Basic Information

Faculty

• 総合人間学部

Professional Memberships

• JAPAN SOCIETY OF COORDINATION CHEMISTRY
• KINKI CHEMICAL SOCIETY, JAPAN
• THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN
• THE CHEMICAL SOCIETY OF JAPAN

Academic Degree

• 修士（工学）(京都大学)
• 博士（工学）(京都大学)

Academic Resume (Graduate Schools)

• 京都大学, 大学院工学研究科修士課程物質エネルギー化学専攻, 修了
• 京都大学, 大学院工学研究科物質エネルギー化学専攻博士後期課程, 修了

Academic Resume (Undergraduate School/Majors)

• 京都大学, 工学部工業化学科, 卒業

High School

• High School

  大阪府立三国丘高等学校

Research History

• From Apr. 2018, To Present

  Kyoto University, Graduate School of Human and Environmental Studies, Assistant Professor
• From Apr. 2017, To Mar. 2018

  Japan Society for the Promotion of Science, Research Fellowship for Young Scientists

ID,URL

• ORCID ID

  0000-0003-1520-5829

• J-Global ID

  201801002567118810

• Researcher number

  90824938

researchmap URL

• https://researchmap.jp/7000023128

Research

Research Topics, Overview of the research

• Research Topics

  · Design and Synthesis of Multinuclear Complex for Catalytic Application
  · Synthesis of Nitrogen-Containing Compounds Utilizing Isocyanides in the Presence of Transition Metal Complex Catalyst

• Overview of the research

  Multinuclear transition metal complexes would exhibit unique reactivity and catalytic ability which are different from well-documented mononuclear complex; however, general synthetic method of them has not relatively been established compared to the mononuclear ones. I am interested in a design and formation of such multinuclear complexes employing newly tailored multidentate ligand.
  I am also interested in the development of catalytic transformation of isocyanides with combination of the use of organometallic reagents directed toward efficient synthesis of nitrogen-containing compounds

Research Interests

• Synthetic Organic Chemistry
• Coordination Chemistry
• Organoimetallic Chemistry

Research Areas

• Nanotechnology/Materials, Synthetic organic chemistry

Papers

• Synthesis of thermoresponsive polymer gels with crosslinked domains containing iridium complexes for ammonia sensing and N-alkylation catalysis

  Shohichi Furukawa; Takahiro Okuno; Takuya Shimbayashi; Hiroki Takeshita; Ken-ichi Fujita; Shohei Ida

  Polymer Journal, Sep. 2023

  
• Sustainable hydrogen production & storage cycle with dihydrolevoglucosenone (Cyrene™): Hydrogen fixing and release based on alcoholic fermentation with Baker's yeast and dehydrogenation

  Takumi Ichimura; Hiroki Maeda; Takuya Shimbayashi; Kohei Okubo; Masayuki Fukushima; Norimitsu Tohnai; Ken-ichi Fujita; Kouki Oka

  International Journal of Hydrogen Energy, Jun. 2024

  
• Rh-catalysed divergent synthesis of polysubstituted pyrroles from α,β-unsaturated ketones via selective single or double insertion of isocyanides

  Takuya Shimbayashi; Taiyou Ishige; Ken-ichi Fujita

  Organic Chemistry Frontiers, Nov. 2023, Peer-reviewed, Lead author, Corresponding author

  
• Effect of Substituents in Functional Bipyridonate Ligands on Ruthenium‐Catalyzed Dehydrogenative Oxidation of Alcohols: An Experimental and Computational Study

  Takuya Shimbayashi; Hajime Ito; Mineyuki Shimizu; Hayato Sano; Shigeyoshi Sakaki; Ken‐ichi Fujita

  ChemCatChem, 10 Oct. 2022, Peer-reviewed, Lead author, Corresponding author

  
• Iridium-Catalyzed Dehydrogenative Reactions

  Takuya Shimbayashi; Ken-ichi Fujita

  Iridium Catalysts for Organic Reactions, 2021

  
• Recent Advances in Homogeneous Catalysis via Metal–Ligand Cooperation Involving Aromatization and Dearomatization

  Takuya Shimbayashi; Ken-ichi Fujita

  Catalysts, 07 Jun. 2020

  Access this paper :

  
• Metal-catalyzed hydrogenation and dehydrogenation reactions for efficient hydrogen storage

