Basic Information

Affiliated programs (koza)

• Graduate School of Engineering, 物質エネルギー化学専攻 物質変換科学講座, 助教

Academic Degree

• 修士（工学）(京都大学)
• 博士（工学）(京都大学)

Research History

• From Apr. 2017, To Present

  京都大学化学研究所, 助教
• From Apr. 2015, To Mar. 2017

  日本学術振興会特別研究員（DC1）
• From Feb. 2012, To Mar. 2013

  住友化学, 火災爆発体感研修 講師兼任（混合混触・反応暴走）
• From Apr. 2010, To Mar. 2013

  住化分析センター, 愛媛事業所 安全工学グループ

ID,URL

• ORCID ID

  0000-0001-7834-9593

• J-Global ID

  201701017196933787

researchmap URL

• https://researchmap.jp/7000019583

Research

Research Topics, Overview of the research

• Research Topics

  Creation of Novel Nanocarbon Materials

• Overview of the research

  Using structurally well-defined fullerenes and nanographenes (NGs) including graphene nanoribbons (GNRs), we design and synthesize novel nanocarbon materials with intriguing functions and properties. Also, we create highly π-conjugated nanocarbon systems such as OF-OF, OF-NG, and CNE-GNR hybrids constituting of our originally-designed molecules of fully-fused carbon nanoelbows (CNEs) and open-fullerenes (OFs).

Research Areas

• Social infrastructure (civil Engineering, architecture, disaster prevention), Safety engineering
• Life sciences, Pharmaceuticals - chemistry and drug development
• Nanotechnology/Materials, Structural/physical organic chemistry

Papers

• A Double Twisted Nanographene with a Contorted Pyrene Core

  Yanping Dong; Zhiyu Zhang; Yoshifumi Hashikawa; He Meng; Fenghua Bai; Kenichiro Itami; Chaolumen

  Angewandte Chemie International Edition, 21 Jun. 2024

  
• Solution Dynamics of Covalent Open‐[60]Fullerene Dimers

  Shu Okamoto; Yoshifumi Hashikawa; Yasujiro Murata

  ChemPlusChem, 18 May 2024

  
• Phosphine‐Mediated Dimerization of Open‐[60]Fullerenes

  Shu Okamoto; Yoshifumi Hashikawa; Yasujiro Murata

  Chemistry – An Asian Journal, 08 Apr. 2024

  
• Reactions of Diaminonaphthalenes with a Cage‐Opened C60 Derivative

  Guanglin Huang; Shumpei Sadai; Yoshifumi Hashikawa; Yasujiro Murata

  Asian Journal of Organic Chemistry, 02 Apr. 2024

  
• Water Adsorption on π-Surfaces of Open-Fullerenes

  Yoshifumi Hashikawa; Shumpei Sadai; Yuka Ikemoto; Yasujiro Murata

  The Journal of Physical Chemistry A, 02 Apr. 2024

  
• Direct Through‐Space Substituent‐π Interactions in Noncovalent Arene–Fullerene Assemblies

  Yoshifumi Hashikawa; Yasujiro Murata

  Chemistry – An Asian Journal, 07 Mar. 2024

  
• Molecular CO₂ Storage: State of a Single-Molecule Gas

  Yoshifumi Hashikawa; Shumpei Sadai; Yasujiro Murata

  ACS Physical Chemistry Au, 16 Jan. 2024

  
• Synthesis of inter-[60]fullerene conjugates with inherent chirality

  Yoshifumi Hashikawa; Shu Okamoto; Yasujiro Murata

  Nature Communications, 15 Jan. 2024

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• Cobalt-Functionalized Open-[60]Fullerenes

  Yoshifumi Hashikawa; Yasujiro Murata

  Organometallics, 04 Jan. 2024

  
• An open-cage bis[60]fulleroid as an electron transport material for tin halide perovskite solar cells

  Wentao Liu; Guanglin Huang; Chien-Yu Chen; Tiancheng Tan; Harata Fuyuki; Shuaifeng Hu; Tomoya Nakamura; MInh Anh Truong; Richard Murdey; Yoshifumi Hashikawa; Yasujiro Murata; Atsushi Wakamiya

