルアミン類とのイオン性相互作用による高効率主鎖らせん不斉誘起

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• イリジウム触媒による脱水素化とC(sp³)-H結合の付加に基づく3-メチルインドール誘導体の合成

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• キラリティのスイッチングと増幅を特徴とする次世代キラル触媒システムの創製

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• Highly-Efficient Ir/t-BuOK Catalyst for Non-Directed C(sp3)-H Borylation

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  OHMURA TOSHIMICHI; MIWA KYOKO; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 08 Sep. 2014

  
• Iridium-Catalyzed Highly-Efficient Borylation of Sterically Hindered C(sp3)-H Bonds

  OHMURA TOSHIMICHI; TORIGOE TAKERU; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 08 Sep. 2014

  
• Utility of a Trimethylsilyl Group as an Equivalent of Hydroxyl Group: Synthesis of Alkanols via Iridium-Catalyzed C(sp3)-H Borylation

  OHMURA TOSHIMICHI; TORIGOE TAKERU; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2014

  
• Synthetic Applications of .ALPHA.-(Acylamino)-alkylboronic Esters: Control of Stereochemical Course in Catalytic Construction of Stereogenic Carbon Centers

  OHMURA TOSHIMICHI; MIWA KYOKO; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2014

  
• ホウ素‐窒素結合形成を鍵とする含窒素芳香環の脱芳香化

  OMURA TOSHIMICHI; MORIMASA YOHEI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2014

  
• Iridium-Catalyzed .ALPHA.-Silyl Effect-Based C(sp3)-H Borylation of Organosilicon Compounds

  OHMURA TOSHIMICHI; TORIGOE TAKERU; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 27 Aug. 2013

  
• 光学活性α‐(アシルアミノ)アルキルボロン酸エステルの立体特異的鈴木‐宮浦カップリング

  OMURA TOSHIMICHI; MIWA KYOKO; SUGINOME MICHINORI

  日本化学会講演予稿集, 08 Mar. 2013

  
• ジボロンおよびシリルボランの無触媒付加反応によるピラジンおよびピリジン類の脱芳香化

  OMURA TOSHIMICHI; MORIMASA YOHEI; OSHIMA KAZUYUKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 08 Mar. 2013

  
• イリジウム触媒によるテトラアルキルシランの位置選択的C(sp³)‐Hボリル化

  OMURA TOSHIMICHI; TORIGOE TAKERU; SUGINOME MICHINORI

  日本化学会講演予稿集, 08 Mar. 2013

  
• らせん高分子配位子PQXphosを用いた不斉シリルホウ素化におけるらせん高分子構造がもたらす触媒活性と選択性の向上

  YAMAMOTO TAKESHI; AKAI YUTO; NAGATA YUYA; OMURA TOSHIMICHI; SUGINOME MICHINORI

  高分子学会予稿集(CD-ROM), 05 Sep. 2012

  
• Effects of Acidic Additives on the Stereochemical Course in Invertive adn Retentive Suzuki-Miyaura Coupling of .ALPHA.-(Acetylamino)benzylboronic Esters

  OHMURA TOSHIMICHI; AWANO TOMOTSUGU; MIWA KYOKO; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 28 Aug. 2012

  
• Selective organic synthesis via boron-based transition metal catalysis

  Michinori Suginome

  ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2012

  
• キラル高分子配位子PQXphosを用いたメチレンシクロプロパンの不斉シリルホウ素化

  AKAI YUTO; YAMAMOTO TAKESHI; NAGATA YUYA; OMURA TOSHIMICHI; SUGINOME MICHINORI

  シンポジウム「モレキュラー・キラリティー」講演要旨集, 17 May 2012

  
• イリジウム触媒によるメチルクロロシラン類のメチル基上でのC‐Hボリル化反応

  OMURA TOSHIMICHI; TORIGOE TAKERU; SUGINOME MICHINORI

  日本化学会講演予稿集, 09 Mar. 2012

  
• 2‐シリルピリジンの合成化学的利用:アルデヒドの無触媒求核的2‐ピリジル化

  OMURA TOSHIMICHI; YASUI RYOHEI; OSHIMA KAZUYUKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 09 Mar. 2012

  
• ホウ素反応剤の位置選択的付加に基づいたピリジンの触媒的脱芳香族化

  OSHIMA KAZUYUKI; OMURA TOSHIMICHI; SUGINOME MICHINORI

  日本化学会講演予稿集, 09 Mar. 2012

  
• 触媒的脱水素化と無触媒C‐Hアルキニル化を鍵とするπ共役型イソインドールの合成

  OMURA TOSHIMICHI; KOMORI YUSUKE; SUGINOME MICHINORI

  日本化学会講演予稿集, 09 Mar. 2012

  
• キラルらせん高分子配位子PQXphosを用いたパラジウム触媒によるメチレンシクロプロパンの不斉開環シリルホウ素化

  AKAI YUTO; YAMAMOTO TAKESHI; NAGATA YUYA; OMURA TOSHIMICHI; SUGINOME MICHINORI

  日本化学会講演予稿集, 09 Mar. 2012

  
• Regioselective Synthesis of Silylated Dihydropyridines via Catalytic Silaboration of Pyridines

  OSHIMA KAZUYUKI; OHMURA TOSHIMICHI; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 23 Aug. 2011

  
• One-Pot Synthesis of Functionalized Isoindoles from Isoindolines via Catalytic Dehydrogenation Followed by C-H Functionalization

  OHMURA TOSHIMICHI; KOMORI YUSUKE; KIJIMA AKIHITO; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 23 Aug. 2011

  
• イリジウム触媒によるイソインドリンの脱水素化/環縮小を経るベンゾシクロブテン合成

  OMURA TOSHIMICHI; KOMORI YUSUKE; SUGINOME MICHINORI

  日本化学会講演予稿集, 11 Mar. 2011

  
• 光学活性(α‐アミド)ベンジルボロン酸エステルの立体特異的鈴木‐宮浦カップリング:添加剤による立体反転と立体保持の制御

  AWANO TOMOTSUGU; OMURA TOSHIMICHI; SUGINOME MICHINORI

  日本化学会講演予稿集, 11 Mar. 2011

  
• (アミノシリル)ボランを用いる触媒的シリレン等価体形成:2‐ビニル置換ベンゾフランおよびベンゾチオフェンとの[4+1]環化付加反応

  MASUDA KOHEI; OMURA TOSHIMICHI; SUGINOME MICHINORI

  日本化学会講演予稿集, 11 Mar. 2011

  
• (アミノシリル)ボランとパラジウム触媒を用いる炭素‐酸素結合へのシリレンの二重挿入によるジシラン生成

  OMURA TOSHIMICHI; TAKASE ICHIRO; SUGINOME MICHINORI

  日本化学会講演予稿集, 11 Mar. 2011

  
• イソインドリンの触媒的脱水素化を経由する1,3‐ジアルキニルイソインドールの合成

  OMURA TOSHIMICHI; KIJIMA AKIHITO; KOMORI YUSUKE; SUGINOME MICHINORI

  日本化学会講演予稿集, 11 Mar. 2011

  
• パラジウム触媒によるピリジンのシリルホウ素化

  OSHIMA KAZUYUKI; OMURA TOSHIMICHI; SUGINOME MICHINORI

  日本化学会講演予稿集, 11 Mar. 2011

  
• (Aminosilyl)boronic Esters as Silylene Precursors. Formation of Pd or Pt Complexes with Si Ligands and Their Reactivity on Unsaturated Compounds.

  JIANG JIAN; TANABE MAKOTO; OSAKADA KOHTARO; OHMURA TOSHIMICHI; SUGINOME MICHINORI

  錯体化学討論会講演要旨集, 16 Sep. 2010

  
• Stereospecific Cross-Coupling of Chiral .ALPHA.-(Acylamino)benzylboronic Esters

  AWANO TOMOTSUGU; OHMURA TOSHIMICHI; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 01 Sep. 2010

  
• Palladium-Catalyzed Silylene Transfer from (Aminosilyl)boronic Esters to 1,3-Dienes and Alkenes

  MASUDA KOHEI; TAKASE ICHIRO; OHMURA TOSHIMICHI; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 01 Sep. 2010

  
• 完全な立体保持で進行する光学活性(α‐アミド)ベンジルボロン酸エステルの鈴木‐宮浦カップリング

  OMURA TOSHIMICHI; AWANO TOMOTSUGU; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2010

  
• パラジウム触媒によるイソインドールのC‐Hアリール化:イソインドリンの脱水素化を経る1,3‐ジアリールイソインドールのワンポット合成

  OMURA TOSHIMICHI; KIJIMA AKIHITO; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2010

  
• ロジウム触媒による第3級アリル型アルコール誘導体のジアステレオ選択的分子内ヒドロシリル化

  OMURA TOSHIMICHI; KUCHIDA KENTA; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2010

  
• パラジウム触媒を用いた(アミノシリル)ボランとアルケニルインドールの反応

  OMURA TOSHIMICHI; MASUDA KOHEI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2010

