基本情報

学部兼担

• 理学部

所属学協会

• 日本薬学会
• 有機合成化学協会
• アメリカ化学会(American Chemical Society)
• 日本化学会

学位

• ＰＨ．Ｄ（ＣＨＥＭＩＳＴＲＹ）(ハワイ大学)

出身大学院・研究科等

• ハワイ大学, 大学院博士課程化学科, 単位修得

出身学校・専攻等

• 京都大学, 工学部, 卒業

使用言語

• 英語

ID,URL

• J-Global ID

  200901002203619805

researchmap URL

• https://researchmap.jp/read0011285

研究

研究テーマ・研究概要

• 研究テーマ

  有機触媒化学分野の開拓

• 研究概要

  　有機分子触媒はそれまで用いられてきた金属触媒に比べて一般に安価であり、廃棄物の毒性が低いなど環境負荷が小さいと見られるものが多く、グリーンケミストリーの観点から高い有用性が期待されている。また水や空気に対して安定であるため、実験技術的な面からも大きなメリットを有するため、産業界での実用化が容易になる。例えば、丸岡氏が考案した「簡素化丸岡触媒® (Simplified Maruoka Catalyst®)」を用いて、長瀬産業が数年前から人工アミノ酸の事業化を行なっており、国内外の製薬会社等からの委託を受けて、医薬原料や医薬中間体製造のために、最大数百キログラム単位で人工アミノ酸を製造している。

研究キーワード

• 合成化学
• Synthetic Chemistry

研究分野

• ナノテク・材料, 有機合成化学
• ライフサイエンス, 生物有機化学
• ナノテク・材料, 構造有機化学、物理有機化学

論文

• The radical acylarylation of N-arylacrylamides with aliphatic aldehydes using the photolysis of hypervalent iodine(iii) reagents

  Sakamoto Ryu; Hirama Naomichi; Maruoka Keiji

  ORGANIC & BIOMOLECULAR CHEMISTRY, 2018年08月14日, 査読有り

  
• BF3-Catalyzed Synthesis of Cyclic Carbamates from Boc-Protected Aminals and Alkynes

  Kano Taichi; Yasumoto Kento; Maruoka Keiji

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018年08月, 査読有り

  
• Synthesis of 1-Aminoindenes through Aza-Prins-Type Cyclization

  Bai Jian-Fei; Yasumoto Kento; Kano Taichi; Maruoka Keiji

  CHEMISTRY-A EUROPEAN JOURNAL, 2018年07月20日, 査読有り

  
• Enantioselective Alkylation of N-Arylhydrazones Derived from -Keto Esters and Isatin Derivatives through Asymmetric Phase-Transfer Catalysis

  Kang Qi-Kai; Selvakumar Sermadurai; Arumugam Natarajan; Almansour Abdulrahman I; Kumar Raju Suresh; Maruoka Keiji

  CHEMISTRY-AN ASIAN JOURNAL, 2018年07月16日, 査読有り

  
• Phase-transfer-catalysed asymmetric synthesis of 2,2-disubstituted 1,4-benzoxazin-3-ones

  Pawliczek Martin; Shimazaki Yuto; Kimura Hidenori; Oberg Kevin M; Zakpur Saman; Hashimoto Takuya; Maruoka Keiji

  CHEMICAL COMMUNICATIONS, 2018年06月28日, 査読有り

  
• Indanol-Based Chiral Organoiodine Catalysts for Enantioselective Hydrative Dearomatization

  Takuya Hashimoto; Yuto Shimazaki; Yamato Omatsu; Keiji Maruoka

  Angewandte Chemie - International Edition, 2018年06月11日, 査読有り

  
• Transition-Metal-Free Direct C−H Silylation of Electron-Deficient Heteroarenes with Hydrosilanes via a Radical Mechanism

  Ryu Sakamoto; Bich-Ngoc Nguyen; Keiji Maruoka

  Asian Journal of Organic Chemistry, 2018年06月01日, 査読有り

  
• Catalyst-controlled diastereoselectivity reversal in the formation of dihydropyrans

  Taichi Kano; Hiroki Maruyama; Chihiro Homma; Keiji Maruoka

  Chemical Communications, 2018年04月11日, 査読有り

  
• A Synthetic Route to Sodium α-Aminoalkanesulfinates and Their Application in the Generation of α-Aminoalkyl Radicals for Radical Addition Reactions

  Ryu Sakamoto; Tomomi Yoshii; Hiroyuki Takada; Keiji Maruoka

  Organic Letters, 2018年04月06日, 査読有り

  
• Copper-Catalyzed C(sp)-C(sp3) Coupling of Terminal Alkynes with Alkylsilyl Peroxides via a Radical Mechanism

  Ryu Sakamoto; Terumasa Kato; Shunya Sakurai; Keiji Maruoka

  Organic Letters, 2018年03月02日, 査読有り

  
• Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: A chiral ammonium borinate catalysis

  Martin Pawliczek; Takuya Hashimoto; Keiji Maruoka

  Chemical Science, 2018年, 査読有り

  
• Asymmetric Synthesis of Less Accessible α-Tertiary Amines from Alkynyl Z-Ketimines

  Taichi Kano; Yusuke Aota; Keiji Maruoka

  Angewandte Chemie - International Edition, 2017年12月18日, 査読有り

  
• Synthesis of Chiral Tritylpyrrolidine Derivatives and Their Application to Asymmetric Benzoyloxylation

  Mio Shimogaki; Hiroki Maruyama; Shingo Tsuji; Chihiro Homma; Taichi Kano; Keiji Maruoka

  JOURNAL OF ORGANIC CHEMISTRY, 2017年12月, 査読有り

  
• Hypervalent Iodine Mediated Chemoselective Iodination of Alkynes

  Yan Liu; Daya Huang; Ju Huang; Keiji Maruoka

  JOURNAL OF ORGANIC CHEMISTRY, 2017年11月, 査読有り

  
• The Direct C-H Difluoromethylation of Heteroarenes Based on the Photolysis of Hypervalent Iodine(III) Reagents That Contain Difluoroacetoxy Ligands

  Ryu Sakamoto; Hirotaka Kashiwagi; Keiji Maruoka

  ORGANIC LETTERS, 2017年10月, 査読有り

  
• Hypervalent iodine(III) catalyzed radical hydroacylation of chiral alkylidenemalonates with aliphatic aldehydes under photolysis

  Sermadurai Selvakumar; Qi-Kai Kang; Natarajan Arumugam; Abdulrahman I. Almansour; Raju Suresh Kumar; Keiji Maruoka

  TETRAHEDRON, 2017年10月, 査読有り

  
• Practical Synthesis of both Enantiomeric Amino Acid, Mannich, and Aldol Derivatives by Asymmetric Organocatalysis

  Yan Liu; Natarajan Arumugam; Abdulrahman I. Almansour; Raju Suresh Kumar; Keiji Maruoka

  CHEMICAL RECORD, 2017年10月, 査読有り

  
• Practical Synthesis of Two Different Pseudoenantiomeric Organocatalysts with cis-Cyclohexanediamine Structure from a Common Chiral Source

  Hyo-Jun Lee; Shin A. Moteki; Natarajan Arumugam; Abdulrahman I. Almansour; Raju Suresh Kumar; Yan Liu; Keiji Maruoka

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2017年09月, 査読有り

  
• Catalyst-Controlled, Enantioselective, and Diastereodivergent Conjugate Addition of Aldehydes to Electron-Deficient Olefins

  S. B. Jennifer Kan; Hiroki Maruyama; Matsujiro Akakura; Taichi Kano; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017年08月, 査読有り

  
• SERS detection and analysis of a single DNA oligomer using a single gold nanoparticle dimer

  Katsunari Maruoka; Koji Sugano; Yoshitada Isono

  TRANSDUCERS 2017 - 19th International Conference on Solid-State Sensors, Actuators and Microsystems, 2017年07月26日, 査読有り

  
• Alkylsilyl Peroxides as Alkylating Agents in the Copper-Catalyzed Selective Mono-N-Alkylation of Primary Amides and Arylamines

  Ryu Sakamoto; Shunya Sakurai; Keiji Maruoka

  CHEMISTRY-A EUROPEAN JOURNAL, 2017年07月, 査読有り

  
• In situ generation of N-Boc-protected alkenyl imines: controlling the E/Z geometry of alkenyl moieties in the Mukaiyama-Mannich reaction

  Jian-Fei Bai; Hajime Sasagawa; Taiga Yurino; Taichi Kano; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2017年07月, 査読有り

  
• In situ generation of less accessible Boc-imines from aldehydes: construction of a quaternary carbon by the Mannich reaction or unprecedented aldol reaction

  Taichi Kano; Chihiro Homma; Keiji Maruoka

  ORGANIC & BIOMOLECULAR CHEMISTRY, 2017年06月, 査読有り

  
• Bis(trialkylsilyl) peroxides as alkylating agents in the copper-catalyzed selective mono-N-alkylation of primary amides

  Ryu Sakamoto; Shunya Sakurai; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2017年06月, 査読有り

  
• Phase-transfer catalyzed asymmetric synthesis of alpha,beta-unsaturated gamma,gamma-disubstituted gamma-lactams

  Alexander Arlt; Hideaki Toyama; Koji Takada; Takuya Hashimoto; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2017年05月, 査読有り

  
• Chiral Tertiary Sulfonium Salts as Effective Catalysts for Asymmetric Base-Free Neutral Phase-Transfer Reactions

  Shiyao Liu; Keiji Maruoka; Seiji Shirakawa

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017年04月, 査読有り

  
• Synthesis of the Right-Side Structure of Type B Physalins

  Masaki Morita; Shuntaro Kojima; Megumi Ohkubo; Hiroyuki Koshino; Daisuke Hashizume; Go Hirai; Keiji Maruoka; Mikiko Sodeoka

  ISRAEL JOURNAL OF CHEMISTRY, 2017年04月, 査読有り

  
• A New Strategy for Organocatalyzed Asymmetric Synthesis of BINOL Derivatives

  Seiji Shirakawa; Keiji Maruoka

  CHEM, 2017年03月, 査読有り

  
• Hydrogen-bonding catalysis of sulfonium salts

  Shiho Kaneko; Yusuke Kumatabara; Shoichi Shimizu; Keiji Maruoka; Seiji Shirakawa

  CHEMICAL COMMUNICATIONS, 2017年01月, 査読有り

  
• Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal: Z -allylating agents

  Taichi Kano; Hiroki Maruyama; Chihiro Homma; Keiji Maruoka

  Chemical Communications, 2017年, 査読有り

  
• The design of environmentally-benign, high-performance organocatalysts for asymmetric catalysis

  Ryu Sakamoto; Keiji Maruoka

  Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 2017年, 査読有り

  
• [2+2] Photocycloadditions between the Carbon-Nitrogen Double Bonds of Imines and Carbon-Carbon Double Bonds

  Ryu Sakamoto; Tsubasa Inada; Shunya Sakurai; Keiji Maruoka

  ORGANIC LETTERS, 2016年12月, 査読有り

  
• Aryl Ketone Catalyzed Radical Allylation of C(sp(3))-H Bonds under Photoirradiation

  Shin Kamijo; Kaori Kamijo; Kiyotaka Maruoka; Toshihiro Murafuji

  ORGANIC LETTERS, 2016年12月, 査読有り

  
• Rate Acceleration of Solid-Liquid Phase-Transfer Catalysis by Rotor-Stator Homogenizer

  Taichi Kano; Yusuke Aota; Keiji Maruoka

  ADVANCED SYNTHESIS & CATALYSIS, 2016年09月, 査読有り

  
• Hydrogen-Bonding Catalysis of Tetraalkylammonium Salts in an Aza-Diels-Alder Reaction

  Yusuke Kumatabara; Shiho Kaneko; Satoshi Nakata; Seiji Shirakawa; Keiji Maruoka

  CHEMISTRY-AN ASIAN JOURNAL, 2016年08月, 査読有り

  
• Catalytic asymmetric synthesis of axially chiral 2-amino-1,1 '-biaryl compounds by phase-transfer-catalyzed kinetic resolution and desymmetrization

  Seiji Shirakawa; Xiangfei Wu; Shiyao Liu; Keiji Maruoka

  TETRAHEDRON, 2016年08月, 査読有り

  
• A Bulky Thiyl-Radical Catalyst for the [3+2] Cyclization of N-Tosyl Vinylaziridines and Alkenes

  Takuya Hashimoto; Kohei Takino; Kazuki Hato; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016年07月, 査読有り

  
• N-Boc-aminals as easily accessible precursors for less accessible N-Boc-imines: facile synthesis of optically active propargylamine derivatives using Mannich-type reactions

  Taiga Yurino; Yusuke Aota; Daisuke Asakawa; Taichi Kano; Keiji Maruoka

  TETRAHEDRON, 2016年06月, 査読有り

  
• Diastereoselective Radical Hydroacylation of Alkylidenemalonates with Aliphatic Aldehydes Initiated by Photolysis of Hypervalent Iodine(III) Reagents