  Chemical Communications, 2024

  
• Open-[60]fullerenols with water adsorbed both inside and outside

  Yoshifumi Hashikawa; Shumpei Sadai; Yuka Ikemoto; Yasujiro Murata

  Chemical Communications, 2024

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• Synthesis of an Open‐Cage C₆₀ Derivative with a Double Stopper

  Guanglin Huang; Yoshifumi Hashikawa; Yasujiro Murata

  ChemistrySelect, 15 Dec. 2023

  
• Water in Fullerenes

  Yoshifumi Hashikawa; Yasujiro Murata

  Bulletin of the Chemical Society of Japan, 15 Sep. 2023

  
• CH₃CN@open‐C₆₀: An Effective Inner‐Space Modification and Isotope Effect Inside a Nano‐Sized Flask

  Guanglin Huang; Yuki Ide; Yoshifumi Hashikawa; Takashi Hirose; Yasujiro Murata

  Chemistry – A European Journal, 13 Jul. 2023

  
• Construction of a 21-Membered-Ring Orifice on [60]Fullerene

  Hashikawa, Y.; Sadai, S.; Murata, Y.

  ChemPlusChem, 25 May 2023

  
• π-Extended Open-[70]Fullerenes with a Fused Azaacene

  Sadai, S.; Hashikawa, Y.; Murata, Y.

  Organic Letters, 28 Apr. 2023

  
• Synthesis of Hydrogen-Bonded Open-[60]Fullerenol Dimers

  Hashikawa, Y.; Sadai, S.; Murata, Y.

  ChemPlusChem, 14 Mar. 2023

  
• C2-insertion into a fullerene orifice

  Hashikawa, Y.; Murata, Y.

  Chemical Communications, 2023

  
• Bilateral π-extension of an open-[60]fullerene in a helical manner

  Hashikawa, Y.; Sadai, S.; Murata, Y.

  Chemical Communications, 2023

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• Open-[60]fullerene-aniline conjugates with near-infrared absorption

  Sadai, S.; Hashikawa, Y.; Murata, Y.

  RSC Advances, 2023

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• Synthesis of open-[70]fullerenes bearing huge orifices

  Hashikawa, Y.; Sadai, S.; Murata, Y.

  Chemical communications (Cambridge, England), 2023

  
• Near-Infrared-Absorbing Chiral Open [60]Fullerenes

  Hashikawa, Y.; Sadai, S.; Okamoto, S.; Murata, Y.

  Angewandte Chemie - International Edition, 09 Jan. 2023

  
• π-Extended Fullerenes with a Reactant Inside

  Hashikawa, Y.; Fujikawa, N.; Murata, Y.

  Journal of the American Chemical Society, 28 Dec. 2022

  
• Phosphorus ylides of cage-opened sulphide [60]fullerene derivatives

  Hashikawa, Y.; Fujikawa, N.; Okamoto, S.; Murata, Y.

  Dalton Transactions, 2022

  
• Utilization of sym-tetrazines as guanidine delivery cycloaddition reagents. An experimental and computational study

  Anamarija Briš; Yasujiro Murata; Yoshifumi Hashikawa; Davor Margetić

  Journal of Molecular Structure, Jan. 2023

  
• Chiral Open-[60]Fullerene Ligands with Giant Dissymmetry Factors

  Yoshifumi Hashikawa; Shu Okamoto; Shumpei Sadai; Yasujiro Murata

  Journal of the American Chemical Society, 28 Sep. 2022

  
• Selective Addition of Aniline to a Cage-opened Diketo Anhydride Derivative of C₆₀

  Yoshifumi Hashikawa; Shumpei Sadai; Jiayue Li; Shu Okamoto; Yasujiro Murata

  Chemistry Letters, 05 Sep. 2022

  
• Aniline‐Mediated Imination and Reduction of a Cage‐Opened C ₆₀ Derivative

  Yoshifumi Hashikawa; Yasujiro Murata

  Asian Journal of Organic Chemistry, Sep. 2022

  
• Consecutive Utilization of Mechanochemical and Microwave Methods for the Synthesis of Boc‐2‐amino‐quinazolin‐4(3 H )‐ones and DFT Study of Mechanism 6π‐Diazaelectrocyclization Process

  Ivana Antol; Zoran Glasovac; Yasujiro Murata; Yoshifumi Hashikawa; Davor Margetić