  
• パラジウム触媒を用いた立体選択的二重結合異性化によるβ‐ボリルアリルシランの立体相補的合成

  OMURA TOSHIMICHI; OSHIMA KAZUYUKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2010

  
• パラジウム触媒による(アミノシリル)ボランとジエニルリン酸エステルの反応:炭素‐酸素結合へのシリレンの挿入

  OMURA TOSHIMICHI; TAKASE ICHIRO; MASUDA KOHEI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2010

  
• Synthesis of .GAMMA.,.DELTA.-Unsaturated Ketones via Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes

  TANIGUCHI HIROKI; OHMURA TOSHIMICHI; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 25 Aug. 2009

  
• Synthesis of 1-Borylisoindoles by Palladium-Catalyzed Dehydrogenation/C-H Borylation of Isoindolines

  OHMURA TOSHIMICHI; KIJIMA AKIHITO; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 25 Aug. 2009

  
• Palladium-Catalyzed Dehydrogenative C-H Borylation of Isoindolines Leading to the Synthesis of Boryl-Substituted Isoindoles

  OMURA TOSHIMICHI; KIJIMA AKIHITO; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2009

  
• Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes

  TANIGUCHI HIROKI; OMURA TOSHIMICHI; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2009

  
• Palladium-Catalyzed Reaction of (Aminosilyl)borane with Alkenes

  OMURA TOSHIMICHI; MASUDA KOHEI; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2009

  
• Cross-Coupling of .ALPHA.-Aminobenzylboronic Esters

  OMURA TOSHIMICHI; AWANO TOMOTSUGU; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2009

  
• Synthesis and Application of Organoborates Derived from Alkyne Silabolation

  OMURA TOSHIMICHI; OSHIMA KAZUYUKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2009

  
• 昨日今日そして明日のケイ素化学 遷移金属触媒とシリレン等価体による炭素‐ケイ素結合形成

  OMURA TOSHIMICHI; SUGINOME MICHINORI

  ケイ素化学協会誌, 10 Nov. 2008

  
• 白金触媒による脱水素ボリル化を基軸としたアルケンの立体選択的官能基化

  OMURA TOSHIMICHI; TAKASAKI YUTA; FURUKAWA HIDEKI; SUGINOME MICHINORI

  有機合成化学セミナー講演予稿集, 08 Sep. 2008

  
• (アミノシリル)ボランのシリレン等価体としての利用:パラジウム触媒を用いた共役ジエンとの反応による2,5‐ジヒドロシロールの合成

  OMURA TOSHIMICHI; MASUDA KOHEI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2008

  
• パラジウム触媒によるアルキンのシリルホウ素化:配位子による位置選択性の逆転

  OMURA TOSHIMICHI; OSHIMA KAZUYUKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2008

  
• パラジウム触媒不斉シリルホウ素化C‐C切断に基づいた2‐アルキル‐1‐メチレンシクロプロパンの速度論的光学分割

  OMURA TOSHIMICHI; TANIGUCHI HIROKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2008

  
• 白金触媒によるアルケンの分子内シリルホウ素化:1,3‐ポリオール骨格の立体選択的構築

  OMURA TOSHIMICHI; FUJITA MASATO; FURUKAWA HIDEKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2008

  
• 白金触媒による脱水素ボリル化/ヒドロシリル化に基づいた1,4‐ペンタジエン‐3‐オール誘導体の非対称1,5‐官能基化

  OMURA TOSHIMICHI; TAKASAKI YUTA; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2008

  
• Palladium-Catalyzed Reaction of Alkynes and 1,3-Dienes with Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents

  OHMURA TOSHIMICHI; MASUDA KOHEI; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 2008

  
• 白金触媒を用いたアルケンの脱水素ボリル化

  OMURA TOSHIMICHI; TAKASAKI YUTA; FURUKAWA HIDEKI; SUGINOME MICHINORI

  触媒討論会討論会A予稿集, 17 Sep. 2007

  
• ORGN 21-Boron-masking strategy for the selective synthesis of oligoarenes via Suzuki-Miyaura coupling

  Michinori Suginome; Hiroyoshi Noguchi; Kosho Hojo; Takayuki Shioda

  ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Aug. 2007

  
• パラジウム触媒による(アミノシリル)ボランと末端アルキンの反応:2,4‐二置換シロールの位置選択的合成

  OMURA TOSHIMICHI; MASUDA KOHEI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2007

  
• パラジウム触媒を用いたアルキンのcis‐およびtrans‐シリルホウ素化

  OMURA TOSHIMICHI; OSHIMA KAZUYUKI; MASUDA KOHEI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2007

  
• アルケンの白金触媒脱水素ボリル化によるβ,β‐二置換アルケニルボランの立体選択的合成

  OMURA TOSHIMICHI; FURUKAWA HIDEKI; TAKASAKI YUTA; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2007

  
• 一置換メチレンシクロプロパンの位置選択的シリルホウ素化C‐C切断反応

  OMURA TOSHIMICHI; TANIGUCHI HIROKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 12 Mar. 2007

  
• 分子内シアノホウ素化の合成化学的利用:鈴木‐宮浦カップリング‐レトロアリル化カップリングによる多置換α,β‐不飽和ニトリルの合成

  OMURA TOSHIMICHI; AWANO TOMOTSUGU; SUGINOME MICHINORI; YORIMITSU HIDEKI; OSHIMA KOICHIRO

  日本化学会講演予稿集, 12 Mar. 2007

  
• Asymmetric Desymmetrization of meso-Methylenecyclopropanes via Palladium-Catalyzed Silaborative C-C Cleavage

  OHMURA TOSHIMICHI; TANIGUCHI HIROKI; KONDO YOSHIYUKI; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 2007

  
• Asymmetric Silaborative C-C Bond Cleavage of Methylenecyclopropanes Catalyzed by Palladium Complexes

  OMURA TOSHIMICHI; KONDO YOSHIYUKI; TANIGUCHI HIROKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2006

  
• Synthesis and Reactions of Silylboranes Modified with Heteroatom Substituents on Silicon

  OMURA TOSHIMICHI; MASUDA KOHEI; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2006

  
• Ligand-Dependent Stereocomplementarity in Platinum-Catalyzed Intramolecular Silaboration of Alkenes

  OMURA TOSHIMICHI; FURUKAWA HIDEKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2006

  
• Palladium-Catalyzed Asymmetric Silaboration of Allenes

  OMURA TOSHIMICHI; TANIGUCHI HIROKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 13 Mar. 2006

  
• Platinum-Catalyzed Stereoselective Intramolecular Silaboration of Alkenes

  OHMURA TOSHIMICHI; FURUKAWA HIDEKI; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 2006

  
• New Development of Synthesis of Organosilicon Compounds. C-Si Bond Formation Using the Activation of C-H Bond.

  OMURA TOSHIMICHI; SUGINOME MICHINORI

  化学, 01 Aug. 2005

  
• Asymmetric Silaboration of Chiral Terminal Allenes Based on "Reagent Control"

  OMURA TOSHIMICHI; TANIGUCHI HIROKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 11 Mar. 2005

  
• Transition Metal-Catalyzed Intramolecular Silaboration of Alkenes

  OMURA TOSHIMICHI; FURUKAWA HIDEKI; SUGINOME MICHINORI

  日本化学会講演予稿集, 11 Mar. 2005

  
• Palladium-Catalyzed Asymmetric Silaboration of Allenes

  OHMURA TOSHIMICHI; TANIGUCHI HIROKI; SUGINOME MICHINORI

  Symp Organomet Chem Jpn, 2005

  
• Enantioface-Selective Silaboration of Terminal Allenes Catalyzed by Palladium Complexes

  SUGINOME MICHINORI; OMURA TOSHIMICHI; MURAKAMI MASAHIRO

  日本化学会講演予稿集, 11 Mar. 2004

  
• Helical Structure of Poly(quinoxaline-2, 3-diyl)s

  SUGINOME Michinori

  Kobunshi, 2004

  
• Catalytic Asymmetric Silaboration of Terminal Allenes via Double Asymmetric Induction

  SUGINOME MICHINORI; OMURA TOSHIMICHI; MIYAKE YOSHIHIRO; MURAKAMI MASAHIRO

  日本化学会講演予稿集, 03 Mar. 2003

  
• ビスメタル化を利用した新規アリルシラン反応剤の精密合成：コンビナトリアルケミストリーとの接点

  有機合成化学協会誌, 2002

  
• o-ジイソシアノベンゼンのリビング重合：らせん状キノキサリンポリマーの機能開拓に向けて

  杉野目 道紀

  有機合成化学協会誌, 2001

  
• Catalytic Activation of Si-Si σ-Bonds Leading to New Synthetic Reactions

  SUGINOME Michinori

  Chemistry and Chemical Industry, 1998

  
• Si-Si結合の触媒的活性化-新しい選択的合成反応への展開-

  化学と工業, 1998

  
• Stereoselective synthesis via palladium-catalyzed intramolecular bis-silylation