  Takuya Shimbayashi; Ken-ichi Fujita

  TETRAHEDRON, Mar. 2020

  
• Effect of a Substituent in Cyclopentadienyl Ligand on Iridium-Catalyzed Acceptorless Dehydrogenation of Alcohols and 2-Methyl-1,2,3,4-tetrahydroquinoline

  Jaeyoung Jeong; Takuya Shimbayashi; Ken-ichi Fujita

  Catalysts, Oct. 2019, Peer-reviewed

  
• Successive Activation of C-H and C-O Bonds of Vinyl Ethers by a Diphosphine and Hydrido-Bridged Diiridium Complex

  Yoshinori Takahashi; Takuya Shimbayashi; Ken-ichi Fujita

  INORGANICS, Oct. 2019

  
• Iridium-Catalyzed Transfer Hydrogenation of Ketones and Aldehydes Using Glucose as a Sustainable Hydrogen Donor

  Masato Yoshida; Ryota Hirahata; Takayoshi Inoue; Takuya Shimbayashi; Ken-ichi Fujita

  Catalysts, May 2019, Peer-reviewed

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• Environmentally Friendly Synthesis of N-Methylated Nitrogen Heterocycles from an Aqueous Solution of Methylamine and Diols

  Takuya Shimbayashi

  HETEROCYCLES, 2019, Peer-reviewed

  
• Recent Progress on Cyclic Nitrenoid Precursors in Transition-metal-catalyzed Nitrene-transfer Reactions

  Takuya Shimbayashi; Kohei Sasakura; Akira Eguchi; Kazuhiro Okamoto; Kouichi Ohe

  Chemistry - A European Journal, 05 Sep. 2018, Peer-reviewed

  
• Divergent Catalytic Approach from Cyclic Oxime Esters to Nitrogen-Containing Heterocycles with Group 9 Metal Catalysts

  Takuya Shimbayashi; Gaku Matsushita; Atsushi Nanya; Akira Eguchi; Kazuhiro Okamoto; Kouichi Ohe

  ACS Catalysis, 09 Jul. 2018, Peer-reviewed

  
• Dehydrogenative Transformation of Alcoholic Substrates in Aqueous Media Catalyzed by an Iridium Complex Having a Functional Ligand with α-Hydroxypyridine and 4,5-Dihydro-1H-imidazol-2-yl Moieties

  Masato Yoshida; Han Wang; Takuya Shimbayashi; Ken-ichi Fujita

  Catalysts, Jul. 2018, Peer-reviewed

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• Facile Construction of Tetrahydropyrrolizines by Iron-Catalyzed Double Cyclization of Alkene-Tethered Oxime Esters with 1,2-Disubstituted Alkenes

  Takuya Shimbayashi; Daiki Nakamoto; Kazuhiro Okamoto; Kouichi Ohe

  Organic Letters, 18 May 2018, Peer-reviewed

  
• Iron-Catalyzed Aminative Cyclization/Intermolecular Homolytic Aromatic Substitution Using Oxime Esters and Simple Arenes

  Takuya Shimbayashi; Kazuhiro Okamoto; Kouichi Ohe

  Chemistry - An Asian Journal, 16 Feb. 2018, Peer-reviewed

  
• Palladium-Catalyzed Selective Formation of Substituted Pyrroles from Alkene-tethered Cyclic Oxime Esters

  Kouichi Ohe; Kazuhiro Okamoto; Tomohiro Oda; Takuya Shimbayashi

  HETEROCYCLES, 2018, Peer-reviewed

  
• Generation of Stable Ruthenium(IV) Ketimido Complexes by Oxidative Addition of Oxime Esters to Ruthenium(II): Reactivity Studies Based on Electronic Properties of the Ru-N Bond

  Takuya Shimbayashi; Kazuhiro Okamoto; Kouichi Ohe

  CHEMISTRY-A EUROPEAN JOURNAL, Nov. 2017, Peer-reviewed

  
• A 7-Step Formal Asymmetric Total Synthesis of Strictamine via an Asymmetric Propargylation and Metal-Mediated Cyclization

  Myles W. Smith; Zhiyao Zhou; Alison X. Gao; Takuya Shimbayashi; Scott A. Snyder

  ORGANIC LETTERS, Mar. 2017, Peer-reviewed

  
• Ruthenium-catalyzed Decarboxylative and Dehydrogenative Formation of Highly Substituted Pyridines from Alkene-tethered Isoxazol-5(4H)-ones

  Kazuhiro Okamoto; Kohei Sasakura; Takuya Shimbayashi; Kouichi Ohe

  CHEMISTRY LETTERS, Aug. 2016, Peer-reviewed

  
• Synthesis of 2H-Azirines by Iridium-Catalyzed Decarboxylative Ring Contraction of Isoxazol-5(4H)-ones