  ChemistrySelect, 05 Apr. 2022

  
• Cage‐Opened C ₆₀ Isomers with Different Reactivities

  Sheng Zhang; Yoshifumi Hashikawa; Yasujiro Murata

  Asian Journal of Organic Chemistry, Mar. 2022

  
• π-Backbonding on Group 9 Metal Complexes Bearing an η²-(H₂O@C₆₀) Ligand

  Yoshifumi Hashikawa; Hiroto Kawasaki; Yasujiro Murata

  Organometallics, 14 Feb. 2022

  
• An H ₂ O ₂ Molecule Stabilized inside Open‐Cage C ₆₀ Derivatives by a Hydroxy Stopper

  Guanglin Huang; Shota Hasegawa; Yoshifumi Hashikawa; Yuki Ide; Takashi Hirose; Yasujiro Murata

  Chemistry – A European Journal, 10 Jan. 2022

  
• Hydrogenation of cage-opened C₆₀ derivatives mediated by frustrated Lewis pairs

  Yoshifumi Hashikawa; Yasujiro Murata

  Organic & Biomolecular Chemistry, 2022

  
• Inelastic Electron Transport and Ortho–Para Fluctuation of Water Molecule in H₂O@C₆₀ Single Molecule Transistors

  Shaoqing Du; Yoshifumi Hashikawa; Haruka Ito; Katsushi Hashimoto; Yasujiro Murata; Yoshiro Hirayama; Kazuhiko Hirakawa

  Nano Letters, 22 Dec. 2021

  
• Amino-Functionalized Cage-Opened C₆₀ Derivatives

  Yoshifumi Hashikawa; Shumpei Sadai; Yasujiro Murata

  Organic Letters, 17 Dec. 2021

  
• Reductive Decarbonylation of a Cage-Opened C₆₀ Derivative

  Yoshifumi Hashikawa; Shumpei Sadai; Yasujiro Murata

  Organic Letters, 17 Dec. 2021

  
• Synthesis and Oligomerization of CpM(CO)₂

  Yoshifumi Hashikawa; Yasujiro Murata

  ACS Omega, 14 Dec. 2021

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• Water‐Mediated Thermal Rearrangement of a Cage‐Opened C 60 Derivative

  Yoshifumi Hashikawa; Yasujiro Murata

  ChemPlusChem, 11 Oct. 2021

  
• Cage-Expansion of Fullerenes

  Sheng Zhang; Yoshifumi Hashikawa; Yasujiro Murata

  Journal of the American Chemical Society, 18 Aug. 2021

  
• Photochemical Orifice Expansion of a Cage-Opened C60 Derivative

  Yoshifumi Hashikawa; Shota Hasegawa; Yasujiro Murata

  Organic Letters, 21 May 2021

  
• Reactions of C 60 with Pyridazine and Phthalazine

  Yoshifumi Hashikawa; Hui Li; Yasujiro Murata

  Chemistry – A European Journal, 12 May 2021

  
• Reactions on a 1,2‐Dicarbonyl Moiety of a Fullerene Skeleton

  Yoshifumi Hashikawa; Jiayue Li; Shu Okamoto; Yasujiro Murata

  Chemistry – A European Journal, 03 May 2021

  
• Nonclassical Abramov Products Formed on Orifices of Cage‐Opened C 60 Derivatives

  Yoshifumi Hashikawa; Shu Okamoto; Yasujiro Murata

  Chemistry – A European Journal, 12 Mar. 2021

  
• Pressure-induced annulative orifice closure of a cage-opened C60 derivative

  Yoshifumi Hashikawa; Kazuro Kizaki; Yasujiro Murata

  Chemical Communications, 2021

  
• Dynamics and magnetic properties of NO molecules encapsulated in open-cage fullerene derivatives evidenced by low temperature heat capacity

  Yoji Horii; Hal Suzuki; Yuji Miyazaki; Motohiro Nakano; Shota Hasegawa; Yoshifumi Hashikawa; Yasujiro Murata

  Physical Chemistry Chemical Physics, 2021

  
• Double-Holed Fullerenes

  Yoshifumi Hashikawa; Teppei Fushino; Yasujiro Murata

  Journal of the American Chemical Society, 09 Nov. 2020

  
• An orifice design: water insertion into C60

  Yoshifumi Hashikawa; Kazuro Kizaki; Takashi Hirose; Yasujiro Murata

  RSC Advances, Nov. 2020

  
• Precise Fixation of an NO molecule inside Carbon Nanopores: A Long-Range Electron-Nuclear Interaction.