  M Suginome; Y Ito

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Nov. 1997

  
• Intramolecular bis-silylation catalyzed by palladium-isocyanide

  Masahiro Murakami; Michinori Suginome; Yoshihiko Ito

  Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 1995

  

Presentations

• Asymmetric Amplification Enabled by Dynamic Helical Macromolecular Catalysts

  SUGINOME Michinori

  2nd JGP Chem & ChemEn International Workshop: Sustainable-oriented Organic Synthesis, Kyoto, Japan, 10 Sep. 2019, Invited

  
• Macromolecular Chiral Catalyst for Transfer, Switch, and Amplification of Chirality in Asymmetric Catalysis

  SUGINOME Michinori

  IUPAC OMCOS-20, Heidelberg, Germany, 24 Jul. 2019, Invited

  
• Asymmetric Catalysis with Chirality-Amplifiable Dynamic Helical Macromolecular Catalysts

  SUGINOME Michinori

  Chirality 2019, Bordeaux, France, 15 Jul. 2019, Invited

  
• Catalytic Asymmetric Reactions in Chiral Solvents

  SUGINOME Michinori

  Markovnikov Congress on Organic Chemistry, Kazan, Russia, 28 Jun. 2019, Invited

  
• Catalytic Chirality Transfer through Single-Handed, Helically Dynamic Macromolecules PQX

  SUGINOME Michinori

  2019 United States–Japan Polymer Symposium, Stanford, CA, USA, 19 Jun. 2019, Invited

  
• Modular Helical Macromolecules as Chirality-Switchable/Amplifiable Chiral Catalysts for Asymmetric Catalysis

  SUGINOME Michinori

  the 19th Bristol Synthesis Meeting, University of Bristol, Bristol, UK, 09 Apr. 2019, Invited

  
• Chirality-Switchable Functions of Helical Macromolecules PQX

  SUGINOME Michinori

  the 1st International Conference on Polymeric and Organic Materials, Yonezawa, Yamagata, 24 Jan. 2019, Invited

  
• Dynamic Helical Macromolecules for Catalytic Transfer, Amplification, and Up-conversion of Molecular Chirality in Asymmetric Synthesis

  SUGINOME Michinori

  Solvay Workshop on Chiral Symmetry Breaking at Molecular Level, Brussels, Belgium, 29 Nov. 2018, Invited

  
• Boryl-Directed Catalytic Borylation of Aromatic and Aliphatic C-H Bonds

  SUGINOME Michinori

  The 13th International Symposium on Organic Reactions (ISOR-13), Hsinchu, Taiwan, 23 Nov. 2018, Invited

  
• Chirality-Switchable Macromolecular Catalysts for Asymmetric Synthesis

  SUGINOME Michinori

  pre-ISOR (International Symposium on Organic Reactions), Taipei, Taiwan, 21 Nov. 2018, Invited

  
• Asymmetric Catalysis in Chiral Solvent

  SUGINOME Michinori

  10th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis, Hsinchu, Taiwan, 27 Sep. 2018, Invited

  
• Catalytic Chirality Transfer through Single-Handed Helical Macromolecules

  SUGINOME Michinori

  Gordon Research Conference (Stereochemistry), Salve Regina University, Newport, RI, USA, 22 Jul. 2018, Invited

  
• Chirality-Switchable Macromolecular Catalysts for Asymmetric Synthesis

  SUGINOME Michinori

  Molecular Chirality Asia, Harbin, China, 04 Jul. 2018, Invited

  
• Directed Catalytic C-H Activation Using Boronyl-Based Directing Groups

  SUGINOME Michinori

  Boron in the Americas (BORAM-XVI), Boston, MA, USA, 26 Jun. 2018, Invited

  
• Selective Organic Synthesis via Transition-Metal Catalysis of Organoboronic Acid Derivatives

  SUGINOME Michinori

  Mini-symposium on Organic Chemistry, Taipei, Taiwan, 21 Jun. 2018, Invited

  
• New Facets of Asymmetric Catalysis with Helical Macromolecular Catalysts Featuring Dynamic Chirality

  SUGINOME Michinori

  ACS National Meeting & Exposition (Herbert C. Brown Award for Creative Research in Synthetic Methods: Symposium in Honor of Gregory C. Fu), New Orleans, Louisiana, USA, 18 Mar. 2018, Invited

  
• Chirality Transfer through Dynamic Helical Macromolecules

  SUGINOME Michinori

  CEMS International Symposium on Supramolecular Chemistry and Functional Materials 2018 (CEMSupra2018), Tokyo, 09 Jan. 2018, Invited

  
• Asymmetric Catalysis with Chirality-Switchable Helical Macromolecules

  SUGINOME Michinori

  Toyota Riken International Workshop on Chirality in Soft Matter, Nagoya, 24 Nov. 2017, Invited

  
• Selective Organic Synthesis via Transition-metal-catalyzed C-H Activation

  SUGINOME Michinori

  Singapore Japan Germany Trilateral Symposium on Precision Synthesis and Catalysis, Singapore, 20 Nov. 2017, Invited

  
• Asymmetric Catalysis with Switch, Amplification, and Transfer of Chirality Using Helical Macromolecular Catalysts

  SUGINOME Michinori

  GDR Chirafun—Chirality, Chemistry and Supuramolecular Catalysis, Strasbourg, France, 02 Oct. 2017, Invited

  
• Switch, Amplification, and Transfer of Chirality in Asymmetric Catalysis Using Helical Macromolecular Catalysts

  SUGINOME Michinori

  1st International Symposium on Catalysis for Sustainable Chemical Synthesis (Joint Symposium of FRIAS/Nagoya IAR), Freiburg, Germany, 25 Sep. 2017, Invited

  
• Directed C-H Functionalization of Organoboronic Acids Using Temporary Modifiers Attached onto the Boron Atom

  SUGINOME Michinori

  16th International Meeting on Boron Chemistry (IMEBORON XVI), Hong Kong, 09 Jul. 2017, Invited

  
• Boryl-Directed Catalytic C-H Functionalizations Using Pirazolylaniline as a Temporary Modifier on the Boron Atom

  SUGINOME Michinori

  Kyoto University International Symposium – Nordic/Kyoto OMCOS 2017, Kyoto, 23 Jun. 2017

  
• Triarylphosphines Attached to Chirality-Switchable Helical Macromolecules as Chiral Ligands in Asymmetric Catalysis

  SUGINOME Michinori

  The 12th International Conference on Heteroatom Chemistry (ICHAC-12), Vancouver, British Columbia, Canada, 11 Jun. 2017, Invited

  
• Chiral Macromolecular Catalysts Enabling Switch, Transfer, and Amplification of Chirality

  SUGINOME Michinori

  3rd International Conference on Molecular & Functional Catalysis (ICMFC2017), Singapore, 27 Feb. 2017, Invited

  
• Polymer-Based, Dynamic Chiral Catalysts for Asymmetric Synthesis

  SUGINOME Michinori

  2016 LMRF Symposium on Frontiers in Asymmetric Catalysis, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China, 18 Sep. 2016, Invited

  
• Polymer-Based, Dynamic Chiral Catalysts for Asymmetric Synthesis

  SUGINOME Michinori

  The 3rd International Conference on Organometallics and Catalysis (OM&Cat 2016), Seoul, Korea, 28 Aug. 2016, Invited

  
• Chirality-Switchable Macromolecular Platform for New Chiral Functions"

  SUGINOME Michinori

  Telluride Conference, Molecular Motors, Rotors, and Switches, Telluride, Colorado, USA, 17 Jul. 2016, Invited

  
• Poly(quinoxaline-2,3-diyl): A Single-Handed Helical Polymer Platform for Creating New Chiral Functions

  SUGINOME Michinori

  2016 Japan-USA Seminar on Polymer Synthesis–Polymer Synthesis for a Sustainable Future–, Niseko, Japan, 23 Jun. 2016

  
• Chirality-Switchable Catalysts in Asymmetric Synthesis

  SUGINOME Michinori

  51st EUCHEM Conference on Stereochemistry (Bürgenstock Conference), 01 May 2016, Invited

  
• Asymmetric Catalysis with Single-Handed Helical Polymer PQX

  SUGINOME Michinori

  The 12th International Symposium on Organic Reactions (ISOR-12), Kyoto, 22 Apr. 2016, Invited

  
• Asymmetric Synthesis with Chirality-Switchable Helical Macromolecular Catalysts

  SUGINOME Michinori

  NYUAD International Chemistry Conference on Organic and Bioorganic Chemistry, NYU Abu-Dhabi Saadiyat Campus, Abu-Dhabi, UAE, 16 Feb. 2016, Invited

  
• Helical-Polymer-Based, Modular, Chirality-Switchable Chiral Catalysts for Highly Enantioselective Asymmetric Reactions