  Sermadurai Selvakumar; Ryu Sakamoto; Keiji Maruoka

  CHEMISTRY-A EUROPEAN JOURNAL, 2016年05月, 査読有り

  
• A Chiral Electrophilic Selenium Catalyst for Highly Enantioselective Oxidative Cyclization

  Yu Kawamata; Takuya Hashimoto; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016年04月, 査読有り

  
• Synthesis of N-Boc-Propargylic and Allylic Amines by Reaction of Organomagnesium Reagents with N-Boc-Aminals and Their Oxidation to N-Boc-Ketimines

  Taichi Kano; Ryohei Kobayashi; Keiji Maruoka

  ORGANIC LETTERS, 2016年01月, 査読有り

  
• Efficient photolytic C-H bond functionalization of alkylbenzene with hypervalent iodine(III) reagent

  Ryu Sakamoto; Tsubasa Inada; Sermadurai Selvakumar; Shin A. Moteki; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2016年, 査読有り

  
• Efficient generation of perfluoroalkyl radicals from sodium perfluoroalkanesulfinates and a hypervalent iodine(III) reagent: mild, metal-free synthesis of perfluoroalkylated organic molecules

  Ryu Sakamoto; Hirotaka Kashiwagi; Sermadurai Selvakumar; Shin A. Moteki; Keiji Maruoka

  ORGANIC & BIOMOLECULAR CHEMISTRY, 2016年, 査読有り

  
• Design of bifunctional quaternary phosphonium salt catalysts for CO2 fixation reaction with epoxides under mild conditions

  Shiyao Liu; Naoki Suematsu; Keiji Maruoka; Seiji Shirakawa

  GREEN CHEMISTRY, 2016年, 査読有り

  
• Effect of aging at room temperature on hydrogen embrittlement behavior of Ni-Ti superelastic alloy immersed in acidic fluoride solution

  Ogawa Toshio; Oda Tetsuro; Maruoka Kuniaki; Sakai Jun'ichi

  INTERNATIONAL JOURNAL OF MECHANICAL AND MATERIALS ENGINEERING, 2015年12月, 査読有り

  
• Boronic Acid-Catalyzed, Highly Enantioselective Aza-Michael Additions of Hydroxamic Acid to Quinone Imine Ketals

  Takuya Hashimoto; Alberto Osuna Galvez; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015年12月, 査読有り

  
• Tetraalkylammonium Salts as Hydrogen-Bonding Catalysts

  Seiji Shirakawa; Shiyao Liu; Shiho Kaneko; Yusuke Kumatabara; Airi Fukuda; Yumi Omagari; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015年12月, 査読有り

  
• Positive Effect of Water in Asymmetric Direct Aldol Reactions with Primary Amine Organocatalyst: Experimental and Computational Studies

  Shin A. Moteki; Hiroki Maruyama; Keiji Nakayama; Hai-Bei Li; Galina Petrova; Satoshi Maeda; Keiji Morokuma; Keiji Maruoka

  CHEMISTRY-AN ASIAN JOURNAL, 2015年10月, 査読有り

  
• Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions (vol 115, pg 5366, 2015)

  Takuya Hashimoto; Keiji Maruoka

  CHEMICAL REVIEWS, 2015年09月, 査読有り

  
• Mechanism of Metal-Free C-H Activation of Branched Aldehydes and Acylation of Alkenes Using Hypervalent Iodine Compound: A Theoretical Study

  Julong Jiang; Romain Ramozzi; Shin Moteki; Asuka Usui; Keiji Maruoka; Keiji Morokuma

  JOURNAL OF ORGANIC CHEMISTRY, 2015年09月, 査読有り

  
• Versatile In Situ Generated N-Boc-Imines: Application to Phase-Transfer-Catalyzed Asymmetric Mannich-Type Reactions

  Taichi Kano; Ryohei Kobayashi; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015年07月, 査読有り

  
• Regio- and Stereoselective Conjugate Addition of Aldehydes to beta-Tosyl Enones under the Catalysis of a Binaphthyl-Modified Chiral Amine

  Taichi Kano; Hisashi Sugimoto; Hiroki Maruyama; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015年07月, 査読有り

  
• Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions

  Takuya Hashimoto; Keiji Maruoka

  CHEMICAL REVIEWS, 2015年06月, 査読有り

  
• Catalytic Asymmetric Diels-Alder Reaction of Quinone Imine Ketals: A Site-Divergent Approach

  Takuya Hashimoto; Hiroki Nakatsu; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015年04月, 査読有り

  
• Phase-Transfer-Catalyzed Asymmetric SNAr Reaction of alpha-Amino Acid Derivatives with Arene Chromium Complexes

  Seiji Shirakawa; Kenichiro Yamamoto; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015年01月, 査読有り

  
• Regioselectivity switch in chiral amine-catalysed asymmetric addition of aldehydes to reactive enals

  Taichi Kano; Hiroki Maruyama; Ryu Sakamoto; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2015年, 査読有り

  
• Phase-transfer-catalyzed asymmetric desymmetrizations of cyclopentanones

  Seiji Shirakawa; Takashi Tokuda; S. B. Jennifer Kan; Keiji Maruoka

  ORGANIC CHEMISTRY FRONTIERS, 2015年, 査読有り

  
• Bronsted acid-catalyzed Mannich reaction through dual activation of aldehydes and N-Boc-imines

  Taichi Kano; Yusuke Aota; Daisuke Asakawa; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2015年, 査読有り

  
• Metal-Free C-H Bond Activation of Branched Aldehydes with a Hypervalent Iodine(III) Catalyst under Visible-Light Photolysis: Successful Trapping with Electron-Deficient Olefins

  Shin A. Moteki; Asuka Usui; Sermadurai Selvakumar; Tiexin Zhang; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014年10月, 査読有り

  
• Effect of Bronsted acid co-catalyst in asymmetric conjugate addition of 3-aryloxindoles to maleimide under base-free phase-transfer conditions

  Seiji Shirakawa; Hiroki Makino; Tomofumi Yoshidome; Keiji Maruoka

  TETRAHEDRON, 2014年10月, 査読有り

  
• A Practical Approach for the Oxidation of Unactivated C-sp3-H Bonds with o-Nitro(diacetoxyiodo)benzene as an Efficient Hypervalent Iodine(III)-Based Oxidizing Agent

  Shin A. Moteki; Sermadurai Selvakumar; Tiexin Zhang; Asuka Usui; Keiji Maruoka

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2014年09月, 査読有り

  
• An organic thiyl radical catalyst for enantioselective cyclization

  Takuya Hashimoto; Yu Kawamata; Keiji Maruoka

  NATURE CHEMISTRY, 2014年08月, 査読有り

  
• Design and synthesis of a biphenyl-based chiral amino sulfonamide with high catalytic performance in Mannich reactions

  Taichi Kano; Hiroki Maruyama; Koichiro Akiyama; Keiji Maruoka

  TETRAHEDRON LETTERS, 2014年07月, 査読有り

  
• Asymmetric phase-transfer reactions under base-free neutral conditions

  Seiji Shirakawa; Keiji Maruoka

  TETRAHEDRON LETTERS, 2014年07月, 査読有り

  
• A Base-Free Neutral Phase-Transfer Reaction System

  Seiji Shirakawa; Lijia Wang; Rongjun He; Satoru Arimitsu; Keiji Maruoka

  CHEMISTRY-AN ASIAN JOURNAL, 2014年06月, 査読有り

  
• Catalytic Asymmetric Synthesis of 3,3 '-Diaryloxindoles as Triarylmethanes with a Chiral All-Carbon Quaternary Center: Phase-Transfer-Catalyzed SNAr Reaction

  Seiji Shirakawa; Kenta Koga; Takashi Tokuda; Kenichiro Yamamoto; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014年06月, 査読有り

  
• Synthesis of 3-Mono-Substituted Binaphthyl-Based Secondary Amine Catalysts via Monobromination of an Axially Chiral Dicarboxylic Acid Derivative

  Taichi Kano; Momotaro Takeda; Ryu Sakamoto; Keiji Maruoka

  JOURNAL OF ORGANIC CHEMISTRY, 2014年05月, 査読有り

  
• Asymmetric Phase-Transfer Catalysis with Homo- and Heterochiral Quaternary Ammonium Salts: A Theoretical Study

  Galina P. Petrova; Hai-Bei Li; Keiji Maruoka; Keiji Morokuma

  JOURNAL OF PHYSICAL CHEMISTRY B, 2014年05月, 査読有り

  
• Catalytic Asymmetric Alkylation of 3-Aryl- Substituted Oxindoles to give 3,3-Disubstituted Oxindoles under Phase- Transfer Conditions

  Fei Deng; Shin A. Moteki; Keiji Maruoka

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2014年04月, 査読有り

  
• Phase- Transfer- Catalyzed Asymmetric a- Arylation of a- Amino Acid Derivatives

  Seiji Shirakawa; Kenichiro Yamamoto; Takashi Tokuda; Keiji Maruoka

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2014年04月, 査読有り

  
• Practical Approach for Asymmetric Hydroxyamination of Aldehydes with in Situ Generated Nitrosocarbonyl Compounds: Application to One-Pot Synthesis of Chiral Allylamines

  Taichi Kano; Fumitaka Shirozu; Keiji Maruoka

  ORGANIC LETTERS, 2014年03月, 査読有り

  
• Amine-Catalyzed Asymmetric Cross-Aldol Reactions Using Heterofunctionalized Acetaldehydes as Nucleophiles

  Taichi Kano; Ryu Sakamoto; Keiji Maruoka

  ORGANIC LETTERS, 2014年02月, 査読有り

  
• Chiral Brønsted acid-catalyzed enantioselective addition of indoles to ketimines

  T. Kano; R. Takechi; R. Kobayashi; K. Maruoka

  Organic and Biomolecular Chemistry, 2014年02月, 査読有り

  
• Efficient asymmetric synthesis of spiro-2(3H)-furanones via phase-transfer-catalyzed alkynylation

  Xiangfei Wu; Seiji Shirakawa; Keiji Maruoka

  ORGANIC & BIOMOLECULAR CHEMISTRY, 2014年, 査読有り

  
• Catalytic enantioselective intramolecular cyclization of N-aryl diazoamides using a titanium-BINOLate complex

  Takuya Hashimoto; Kumiko Yamamoto; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2014年, 査読有り

  
• Remote chirality control based on the organocatalytic asymmetric Mannich reaction of α-thio acetaldehydes

  T. Kano; R. Sakamoto; K. Maruoka

  Chemical Communications, 2014年, 査読有り

  
• Kinetic resolution of axially chiral 2-amino-1,1′-biaryls by phase-transfer-catalyzed N-allylation

  S. Shirakawa; X. Wu; K. Maruoka

  Angewandte Chemie - International Edition, 2013年12月, 査読有り

  
• Metal-Free Enantioselective Hydroxyamination of Aldehydes with Nitrosocarbonyl Compounds Catalyzed by an Axially Chiral Amine

  Taichi Kano; Fumitaka Shirozu; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013年12月, 査読有り

  
• Phase-Transfer-Catalyzed Asymmetric Synthesis of Axially Chiral Anilides

  Kun Liu; Xiangfei Wu; S. B. Jennifer Kan; Seiji Shirakawa; Keiji Maruoka

  CHEMISTRY-AN ASIAN JOURNAL, 2013年12月, 査読有り

  
• In situ assembled boronate ester assisted chiral carboxylic acid catalyzed asymmetric trans-aziridinations

  Takuya Hashimoto; Alberto Osuna Gálvez; Keiji Maruoka

  Journal of the American Chemical Society, 2013年11月27日, 査読有り

  
• Chiral Organotin Hydride Catalyzed Enantioselective Radical Cyclization of Aldehydes

  Seiji Shirakawa; Asuka Usui; S. B. Jennifer Kan; Keiji Maruoka

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2013年11月, 査読有り

  
• Development of Synthetic Transformations by Control of Acid-Catalyzed Reactions of Diazocarbonyl Compounds

  Takuya Hashimoto; Keiji Maruoka

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2013年11月, 査読有り

  
• Axially Chiral Dicarboxylic Acid Catalyzed Activation of Quinone Imine Ketals: Enantioselective Arylation of Enecarbamates

  Takuya Hashimoto; Hiroki Nakatsu; Yuka Takiguchi; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013年10月, 査読有り

  
• Organocatalytic asymmetric synthesis of propargylamines with two adjacent stereocenters: Mannich-type reactions of in situ generated C-alkynyl imines with β-keto esters

  T. Kano; T. Yurino; K. Maruoka

  Angewandte Chemie - International Edition, 2013年10月, 査読有り

  
• Site-Selective Oxidation of Unactivated C-sp3-H Bonds with Hypervalent Iodine(III) Reagents

  Shin A. Moteki; Asuka Usui; Tiexin Zhang; Cesar R. Solorio Alvarado; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013年08月, 査読有り