  Yoshifumi Hashikawa; Shota Hasegawa; Yasujiro Murata

  Angewandte Chemie (International ed. in English), 16 Oct. 2020

  
• Cation recognition on a fullerene-based macrocycle

  Yoshifumi Hashikawa; Yasujiro Murata

  Chemical Science, Oct. 2020

  
• Synthesis of a Dihydroxylated Open-Cage [70]Fullerene by a Reductive Ring-Closure Reaction.

  Yoshifumi Hashikawa; Yuma Shimizu; Yasujiro Murata

  Organic letters, Oct. 2020

  
• EPR study of NO radicals encased in modified open C60 fullerenes

  Klaus-Peter Dinse; Tatsuhisa Kato; Shota Hasegawa; Yoshifumi Hashikawa; Yasujiro Murata; Robert Bittl

  Magnetic Resonance, 10 Sep. 2020

  
• Organophosphorus zwitterions engaged in a conjugated macrocycle on fullerene

  Yoshifumi Hashikawa; Shu Okamoto; Yasujiro Murata

  Communications Chemistry, Jul. 2020

  
• A Single H2O molecule inside hydrophobic carbon nanocavities: Effect of local electrostatic potential

  Yoshifumi Hashikawa; Yasujiro Murata

  Chemistry Letters, 2020, Peer-reviewed

  
• Propeller-shaped aluminum complexes with an azaperylene core in the ligands

  Masahiro Tsukao; Yoshifumi Hashikawa; Nana Toyama; Masahiro Muraoka; Michihisa Murata; Takahiro Sasamori; Atsushi Wakamiya; Yasujiro Murata

  Inorganics, 01 Sep. 2019, Peer-reviewed

  
• H2O/Olefinic-π Interaction inside a Carbon Nanocage.

  Yoshifumi Hashikawa; Yasujiro Murata

  Journal of the American Chemical Society, 14 Aug. 2019, Peer-reviewed

  
• Tuneable single-molecule electronic conductance of C60 by encapsulation.

  Shintaro Fujii; Haruna Cho; Yoshifumi Hashikawa; Tomoaki Nishino; Yasujiro Murata; Manabu Kiguchi

  Physical chemistry chemical physics : PCCP, 21 Jun. 2019, Peer-reviewed

  
• Rotational Motion and Nuclear Spin Interconversion of H2O Encapsulated in C60 Appearing in the Low-Temperature Heat Capacity.

  Hal Suzuki; Motohiro Nakano; Yoshifumi Hashikawa; Yasujiro Murata

  The journal of physical chemistry letters, 21 Mar. 2019, Peer-reviewed

  
• Probing the Regioselectivity with Encapsulated H2 : Diels-Alder Reaction of an Open-Cage C60 Derivative with Anthracene.

  Yoshifumi Hashikawa; Yasujiro Murata

  Chemistry (Weinheim an der Bergstrasse, Germany), 18 Feb. 2019, Peer-reviewed

  
• A single but hydrogen-bonded water molecule confined in an anisotropic subnanospace.

  Yoshifumi Hashikawa; Shota Hasegawa; Yasujiro Murata

  Chemical communications (Cambridge, England), 04 Dec. 2018, Peer-reviewed

  
• Wavelength-Dependent Efficiency of Sequential Photooxygenation: C=C Bond Cleavage on Open-Cage C60 Derivatives.

  Yoshifumi Hashikawa; Yasujiro Murata

  ChemPlusChem, Dec. 2018, Peer-reviewed

  
• Construction of a Metal-Free Electron Spin System by Encapsulation of an NO Molecule Inside an Open-Cage Fullerene C60 Derivative.

  Shota Hasegawa; Yoshifumi Hashikawa; Tatsuhisa Kato; Yasujiro Murata

  Angewandte Chemie (International ed. in English), 24 Sep. 2018, Peer-reviewed

  
• Probing the interaction between the encapsulated water molecule and the fullerene cages in H2O@C60- and H2O@C59N.