  SUGINOME Michinori

  Pacifichem 2015, Symposium on Asymmetric Supramolecular Catalysis, Biology, and Materials, Honolulu, Hawaii, USA, 15 Dec. 2015, Invited

  
• Masked Boronyl Groups as a Convertible Directing Group

  SUGINOME Michinori

  Pacifichem 2015, Symposium on Organoboron Chemistry-Applications in Organic Synthesis, Biology, and Materials, Honolulu, Hawaii, USA, 15 Dec. 2015

  
• New Functions of Single-Handed, Chirality-Switchable Helical Macromolecules PQX

  SUGINOME Michinori

  KIPS International Symposium, the Third Akron-Beijing-Kyoto Trilateral Symposium on Polymer Science and Technology, Kyoto, Japan, 27 Oct. 2015, Invited

  
• Design, Synthesis, and New Functions of Chirality-Switchable Helical Macromolecules

  SUGINOME Michinori

  Kickoff Meeting of LIA CNPA, IECB, University of Bordeaux, France, 02 Oct. 2015, Invited

  
• Helical Macromolecular Catalysts for Next-Generation Catalytic Asymmetric Synthesis

  SUGINOME Michinori

  the 3rd International Symposium on Process Chemistry (ISPC 2015), Kyoto, Japan,, 13 Jul. 2015, Invited

  
• Interplay of Silicon and Boron in Catalysis

  SUGINOME Michinori

  the 46th Silicon Symposium at UC Davis, Davis, CA, USA, 21 Jun. 2015, Invited

  
• New Functions of Chirality-Switchable Helical Macromolecules

  SUGINOME Michinori

  Symposium on Foldamers 2015, Bordeaux, France, 26 Jan. 2015, Invited

  
• New Functions of Chirality-switchable, Single-handed Macromolecules

  SUGINOME Michinori

  Germany-Japan Bilateral Meeting on Organic Synthesis and Materials, Berlin, Germany, 10 Sep. 2014, Invited

  
• Interplay of Silicon and Boron in Transition Metal Catalysis

  SUGINOME Michinori

  XXV Congresso Della Societa' Chimica Italiana, Rende, Italy, 08 Sep. 2014, Invited

  
• Interplay of Silicon and Boron in Transition Metal Catalysis

  SUGINOME Michinori

  The 17th International Symposium on Silicon Chemistry (ISOS XVII 2014), Berlin, Germany, 03 Aug. 2014, Invited

  
• New Functions of Chirality-Switchable Helical Macromolecules

  SUGINOME Michinori

  International Symposium on Chiral Discrimination (Chirality 2014), Prague, Czech Republic, 27 Jul. 2014, Invited

  
• Synthesis and Functions of Screw-Sense-Switchable Helical Polyquinoxalines

  SUGINOME Michinori

  IUPAC MACRO 2014, Chiang Mai, Thailand, 06 Jun. 2014, Invited

  
• New Functions of Chirality-Switchable Helical Macromolecules

  SUGINOME Michinori

  IGER International Symposium on Chemical Science in Asia, Nagoya University, 26 May 2014, Invited

  
• Interplay of Silicon and Boron in Transition Metal Catalysis

  SUGINOME Michinori

  International Symposium on Catalysis and Fine Chemicals 2013 (C&FC 2013), Renmin University, Beijing, China, 01 Dec. 2013, Invited

  
• Helical-Polymer-Based Thin Film for Selective Reflection of Visible Light: Reversible Full Color Tuning with Switch of CPL Handedness

  SUGINOME Michinori

  post-ISOR symposium 2013, Taipei, Taiwan, 23 Nov. 2013, Invited

  
• Interplay of Silicon and Boron in Transition Metal Catalysis

  SUGINOME Michinori

  the 11th International Conference on Organic Reactions (ISOR11), Taipei, Taiwan, 19 Nov. 2013, Invited

  
• Chirality-Switchable catalysts in Asymmetric Synthesis

  SUGINOME Michinori

  23rd Conference on Opticall Active Compounds (Yamada-Koga Prize Award Ceremony), Tokyo,, 01 Nov. 2013, Invited

  
• New Functions of Chirality-Switchable, Single-Handed Helical Macromolecules

  SUGINOME Michinori

  14th Tetrahedron Symposium Asia Edition, Seoul, Korea, 22 Oct. 2013, Invited

  
• Interplay of Silicon and Boron in Transition Metal Catalysis

  SUGINOME Michinori

  the 16th Korea-Japan Seminar on Organic Chemistry, Sendai, 28 Sep. 2013, Invited

  
• Chirality-Switchable Polymer-Based Ligands for Asymmetric Catalysis"

  SUGINOME Michinori

  the 2nd international Conference on the Frontier research in Organic Synthesis and Materials, Hsinchu, Taiwan, 21 Sep. 2013, Invited

  
• Macromolecular and Supramolecualr Functions of Chirality-Switchable, Single-Handed Polymers

  SUGINOME Michinori

  the 14th Tetrahedron Conference, Vienna, Austria, 25 Jun. 2013, Invited

  
• Catalytic Asymmetric Synthesis Using Chirality-Switchable, Single-Handed Helical Polymer Catalysts

  SUGINOME Michinori

  Inaugural KAUST-Symposium on Functional Molecules and Materials (1st KFMM), Thuwal, Saudi Arabia, 17 Dec. 2012, Invited

  
• Catalytic Asymmetric Synthesis with Chirality-Switchable Ligands

  SUGINOME Michinori

  8th RIKEN International Symposium on Frontiers in Organometallic Chemistry, 30 Nov. 2012, Invited

  
• Catalytic Asymmetric Synthesis on the Basis of Single-Handed, Chirality-Switchable Polymer Scaffold

  SUGINOME Michinori

  7th International Forum on Chemistry of Functionalized Organic Chemicals (IFOC-7), 18 Nov. 2012, Invited

  
• Single-Handed Helical Polymer as a New Scaffold for Chiral Ligands in Catalytic Asymmetric Reactions

  SUGINOME Michinori

  Cambodian Malaysian Chemical Conference, 19 Oct. 2012, Invited

  
• Helical-Polymer-Based Chiral Phosphine PQXphos as Highly Enantioselective, Chirality-Switchable Ligands for Asymmetric Catalysis

  SUGINOME Michinori

  International Conference "Catalysis in Organic Synthesis" (ICCOS-2012), 15 Sep. 2012, Invited

  
• Chirality-Switchable Ligand for Catalytic Asymmetric Synthesis”

  SUGINOME Michinori

  6th Takeda Science Foundation Symposium on PharmaSciences, 13 Sep. 2012, Invited

  
• Selective Organic Synthesis via Boron-Based Transition Metal Catalysis

  SUGINOME Michinori

  Celebration of International Chemistry, 244th ACS National Meeting and Exposition, 19 Aug. 2012, Invited

  
• Chirality-Switchable Ligand for Asymmetric Synthesis

  SUGINOME Michinori

  7th Asian European Symposium on Metal-Mediated Efficient Organic Synthesis, 22 Jul. 2012, Invited

  
• Two Enantiomers from a Single Enantiomer

  SUGINOME Michinori

  6th Spanish Portuguese, Japanese Organic Chemistry Symposium, 17 Jul. 2012, Invited

  
• Helical-Polymer-Based Chiral Catalyst for Asymmetric Catalysis

  SUGINOME Michinori

  International Conference on Functional Materials and Related Devices, 15 Jun. 2012, Invited

  
• Chirality-Switchable Polymer-Based Ligands for Catalytic Asymmetric Synthesis

  SUGINOME Michinori

  International Green Catalysis Symposium_Advanced Spring School on Green Catalysis, 07 Mar. 2012, Invited

  
• Asymmetric Catalysis Using Chiral Polymer Ligand Featuring Switch of Helical Chirality

  SUGINOME Michinori

  the 6th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-6), 11 Dec. 2011, Invited

  
• Chirality-Switchable Polymer_Based Chiral Ligand in Asymmetric Catalysis

  SUGINOME Michinori

  International Symposium on Catalysis and Fine Chemicals 2011 (C&FC 2011), 04 Dec. 2011, Invited

  
• Inversion or Retention? Highly Stereospecific Suzuki_Miyaura Coupling of Chiral a-(Acylamino)benzylboronic Esters

  SUGINOME Michinori

  the 10th International Conference on Organic Reactions (ISOR10), 21 Nov. 2011, Invited

  
• Helically Chiral Polyquinoxalines as Chirality-Switchable Ligand in Asymmetric Catalysis"

  SUGINOME Michinori

  the 15th Korea-Japan Organic Chemistry Symposium, 30 Sep. 2011, Invited

  
• Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand

  SUGINOME Michinori

  16th Symposium on Organometallic Chemistry Directed Toward Organic Synthesis (IUPAC OMCOS-16), 24 Jul. 2011, Invited

  
• New Accesses to Functionalized Organoboronic Acids Using Protecting and Directing Groups on the Boron Atom

  SUGINOME Michinori

  Pacifichem 2010, 15 Dec. 2010, Invited

  
• From Iterative Synthesis to Application to Chiral Ligand: New Aspects of the Chemistry of Polyarenes

  SUGINOME Michinori

  the 18th International Conference on Organic Synthesis (IUPAC ICOS-18), 01 Aug. 2010, Invited

  

Books and Other Publications

• 有機合成のための新触媒反応101

  有機合成化学協会; 檜山,野崎,中尾,中野編, Contributor

  東京化学同人, Nov. 2021

  Find Kyoto University's collection of books :

  
• C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds

  杉野目 道紀

  In Comprehensive Organometallic Chemistry III; Crabtree, R. and Mingos, M. Eds.; Ojima, I. Vol. Ed.; Elsevier,Volume 10, pp 725-787, 2007, Not refereed

  
• 有機合成のための触媒反応１０３（共著） 檜山・野崎編

  杉野目 道紀

  東京化学同人,, 2004, Not refereed

  
• Isocyanides and Related Compounds In Science of Synthesis Vol. 19

  杉野目 道紀

  Thieme,19, pp.445, 2004, Not refereed

  
• Palladium-catalyzed or -promoted oxidation via 1,2- or 1,4-elimination: oxidation of silyl enol ethers and related enol derivatives to α_β-unsaturated enones and other carbonyl compounds In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed.