  
• Contribution of cage-shaped structure of physalins to their mode of action in inhibition of NF-κB activation

  M. Ozawa; M. Morita; G. Hirai; S. Tamura; M. Kawai; A. Tsuchiya; K. Oonuma; K. Maruoka; M. Sodeoka

  ACS Medicinal Chemistry Letters, 2013年08月, 査読有り

  
• Catalytic Asymmetric Three-Component 1,3-Dipolar Cycloaddition of Aldehydes, Hydrazides, and Alkynes

  Takuya Hashimoto; Yuka Takiguchi; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013年08月, 査読有り

  
• Design of Chiral Bifunctional Quaternary Phosphonium Bromide Catalysts Possessing an Amide Moiety

  Seiji Shirakawa; Takashi Tokuda; Atsuyuki Kasai; Keiji Maruoka

  ORGANIC LETTERS, 2013年07月, 査読有り

  
• Production at the Curie Level of No-Carrier-Added 6-F-18-Fluoro-L-Dopa

  Lionel C. Libert; Xavier Franci; Alain R. Plenevaux; Takashi Ooi; Keiji Maruoka; Andre J. Luxen; Christian F. Lemaire

  JOURNAL OF NUCLEAR MEDICINE, 2013年07月, 査読有り

  
• Development of Axially Chiral Dicarboxylic Acid Catalyzed Asymmetric Transformations

  Takuya Hashimoto; Keiji Maruoka

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2013年05月, 査読有り

  
• Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-Transfer Conditions

  Taichi Kano; Yumi Hayashi; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013年05月, 査読有り

  
• Recent developments in asymmetric phase-transfer reactions

  Seiji Shirakawa; Keiji Maruoka

  Angewandte Chemie - International Edition, 2013年04月15日, 査読有り

  
• Efficient approach for the design of effective chiral quaternary phosphonium salts in asymmetric conjugate additions

  Seiji Shirakawa; Atsuyuki Kasai; Takashi Tokuda; Keiji Maruoka

  Chemical Science, 2013年04月02日, 査読有り

  
• Phase-transfer-catalyzed asymmetric conjugate cyanation of alkylidenemalonates with KCN in the presence of a Brønsted acid additive

  Y. Liu; S. Shirakawa; K. Maruoka

  Organic Letters, 2013年03月15日, 査読有り

  
• Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

  Takuya Hashimoto; Kazuki Sakata; Fumiko Tamakuni; Mark J. Dutton; Keiji Maruoka

  NATURE CHEMISTRY, 2013年03月, 査読有り

  
• Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

  Takuya Hashimoto; Kazuki Sakata; Fumiko Tamakuni; Mark J. Dutton; Keiji Maruoka

  NATURE CHEMISTRY, 2013年03月, 査読有り

  
• Reactions Triggered by Lewis Acidic Organoaluminum Species

  Yuki Naganawa; Keiji Maruoka

  MODERN ORGANOALUMINUM REAGENTS: PREPARATION, STRUCTURE, REACTIVITY AND USE, 2013年, 査読有り

  
• Enantioselective alkylation of 2-[(4-Chlorobenzyliden)amino]propanoic acid tert-butyl ester: Synthesis of (R)-2-amino-2-methyl-3-phenylpropanoic acid tert-butyl ester

  Seiji Shirakawa; Kenichiro Yamamoto; Kun Liu; Keiji Maruoka

  Organic Syntheses, 2013年, 査読有り

  
• Enantioselective alkylation of N-(Diphenylmethylene)glycinate tert-butyl ester: Synthesis of (R)-2-(Benzhydrylidenamino)-3-phenylpropanoic acid tert-butyl ester

  Seiji Shirakawa; Kenichiro Yamamoto; Kun Liu; Keiji Maruoka

  Organic Syntheses, 2013年, 査読有り

  
• Unusual anti-selective asymmetric conjugate addition of aldehydes to nitroalkenes catalyzed by a biphenyl-based chiral secondary amine

  Taichi Kano; Hisashi Sugimoto; Osamu Tokuda; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2013年, 査読有り

  
• Acid-Catalyzed In Situ Generation of Less Accessible or Unprecedented N-Boc Imines from N-Boc Aminals

  Taichi Kano; Taiga Yurino; Daisuke Asakawa; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013年, 査読有り

  
• Reactions triggered by lewis acidic organoaluminum species

  Yuki Naganawa; Keiji Maruoka

  Topics in Organometallic Chemistry, 2013年, 査読有り

  
• One-pot cross double-Mannich reaction of acetaldehyde catalyzed by a binaphthyl-based amino sulfonamide

  Taichi Kano; Ryu Sakamoto; Yukako Yamaguchi; Ken-ichi Itoh; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2013年, 査読有り

  
• Stereoselective synthesis of cyclic amino acids via asymmetric phase-transfer catalytic alkylation

  Taichi Kano; Takeshi Kumano; Ryu Sakamoto; Keiji Maruoka

  ORGANIC & BIOMOLECULAR CHEMISTRY, 2013年, 査読有り

  
• Unique properties of chiral biaryl-based secondary amine catalysts for asymmetric enamine catalysis

  Taichi Kano; Keiji Maruoka

  CHEMICAL SCIENCE, 2013年, 査読有り

  
• Catalytic Asymmetric Synthesis of 3-Substituted Proline Derivatives by Using Phase-Transfer-Catalyzed Conjugate Addition

  Yan Liu; Asuka Usui; Seiji Shirakawa; Keiji Maruoka

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2012年10月, 査読有り

  
• In Situ Preparation of Chiral Bifunctional Catalysts and Their Application to Asymmetric Michael Addition Reactions

  Shin A. Moteki; Peter Gakio Kirira; Satoru Arimitsu; Keiji Maruoka

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2012年09月, 査読有り

  
• Organic Chemistry: Another Ace in the Pack

  Sung Ho Kang; Keiji Maruoka; Deqing Zhang; Richard Threlfall

  ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2012年09月, 査読有り

  
• Axially chiral dicarboxylic acid catalyzed asymmetric semipinacol rearrangement of cyclic β-hydroxy-α-diazo esters

  T. Hashimoto; S. Isobe; C.K.A. Callens; K. Maruoka

  Tetrahedron, 2012年09月, 査読有り

  
• Powerful Amino Diol Catalyst for Effecting the Direct Asymmetric Conjugate Addition of Aldehydes to Acrylates

  Taichi Kano; Fumitaka Shirozu; Matsujiro Akakura; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012年09月, 査読有り

  
• Asymmetric Phase-Transfer Catalysis

  Seiji Shirakawa; Shin A. Moteki; Keiji Maruoka

  Modern Tools for the Synthesis of Complex Bioactive Molecules, 2012年08月30日, 査読有り

  
• The Proline-Catalyzed Mannich Reaction and the Advent of Enamine Catalysis

  Benjamin List; Sai-Hu Liao; Seiji Shirakawa; Keiji Maruoka; Liu-Zhu Gong; Wen-Jing Xiao

  Organic Chemistry - Breakthroughs and Perspectives, 2012年08月23日, 査読有り

  
• New Neutral Reaction System with Crown Ether-KCl Complexes in Aqueous Solution

  Seiji Shirakawa; Lijia Wang; Atsuyuki Kasai; Keiji Maruoka

  CHEMISTRY-A EUROPEAN JOURNAL, 2012年07月, 査読有り

  
• Kinetically Controlled One-Pot Formation of DEFGH-Rings of Type B Physalins through Domino-Type Transformations

  Masaki Morita; Go Hirai; Megumi Ohkubo; Hiroyuki Koshino; Daisuke Hashizume; Keiji Maruoka; Mikiko Sodeoka

  ORGANIC LETTERS, 2012年07月, 査読有り

  
• Efficient Asymmetric Synthesis of a Bicyclic Amino Acid as a Core Structure of Telaprevir

  Seiji Shirakawa; Yan Liu; Asuka Usui; Keiji Maruoka

  CHEMCATCHEM, 2012年07月, 査読有り

  
• New chiral phase-transfer catalysts possessing a 6,6′-bridged ring on the biphenyl unit: Application to the synthesis of α,α-dialkyl- α-amino acids

  Y. Kubota; S. Shirakawa; T. Inoue; K. Maruoka

  Tetrahedron Letters, 2012年07月, 査読有り

  
• Stereocontrolled Synthesis of Vicinal Diamines by Organocatalytic Asymmetric Mannich Reaction of N-Protected Aminoacetaldehydes: Formal Synthesis of (-)-Agelastatin A

  Taichi Kano; Ryu Sakamoto; Matsujiro Akakura; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012年05月, 査読有り

  
• Catalytic Asymmetric Synthesis of Axially Chiral o-lodoanilides by Phase-Transfer Catalyzed Alkylations

  Seiji Shirakawa; Kun Liu; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012年01月, 査読有り

  
• Organocatalysis: a web collection

  Keiji Maruoka; Benjamin List; Hisashi Yamamoto; Liu-Zhu Gong

  CHEMICAL COMMUNICATIONS, 2012年, 査読有り

  
• The direct catalytic asymmetric aldol reaction of α-substituted nitroacetates with aqueous formaldehyde under base-free neutral phase-transfer conditions

  S. Shirakawa; K. Ota; S.J. Terao; K. Maruoka

  Organic and Biomolecular Chemistry, 2012年, 査読有り

  
• Molecular recognition of ketomalonates by asymmetric aldol reaction of aldehydes with secondary-amine organocatalysts

  Taichi Kano; Sunhwa Song; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2012年, 査読有り

  この論文にアクセスする：

  
• Highly Diastereo- and Enantioselective Mannich Reactions of Synthetically Flexible Ketimines with Secondary Amine Organocatalysts

  Taichi Kano; Sunhwa Song; Yasushi Kubota; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012年, 査読有り

  
• An Achiral-Acid-Induced Switch in the Enantioselectivity of a Chiral cis-Diamine-Based Organocatalyst for Asymmetric Aldol and Mannich Reactions

  Shin A. Moteki; Jianwei Han; Satoru Arimitsu; Matsujiro Akakura; Keiji Nakayama; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012年, 査読有り

  
• A Catalytic Asymmetric Ugi-type Reaction With Acyclic Azomethine Imines

  Takuya Hashimoto; Hidenori Kimura; Yu Kawamata; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012年, 査読有り

  
• Designer chiral phase-transfer catalysts for green sustainable chemistry

  Keiji Maruoka

  PURE AND APPLIED CHEMISTRY, 2012年, 査読有り

  
• Efficient Organocatalytic Cross-Aldol Reaction between Aliphatic Aldehydes through Their Functional Differentiation

  Taichi Kano; Hisashi Sugimoto; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011年11月, 査読有り

  
• Phase-Transfer-Catalyzed Asymmetric Synthesis of 1,1-Disubstituted Tetrahydroisoquinolines

  Seiji Shirakawa; Kun Liu; Hironobu Ito; Thanh Nguyen Le; Keiji Maruoka

  ADVANCED SYNTHESIS & CATALYSIS, 2011年10月, 査読有り

  
• Catalytic Asymmetric Synthesis of Isoxazoline-N-oxides through Conjugate Addition-Cyclization under Phase-Transfer Conditions

  Taichi Kano; Akihiro Yamamoto; Sunhwa Song; Keiji Maruoka

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2011年10月, 査読有り

  
• Phase-transfer-catalyzed asymmetric alkylation with epoxy triflates as alkylating agents: Highly stereoselective synthesis of γ,δ-epoxy- α-amino acids

  S. Arimitsu; D. Kato; K. Maruoka

  Chemistry Letters, 2011年10月, 査読有り

  
• Generation and exploitation of acyclic azomethine imines in chiral Bronsted acid catalysis

  Takuya Hashimoto; Hidenori Kimura; Yu Kawamata; Keiji Maruoka

  NATURE CHEMISTRY, 2011年08月, 査読有り

  
• Award Address (Arthur C. Cope Scholar Awards (CSS) sponsored by The Arthur C. Cope Fund). Design of high-performance bifunctional organocatalysts for practical asymmetric synthesis

  Keiji Maruoka

  ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011年08月, 査読有り

  
• Synthetic Application and Structural Elucidation of Axially Chiral Dicarboxylic Acid: Asymmetric Mannich-type Reaction with Diazoacetate, (Diazomethyl)phosphonate, and (Diazomethyl)sulfone

  Takuya Hashimoto; Hidenori Kimura; Hiroki Nakatsu; Keiji Maruoka

  JOURNAL OF ORGANIC CHEMISTRY, 2011年08月, 査読有り

  
• Generation and exploitation of acyclic azomethine imines in chiral Brønsted acid catalysis

  T. Hashimoto; H. Kimura; Y. Kawamata; K. Maruoka

  Nature Chemistry, 2011年08月, 査読有り

  
• Modular synthesis of axially chiral 3,3′-disilyl dicarboxylic acids by silalactones