  Guo-Zhu Zhu; Yuan Liu; Yoshifumi Hashikawa; Qian-Fan Zhang; Yasujiro Murata; Lai-Sheng Wang

  Chemical science, 07 Jul. 2018, Peer-reviewed

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• Synthesis and properties of open-cage fullerene C60 derivatives: Impact of the extended P-π conjugation

  Yoshifumi Hashikawa; Hidefumi Yasui; Kei Kurotobi; Yasujiro Murata

  Materials Chemistry Frontiers, 2018, Peer-reviewed

  
• Facile Access to Azafullerenyl Cation C59N+ and Specific Interaction with Entrapped Molecules.

  Yoshifumi Hashikawa; Yasujiro Murata

  Journal of the American Chemical Society, 27 Dec. 2017, Peer-reviewed

  
• High-Resolution Photoelectron Imaging of Cryogenically-Cooled C59N- and (C59N)22- Azafullerene Anions.

  Guo-Zhu Zhu; Yoshifumi Hashikawa; Yuan Liu; Qian-Fan Zhang; Ling Fung Cheung; Yasujiro Murata; Lai-Sheng Wang

  The journal of physical chemistry letters, 21 Dec. 2017, Peer-reviewed

  
• Palladium-Catalyzed Cyclization: Regioselectivity and Structure of Arene-Fused C60 Derivatives.

  Yoshifumi Hashikawa; Michihisa Murata; Atsushi Wakamiya; Yasujiro Murata

  Journal of the American Chemical Society, 15 Nov. 2017, Peer-reviewed

  
• Solvent-Coordinated Tin Halide Complexes as Purified Precursors for Tin-Based Perovskites.

  Masashi Ozaki; Yukie Katsuki; Jiewei Liu; Taketo Handa; Ryosuke Nishikubo; Shinya Yakumaru; Yoshifumi Hashikawa; Yasujiro Murata; Takashi Saito; Yuichi Shimakawa; Yoshihiko Kanemitsu; Akinori Saeki; Atsushi Wakamiya

  ACS omega, 31 Oct. 2017, Peer-reviewed

  
• Single Molecular Junction Study on H2 O@C60 : H2 O is "Electrostatically Isolated".

  Satoshi Kaneko; Yoshifumi Hashikawa; Shintaro Fujii; Yasujiro Murata; Manabu Kiguchi

  Chemphyschem : a European journal of chemical physics and physical chemistry, 19 May 2017, Peer-reviewed

  
• Orientation of a Water Molecule: Effects on Electronic Nature of the C59N Cage.

  Yoshifumi Hashikawa; Michihisa Murata; Atsushi Wakamiya; Yasujiro Murata

  The Journal of organic chemistry, 21 Apr. 2017, Peer-reviewed

  
• Structural modification of open-cage fullerene C60 derivatives having a small molecule inside their cavities

  Yoshifumi Hashikawa; Michihisa Murata; Atsushi Wakamiya; Yasujiro Murata

  Canadian Journal of Chemistry, 2017, Peer-reviewed

  
• Co(I)-Mediated Removal of Addends on the C60 Cage and Formation of the Monovalent Cobalt Complex CpCo(CO)(η2-C60).

  Yoshifumi Hashikawa; Michihisa Murata; Atsushi Wakamiya; Yasujiro Murata

  Organic letters, 16 Dec. 2016

  
• Water Entrapped inside Fullerene Cages: A Potential Probe for Evaluation of Bond Polarization.

  Yoshifumi Hashikawa; Michihisa Murata; Atsushi Wakamiya; Yasujiro Murata

  Angewandte Chemie (International ed. in English), 10 Oct. 2016, Peer-reviewed

  
• Synthesis and Properties of Endohedral Aza[60]fullerenes: H₂O@C₅₉N and H₂@C₅₉N as Their Dimers and Monomers.

  Yoshifumi Hashikawa; Michihisa Murata; Atsushi Wakamiya; Yasujiro Murata

  Journal of the American Chemical Society, 30 Mar. 2016, Peer-reviewed

  
• Synthesis of open-cage ketolactam derivatives of fullerene C60 encapsulating a hydrogen molecule.