  杉野目 道紀

  Wiley,pp. 2873, 2002, Not refereed

  
• Bis-Silylation and Silaboration: Efficient Accesses to New Organosilicon Reagents for Organic Synthesis 有機合成 創造の軌跡 126のマイルストーン

  杉野目 道紀

  化学同人,pp.194, 2002, Not refereed

  
• Synthesis of oligomeric and polymeric materials via palladium-catalyzed successive migratory insertion of isonitriles In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed. E. Negishi

  杉野目 道紀

  Wiley,pp. 2705, 2002, Not refereed

  
• Activation of Si-Si Bonds by Transition-Metal Complexes. Topics in Organometallic Chemistry

  杉野目 道紀

  Springer,/,132, 1999, Not refereed

  
• New Organic Synthesis Based upon Palladium-Catalyzed Activation of Silicon-Siliconγ-Bonds. (Transition-Metal Catalyzed Reactions)

  杉野目 道紀

  Blackwell Science,/,419, 1999, Not refereed

  

Awards

• 1999

  the Chemical Society of Japan, the Chemical Society of Japan Award for Young Chemists
• 2001

  the Society of Silicon Chemistry, the Society of Silicon Chemistry Award for Young Chemists
• 2005

  Banyu Life Science Foundation International, Nagoya Silver Medal
• 2005

  the Society of Synthetic Organic Chemistry, Mukaiyama Award
• 2010

  JSPS, JSPS Prize
• 2013

  the Chemical Society of Japan, the Chemical Society of Japan Award for Creative Work
• 2015

  Humboldt Foundation (Germany), the Humboldt Research Award
• 2020

  Molecular Chirality Research Organization, Molecular Chirality Award
• 2021

  American Chemical Society, Arthur C. Cope Scholar Award
• 2021

  the Society of Polymer Chemistry, Japan, The Award of the Society of Polymer Science, Japan

External funds: Kakenhi

• Dynamic Chiral Macromolecular Catalyst for Asymmetric Amplification

  Grant-in-Aid for Scientific Research (S)

  Broad Section E

  Kyoto University

  杉野目 道紀

  From 31 Aug. 2020, To 31 Mar. 2025, Granted

  触媒的不斉合成;不斉増幅;高分子触媒;動的キラリティ;らせん高分子;キラルシフト試薬;動的不斉転写;不斉合成;触媒設計;有機金属化学;機能性高分子;キラル高分子

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20H05674/
• Catalytic Asymmetric Synthesis Utilizing Chiral Non-Bonding Interaction and Dynamic Covalent Bond as a Source of Chirality

  Grant-in-Aid for Scientific Research (A)

  Medium-sized Section 33:Organic chemistry and related fields

  Kyoto University

  杉野目 道紀

  From 01 Apr. 2020, To 31 Mar. 2021, Discontinued

  不斉合成;キラルポリマー;らせん高分子;不斉増幅;動的キラリティ;高分子触媒;動的らせん高分子;動的キラル触媒

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20H00377/
• Design and Creation of New Chiral Reaction Environment Utilizing Helical Macromolecular Architectures

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  Michinori Suginome

  From 29 Jun. 2015, To 31 Mar. 2020, Project Closed

  不斉合成;高分子触媒;不斉増幅;キラル溶媒;らせん高分子;動的キラリティ;キラル触媒;キラリティスイッチング;キラル高分子;有機触媒;遷移金属触媒;不斉触媒反応;不斉クロスカップリング;キラル配位子;リモネン;不斉転写;不斉求核触媒;速度論的光学分割;アミノピリジン;小角中性子散乱;高分子合成;高分子機能;ビピリジン;転位反応;シクロプロパン化;重合後修飾;合成化学;触媒化学

  https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-15H05811/
• キラル小分子との1:1相互作用に基づいた高分子らせん不斉の高度可逆的スイッチング

  Grant-in-Aid for Challenging Exploratory Research

  Kyoto University

  杉野目 道紀

  From 01 Apr. 2008, To 31 Mar. 2010, Project Closed

  らせんポリマー;構造制御;動的らせん;キノキサリン;キラル側鎖;ボロン酸;不斉誘起

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20655024/
• Boron-Masking Strategy for New Transformations of Organoboronic Acids

  Grant-in-Aid for Scientific Research (A)

  Kyoto University

  Michinori SUGINOME

  From 01 Apr. 2007, To 31 Mar. 2011, Project Closed

  合成有機化学;有機ボロン酸;クロスカップリング;反復合成;保護基;マスキング;アントラニルアミド;オルト位C-H結合活性化;配向基;有機合成化学;1,8-ジアミノナフタレン;ジボリル化;脱水素ホウ素化;分枝オリゴアレーン;C-H官能基化;クロスカップリソグ;繰り返し合成;デンドリマー;オリゴ(フェニレン-ビニレン)

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19205007/
• 有機ホウ素化合物の特異的活性化作用に基づいた触媒的アミノ化炭素-炭素結合形成反応

  Grant-in-Aid for Exploratory Research

  Kyoto University

  杉野目 道紀

  From 01 Apr. 2005, To 31 Mar. 2006, Project Closed

  アミノ化;還元;水素化ホウ素ナトリウム;アルデヒド;アミノボラン;ホウ素化合物;イミニウムイオン

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17655040/
• Chiral Helical Polymer Ligands for Catalytic Asymmetric Synthsis with High Degree of Chiral Amplification

  Grant-in-Aid for Scientific Research (B)

  Kyoto University

  Michinori SUGINOME

  From 01 Apr. 2005, To 31 Mar. 2007, Project Closed

  キラル高分子;分子触媒;触媒的不斉合成;不斉重合;ヒドロシリル化;らせんポリマー;パラジウム触媒;キラル配位子;不斉合成;リビング重合;らせん高分子;高分子配位子;光学活性ポリマー;スチレン;ケイ素化合物, Chiral Polymer;Molecular Catalyst;Catalytic Asymmetric Synthesis;Asymmetric Polymerization;Hydrosilylation;Helical Polymer;Palladium Catalyst;Chiral Ligand

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17350048/
• Development of New Molecular Transformations Based on Transition-Metal Catalyzed Cyanoboration of Carbon-Carbon Multiple Bonds

  Grant-in-Aid for Scientific Research on Priority Areas

  Science and Engineering

  Kyoto University

  Michinori SUGINOME

  From 01 Apr. 2005, To 31 Mar. 2009, Project Closed

  有機合成化学;触媒的ホウ素化;シアノホウ素化;クロスカップリング;レトロアリル化;カルボホウ素化;パラジウム触媒;ニッケル触媒;立体相補的合成;シアノボラン;付加反応;アルキニルボラン;遷移金属触媒;ホウ素化合物;反応機構;α,β-不飽和ニトリル;クロロボラン;アルキニルホウ素化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17065012/
• Solid-Phase Synthesis of Chiral Silicon-Based Reagents and Their Application to Organic Synthesis

  Grant-in-Aid for Scientific Research (A)

  Kyoto University

  Michinori SUGINOME

  From 01 Apr. 2002, To 31 Mar. 2005, Project Closed

  光学活性アリルシラン;アルケニルボラン;触媒的不斉合成;不斉付加反応;不斉面選択的反応;ホウ素化合物;ケイ素化合物;パラジウム触媒;不斉合成;アリルシラン;ビスシリル化;環化, Optically Active Allylsilane;Alkenylborane;Catalytic Asymmetric Synthesis;Asymmetric Addition Reaction;Enantio-face Selective Reaction;Boron Compounds;Silicon Compounds;Palladium Catalyst