  Kazuhiro Okamoto; Takuya Shimbayashi; Masato Yoshida; Atsushi Nanya; Kouichi Ohe

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Jun. 2016, Peer-reviewed

  
• C-H Activation Induced by Oxidative Addition of N-O Bonds in Oxime Esters: Formation of Rhodacycles and Cycloaddition with Alkynes

  Takuya Shimbayashi; Kazuhiro Okamoto; Kouichi Ohe

  ORGANOMETALLICS, Jun. 2016, Peer-reviewed

  
• Indium-Catalyzed [2+2] Cycloaddition of Allylsilanes to Internal Alkynones

  Kazuhiro Okamoto; Takuya Shimbayashi; Eisuke Tamura; Kouichi Ohe

  ORGANIC LETTERS, Dec. 2015, Peer-reviewed

  
• Synthesis of Imidazoles and Pyrimidines Using Palladium-Catalyzed Decarboxylatiye Intramolecular Condensation of 1,2,4-Oxadiazol-5(4H)-ones

  Takuya Shimbayashi; Kazuhiro Okamoto; Kouichi Ohe

  SYNLETT, Aug. 2014, Peer-reviewed

  
• Palladium-Catalyzed Aza-Wittig-Type Condensation of Isoxazol-5(4H)-ones with Aldehydes

  Kazuhiro Okamoto; Takuya Shimbayashi; Eisuke Tamura; Kouichi Ohe

  Chemistry - A European Journal, Jan. 2014, Peer-reviewed

  

Books and Other Publications

• Advances in Chemistry Research Vol. 48

  Bojidarka Ivanova; Michael Spiteller; Sofia Ahmed; Noureen Anwar; Muhammad Ali Sheraz; Iqbal Ahmad; Seijiro Hosokawa; Takuya Shimbayashi; Ken-ichi Fujita, Contributor, Environmentally Benign N-Alkylation of Amines, Ammonia, and Related Compounds Catalyzed by Ir Complexes Using Alcohols as Alkylating Reagents

  Nova Science Publishers, Jan. 2019, Not refereed

  Find Kyoto University's collection of books :

  

External funds: Kakenhi

• Studies on synthesis of dinuclear metal complex bearing quinoline-based multidentate ligand directed toward catalytic application

  Grant-in-Aid for Early-Career Scientists

  Basic Section 34010:Inorganic/coordination chemistry-related

  Kyoto University

  Takuya Shimbayashi

  From 01 Apr. 2020, To 31 Mar. 2024, Project Closed

  キノリン;ホスフィン;多座配位子;白金;二核錯体;歪み;遷移金属錯体;キノリン配位子;ホスフィン配位子;ルテニウム;白金錯体;二核構造;触媒反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20K15299/
• Development of environmentally benign oxidation system utilizing iron complex catalyst bearing functional ligand

  Grant-in-Aid for Research Activity Start-up

  0502:Inorganic/coordination chemistry, analytical chemistry, inorganic materials chemistry, energy-related chemistry, and related fields

  Kyoto University

  Takuya SHIMBAYASHI

  From 24 Aug. 2018, To 31 Mar. 2020, Project Closed

  脱水素的酸化;錯体触媒;協働作用配位子;鉄錯体;酸化反応;機能性配位子;計算化学;環境調和型物質変換;脱水素化;アルコール;環境調和的物質変換;酸化還元反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K21137/
• Development of catalytic reactions towards a realization of a hydrogen society

  Grant-in-Aid for Scientific Research (B)

  Basic Section 33020:Synthetic organic chemistry-related

  Kyoto University

  Ken-ichi Fujita

  From 01 Apr. 2019, To 31 Mar. 2022, Project Closed

  水素;脱水素化;触媒;イリジウム;ルテニウム;グリセロール;糖類;均一系触媒;不均一系触媒;計算化学

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19H02715/
• 多座イソシアニド配位錯体触媒系の開発

  Grant-in-Aid for Early-Career Scientists

  Basic Section 33020:Synthetic organic chemistry-related

  Kyoto University

  新林 卓也

  From 01 Apr. 2025, To 31 Mar. 2028, Adopted

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25K18032/

Education

Teaching subject(s)

• From 01 Apr. 2025, To 31 Mar. 2026

  Studies on Synthesis, Reactions, and Structures of Organic Molecules

  9152, Fall, Faculty of Integrated Human Studies, 8
• From 01 Apr. 2025, To 31 Mar. 2026