  Yoshifumi Hashikawa; Michihisa Murata; Atsushi Wakamiya; Yasujiro Murata

  Organic letters, 06 Jun. 2014, Peer-reviewed

  

Misc.

• Difference in Reactivity of Open-Cage C₆₀ Derivatives Bearing a C=C or C=N Moiety on Their Openings

  木崎和郎; KIM Kyusun; 橋川祥史; 廣瀬崇至; 村田靖次郎

  日本化学会春季年会講演予稿集(CD-ROM), 2020

  
• トリアジン誘導体を用いたH₂O@C₆₀の大量合成法の開発

  木崎和郎; KIM Kyusun; 橋川祥史; 廣瀬崇至; 村田靖次郎

  基礎有機化学討論会要旨集, 2019

  
• 開口部に水素結合をもつ水酸化開口フラーレンC₆₀誘導体の合成と物性

  長谷川翔大; 橋川祥史; 若宮淳志; 村田靖次郎

  日本化学会春季年会講演予稿集(CD-ROM), 06 Mar. 2018

  
• Pd触媒を用いたフラーレン誘導体の位置選択的構造修飾

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  日本化学会春季年会講演予稿集(CD-ROM), 06 Mar. 2018

  
• フラーレン金属錯体の合成と内包水分子の動的挙動

  川崎皓斗; 橋川祥史; 若宮淳志; 村田靖次郎

  日本化学会春季年会講演予稿集(CD-ROM), 06 Mar. 2018

  
• フラーレン空間内部において静電的摂動を受けた孤立水分子の運動性評価

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  Abstracts. Annual Meeting of the NMR Society of Japan, 14 Nov. 2017

  
• 小分子内包フラーレンにおける分子内相互作用の解明

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  基礎有機化学討論会要旨集, 07 Sep. 2017

  
• フラーレンに内包された水分子をNMRプローブとする結合分極の評価

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  日本化学会春季年会講演予稿集(CD-ROM), 03 Mar. 2017

  
• 水分子内包フラーレンのプロトン緩和時間を利用した結合分極の評価

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  基礎有機化学討論会要旨集, 01 Sep. 2016

  
• アザフラーレンC₅₉Nに内包された水分子の動的挙動

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  日本化学会春季年会講演予稿集(CD-ROM), 10 Mar. 2016

  
• かご型炭素クラスターC₆₀およびC₅₉Nに内包されたH₂OとH₂の¹H NMR緩和時間

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎; 村田靖次郎

  Abstracts. Annual Meeting of the NMR Society of Japan, 06 Nov. 2015

  
• 内包アザフラーレンの合成および内包分子の核磁気緩和

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎; 村田靖次郎

  基礎有機化学討論会要旨集, 24 Sep. 2015

  
• 水分子内包アザフラーレンの合成

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  日本化学会講演予稿集, 11 Mar. 2015

  
• 水素分子を内包したアザフラーレン前駆体の合成

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  基礎有機化学討論会要旨集, 25 Aug. 2014

  
• フラーレンC₆₀のケトラクタム誘導体における開口部拡大反応

  橋川祥史; 村田理尚; 若宮淳志; 村田靖次郎

  日本化学会講演予稿集, 12 Mar. 2014

  

Books and Other Publications

• Cutting-edge Technology in Fullerene Derivatives and Endohedral Fullerenes

  Yoshifumi Hashikawa, Contributor, 第3章 内包フラーレンの合成と誘導体化 水分子内包フラーレン

  シーエムシー出版, Apr. 2014, Not refereed

  

External funds: Kakenhi

• Creation of Experimental Hydration Models Based on Spherical pi-Systems

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  橋川 祥史

  From 01 Apr. 2022, To 31 Mar. 2024, Granted

  水分子;水素結合;会合;疎水性;π共役

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-22H04538/
• Construc on of Higher Order Structures Integrated by Precisely Arranged Hydroxy Groups in a 3D Manner

  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

  Science and Engineering

  Kyoto University

  橋川 祥史

  From 01 Apr. 2020, To 31 Mar. 2022, Project Closed

  フラーレン;水分子;水素結合;会合;疎水性;π共役;NMR;リチウムイオン

  https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-20H05218/
• Creation of Carbon Nanocages Targeting Single Molecule Chemistry