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-14205126/
• 不斉配位子のコンビナトリアル最適化を可能にする新しい光学活性オリゴマー骨格の開拓

  Grant-in-Aid for Exploratory Research

  Kyoto University

  杉野目 道紀

  From 01 Apr. 2001, To 31 Mar. 2002, Project Closed

  不斉合成;配位子;オリゴマー;ヒドロシリル化;らせん;パラジウム;不斉開始剤;らせんポリマー

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13875175/
• ヘリックス形成分子により電子移動を制御したレドックス系の開発

  Grant-in-Aid for Scientific Research on Priority Areas

  Science and Engineering

  Kyoto University

  木村 俊作

  From 01 Apr. 2001, To 31 Mar. 2004, Project Closed

  ヘリックスペプチド;長距離電子移動;自己組織化膜;ダイポールモーメント;ホッピング機構;フェロセン;ヘリックス;分子組織化;電子移動;レドックス;導電性

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13128204/
• Asymmetric Organic Synthesis Via New Enantioenriched Allylsilanes

  Grant-in-Aid for Scientific Research (C)

  KYOTO UNIVERSITY

  Michinori SUGINOME

  From 01 Apr. 1999, To 31 Mar. 2001, Project Closed

  不斉合成;アリルシラン;ビスシリル化;環化;立体選択性;ルイス酸;キラリティートランスファー;パラジウム触媒;シクロアルケン;光学活性アリルシラン;テトラヒドロフラン;オキセパン;アルデヒド;不斉転写, Asymmetric Synthesis;Allylsilane;Bis-silylation;Cyclization;Stereoselectivity;Lewis Acid;Chirality Transfer;Palladium Catalyst

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-11650873/
• ホウ素-ケイ素結合活性化を鍵とする触媒的炭素-炭素結合形成反応の開発

  Grant-in-Aid for Scientific Research on Priority Areas (A)

  Kyoto University

  杉野目 道紀

  From 01 Apr. 1999, To 31 Mar. 2000, Project Closed

  シリルボラン;遷移金属触媒;パラジウム;ニッケル;付加反応;シリルホウ素化;ジエン;アレン

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-11120225/
• 遷移金属触媒によるホウ素-ケイ素結合活性化を鍵とする新合成反応

  Grant-in-Aid for Scientific Research on Priority Areas (A)

  Kyoto University

  杉野目 道紀

  From 01 Apr. 1998, To 31 Mar. 1999, Project Closed

  シリルボラン;炭素-炭素結合形成;ニッケル;パラジウム;白金

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10133226/
• Synthesis of novel tetradentate ligands with helical chirality and their application to catalytic asymmetric reactions

  Grant-in-Aid for Scientific Research (C)

  KYOTO UNIVERSITY

  Tadashi MIZUTAMI

  From 01 Apr. 1997, To 31 Mar. 1999, Project Closed

  光学活性らせん状分子;重合;立体規則性;らせん方向選択性;ビナフチルパラジウム;ポリキノキサリン;ジイソシアノベンゼン;不斉重合;ホスフィン配位子;パラジウム, optically active helical molecule;polymerization;stereoselectivity;screw-sense selection;binaphthylpalladium;poly (quinoxaline);diisocyanobenzene

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-09650934/
• 高活性遷移金属シリル錯体触媒によるケイ素-ケイ素結合メタセシス重合反応

  Grant-in-Aid for Scientific Research on Priority Areas

  Kyoto University

  杉野目 道紀

  From 01 Apr. 1997, To 31 Mar. 1998, Project Closed

  パラジウム(IV);ジシラン;トリシラン;触媒;有機ケイ素ポリマー;開環重合

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-09239226/
• XIV属金属元素を主鎖に含む機能性大環状化合物の新規合成法の開発

  Grant-in-Aid for Scientific Research (C)

  Kyoto University

  杉野目 道紀

  From 01 Apr. 1996, To 31 Mar. 1997, Project Closed

  大環状化合物;有機ケイ素化合物;環拡大オリゴメリゼーション;パラジウム触媒;ジシロキサン;ビスシリルイミン;イソニトリル;ケイ素-ケイ素結合

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08651007/
• Asymmetric Synthesis of Usseful Natural Products by Means of Organosilicon Compounds

  Grant-in-Aid for Scientific Research (B)

  KYOTO UNIVERSITY

  Yoshihiko ITO

  From 01 Apr. 1995, To 31 Mar. 1997, Project Closed

  有機ケイ素化合物;オレフィンのビス-シリル化反応;パラジウム(0)イソニトリル錯体;炭素-ケイ素結合の酸化的変換;立体選択的分子内ビス-シリル化;(-)アヴェナシオリドの全合成;アベノシオリドの全合成;ビス・シリル化反応;オレフィンの分子内ビス・シリル化;パラジウム(o)イソシアニド錯体;パラジウム・第三級アルキルイソニトリル錯体, Bis-silylation of olefins;Palladium tert-alkyl isocyanide complex;Avenaciolide;Organosilicon Compounds;Oxidative Cleavage of Carbon-silicon Bonds;Intramolecular Bis-silylation

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07454164/
• 光学活性イソシアニド配位子を用いた新規不斉触媒反応の開発

  Grant-in-Aid for Encouragement of Young Scientists (A)

  Kyoto University

  杉野目 道紀

  From 01 Apr. 1994, To 31 Mar. 1995, Project Closed

  光学活性イソシアニド;ビスシリル化;不斉合成;ジシラン;パラジウム;触媒;トリオール

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-06855105/
• Preparation of Optically Active Helical Polymer Materials for Separation of Optically Active Compounds

  Grant-in-Aid for Developmental Scientific Research (B)

  KYOTO UNIVERSITY

  Yoshihiko ITO

  From 01 Apr. 1994, To 31 Mar. 1996, Project Closed

  螺旋状ポリ(キノキサリン);光学活性ポリ(キノキサリン);螺旋状ポリマー;1,2-ジイソシアノベンゼン;螺旋方向の制御;立体選択的重合;不斉重合;ポリ(キノキサリン);螺旋ポリ(キノキサリン);ポリキノキサリン;らせん構造;ジイソシアノベンゼン;パラジウム;リビング重合;光学活性ポリマー;光学活性クロマト・カラム, Helical Poly (quinoxaline) s;Optically Active Poly (quinoxaline) s;Helical Polymers;1,2-Diisocyanobenzene;Screw Sense Selective Polymerization;Stereoselective Polymerization;Asymmetric Polymerization

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-06555279/

External funds: others

• 自動合成の実現に向けた共役芳香族オリゴ マーの反復固相合成法の開発

  独立行政法人科学技術振興機構 研究成果活用プラザ京都 館長　松波弘之
• Design, Synthesis, and Reactions of Novel Functionalized Boron Compounds

  PRESTO　（さきがけ）

  From Dec. 2001, To Mar. 2005

  杉野目道紀
• キラルナノ分子ロッドによる機能の階層的不斉集積と組織化

  CREST (JST)

  From Oct. 2009, To Mar. 2015

  杉野目道紀
• キラリティのスイッチングと増幅を特徴とする次世代キラル触媒システムの創製

  CREST(JST)

  From Oct. 2014, To Mar. 2020

  杉野目道紀

Education

Teaching subject(s)

• From 01 Apr. 2024, To 31 Mar. 2025

  Introduction to Chemical Science and Technology

  7501, Spring, Faculty of Engineering, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Organic Chemistry II (Advanced Chemistry)

  7414, Spring, Faculty of Engineering, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Basic Organic Chemistry I

  N347, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Organotransition Metal Chemistry 1

  H041, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2023, To 31 Mar. 2024

  Organic Chemistry II (Advanced Chemistry)

  7414, Spring, Faculty of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Introduction to Industrial Chemistry

  7405, Spring, Faculty of Engineering, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Basic Organic Chemistry I

  N347, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Organic System Design

  H802, Spring, Graduate School of Engineering, 1.5
• From 01 Apr. 2022, To 31 Mar. 2023

  Basic Organic Chemistry I

  N347, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Organic Chemistry II (Advanced Chemistry)

  7414, Spring, Faculty of Engineering, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Introduction to Industrial Chemistry

  7405, Spring, Faculty of Engineering, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Organotransition Metal Chemistry 1