  T. Hashimoto; T. Takagaki; H. Kimura; K. Maruoka

  Chemistry - An Asian Journal, 2011年08月, 査読有り

  
• Desymmetrizing asymmetric ring expansion of cyclohexanones with α-diazoacetates catalyzed by chiral aluminum Lewis acid

  T. Hashimoto; Y. Naganawa; K. Maruoka

  Journal of the American Chemical Society, 2011年06月, 査読有り

  
• Chiral Brønsted acid-catalyzed asymmetric trisubstituted aziridine synthesis using α-diazoacyl oxazolidinones

  T. Hashimoto; H. Nakatsu; K. Yamamoto; K. Maruoka

  Journal of the American Chemical Society, 2011年06月, 査読有り

  
• Development of a practical synthetic method for n-tert-butoxycarbonyl α-ketimino esters

  T. Hashimoto; Y. Kumiko; K. Maruoka

  Chemistry Letters, 2011年03月, 査読有り

  
• Asymmetric trisubstituted aziridination of aldimines and ketimines using N-α-Diazoacyl camphorsultams

  T. Hashimoto; H. Nakatsu; K. Yamamoto; S. Watanabe; K. Maruoka

  Chemistry - An Asian Journal, 2011年02月, 査読有り

  
• Catalytic asymmetric alkynylation of C1-substituted C,N-cyclic azomethine imines by Cu ^I/chiral brønsted acid co-catalyst

  T. Hashimoto; M. Omote; K. Maruoka

  Angewandte Chemie - International Edition, 2011年, 査読有り

  
• Catalytic asymmetric synthesis of 1,1-disubstituted tetrahydro-β- carbolines by phase-transfer catalyzed alkylations

  S. Shirakawa; K. Liu; H. Ito; K. Maruoka

  Chemical Communications, 2011年, 査読有り

  
• The first example of the direct asymmetric conjugate addition of aldehydes to a methylenemalonate promoted by an axially chiral amino diol catalyst

  Taichi Kano; Fumitaka Shirozu; Koichi Tatsumi; Yasushi Kubota; Keiji Maruoka

  CHEMICAL SCIENCE, 2011年, 査読有り

  
• syn-Selective asymmetric cross-aldol reactions between aldehydes and glyoxylic acid derivatives catalyzed by an axially chiral amino sulfonamide

  Taichi Kano; Akira Noishiki; Ryu Sakamoto; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2011年, 査読有り

  
• Diastereo- and enantioselective conjugate addition of α-substituted nitroacetates to maleimides under base-free neutral phase-transfer conditions

  S. Shirakawa; S.J. Terao; R. He; K. Maruoka

  Chemical Communications, 2011年, 査読有り

  
• Asymmetric Neutral Amination of Nitroolefins Catalyzed by Chiral Bifunctional Ammonium Salts in Water-Rich Biphasic Solvent

  Lijia Wang; Seiji Shirakawa; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011年, 査読有り

  
• Asymmetric Inverse-Electron-Demand 1,3-Dipolar Cycloaddition of C,N-Cyclic Azomethine Imines: An Umpolung Strategy

  Takuya Hashimoto; Masato Omote; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011年, 査読有り

  
• Catalytic asymmetric syntheses of isoxazoline-N-oxides under phase-transfer conditions

  Taichi Kano; Akihiro Yamamoto; Sunhwa Song; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2011年, 査読有り

  この論文にアクセスする：

  
• Design of Structurally Rigid trans-Diamine-Based Tf-Amide Organocatalysts with a Dihydroanthracene Framework for Asymmetric Conjugate Additions of Heterosubstituted Aldehydes to Vinyl Sulfones

  Shin A. Moteki; Senmiao Xu; Satoru Arimitsu; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010年12月, 査読有り

  
• Development of Highly Selective Organic Reactions Catalyzed by Designed Amine Organocatalysts

  Taichi Kano; Keiji Maruoka

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2010年12月, 査読有り

  
• Catalytic asymmetric synthesis of cyclic amino acids and alkaloid derivatives: application to (+)-dihydropinidine and Selfotel synthesis

  Taichi Kano; Takeshi Kumano; Ryu Sakamoto; Keiji Maruoka

  CHEMICAL SCIENCE, 2010年10月, 査読有り

  
• Highly Practical Amino Acid and Alkaloid Synthesis Using Designer Chiral Phase Transfer Catalysts as High-Performance Organocatalysts

  Keiji Maruoka

  CHEMICAL RECORD, 2010年10月, 査読有り

  
• Erratum: Catalytic enantioselective 1,3-dipolar cycloaddition of C,N-cyclic azomethine imines with α,β-unsaturated aldehydes (Journal of the American Chemical Society (2010) 132 (40764077))

  T. Hashimoto; Y. Maeda; M. Omote; H. Nakatsu; K. Maruoka

  Journal of the American Chemical Society, 2010年08月25日, 査読有り

  
• Phase-Transfer-Catalyzed olefin isomerization/α-Alkylation of α-Alkynylcrotonates as a route for 1,4-Enynes

  T. Hashimoto; K. Sakata; K. Maruoka

  Advanced Synthesis and Catalysis, 2010年07月, 査読有り

  
• Asymmetric Phase-Transfer Catalysis for the Production of Non-Proteinogenic α-Amino Acids

  M. Ikunaka; K. Maruoka

  Asymmetric Catalysis on Industrial Scale: Challenges, Approaches and Solutions: Second Edition, 2010年06月08日, 査読有り

  
• Catalytic asymmetric synthesis of cyclic α-alkyl-amino acid derivatives by C,N-double alkylation

  T. Kano; R. Sakamoto; H. Mii; Y.-G. Wang; K. Maruoka

  Tetrahedron, 2010年06月, 査読有り

  
• Axially chiral dicarboxylic acid-catalyzed asymmetric imino aza-enamine reaction/oxidation as a Strecker reaction surrogate

  Takuya Hashimoto; Hidenori Kimura; Keiji Maruoka

  TETRAHEDRON-ASYMMETRY, 2010年05月, 査読有り

  
• Phase-transfer catalyzed asymmetric conjugate additions of β-ketoesters to acetylenic ketones

  Q. Lan; X. Wang; S. Shirakawa; K. Maruoka

  Organic Process Research and Development, 2010年05月, 査読有り

  
• Stereoselective synthesis of trisubstituted aziridines with N -α-diazoacyl camphorsultam

  T. Hashimoto; H. Nakatsu; S. Watanabe; K. Maruoka

  Organic Letters, 2010年04月, 査読有り

  
• Asymmetric Organocatalysis

  Allan J.B. Watson; David W.C. MacMillan; Yi Wang; Li Deng; Seiji Shirakawa; Keiji Maruoka

  Catalytic Asymmetric Synthesis: Third Edition, 2010年03月26日, 査読有り

  
• Catalytic enantioselective 1,3-dipolar cycloaddition of C,N-cyclic azomethine imines with α,β-unsaturated aldehydes

  T. Hashimoto; Y. Maeda; M. Omote; H. Nakatsu; K. Maruoka

  Journal of the American Chemical Society, 2010年03月, 査読有り

  
• Enantioselective Formal Alkenylations of Imines Catalyzed by Axially Chiral Dicarboxylic Acid Using Vinylogous Aza-Enamines

  Takuya Hashimoto; Hidenori Kimura; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010年, 査読有り

  
• Direct asymmetric bromination of aldehydes catalyzed by a binaphthyl-based secondary amine: highly enantio- and diastereoselective one-pot synthesis of bromohydrins

  Taichi Kano; Fumitaka Shirozu; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2010年, 査読有り

  
• Development of 5-silylethynyl-1,3-dioxolan-4-one as a new prochiral template for asymmetric phase-transfer catalysis

  Takuya Hashimoto; Kazuhiro Fukumoto; Naoyuki Abe; Kazuki Sakata; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2010年, 査読有り

  
• Metal-Free Direct Asymmetric Aminoxylation of Aldehydes Catalyzed by a Binaphthyl-Based Chiral Amine

  Taichi Kano; Haruka Mii; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010年, 査読有り

  
• Desymmetrizing asymmetric ring expansion: Stereoselective synthesis of 7-membered cyclic β-keto carbonyl compounds with an α-hydrogen

  T. Hashimoto; Y. Naganawa; K. Maruoka

  Chemical Communications, 2010年, 査読有り

  
• Phase-Transfer-Catalyzed Asymmetric Alkylation of alpha-Benzoyloxy-beta-keto Esters: Stereoselective Construction of Congested 2,3-Dihydroxycarboxylic Acid Esters

  Takuya Hashimoto; Keigo Sasaki; Kazuhiro Fukumoto; Yuichi Murase; Naoyuki Abe; Takashi Ooi; Keiji Maruoka

  CHEMISTRY-AN ASIAN JOURNAL, 2010年, 査読有り

  
• Chiral bifunctional phase transfer catalysts for asymmetric fluorination of β-keto esters

  X. Wang; Q. Lan; S. Shirakawa; K. Maruoka

  Chemical Communications, 2010年, 査読有り

  
• Enantioselective Base-Free Phase-Transfer Reaction in Water-Rich Solvent

  Rongjun He; Seiji Shirakawa; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009年11月, 査読有り

  
• Al Lewis acid-catalyzed regiodivergent 1,2-rearrangement of α-siloxy aldehydes: scope and mechanism

  K. Ohmatsu; T. Tanaka; T. Ooi; K. Maruoka

  Tetrahedron, 2009年09月, 査読有り

  
• Design of Sophisticated Bidentate Lewis Acids and Organocatalysts for Fine Organic Synthesis

  Keiji Maruoka

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2009年08月, 査読有り

  
• Stereoselective synthesis of α-alkyl-β-keto imides via asymmetric redox C-C bond formation between α-alkyl-α-diazocarbonyl compounds and aldehydes

  T. Hashimoto; H. Miyamoto; Y. Naganawa; K. Maruoka

  Journal of the American Chemical Society, 2009年08月, 査読有り

  
• Binaphthyl-modified quaternary phosphonium salts as chiral phase transfer catalysts: Application to asymmetric amination of β-keto esters

  R. He; K. Maruoka

  Synthesis, 2009年07月, 査読有り

  
• Highly efficient asymmetric amination of β-keto esters catalyzed by chiral quaternary ammonium bromides

  Q. Lan; X. Wang; R. He; C. Ding; K. Maruoka

  Tetrahedron Letters, 2009年07月, 査読有り

  
• Catalytic asymmetric synthesis of cyclic α-alkyl-amino acid derivatives having a tetrasubstituted α-carbon

  Y.-G. Wang; H. Mii; T. Kano; K. Maruoka

  Bioorganic and Medicinal Chemistry Letters, 2009年07月, 査読有り

  
• Stereoselective Construction of Seven-Membered Rings with an All-Carbon Quaternary Center by Direct Tiffeneau-Demjanov-type Ring Expansion

  Takuya Hashimoto; Yuki Naganawa; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009年05月, 査読有り

  
• Organocatalytic Approach to Enantioselective One-Pot Synthesis of Pyrrolidine, Hexahydropyrrolizine, and Octahydroindolizine Core Structures

  Yong-Gang Wang; Takeshi Kumano; Taichi Kano; Keiji Maruoka

  ORGANIC LETTERS, 2009年05月, 査読有り

  
• Rate Enhancement of Phase Transfer Catalyzed Conjugate Additions by CsCl

  Taichi Kano; Takeshi Kumano; Keiji Maruoka

  ORGANIC LETTERS, 2009年05月, 査読有り

  
• Enantioselectivity Switch in Direct Asymmetric Aminoxylation Catalyzed by Binaphthyl-Based Chiral Secondary Amines

  Taichi Kano; Akihiro Yamamoto; Fumitaka Shirozu; Keiji Maruoka

  SYNTHESIS-STUTTGART, 2009年05月, 査読有り

  
• Asymmetric Phase-Transfer Catalysis as a Practical Organocatalytic Method

  Keiji Maruoka

  SYNLETT, 2009年03月, 査読有り

  
• Direct Asymmetric Benzoyloxylation of Aldehydes Catalyzed by 2-Tritylpyrrolidine

  Taichi Kano; Haruka Mii; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009年03月, 査読有り

  
• Phase-transfer-catalyzed enantioselective alkylation of α-benzoyloxy-β-keto ester

  T. Hashimoto; K. Sasaki; K. Fukumoto; Y. Murase; T. Ooi; K. Maruoka

  Synlett, 2009年03月, 査読有り

  
• Enantioselective alkylation of α-fluoro-β-keto esters by asymmetric phase-transfer catalysis

  C. Ding; K. Maruoka

  Synlett, 2009年03月, 査読有り

  
• α-Chiral acetylenes having an all-carbon quaternary center: Phase transfer catalyzed enantioselective a alkylation of a-alkyl-a-alkynyl esters

  T. Hashimoto; K. Sakata; K. Maruoka

  Angewandte Chemie - International Edition, 2009年, 査読有り

  
• Catalytic enantioselective construction of all-carbon quaternary stereocenters by an organocatalytic Diels-Alder reaction of α-substituted α,β-unsaturated aldehydes