  Grant-in-Aid for Early-Career Scientists

  Basic Section 33010:Structural organic chemistry and physical organic chemistry-related

  Kyoto University

  Yoshifumi Hashikawa

  From 01 Apr. 2020, To 31 Mar. 2022, Project Closed

  ナノカーボン;π共役系;フラーレン;拡張フラーレン;緩和時間;水分子;金属錯体;ホスフィン;磁気相互作用;動的挙動

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20K15260/
• Nanostructural Control and Function Exploration of Weak-Interaction-Based Three-Dimensional Pi-Conjugated Molecules

  Grant-in-Aid for Early-Career Scientists

  Basic Section 33010:Structural organic chemistry and physical organic chemistry-related

  Kyoto University

  Yoshifumi Hashikawa

  From 01 Apr. 2018, To 31 Mar. 2020, Project Closed

  水分子;緩和時間;核磁気共鳴;電子スピン共鳴;フラーレン;水素結合;回転運動;電子スピン;π拡張;反応性;金属錯体

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K14200/
• 分子間相互作用に基づく球状π空間の物性制御

  Grant-in-Aid for Research Activity Start-up

  Kyoto University

  橋川 祥史

  From 25 Aug. 2017, To 31 Mar. 2019, Project Closed

  フラーレン;内包フラーレン;開口フラーレン誘導体;電子スピン;緩和時間;反応性;金属錯体

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H06789/

External funds: others

• 共役ナノカーボン複合体の創製と物性解明

  公益財団法人 新世代研究所, 2023年度 新世代研究所ATI研究助成（RGR0505）

  From Oct. 2023, To Sep. 2024
• 機能性エルボー型ナノカーボン材料の創製

  マツダ財団, 第38回（2022年度）マツダ研究助成

  From Nov. 2022, To Mar. 2024

  橋川 祥史
• 金属ドープ型球面π共役系の創製

  京都大学, 2022年度 京都大学研究費獲得支援事業【いしずえ】

  From 01 Apr. 2022, To 31 Mar. 2023

  橋川 祥史
• フラーレンドープ型金属酸化物ナノワイヤの形成と物性評価

  令和2年度 統合物質創製化学研究推進機構「融合創発研究」

  From 01 Apr. 2020, To 31 Mar. 2021

  代表
• 小分子導入にもとづくC60骨格への電子的効果の検証

  平成30年度 統合物質創製化学研究推進機構「融合創発研究」

  From Jul. 2018, To Mar. 2019

  代表
• 官能基の配列方向に由来するキラリティを有する開口フラーレン誘導体の触媒的光学分割

  平成30年度 化学研究所らしい融合的・開拓的研究

  From Apr. 2018, To Mar. 2019

  分担
• 分子間相互作用に基づく球状π空間の物性制御

  平成29年度 京都大学若手研究者スタートアップ研究費

  From Apr. 2017, To Sep. 2017

  代表
• 葉酸修飾フィトールの合成とがん選択的DDSへの応用

  公益財団法人 えひめ産業振興財団

  From Apr. 2009, To Mar. 2010

Education

Teaching subject(s)

• From Apr. 2018, To Mar. 2019

  Energy and Hydrocarbon Chemistry, Adv. III

  Spring, 工学研究科
• From Apr. 2018, To Mar. 2019

  Energy and Hydrocarbon Chemistry, Adv. IV

  Spring, 工学研究科

Part-time lecturer

• From 01 Oct. 2023, To 31 Mar. 2024

  先端化学実験Ⅱ（先端化学）

  後期96時間, 京都大学, 工学部
• From 01 Oct. 2022, To 31 Mar. 2023

  先端化学実験Ⅱ（先端化学）

  後期96時間, 工学部

Administration

Faculty management (title, position)

• From 01 Apr. 2018, To 31 Mar. 2019

  化学研究所安全衛生委員会 委員
• From 01 Apr. 2021, To 31 Mar. 2023

  化学物質専門委員会　委員
• From 01 Apr. 2021, To 31 Mar. 2023

  化学物質専門小委員会　委員
• From 01 Apr. 2021, To 31 Mar. 2023

  京都大学宇治地区化学物質管理委員会
• From 01 Apr. 2021, To 31 Mar. 2022

  化学研究所図書委員会委員