  H041, Spring, Graduate School of Engineering, 1.5
• From Apr. 2011, To Mar. 2012

  Basic Organic Chemistry A

  Spring, 全学共通科目
• From Apr. 2011, To Mar. 2012

  有機設計学

  Spring, 工学研究科
• From Apr. 2011, To Mar. 2012

  有機化学ＩＩ（工業基礎化学）［T15・T18］

  Spring, 工学部
• From Apr. 2011, To Mar. 2012

  有機化学ＩＩ（工業基礎化学）［T16・T17］

  Spring, 工学部
• From Apr. 2011, To Mar. 2012

  合成・生物化学特論第一

  Fall, 工学研究科
• From Apr. 2011, To Mar. 2012

  有機金属化学１

  Spring, 工学研究科
• From Apr. 2012, To Mar. 2013

  Basic Organic Chemistry A

  Spring, 全学共通科目
• From Apr. 2012, To Mar. 2013

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2012, To Mar. 2013

  Organotransition Metal Chemistry 1

  Spring, 工学研究科
• From Apr. 2013, To Mar. 2014

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2013, To Mar. 2014

  Organotransition Metal Chemistry 1

  Spring, 工学研究科
• From Apr. 2013, To Mar. 2014

  Organic System Design

  Spring, 工学研究科
• From Apr. 2013, To Mar. 2014

  Synthetic Chemistry and Biological Chemistry, Adv. I

  Fall, 工学研究科
• From Apr. 2013, To Mar. 2014

  Special Experiments and Exercises Synthetic Chemistry and Biological Chemistry

  Year-long, 工学研究科
• From Apr. 2013, To Mar. 2014

  Master's Thesis

  Year-long, 工学研究科
• From Apr. 2013, To Mar. 2014

  Special Seminar 1 in Synthetic Chemistry and Biological Chemistry

  Spring, 工学研究科
• From Apr. 2013, To Mar. 2014

  Special Seminar 2 in Synthetic Chemistry and Biological Chemistry

  Fall, 工学研究科
• From Apr. 2013, To Mar. 2014

  Special Seminar 3 in Synthetic Chemistry and Biological Chemistry

  Fall, 工学研究科
• From Apr. 2013, To Mar. 2014

  Basic Organic Chemistry A

  Spring, 全学共通科目
• From Apr. 2014, To Mar. 2015

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2014, To Mar. 2015

  Organotransition Metal Chemistry 1

  Spring, 工学研究科
• From Apr. 2014, To Mar. 2015

  Science and Technology for Making Substances

  Spring, 工学研究科
• From Apr. 2014, To Mar. 2015

  Basic Organic Chemistry A

  Spring, 全学共通科目
• From Apr. 2015, To Mar. 2016

  Basic Organic Chemistry I

  Spring, 全学共通科目
• From Apr. 2015, To Mar. 2016

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2015, To Mar. 2016

  Organic System Design

  Spring, 工学研究科
• From Apr. 2016, To Mar. 2017

  Basic Organic Chemistry I

  Spring, 全学共通科目
• From Apr. 2016, To Mar. 2017

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2016, To Mar. 2017

  Organotransition Metal Chemistry 1

  Spring, 工学研究科
• From Apr. 2017, To Mar. 2018

  Basic Organic Chemistry I

  Spring, 全学共通科目
• From Apr. 2017, To Mar. 2018

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2017, To Mar. 2018

  Organic System Design

  Spring, 工学研究科
• From Apr. 2018, To Mar. 2019

  Basic Organic Chemistry I

  Spring, 全学共通科目
• From Apr. 2018, To Mar. 2019

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2019, To Mar. 2020

  Basic Organic Chemistry I

  Spring, 全学共通科目
• From Apr. 2019, To Mar. 2020

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2019, To Mar. 2020

  Organic System Design

  Spring, 工学研究科
• From Apr. 2020, To Mar. 2021

  Basic Organic Chemistry I

  Spring, 全学共通科目
• From Apr. 2020, To Mar. 2021

  Organic Chemistry II (Fundamental Chemistry)

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Basic Organic Chemistry I

  Spring, 全学共通科目
• From Apr. 2021, To Mar. 2022

  Introduction to Industrial Chemistry

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Introduction to Industrial Chemistry

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Introduction to Industrial Chemistry

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Introduction to Industrial Chemistry

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Organic Chemistry II (Advanced Chemistry)

  Spring, 工学部
• From Apr. 2021, To Mar. 2022

  Organic System Design

  Spring, 工学研究科

Participation in PhD Defense

• Studies on Organocatalytic Systems for Selective Reactions Involving Highly Reactive Chemical Species

  MURATA RYUICHI, Graduate School of Engineering, Sub-chief Examiner

  25 Mar. 2024
• Development of Radical-Mediated Synthetic Methods via Single-Electron Transfer by Transition Metal Catalysts

  OKU NAOKI, Graduate School of Engineering, Chief Examiner

  25 Mar. 2024
• Alkenyl Boronates as Vinyl Monomers of Radical Polymerization:Polymer Synthesis and Functions Driven by Chemical Properties of Boron

  MAKINO HIROSHI, Graduate School of Engineering, Sub-chief Examiner

  25 Mar. 2024
• Substituent-Dependent Optical Responses of Pillar[n]arenes

  WADA KEISUKE, Graduate School of Engineering, Sub-chief Examiner

  25 Mar. 2024
• Water-Soluble Helical Polymers as Chiral Catalysts in Asymmetric Reactions in Water

  KAMIYA NAOAKI, Graduate School of Engineering, Chief Examiner

  23 May 2023
• Studies on Functionalization of Carbon-Fluorine Bonds Catalyzed by Aluminum-Rhodium Complexes

  FUJII IKUYA, Graduate School of Engineering, Sub-chief Examiner

  23 Mar. 2023
• New Synthetic Approaches to Heterocyclic Compounds Based on Iridium-Catalyzed Transformations of C(sp3)-H Bonds

  YAGI KAITO, Graduate School of Engineering, Chief Examiner

  23 Mar. 2023
• Kinetic and Thermodynamic Effects of Nonbonding Interaction of Small Molecules on Dynamically Helical Poly(quinoxaline-2,3-diyI) s

  FUJIE TAKAYA, Graduate School of Engineering, Chief Examiner

  23 Mar. 2023
• Studies on Organocatalysis of Carbon-Carbon Double Bonds

  NAGANO TAGUI, Graduate School of Engineering, Sub-chief Examiner

  23 Mar. 2023
• Development of Iridium-Catalyzed Skeletal Transformations of Aryl Ethers through Carbon-Carbon Bond Formation

  KUSAKA SATOSHI, Graduate School of Engineering, Chief Examiner

  25 Jul. 2022
• Rapid Electrochemical Synthesis via Cationic Intermediates in Flow

  TAKUMI MASAHIRO, Graduate School of Engineering, Chief Examiner

  23 Mar. 2023
• Studies on Reactions Promoted by Photo-generated Bromine Radical

  KAWASAKI TAIRIN, Graduate School of Engineering, Sub-chief Examiner

  23 Mar. 2022
• Studies on Catalytic Denitrative Transformations of Organic Nitro Compounds

  KASHIHARA MYUTO, Graduate School of Engineering, Sub-chief Examiner

  23 Mar. 2022
• Studies on π-extended helicenes

  NAKAKUKI YUSUKE, Graduate School of Engineering, Sub-chief Examiner

  23 Mar. 2022
• Organocatalytic Diboration and Silaboration Based on Pyridine-Mediated Activation of Boron-Containing σ-Bond

  MORIMASA YOHEI, Graduate School of Engineering, Chief Examiner

  26 Jul. 2021
• The discovery of orally effective thyrotropin-releasing hormone (TRH) mimetic：Rovatirelin Hydrate

  KOBAYASHI NAOTAKE, Graduate School of Engineering, Sub-chief Examiner

  23 Mar. 2022

Part-time lecturer

• From 01 Oct. 2018, To 31 Oct. 2018

  国立大学法人東北大学, 大学院理学研究科
• From 01 Sep. 2018, To 31 Mar. 2019

  東京大学, 大学院工学系研究科
• From 01 Apr. 2018, To 31 Mar. 2019

  国立大学法人長岡技術科学大学
• From 08 Apr. 2020, To 03 Jun. 2020

  名古屋市立大学

Administration

School management (title, position)

• From 01 Oct. 2022, To 30 Sep. 2024

  副学長
• From 01 Apr. 2024, To 31 Mar. 2025

  大学院教育支援機構 大学院共通・横断教育企画評価専門委員会 研究科横断教育特別部会
• From 01 Oct. 2022, To 31 Mar. 2023

  総合生存学館新体制移行準備委員会 委員
• From 01 Apr. 2023, To 31 Mar. 2024

  大学院教育支援機構 大学院共通・横断教育企画評価専門委員会 研究科横断教育特別部会 委員
• From 01 Apr. 2023

  教育制度委員会共同学位プログラム専門委員会 委員長
• From 01 Apr. 2023

  教育制度委員会 副委員長
• From 27 Dec. 2022, To 03 Feb. 2023

  国際卓越研究大学構想検討委員会　研究等体制強化計画検討タスクフォース　「学部教育の将来像」検討小委員会 委員長
• From 11 Oct. 2022, To 12 Sep. 2023