  T. Kano; Y. Tanaka; K. Osawa; T. Yurino; K. Maruoka

  Chemical Communications, 2009年, 査読有り

  
• A Designer Axially Chiral Amino Sulfonamide as an Efficient Organocatalyst for Direct Asymmetric anti-Selective Mannich Reactions and syn-Selective Cross-Aldol Reactions

  Taichi Kano; Yukako Yamaguchi; Keiji Maruoka

  CHEMISTRY-A EUROPEAN JOURNAL, 2009年, 査読有り

  
• Phosphonium Salts as Chiral Phase-Transfer Catalysts: Asymmetric Michael and Mannich Reactions of 3-Aryloxindoles

  Rongjun He; Changhua Ding; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009年, 査読有り

  
• Organocatalyzed direct asymmetric α-halogenation of carbonyl compounds

  M. Ueda; T. Kano; K. Maruoka

  Organic and Biomolecular Chemistry, 2009年, 査読有り

  
• A Designer Axially Chiral Amino Sulfonamide as an Efficient Organocatalyst for Direct Asymmetric Mannich Reactions of N-Boc-Protected Imines

  Taichi Kano; Yukako Yamaguchi; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009年, 査読有り

  
• Complete Switch of Product Selectivity in Asymmetric Direct Aldol Reaction with Two Different Chiral Organocatalysts from a Common Chiral Source

  Keiji Nakayama; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008年12月, 査読有り

  
• Design of an axially chiral dicarboxylic acid and its application in syntheses of optically active β-amino acids and β-amino phosphonic acid derivatives

  T. Hashimoto; K. Maruoka

  Synthesis, 2008年11月, 査読有り

  
• Trans-Selective Asymmetric Aziridination of Diazoacetamides and N-Boc Imines Catalyzed by Axially Chiral Dicarboxylic Acid

  Takuya Hashimoto; Nanase Uchiyama; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008年11月, 査読有り

  
• Asymmetric Phase-Transfer Catalysis

  Xisheng Wang; Quan Lan; Keiji Maruoka

  Handbook of Asymmetric Heterogeneous Catalysis, 2008年09月12日, 査読有り

  
• A tribute to Professor Ryoji Noyori on the occasion of his 70(th) birthday

  Joe P. Richmond; Martin Banwell; Daniel Bellus; Kilian Muniz; Koichi Narasaka; Yoshio Okamoto; Jun Okuda; Manfred Schlosser; Ichiro Shinkai; Kuniaki Tatsuta; Gerard van Koten; Xiao-Zeng You; Varinder K. Aggarwal; Takuzo Aida; Howard Alper; Chunli Bai; Kankan Bhattacharyya; Hans-Ulrich Blaser; Benoit Pugin; Felix Spindler; John M. Brown; Stephen L. Buchwald; Albert S. C. Chan; Naoto Chatani; Scott E. Denmark; Francois Diederich; Michael P. Doyle; Greg Fu; Akira Fujishima; Stephen Hanessian; Shunichi Hashimoto; Masahiko Hayashi; Tamejiro Hiyama; Peter Hofmann; Zhaomin Hou; Tsuneo Imamoto; Kunisuke Izawa; Eric Jacobsen; Tsutomu Katsuki; Sunggak Kim; Shu Kobayashi; Koichi Komatsu; Hidenori Kumobayashi; E. Peter Kuendig; Eun Lee; Walter Leitner; Steven V. Ley; Bruce Lipshutz; Lu Yixin; Keiji Maruoka; Shun-Ichi Murahashi; Shinji Murai; K. C. Nicolaou; Hisao Nishiyama; Takeshi Ohkuma; Tetsuo Ohta; Koichiro Oshima; Junzo Otera; Andreas Pfaltz; Manfred T. Reetz; Alfredo Ricci; Mitsuo Sawamoto; Michelangelo Scalone; K. Barry Sharpless; Roger Sheldon; Victor Snieckus; Mikiko Sodeoka; Makoto Tokunaga; Kiyoshi Tomioka; Yoshio Umezawa; Yasuhiro Uozumi; Chi-Huey Wong; Henry N. C. Wong; Yoshinori Yamamoto; Daoben Zhu

  ADVANCED SYNTHESIS & CATALYSIS, 2008年09月, 査読有り

  
• Facile synthesis of structurally diverse 3,3′-disubstituted 1,1′-binaphthyl-2,2′-diamines in optically pure forms

  T. Kano; Y. Tanaka; K. Osawa; T. Yurino; K. Maruoka

  Journal of Organic Chemistry, 2008年09月, 査読有り

  
• Practical asymmetric synthesis of α-methylserine derivatives under mild phase-transfer conditions

  K. Nakayama; K. Maruoka

  Tetrahedron Letters, 2008年09月, 査読有り

  
• Direct asymmetric aminoxylation reaction catalyzed by a binaphthyl-based chiral amino sulfonamide with high catalytic performance

  Taichi Kano; Akihiro Yamamoto; Keiji Maruoka

  TETRAHEDRON LETTERS, 2008年09月, 査読有り

  
• Practical aspects of recent asymmetric phase-transfer, catalysis

  Keiji Maruoka

  ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2008年07月, 査読有り

  
• Chiral Quaternary Ammonium Fluorides for Asymmetric Synthesis

  Keiji Maruoka; Seiji Shirakawa; Takashi Ooi

  Asymmetric Phase Transfer Catalysis, 2008年06月11日, 査読有り

  
• The Basic Principle of Phase-Transfer Catalysis and Some Mechanistic Aspects

  Takuya Hashimoto; Keiji Maruoka

  Asymmetric Phase Transfer Catalysis, 2008年06月11日, 査読有り

  
• Binaphthyl-and Biphenyl-Modified Chiral Phase-Transfer Catalysts for Asymmetric Synthesis

  Keiji Maruoka

  Asymmetric Phase Transfer Catalysis, 2008年06月11日, 査読有り

  
• Asymmetric Phase Transfer Catalysis

  Keiji Maruoka

  Asymmetric Phase Transfer Catalysis, 2008年06月11日, 査読有り

  
• Asymmetric imino aza-enamine reaction catalyzed by axially chiral dicarboxylic acid: Use of arylaldehyde N,N-dialkylhydrazones as acyl anion equivalent

  Takuya Hashimoto; Maya Hirose; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008年06月, 査読有り

  
• Direct asymmetric aminoxylation reaction catalyzed by axially chiral amino acids

  Taichi Kano; Akihiro Yamamoto; Haruka Mii; Jun Takai; Seiji Shirakawa; Keiji Maruoka

  CHEMISTRY LETTERS, 2008年03月, 査読有り

  
• Direct asymmetric iodination of aldehydes using an axially chiral bifunctional amino alcohol catalyst

  Taichi Kano; Mitsuhiro Ueda; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008年03月, 査読有り

  
• Combinatorial approach for the design of new, simplified chiral phase-transfer catalysts with high catalytic performance for practical asymmetric synthesis of α-alkyl-α-amino acids

  M. Kitamura; Y. Arimura; S. Shirakawa; K. Maruoka

  Tetrahedron Letters, 2008年03月, 査読有り

  
• Brønsted acid-catalyzed insertion of aryldiazoacetates to sp ² carbon-CHO bond: Facile construction of chiral all-carbon quaternary center

  T. Hashimoto; Y. Naganawa; K. Maruoka

  Journal of the American Chemical Society, 2008年02月27日, 査読有り

  
• anti-Selective direct asymmetric Mannich reactions catalyzed by chiral pyrrolidine-based amino sulfonamides

  Taichi Kano; Yoshio Hato; Akihiro Yamamoto; Keiji Maruoka

  TETRAHEDRON, 2008年02月, 査読有り

  
• Preface

  K. Maruoka

  Asymmetric Phase Transfer Catalysis, 2008年, 査読有り

  
• Complete switch of migratory aptitude in aluminum-catalyzed 1,2-rearrangement of differently α,α-disubstituted a-siloxy aldehydes

  K. Ohmatsu; T. Tanaka; T. Ooi; K. Maruoka

  Angewandte Chemie - International Edition, 2008年, 査読有り

  
• Asymmetric 1,3-dipolar cycloadditions of N-benzyl and N-diphenylmethyl nitrones and α,β-unsaturated aldehydes catalyzed by bis-titanium chiral lewis acids

  T. Hashimoto; M. Omote; Y. Hato; T. Kano; K. Maruoka

  Chemistry - An Asian Journal, 2008年, 査読有り

  
• Syntheses of manzacidins: a stage for the demonstration of synthetic methodologies

  Takuya Hashimoto; Keiji Maruoka

  ORGANIC & BIOMOLECULAR CHEMISTRY, 2008年, 査読有り

  
• Combinatorial design of simplified high-performance chiral phase-transfer catalysts for practical asymmetric synthesis of α-alkyl- and α,α-dialkyl-α-amino acids

  M. Kitamura; S. Shirakawa; Y. Arimura; X. Wang; K. Maruoka

  Chemistry - An Asian Journal, 2008年, 査読有り

  
• Binaphthyl-modified quaternary phosphonium salts as chiral phase-transfer catalysts: Asymmetric amination of β-keto esters

  R. He; X. Wang; T. Hashimoto; K. Maruoka

  Angewandte Chemie - International Edition, 2008年, 査読有り

  
• Design of chiral bifunctional secondary amine catalysts for asymmetric enamine catalysis

  Taichi Kano; Keiji Maruoka

  CHEMICAL COMMUNICATIONS, 2008年, 査読有り

  
• 6,6′-Substituent effect of BINOL in bis-titanium chiral Lewis acid catalyzed 1,3-dipolar cycloaddition of nitrones

  T. Hashimoto; M. Omote; K. Maruoka

  Organic and Biomolecular Chemistry, 2008年, 査読有り

  
• Recent development and application of chiral phase-transfer catalysts

  Takuya Hashimoto; Keiji Maruoka

  CHEMICAL REVIEWS, 2007年12月, 査読有り

  
• Asymmetric 1,3-dipolar cycloadditions of nitrones and methacrolein catalyzed by chiral bis-titanium lewis acid: A dramatic effect of N-substituent on nitrone

  Takuya Hashimoto; Masato Omote; Taichi Kano; Keiji Maruoka

  ORGANIC LETTERS, 2007年11月, 査読有り

  
• Practical stereoselective synthesis of β-branched aα-amino acids through efficient kinetic resolution in the phase-transfer-catalyzed asymmetric alkylations

  T. Ooi; D. Kato; K. Inamura; K. Ohmatsu; K. Maruoka

  Organic Letters, 2007年09月, 査読有り

  
• Preface

  Keiji Maruoka

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2007年08月, 査読有り

  
• Design of axially chiral dicarboxylic acid for asymmetric Mannich reaction of arylaldehyde N-Boc imines and diazo compounds

  Takuya Hashimoto; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007年08月, 査読有り

  
• Asymmetric organocatalytic oxy-Michael addition of alcohols to α,β-unsaturated aldehydes

  T. Kano; Y. Tanaka; K. Maruoka

  Tetrahedron, 2007年08月, 査読有り

  
• Asymmetric conjugate additions of α-substituted-α-cyanoacetates to acetylenic ketones by chiral phase transfer catalysis

  Q. Lan; X. Wang; K. Maruoka

  Tetrahedron Letters, 2007年07月, 査読有り

  
• Convenient preparation of chiral phase-transfer catalysts with conformationally fixed biphenyl core for catalytic asymmetric synthesis of α-alkyl- and α,α-dialkyl-α-amino acids: application to the short asymmetric synthesis of BIRT-377

  Y.-G. Wang; M. Ueda; X. Wang; Z. Han; K. Maruoka

  Tetrahedron, 2007年06月, 査読有り

  
• Design of chiral phase transfer catalyst with conformationally fixed biphenyl core: Application to asymmetric alkylation of glycine derivatives

  Yong-Gang Wang; Keiji Maruoka

  ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2007年05月, 査読有り

  
• Ammonium Ions as Chiral Templates

  Takashi Ooi; Keiji Maruoka

  Enantioselective Organocatalysis: Reactions and Experimental Procedures, 2007年04月12日, 査読有り

  
• Aliphatic and Aromatic Claisen Rearrangement

  Hayato Ichikawa; Keiji Maruoka

  The Claisen Rearrangement: Methods and Applications, 2007年03月15日, 査読有り

  
• Design of simple, yet very active chiral phase transfer catalysts for practical amino acid synthesis

  Keiji Maruoka

  ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007年03月, 査読有り

  
• Effects of aromatic substituents on binaphthyl-based chiral spiro-type ammonium salts in asymmetric phase-transfer reactions

  Taichi Kano; Quan Lan; Xisheng Wang; Keiji Maruoka

  ADVANCED SYNTHESIS & CATALYSIS, 2007年03月, 査読有り

  
• Catalytic asymmetric rearrangement of α,α-disubstituted α-siloxy aldehydes to optically active acyloins using axially chiral organoaluminum Lewis acids