  Lecture and Exercise on Organic Molecular Structures and Properties B

  9242, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2025, To 31 Mar. 2026

  Frontier of Chemistry

  9129, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2025, To 31 Mar. 2026

  Advanced Chemistry and Materials Science

  KK21, Spring, Graduate School of Human and Environmental Studies, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Fundamental Chemical Experiments

  N308, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Studies on Synthesis, Reactions, and Structures of Organic Molecules

  9152, Fall, Faculty of Integrated Human Studies, 8
• From 01 Apr. 2024, To 31 Mar. 2025

  Lecture and Exercise on Organic Molecular Structures and Properties B

  9242, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Frontier of Chemistry

  9129, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Introduction to Natural Sciences B

  0075, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Advanced Chemistry and Materials Science

  KK21, Spring, Graduate School of Human and Environmental Studies, 2
• From 01 Apr. 2024, To 31 Mar. 2025

  Fundamentals for Transdisciplinary Research 9

  KK10, Fall, Graduate School of Human and Environmental Studies, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Fundamental Chemical Experiments

  N308, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Studies on Synthesis, Reactions, and Structures of Organic Molecules

  9152, Fall, Faculty of Integrated Human Studies, 8
• From 01 Apr. 2023, To 31 Mar. 2024

  Frontier of Chemistry

  9129, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Lecture and Exercise on Organic Molecular Structures and Properties B

  9242, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2023, To 31 Mar. 2024

  Advanced Chemistry and Materials Science

  KK21, Spring, Graduate School of Human and Environmental Studies, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Fundamental Chemical Experiments

  N308, Spring, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Studies on Synthesis, Reactions, and Structures of Organic Molecules

  9152, Fall, Faculty of Integrated Human Studies, 8
• From 01 Apr. 2022, To 31 Mar. 2023

  Lecture and Exercise on Organic Molecular Structures and Properties B

  9242, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Advanced Chemistry and Materials Science

  3005, Spring, Graduate School of Human and Environmental Studies, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Advanced Exercise of Chemistry III

  N327, Fall, Institute for Liberal Arts and Sciences, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Introduction to Science B

  0073, Fall, Faculty of Integrated Human Studies, 2
• From 01 Apr. 2022, To 31 Mar. 2023

  Frontier of Chemistry

  9129, Fall, Faculty of Integrated Human Studies, 2
• From Apr. 2019, To Mar. 2020

  Lecture and Exercise on Organic Molecular Structures and Properties B

  Fall, 総合人間学部
• From Apr. 2019, To Mar. 2020

  Frontier of Chemistry

  Fall, 総合人間学部
• From Apr. 2019, To Mar. 2020

  Fundamental Chemical Experiments

  Spring, 全学共通科目
• From Apr. 2019, To Mar. 2020

  Advanced Exercise of Chemistry III

  Fall, 全学共通科目
• From Apr. 2019, To Mar. 2020

  Studies on Synthesis, Reactions, and Structures of Organic Molecules

  Fall, 総合人間学部
• From Apr. 2020, To Mar. 2021

  Lecture and Exercise on Organic Molecular Structures and Properties B

  Fall, 総合人間学部
• From Apr. 2020, To Mar. 2021

  Frontier of Chemistry

  Fall, 総合人間学部
• From Apr. 2020, To Mar. 2021

  Fundamental Chemical Experiments

  Spring, 全学共通科目
• From Apr. 2020, To Mar. 2021

  Advanced Exercise of Chemistry III -The Chemistry of Organic Compounds-

  Fall, 全学共通科目
• From Apr. 2020, To Mar. 2021

  Studies on Synthesis, Reactions, and Structures of Organic Molecules

  Fall, 総合人間学部
• From Apr. 2021, To Mar. 2022

  Lecture and Exercise on Organic Molecular Structures and Properties B

  Fall, 総合人間学部
• From Apr. 2021, To Mar. 2022

  Frontier of Chemistry

  Fall, 総合人間学部
• From Apr. 2021, To Mar. 2022

  Fundamental Chemical Experiments

  Spring, 全学共通科目
• From Apr. 2021, To Mar. 2022

  Advanced Exercise of Chemistry III -The Chemistry of Organic Compounds-

  Fall, 全学共通科目
• From Apr. 2021, To Mar. 2022

  Studies on Synthesis, Reactions, and Structures of Organic Molecules

  Fall, 総合人間学部