  国際卓越研究大学構想検討委員会　研究等体制強化計画検討タスクフォース 委員
• From 21 Feb. 2022, To 30 Jun. 2022

  戦略調整会議研究戦略・人材育成検討委員会 委員
• From 13 Jul. 2021, To 31 Mar. 2022

  総合生存学館教育研究体制等の在り方検討特別委員会 委員
• From 01 Apr. 2022, To 31 Mar. 2024

  学修・教育支援特別委員会 委員
• From 01 Apr. 2022, To 30 Sep. 2022

  大学院教育支援機構協議会 協議員
• From 01 Apr. 2013

  大学評価委員会 点検・評価実行委員会 委員
• From 01 Apr. 2011, To 31 Mar. 2015

  大学評価小委員会 委員
• From 01 Apr. 2013, To 31 Mar. 2015

  点検・評価実行委員会 委員
• From 01 May 2014, To 30 Sep. 2016

  教育制度委員会 委員
• From 01 Oct. 2014, To 30 Sep. 2016

  全学共用スペース有効活用専門委員会 5号委員
• From 01 Oct. 2014

  大学評価委員会点検・評価実行委員会 副委員長
• From 16 Oct. 2014, To 31 Mar. 2016

  京都大学博士課程教育リーディングプログラム運営委員会 委員
• From 16 Oct. 2014, To 31 Mar. 2016

  京都大学博士課程教育リーディングプログラム運営会議 委員
• From 16 Oct. 2014, To 30 Sep. 2016

  国際戦略委員会 委員
• From 16 Oct. 2014, To 31 Mar. 2015

  教育制度委員会WG３ 主査
• From 16 Oct. 2014

  博士課程教育リーディングプログラム運営委員会　インターンシップ企画ＷＧ 主査
• From 01 Nov. 2014

  大学評価委員会 副委員長
• From 04 Dec. 2014

  博士課程教育リーディングプログラム運営委員会　学位審査・規定等検討ＷＧ 主査
• From 01 Apr. 2015, To 31 Mar. 2016

  障害者入試委員会 委員
• From 01 Apr. 2015, To 31 Mar. 2016

  入学試験委員会 委員
• From 01 Apr. 2015, To 31 Mar. 2016

  教育制度委員会WG3 主査
• From 16 Oct. 2014, To 03 Jun. 2016

  国際戦略委員会 委員
• From 01 Apr. 2016, To 30 Sep. 2016

  国際教育委員会 委員
• From 01 Apr. 2016, To 30 Sep. 2016

  国際教育委員会企画・運営等専門委員会 委員長
• From 01 Apr. 2016, To 30 Sep. 2016

  入学試験委員会 委員
• From 01 Apr. 2016, To 31 Mar. 2017

  障害者入試委員会 委員
• From 01 Oct. 2014, To 30 Sep. 2016

  教育制度委員会 委員
• From 01 Apr. 2016, To 31 Mar. 2017

  教育制度委員会WG3 主査
• From 01 Apr. 2016, To 31 Mar. 2017

  スーパーグローバルコース実施運営協議会 委員
• From 01 Apr. 2016, To 31 Mar. 2017

  スーパーグローバルコース実施運営協議会企画運営幹事会 副議長
• From 16 Oct. 2014, To 15 Oct. 2016

  博士課程教育リーディングプログラム運営会議 委員
• From 16 Oct. 2014, To 15 Oct. 2016

  博士課程教育リーディングプログラム運営委員会 委員
• From 16 Oct. 2014, To 15 Oct. 2016

  博士課程教育リーディングプログラム学位審査・規定等検討ＷＧ 主査
• From 12 Jul. 2016, To 31 Mar. 2017

  指定国立大学法人制度検討ワーキンググループ 委員
• From 30 Sep. 2016, To 31 Mar. 2017

  指定国立大学法人制度検討タスクフォース 委員
• From 16 Oct. 2014, To 30 Sep. 2018

  理事補
• From 01 Dec. 2015, To 31 Mar. 2018

  スーパーグローバルコース実施運営協議会 委員
• From 01 Apr. 2016, To 31 Mar. 2018

  スーパーグローバルコース企画運営幹事会 委員
• From 01 Oct. 2016, To 30 Sep. 2018

  教育制度委員会 委員
• From 16 Oct. 2014, To 31 Mar. 2018

  博士課程教育リーディングプログラム運営会議 委員
• From 16 Oct. 2014, To 31 Mar. 2018

  博士課程教育リーディングプログラム運営委員会 副委員長
• From 13 Jan. 2015, To 31 Mar. 2018

  博士課程教育リーディングプログラム学位審査・規定等検討ＷＧ 主査
• From 01 Oct. 2016, To 30 Sep. 2018

  国際教育委員会 委員
• From 01 Apr. 2017, To 31 Mar. 2019

  国際教育委員会企画運営委員会 委員
• From 01 Apr. 2017, To 31 Mar. 2018

  入学試験委員会 委員
• From 01 Apr. 2017, To 31 Mar. 2018

  全学共用スペース有効活用専門委員会 5号委員
• From 01 Oct. 2014, To 30 Sep. 2018

  全学共用スペース有効活用専門委員会 5号委員
• From 01 Jun. 2017, To 31 Mar. 2019

  国際高等教育院 基盤企画評価専門委員会 研究科横断教育特別部会 委員
• From 01 Oct. 2016, To 30 Sep. 2018

  国際教育委員会企画運営委員会 委員
• From 01 Apr. 2018, To 0000

  教育IR推進室 室員
• From 01 Apr. 2016, To 31 Mar. 2019

  スーパーグローバルコース企画運営幹事会 副議長
• From 01 Dec. 2015, To 31 Mar. 2020

  スーパーグローバルコース実施運営協議会 委員
• From 01 Oct. 2016

  教育制度委員会 委員
• From 01 Apr. 2018, To 31 Mar. 2019

  入学試験委員会 委員
• From 16 Oct. 2014, To 30 Sep. 2020

  理事補
• From 01 Oct. 2018, To 30 Sep. 2020

  戦略調整会議 委員
• From 01 Oct. 2018, To 30 Sep. 2020

  戦略調整会議GSTセンター小委員会 委員長
• From 05 Jun. 2018, To 30 Sep. 2020

  戦略調整会議留学生リクルーティングオフィス小委員会 委員長
• From 01 Apr. 2019, To 31 Mar. 2020

  国際高等教育院 基盤企画評価専門委員会 研究科横断教育特別部会 委員
• From 15 May 2018, To 31 Mar. 2020

  大学院横断教育プログラム推進センター運営委員会 委員
• From 01 Oct. 2018, To 30 Sep. 2020

  国際教育委員会 委員
• From 01 Oct. 2018, To 30 Sep. 2020

  国際教育委員会企画運営委員会 委員
• From 01 Apr. 2019, To 31 Mar. 2020

  入学試験委員会 委員
• From 01 Oct. 2014, To 30 Sep. 2020

  全学共用スペース有効活用専門委員会 委員
• From 01 Apr. 2019, To 31 Mar. 2020

  2020年度特色入試実行委員会委員
• From 01 Apr. 2020, To 31 Mar. 2021

  国際高等教育院 基盤企画評価専門委員会 研究科横断教育特別部会 委員
• From 01 Apr. 2019, To 31 Mar. 2021

  教育制度委員会教育質保証専門委員会 委員長
• From 01 Apr. 2020, To 30 Sep. 2020

  スーパーグローバルコース企画運営幹事会 副議長
• From 01 Dec. 2015, To 30 Sep. 2020

  スーパーグローバルコース実施運営協議会 協議員
• From 15 May 2018, To 30 Sep. 2020

  大学院横断教育プログラム推進センター運営協議会 協議員
• From 01 Apr. 2020, To 30 Sep. 2020

  入学試験委員会 委員
• From 01 Apr. 2020, To 30 Sep. 2020

  戦略調整会議京都大学の将来像検討小委員会 委員
• From 01 Oct. 2020, To 30 Sep. 2022

  全学情報セキュリティ委員会 委員
• From 01 Apr. 2021, To 31 Mar. 2022

  国際高等教育院 基盤企画評価専門委員会 研究科横断教育特別部会 委員
• From 01 Oct. 2020, To 30 Sep. 2022

  副学長
• From 01 Apr. 2021, To 31 Mar. 2023

  桂インテックセンター センター長
• From 01 Apr. 2019, To 30 Sep. 2020

  教育制度委員会教育質保証専門委員会 委員長
• From 01 Oct. 2020

  大学院横断教育プログラム推進センター運営委員会 委員長
• From 01 Oct. 2020

  大学院横断教育プログラム推進センター運営委員会 議長
• From 01 Apr. 2021, To 31 Mar. 2023

  GST推進室 室員
• From 01 Feb. 2020, To 31 Mar. 2021

  GST推進室 室員
• From 01 Oct. 2020

  教育制度委員会 副委員長
• From 01 Apr. 2021, To 31 Mar. 2022

  図書館協議会 協議員
• From 01 Apr. 2021, To 31 Mar. 2022

  学修・教育支援特別委員会 委員
• From 01 Apr. 2021, To 31 Mar. 2023

  教育研究評議会 評議員
• From 01 Apr. 2021, To 31 Mar. 2023

  部局長会議
• From 01 Apr. 2021, To 31 Mar. 2023

  研究科長部会