  T. Ooi; K. Ohmatsu; K. Maruoka

  Journal of the American Chemical Society, 2007年03月, 査読有り

  
• New, chiral phase transfer catalysts for effecting asymmetric conjugate additions of α-alkyl-α-cyanoacetates to acetylenic esters

  X. Wang; M. Kitamura; K. Maruoka

  Journal of the American Chemical Society, 2007年02月, 査読有り

  
• Advantage of in situ generation of N-arylsulfonyl imines from α-amide sulfones in the phase-transfer-catalyzed asymmetric Strecker reaction

  T. Ooi; Y. Uematsu; J. Fujimoto; K. Fukumoto; K. Maruoka

  Tetrahedron Letters, 2007年02月, 査読有り

  
• Development and applications of C-2-symmetric, chiral, phase-transfer catalysts

  Takashi Ooi; Keiji Maruoka

  ALDRICHIMICA ACTA, 2007年, 査読有り

  
• Development and applications of C₂-symmetric, chiral, phase-transfer catalysts

  T. Ooi; K. Maruoka

  Aldrichimica Acta, 2007年, 査読有り

  
• Construction of stereodefined 1,1,2,2-tetrasubstituted cyclopropanes by acid catalyzed reaction of aryldiazoacetates and α-substituted acroleins

  T. Hashimoto; Y. Naganawa; T. Kano; K. Maruoka

  Chemical Communications, 2007年, 査読有り

  
• Design of bmaphthyl-modified symmetrical chiral phase-transfer catalysts: Substituent effect of 4,4′,6,6′-positions of binaphthyl rings in the asymmetric alkylation of a glycine derivative

  S. Shirakawa; M. Ueda; Y. Tanaka; T. Hashimoto; K. Maruoka

  Chemistry - An Asian Journal, 2007年, 査読有り

  
• exo-selective asymmetric Diels-Alder reaction catalyzed by diamine salts as organocatalysts

  Taichi Kano; Youhei Tanaka; Keiji Maruoka

  CHEMISTRY-AN ASIAN JOURNAL, 2007年, 査読有り

  
• Recent advances in asymmetric phase-transfer catalysis

  Takashi Ooi; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007年, 査読有り

  
• syn-selective and enantioselective direct cross-aldol reactions between aldehydes catalyzed by an axially chiral amino sulfonamide

  Taichi Kano; Yukako Yamaguchi; Youhei Tanaka; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007年, 査読有り

  
• Design of C-2-symmetric chiral phase-transfer catalysts for practical asymmetric synthesis

  Keiji Maruoka

  CHIMIA, 2007年, 査読有り

  
• Design of chiral organocatalysts for practical asymmetric synthesis of amino acid derivatives

  Keiji Maruoka; Takashi Ooi; Taichi Kano

  CHEMICAL COMMUNICATIONS, 2007年, 査読有り

  
• Asymmetric phase-transfer catalysis of homo- and heterochiral quaternary ammonium salts: development and application of conformationally flexible chiral phase-transfer catalysts

  Takashi Ooi; Yukitaka Uematsu; Minoru Kameda; Keiji Maruoka

  TETRAHEDRON, 2006年12月, 査読有り

  
• Design of a C-2-symmetric chiral pyrrolidine-based amino sulfonamide: application to anti-selective direct asymmetric Mannich reactions

  Taichi Kano; Yoshio Hato; Keiji Maruoka

  TETRAHEDRON LETTERS, 2006年11月, 査読有り

  
• Synthesis of a biphenyl-based axially chiral amino acid as a highly efficient catalyst for the direct asymmetric aldol reaction

  Taichi Kano; Osamu Tokuda; Keiji Maruoka

  TETRAHEDRON LETTERS, 2006年10月, 査読有り

  
• ORGN 297-Designer chiral phase transfer catalysts for practical asymmetric synthesis

  Keiji Maruoka

  ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006年09月, 査読有り

  
• Asymmetric synthesis of α-acyl-γ-butyrolactones possessing all-carbon quaternary stereocenters by phase-transfer-catalyzed alkylation

  T. Ooi; T. Miki; K. Fukumoto; K. Maruoka

  Advanced Synthesis and Catalysis, 2006年08月, 査読有り

  
• Design of a binaphthyl-based axially chiral amino acid as an organocatalyst for direct asymmetric aldol reactions

  Taichi Kano; Osamu Tokuda; Jun Takai; Keiji Maruoka

  CHEMISTRY-AN ASIAN JOURNAL, 2006年07月, 査読有り

  
• Highly efficient trialkylsilylcyanation of aldehydes, ketones and imines catalyzed by a nucleophilic N-heterocyclic carbene

  Taichi Kano; Kouji Sasaki; Teppei Konishi; Haruka Mii; Keiji Maruoka

  TETRAHEDRON LETTERS, 2006年07月, 査読有り

  
• exo-Selective asymmetric Diels-Alder reaction catalyzed by diamine salts as organocatalysts

  Taichi Kano; Youhei Tanaka; Keiji Maruoka

  ORGANIC LETTERS, 2006年06月, 査読有り

  
• Direct asymmetric hydroxyamination reaction catalyzed by an axially chiral secondary amine catalyst

  Taichi Kano; Mitsuhiro Ueda; Jun Takai; Keiji Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006年05月, 査読有り

  
• Organocatalytic oxy-Michael addition of alcohols to α,β-unsaturated aldehydes

  T. Kano; Y. Tanaka; K. Maruoka

  Tetrahedron Letters, 2006年05月, 査読有り

  
• Phase-Transfer Catalysis

  Takashi Ooi; Keiji Maruoka

  Quaternary Stereocenters: Challenges and Solutions for Organic Synthesis, 2006年04月05日, 査読有り

  
• Asymmetric Strecker reaction of aldimines using aqueous potassium cyanide by phase-transfer catalysis of chiral quaternary ammonium salts with a tetranaphthyl backbone

  T Ooi; Y Uematsu; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006年03月, 査読有り

  
• Highly enantioselective monoalkylation of p-chlorobenzaldehyde imine of glycine tert-butyl ester under mild phase-transfer conditions

  T Ooi; Y Arimura; Y Hiraiwa; LM Yuan; T Kano; T Inoue; J Matsumoto; K Maruoka

  TETRAHEDRON-ASYMMETRY, 2006年02月, 査読有り

  
• Enantioselective 1,3-dipolar cycloaddition reaction between diazoacetates and α-substituted acroleins: Total synthesis of manzacidin A

  T. Kano; T. Hashimoto; K. Maruoka

  Journal of the American Chemical Society, 2006年02月, 査読有り

  
• Design of chiral tin(IV) aryloxide as a mild Lewis acid catalyst for enantioselective Diels-Alder reaction

  T Kano; T Konishi; S Konishi; K Maruoka

  TETRAHEDRON LETTERS, 2006年02月, 査読有り

  
• Highly diastereo- and enantioselective formal conjugate addition of nitroalkanes to nitroalkenes by chiral ammonium bifluoride catalysis

  Takashi Ooi; Saki Takada; Kanae Doda; Keiji Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006年, 査読有り

  
• Construction of enantiomerically enriched tertiary α- hydroxycarboxylic acid derivatives by phase-transfer-catalyzed asymmetric alkylation of diaryloxazolidin-2,4-diones

  T. Ooi; K. Fukumoto; K. Maruoka

  Angewandte Chemie - International Edition, 2006年, 査読有り

  
• Asymmetric Michael addition of silyl nitronates to cyclic α,β-unsaturated ketones catalyzed by chiral quaternary ammonium bifluorides: Isolation and selective functionalization of enol silyl ethers of optically active γ-nitro ketones

  T. Ooi; K. Doda; S. Takada; K. Maruoka

  Tetrahedron Letters, 2006年01月, 査読有り

  
• Convenient preparation of highly active phase-transfer catalyst for catalytic asymmetric synthesis of α-alkyl- and α,α-dialkyl- α-amino acids: Application to the short asymmetric synthesis of BIRT-377

  Z. Han; Y. Yamaguchi; M. Kitamura; K. Maruoka

  Tetrahedron Letters, 2005年12月, 査読有り

  
• anti-Selective direct asymmetric Mannich reactions catalyzed by axially chiral amino sulfonamide as an organocatalyst

  T Kano; Y Yamaguchi; O Tokuda; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005年11月, 査読有り

  
• N-spiro chiral quaternary ammonium bromide catalyzed diastereo- and enantioselective conjugate addition of nitroalkanes to cyclic α,β-unsaturated ketones under phase-transfer conditions

  T. Ooi; S. Takada; S. Fujioka; K. Maruoka

  Organic Letters, 2005年11月, 査読有り

  
• A practical synthesis of (S)-2-Cyclohexyl-2-phenylglycolic acid via organocatalytic asymmetric construction of a tetrasubstituted carbon center

  O Tokuda; T Kano; WG Gao; T Ikemoto; K Maruoka

  ORGANIC LETTERS, 2005年10月, 査読有り

  
• Asymmetric 1,3-dipolar cycloaddition reaction of nitrones and acrolein with a bis-titanium catalyst as chiral lewis acid

  T Kano; T Hashimoto; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005年08月, 査読有り

  
• Design of next-generation chiral acid-base catalysts and application to fine organic synthesis

  K Maruoka

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2005年07月, 査読有り

  
• Importance of chiral phase-transfer catalysts with dual functions in obtaining high enantioselectivity in the Michael reaction of malonates and chalcone derivatives

  T Ooi; D Ohara; K Fukumoto; K Maruoka

  ORGANIC LETTERS, 2005年07月, 査読有り

  
• Chiral designer phase-transfer catalysts for practical asymmetric synthesis

  K Maruoka

  PURE AND APPLIED CHEMISTRY, 2005年07月, 査読有り

  
• Highly enantioselective phase-transfer-catalyzed alkylation of protected α-amino acid amides toward practical asymmetric synthesis of vicinal diamines, α-amino ketones, and α-amino alcohols

  T. Ooi; M. Takeuchi; D. Kato; Y. Uematsu; E. Tayama; D. Sakai; K. Maruoka

  Journal of the American Chemical Society, 2005年04月, 査読有り

  
• Enantioselective acylation of secondary alcohols catalyzed by chiral N-heterocyclic carbenes

  T Kano; K Sasaki; K Maruoka

  ORGANIC LETTERS, 2005年03月, 査読有り

  
• Powerful chiral phase-transfer catalysts for the asymmetric synthesis of α-alkyl- and α,α-dialkyl-α-amino acids

  M. Kitamura; S. Shirakawa; K. Maruoka

  Angewandte Chemie - International Edition, 2005年02月, 査読有り

  
• A case of Coats' disease in a low-birth-weight infant

  K Maruoka; M Yamamoto; H Fujita; Y Tahara; T Ishibashi

  OPHTHALMOLOGICA, 2005年, 査読有り

  
• Asymmetric synthesis of functionalized aza-cyclic amino acids with quaternary stereocenters by a phase-transfer-catalyzed alkylation strategy

  T Ooi; T Miki; K Maruoka

  ORGANIC LETTERS, 2005年01月, 査読有り

  
• Dramatic rate enhancement of asymmetric phase-transfer-catalyzed alkylations

  S Shirakawa; K Yamamoto; M Kitamura; T Ooi; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005年, 査読有り

  
• Design of an axially chiral amino acid with a binaphthyl backbone as an organocatalyst for a direct asymmetric aldol reaction

  T Kano; J Takai; O Tokuda; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005年, 査読有り

  
• Organoaluminum-mediated selective 1,2-rearrangement of γ,γ- disubstituted γ-amino α,β-unsaturated carbonyl compounds leading to unsymmetrically substituted pyrroles

  T. Ooi; K. Ohmatsu; H. Ishii; A. Saito; K. Maruoka

  Tetrahedron Letters, 2004年12月, 査読有り

  
• Highly enantioselective conjugate addition of nitroalkanes to alkylidenemalonates using efficient phase-transfer catalysis of N-spiro chiral ammonium bromides

  T Ooi; S Fujioka; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004年09月, 査読有り

  
• anti-Selective asymmetric synthesis of beta-hydroxy-alpha-amino acid esters by the in situ generated chiral quaternary ammonium fluoride-catalyzed Mukaiyama-type aldol reaction

  T Ooi; M Taniguchi; K Doda; K Maruoka

  ADVANCED SYNTHESIS & CATALYSIS, 2004年08月, 査読有り

  
• anti-Selective asymmetric synthesis of β-hydroxy-α-amino acid esters by the in situ generated chiral quaternary ammonium fluoride-catalyzed mukaiyama-type aldol reaction

  T. Ooi; M. Taniguchi; K. Doda; K. Maruoka

  Advanced Synthesis and Catalysis, 2004年08月, 査読有り

  
• Asymmetric organocatalysis of structurally well-defined chiral quaternary ammonium fluorides

  T Ooi; K Maruoka

  ACCOUNTS OF CHEMICAL RESEARCH, 2004年08月, 査読有り

  
• Development of highly diastereo- and enantioselective direct asymmetric aldol reaction of a glycinate Schiff base with aldehydes catalyzed by chiral quaternary ammonium salts

  T Ooi; M Kameda; M Taniguchi; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004年08月, 査読有り

  
• Evaluation of the relationship between the catalyst structure and regio- as well as stereoselectivity in the chiral ammonium bifluoride-catalyzed asymmetric addition of silyl nitronates to α,β-unsaturated aldehydes

  T. Ooi; K. Morimoto; K. Doda; K. Maruoka

  Chemistry Letters, 2004年07月, 査読有り

  
• Catalytic asymmetric synthesis of a nitrogen analogue of dialkyl tartrate by direct Mannich reaction under phase-transfer conditions

  T Ooi; M Kameda; J Fujii; K Maruoka

  ORGANIC LETTERS, 2004年07月, 査読有り

  
• Design of new chiral phase-transfer catalysts with dual functions for highly enantioselective epoxidation of α,β-unsaturated ketones

  T. Ooi; D. Ohara; M. Tamura; K. Maruoka

  Journal of the American Chemical Society, 2004年06月, 査読有り

  
• Efficient asymmetric catalysis of chiral organoaluminum complex for enantioselective ene reactions of aldehydes

  T Ooi; K Ohmatsu; D Uraguchi; K Maruoka

  TETRAHEDRON LETTERS, 2004年05月, 査読有り

  
• Development of a recyclable fluorous chiral phase-transfer catalyst: Application to the catalytic asymmetric synthesis of α-amino acids

  S. Shirakawa; Y. Tanaka; K. Maruoka

  Organic Letters, 2004年04月, 査読有り

  
• Design of new polyamine-based chiral phase-transfer catalysts for the enantioselective synthesis of phenylalanine

  T Kano; S Konishi; S Shirakawa; K Maruoka

  TETRAHEDRON-ASYMMETRY, 2004年04月, 査読有り

  
• (2,7-disubstituted-1,8-biphenylenedioxy)bis(dimethylaluminum) as bidentate organoaluminum Lewis acids: Elucidation and synthetic utility of the double electrophilic activation phenomenon

  T Ooi; M Takahashi; M Yamada; E Tayama; K Omoto; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004年02月, 査読有り

  
• Highly enantioselective alkylation of glycine methyl and ethyl ester derivatives under phase-transfer conditions: its synthetic advantage

  T Ooi; Y Uematsu; K Maruoka

  TETRAHEDRON LETTERS, 2004年02月, 査読有り

  
• Meerwein-Ponndorf-Verley alkynylation of aldehydes: Essential modification of aluminium alkoxides for rate acceleration and asymmetric synthesis

  T Ooi; T Miura; K Ohmatsu; A Saito; K Maruoka

  ORGANIC & BIOMOLECULAR CHEMISTRY, 2004年, 査読有り

  
• Enantioselective Synthesis of α-Amino Acids by Chiral Phase-Transfer Catalysis

  T. Ooi; K. Maruoka

  Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 2003年12月, 査読有り

  
• A new N-spiro C-2-symmetric chiral quaternary ammonium bromide consisting of 4,6-disubstituted biphenyl subunit as an efficient chiral phase-transfer catalyst

  T Ooi; Y Kubota; K Maruoka

  SYNLETT, 2003年09月, 査読有り

  
• A scalable synthesis of (R)-3,5-dihydro-4H-dinaphth[2,1-c:1′2′ -e]azepine

  M. Ikunaka; K. Maruoka; Y. Okuda; T. Ooi

  Organic Process Research and Development, 2003年09月, 査読有り

  
• Catalytic asymmetric allylation of aldehydes and related reactions with bis(((S)-binaphthoxy)(isopropoxy)titanium) oxide as a μ-oxo-type chiral Lewis acid

  H. Hanawa; D. Uraguchi; S. Konishi; T. Hashimoto; K. Maruoka

  Chemistry - A European Journal, 2003年09月, 査読有り

  
• Fluorotetraphenylbismuth: A new reagent for efficient regioselective α-phenylation of carbonyl compounds

  T. Ooi; R. Goto; K. Maruoka

  Journal of the American Chemical Society, 2003年09月, 査読有り

  
• Enantioselective amino acid synthesis by chiral phase-transfer catalysis

  K Maruoka; T Ooi

  CHEMICAL REVIEWS, 2003年08月, 査読有り

  
• Highly enantioselective Michael addition of silyl nitronates to α,β-unsaturated aldehydes catalyzed by designer chiral ammonium bifluorides: Efficient access to optically active γ-nitro aldehydes and their enol silyl ethers

  T. Ooi; K. Doda; K. Maruoka

  Journal of the American Chemical Society, 2003年07月, 査読有り

  
• Symmetrical 4,4′,6,6′-tetraarylbinaphthyl-substituted ammonium bromide as a new, chiral phase-transfer catalyst

  T. Hashimoto; Y. Tanaka; K. Maruoka

  Tetrahedron Asymmetry, 2003年06月, 査読有り

  
• Catalytic asymmetric methallylation and propargylation of aldehydes with bis(((S)-binaphthoxy)(isopropoxy)titanium) oxide

  S Konishi; H Hanawa; K Maruoka

  TETRAHEDRON-ASYMMETRY, 2003年06月, 査読有り

  
• New, improved procedure for the synthesis of structurally diverse N-spiro C-2-symmetric chiral quaternary ammonium bromides

  T Ooi; Y Uematsu; K Maruoka

  JOURNAL OF ORGANIC CHEMISTRY, 2003年05月, 査読有り

  
• Design of N-spiro C₂-symmetric chiral quaternary ammonium bromides as novel chiral phase-transfer catalysts: Synthesis and application to practical asymmetric synthesis of α-amino acids

  T. Ooi; M. Kameda; K. Maruoka

  Journal of the American Chemical Society, 2003年04月, 査読有り

  
• Substituent effect of binaphthyl-modified spiro-type chiral phase-transfer catalysts

  T Hashimoto; K Maruoka

  TETRAHEDRON LETTERS, 2003年04月, 査読有り

  
• Isopropoxyaluminum 1,1′-biphenyl-2-oxy-2′-perfluorooctanesulfonamide as a catalyst for Tishchenko reaction

  T. Ooi; K. Ohmatsu; K. Sasaki; T. Miura; K. Maruoka

  Tetrahedron Letters, 2003年04月, 査読有り

  
• Asymmetric skeletal rearrangement of symmetrically α,α-disubstituted α-amino aldehydes: A new entry to optically active α-hydroxy ketones

  T. Ooi; A. Saito; K. Maruoka

  Journal of the American Chemical Society, 2003年03月, 査読有り

  
• Designer chiral quaternary ammonium bifluorides as an efficient catalyst for asymmetric nitroaldol reaction of silyl nitronates with aromatic aldehydes

  T Ooi; K Doda; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003年02月, 査読有り

  
• Bis(((S)-binaphthoxy)(isopropoxy)titanium) oxide as a μ-oxo-type chiral Lewis acid: Application to catalytic asymmetric allylation of aldehydes

  H. Hanawa; T. Hashimoto; K. Maruoka

  Journal of the American Chemical Society, 2003年02月, 査読有り

  
• Highly enantioselective construction of quaternary stereocenters on beta-keto esters by phase-transfer catalytic asymmetric alkylation and Michael reaction (vol 42, pg 3796, 2003)

  K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003年, 査読有り

  
• Bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]dimethylaluminum catalyst for effecting Tishchenko reaction

  S Shirakawa; J Takai; K Sasaki; T Miura; K Maruoka

  HETEROCYCLES, 2003年01月, 査読有り

  
• Practical asymmetric synthesis of vicinal diamines through the catalytic highly enantioselective alkylation of glycine amide derivatives

  T Ooi; D Sakai; M Takeuchi; E Tayama; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003年, 査読有り

  
• Highly enantioselective construction of quaternary stereocenters on β-keto esters by phase-transfer catalytic asymmetric alkylation and Michael reaction

  T. Ooi; T. Miki; M. Taniguchi; M. Shiraishi; M. Takeuchi; K. Maruoka

  Angewandte Chemie - International Edition, 2003年, 査読有り

  
• Synthetic utility of bowl-shaped tris(2,6-diphenylbenzyl)silyl glyoxylate as a stable glyoxylate: application to highly diastereoselective aldol reactions

  S Shirakawa; K Maruoka

  TETRAHEDRON LETTERS, 2003年01月, 査読有り

  
• Highly stereoselective N-terminal functionalization of small peptides by chiral phase-transfer catalysis

  T Ooi; E Tayama; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003年, 査読有り

  
• Catalytic enantioselective allylation of ketones with novel chiral bis-titanium(IV) catalyst

  S Kii; K Maruoka

  CHIRALITY, 2003年01月, 査読有り

  
• Activation of ether functionality of allyl vinyl ethers by chiral bis(organoaluminum) Lewis acids: application to asymmetric Claisen rearrangement

  E Tayama; A Saito; T Ooi; K Maruoka

  TETRAHEDRON, 2002年10月, 査読有り

  
• Practical Oppenauer (OPP) oxidation of alcohols with a modified aluminum catalyst

  T Ooi; H Otsuka; T Miura; H Ichikawa; K Maruoka

  ORGANIC LETTERS, 2002年08月, 査読有り

  
• Asymmetric induction in the Neber rearrangement of simple ketoxime sulfonates under phase-transfer conditions: Experimental evidence for the participation of an anionic pathway

  T Ooi; M Takahashi; K Doda; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002年07月, 査読有り

  
• Catalytic, enantioselective hetero-Diels-Alder reaction with novel, chiral bis-titanium(IV) catalyst

  S Kii; T Hashimoto; K Maruoka

  SYNLETT, 2002年06月, 査読有り

  
• Evaluation of the Efficiency of the Chiral Quaternary Ammonium Salt β-Np-NAS-Br in the Organic-Aqueous Phase-Transfer Alkylation of a Protected Glycine Derivative

  T. Ooi; Y. Uematsu; K. Maruoka

  Advanced Synthesis and Catalysis, 2002年05月, 査読有り

  
• Unusually stable silyl ketones with bowl-shaped tris(2,6-diphenylbenzyl)silyl group for various nucleophilic attacks and alpha-deprotonation

  S Shirakawa; N Komatsu; A Iwasaki; K Maruoka

  SYNLETT, 2002年04月, 査読有り

  
• Chemoselective reduction of saturated aldehydes and ketones over unsaturated carbonyls with bowl-shaped tris(2,6-diphenylbenzyl)tin hydride

  K Sasaki; N Komatsu; S Shirakawa; K Maruoka

  SYNLETT, 2002年04月, 査読有り

  
• Unusually stable silyl ketones with bowl-shaped tris(2,6-diphenylbenzyl)silyl group for various nucleophilic attacks and α-deprotonation

  S. Shirakawa; N. Komatsu; A. Iwasaki; K. Maruoka

  Synlett, 2002年04月, 査読有り

  
• Catalytic Meerwein-Ponndorf-Verley (MPV) and Oppenauer (OPP) reactions: Remarkable acceleration of the hydride transfer by powerful bidentate aluminum alkoxides

  T Ooi; T Miura; Y Itagaki; Ichikawa, I; K Maruoka

  SYNTHESIS-STUTTGART, 2002年02月, 査読有り

  
• A highly chemoselective Mukaiyama aldol reaction of saturated aldehyde over unsaturated aldehyde with enol tris(2,6-diphenylbenzyl)silyl ether

  S Shirakawa; K Maruoka

  TETRAHEDRON LETTERS, 2002年02月, 査読有り

  
• Prospective evaluation of suspected stenoocclusive disease of the intracranial artery: Combined MR angiography and CT angiography compared with digital subtraction angiography

  T Hirai; Y Korogi; K Ono; M Nagano; K Maruoka; S Uemura; M Takahashi

  AMERICAN JOURNAL OF NEURORADIOLOGY, 2002年01月, 査読有り

  
• Practical approach for catalytic asymmetric allylation of aldehydes with a chiral bidentate titanium(IV) complex (vol 42, pg 1935, 2001)

  S Kii; K Maruoka

  TETRAHEDRON LETTERS, 2002年01月, 査読有り

  
• Bis-zirconium and bis-hafnium catalysts for the strong activation of carbonyl substrates (vol 41, pg 5543, 2000)

  H Hanawa; S Kii; N Asao; K Maruoka

  TETRAHEDRON LETTERS, 2002年01月, 査読有り

  
• Conformationally flexible, chiral quaternary ammonium bromides for asymmetric phase-transfer catalysis

  T Ooi; Y Uematsu; M Kameda; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002年, 査読有り

  
• Direct asymmetric aldol reactions of glycine Schiff base with aldehydes catalyzed by chiral quaternary ammonium salts

  T Ooi; M Taniguchi; M Kameda; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002年, 査読有り

  
• Bidentate Lewis acid catalysts in asymmetric synthesis

  K Maruoka

  PURE AND APPLIED CHEMISTRY, 2002年01月, 査読有り

  
• Esterification of carboxylic acids catalyzed by in situ generated tetraalkylammonium fluorides

  T Ooi; H Sugimoto; K Doda; K Maruoka

  TETRAHEDRON LETTERS, 2001年12月, 査読有り

  
• A convergent, homochiral bis(amino alcohol) for obtaining high enantioselectivity in the addition of diethylzinc to aldehydes

  T Ooi; A Saito; K Maruoka

  CHEMISTRY LETTERS, 2001年11月, 査読有り

  
• Design of new, chiral phase-transfer catalysts for practical, catalytic asymmetric synthesis

  K Maruoka

  JOURNAL OF FLUORINE CHEMISTRY, 2001年11月, 査読有り

  
• Erratum: Tris(2,6-diphenylbenzyl)amine (TDA) and tris(2,6-diphenylbenzyl)phosphine (TDP) with unique bowl-shaped structures: Synthetic application of functionalized TDA to chemoselective silylation of benzylic alcohols (Tetrahedron Letters (2001) 42 (5467

  M. Naiki; S. Shirakawa; K. Kon-i; Y. Kondo; K. Maruoka

  Tetrahedron Letters, 2001年10月29日, 査読有り

  
• Concise, catalytic asymmetric synthesis of tetrahydroisoquinoline- and dihydroisoquinoline-3-carboxylic acid derivatives

  T Ooi; M Takeuchi; K Maruoka

  SYNTHESIS-STUTTGART, 2001年08月, 査読有り

  
• Tris(2,6-diphenylbenzyl)amine (TDA) and tris(2,6-diphenylbenzyl)phosphine (TDP) with unique bowl-shaped structures: synthetic application of functionalized TDA to chemoselective silylation of benzylic alcohols

  M Naiki; S Shirakawa; K Kon-i; Y Kondo; K Maruoka

  TETRAHEDRON LETTERS, 2001年08月, 査読有り

  
• Advantage of anaerobic conditions in the highly enantioselective synthesis of alpha,alpha-dialkyl-alpha-amino acids by chiral phase-transfer catalysis

  T Ooi; M Takeuchi; D Ohara; K Maruoka

  SYNLETT, 2001年07月, 査読有り

  
• Advantage of anaerobic conditions in the highly enantioselective synthesis of α,α-dialkyl-α-amino acids by chiral phase-transfer catalysis

  T. Ooi; M. Takeuchi; D. Ohara; K. Maruoka

  Synlett, 2001年07月, 査読有り

  
• o-(o-iodophenyl)phenylselenenyl ethers/t-BuLi system as an alkyllithium equivalent with structural variations

  T Ooi; D Sakai; M Takada; N Komatsu; K Maruoka

  SYNLETT, 2001年06月, 査読有り

  
• Distinct advantage of the in situ generation of quaternary ammonium fluorides under phase-transfer conditions toward catalytic asymmetric synthesis

  T Ooi; K Doda; K Maruoka

  ORGANIC LETTERS, 2001年05月, 査読有り

  
• Utilization of o-[(E)-2-trimethylsilyl-2-iodovinyl]phenylthioderivatives as carbon radical precursors by anchimeric approach

  T Ooi; M Furuya; D Sakai; Y Hokke; K Maruoka

  SYNLETT, 2001年04月, 査読有り

  
• Bidentate Lewis acids for organic synthesis

  K Maruoka

  CATALYSIS TODAY, 2001年03月, 査読有り

  
• Practical approach for catalytic asymmetric allylation of aldehydes with a chiral bidentate titanium(IV) complex

  S Kii; K Maruoka

  TETRAHEDRON LETTERS, 2001年03月, 査読有り

  
• Facile conversion of trialkylsilyl esters to alkyl esters mediated by tetrabutylammonium fluoride trihydrate

  T Ooi; H Sugimoto; K Maruoka

  HETEROCYCLES, 2001年02月, 査読有り

  
• Rapid and mild generation of carbon radicals from o(o-iodophenyl)phenylthio derivatives by an anchimeric approach

  T Ooi; M Furuya; D Sakai; K Maruoka

  ADVANCED SYNTHESIS & CATALYSIS, 2001年02月, 査読有り

  
• Bowl-shaped tris(2,6-diphenylbenzyl)tin hydride: A unique reducing agent for radical and ionic chemistry

  K Sasaki; Y Kondo; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001年, 査読有り

  
• Lewis acid control of asymmetric synthesis - Preface

  K Maruoka

  TETRAHEDRON, 2001年01月, 査読有り

  
• Zr(OBut)(4) as an effective promoter for the Meerwein-Ponndorf-Verley alkynylation and cyanation of aldehydes: development of new asymmetric cyanohydrin synthesis

  T Ooi; T Miura; K Takaya; H Ichikawa; K Maruoka

  TETRAHEDRON, 2001年01月, 査読有り

  
• Bowl-shaped tris(2,6-diphenylbenzyl)tin hydride: A unique reducing agent for radical and ionic chemistry

  K Sasaki; Y Kondo; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001年, 査読有り

  
• Practical approach to the Meerwein-Ponndorf-Verley reduction of carbonyl substrates with new aluminum catalysts

  T Ooi; H Ichikawa; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001年, 査読有り

  
• Remarkable template effect of a Lewis acid receptor in the intramolecular radical cyclization: control of reaction pathway as well as stereochemistry

  T Ooi; Y Hokke; E Tayama; K Maruoka

  TETRAHEDRON, 2001年01月, 査読有り

  
• New chiral bis-titanium(IV) catalyst with dibenzofuran spacer for catalytic asymmetric allylation of aldehydes and aryl ketones

  H Hanawa; S Kii; K Maruoka

  ADVANCED SYNTHESIS & CATALYSIS, 2001年01月, 査読有り

  
• Dramatic rate enhancement by ultrasonic irradiation in liquid-liquid phase-transfer catalytic reactions

  T Ooi; E Tayama; K Doda; M Takeuchi; K Maruoka

  SYNLETT, 2000年10月, 査読有り

  
• Facile synthesis of L-Dopa tert-butyl cater by catalytic enantioselective phase-transfer alkylation

  T Ooi; M Kameda; H Tannai; K Maruoka

  TETRAHEDRON LETTERS, 2000年10月, 査読有り

  
• Tris(2,6-diphenylbenzyl)silyl group as a new and highly effective protector for carboxylic acids: Unusual behavior of such carboxylic esters toward common nucleophiles and bases

  A Iwasaki; Y Kondo; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000年10月, 査読有り

  
• Chiral zirconium alkoxides-mediated asymmetric Meerwein-Ponndorf-Verley cyanation of aldehydes

  T Ooi; K Takaya; T Miura; H Ichikawa; K Maruoka

  SYNLETT, 2000年08月, 査読有り

  
• Unique synthetic utility of BF₃·OEt₂ in the highly diastereoselective reduction of hydroxy carbonyl and dicarbonyl substrates

  O. Takashi; D. Uraguchi; J. Morikawa; K. Maruoka

  Organic Letters, 2000年07月, 査読有り

  
• Dramatic enhancement of reactivity of organosilicon compounds induced by complexation of bis(allyl)silanes with fluoride ion

  A Shibato; Y Itagaki; E Tayama; Y Hokke; N Asao; K Maruoka

  TETRAHEDRON, 2000年07月, 査読有り

  
• Bis-zirconium and bis-hafnium catalysts for the strong activation of carbonyl substrates

  H Hanawa; S Kii; N Asao; K Maruoka

  TETRAHEDRON LETTERS, 2000年07月, 査読有り

  
• Practical catalytic enantioselective synthesis of α,α-dialkyl-α-amino acids by chiral phase-transfer catalysis [10]

  T. Ooi; M. Takeuchi; M. Kameda; K. Maruoka

  Journal of the American Chemical Society, 2000年05月, 査読有り

  
• Efficient catalytic procedure for etherification of alcohols with MeAl(NTf2)(2)

  T Ooi; H Ichikawa; Y Itagaki; K Maruoka

  HETEROCYCLES, 2000年02月, 査読有り

  
• "Amphiphilic" cleavage of gamma-stannyl ketones with ATPH/RLi: Application to enone fragmentation by the conjugate addition - Cleavage sequence

  Y Kondo; K Kon-i; A Iwasaki; T Ooi; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000年, 査読有り

  
• Zr(OBut)(4) as a new promoter for the Meerwein-Ponndorf-Verley alkynylation and cyanation of aldehydes

  T Ooi; K Takaya; T Miura; K Maruoka

  SYNLETT, 2000年01月, 査読有り

  
• Chemistry of chelate-type hypervalent boron and aluminum: Utilization for selective organic synthesis

  D Uraguchi; T Ooi; K Maruoka

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2000年01月, 査読有り

  
• \\'Amphiphilic\\' cleavage of γ-stannyl ketones with ATPH/RLi: Application to enone fragmentation by the conjugate addition - Cleavage sequence

  Y. Kondo; K. Kon-i; A. Iwasaki; T. Ooi; K. Maruoka

  Angewandte Chemie - International Edition, 2000年, 査読有り

  
• Highly efficient amphiphilic cleavage of γ-iodo carbonyl substrates with aluminum tris(2,6-diphenylphenoxide)/t-BuLi system

  Y. Kondo; K. Kon-i; T. Ooi; K. Maruoka

  Tetrahedron Letters, 1999年12月, 査読有り

  
• Double coordination ability of bis(dimethylaluminum) sulfate toward carbonyl substrates

  H Hanawa; N Maekawara; K Maruoka

  TETRAHEDRON LETTERS, 1999年11月, 査読有り

  
• Catalytic, high-speed Tishchenko reaction using (2,7-dimethyl-1,8-biphenylenedioxy)bis(diisopropoxyaluminum) as a powerful bidentate catalyst

  T Ooi; T Miura; K Takaya; K Maruoka

  TETRAHEDRON LETTERS, 1999年10月, 査読有り

  
• Remarkable catalytic activity of Me3Ga in the alkylation of hetero-substituted epoxides with alkynyllithiums

  T Ooi; J Morikawa; H Ichikawa; K Maruoka

  TETRAHEDRON LETTERS, 1999年08月, 査読有り

  
• Double coordination and activation ability of methylalumoxane (MAO) for hetero functionality: Pivotal role as polymerization cocatalyst

  H Hanawa; N Abe; K Maruoka

  TETRAHEDRON LETTERS, 1999年07月, 査読有り

  
• Highly efficient alkylation of epoxides with R3Al/H2O systems based on the double activation of epoxy oxygens

  N Abe; H Hanawa; K Maruoka; M Sasaki; M Miyashita

  TETRAHEDRON LETTERS, 1999年07月, 査読有り

  
• Molecular design of a C₂-symmetric chiral phase-transfer catalyst for practical asymmetric synthesis of α-amino acids [12]

  T. Ooi; M. Kameda; K. Maruoka

  Journal of the American Chemical Society, 1999年07月, 査読有り

  
• Efficient synthesis of aromatic sec-amides from esters: Synthetic utility of bislithium amides

  T Ooi; E Tayama; M Yamada; K Maruoka

  SYNLETT, 1999年06月, 査読有り

  
• Pentacoordinate organoaluminum chemistry: Catalytic efficiency of Me3Al in the epoxide cleavage with alkynyllithiums

  T Ooi; N Kagoshima; H Ichikawa; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999年04月, 査読有り

  
• Hypercoordination of aluminum: Evidence for the implication of pentacoordinate complexes in the R2AlCl-promoted reduction of alkoxycarbonyl substrates

  T Ooi; J Morikawa; D Uraguchi; K Maruoka

  TETRAHEDRON LETTERS, 1999年04月, 査読有り

  
• The synthetic utility of the hypercoordination of boron and aluminum

  K Maruoka; T Ooi

  CHEMISTRY-A EUROPEAN JOURNAL, 1999年03月, 査読有り

  
• Unique property of copper(I) chloride as a radical initiator as well as a Lewis acid: Application to CuCl-catalyzed aldol reaction of α,β- unsaturated ketones with Bu₃SnH

  T. Ooi; K. Doda; D. Sakai; K. Maruoka

  Tetrahedron Letters, 1999年03月, 査読有り

  
• Simultaneous functional group manipulation in the Meerwein-Ponndorf-Verley reduction process catalyzed by bidentate aluminum reagent

  T Ooi; Y Itagaki; T Miura; K Maruoka

  TETRAHEDRON LETTERS, 1999年03月, 査読有り

  
• The synthetic utility of the hypercoordination of boron and aluminum

  K. Maruoka; T. Ooi

  Chemistry - A European Journal, 1999年, 査読有り

  
• Pentacoordinate vs. tetracoordinate complexation for alkoxycarbonyl compounds with dialkylboron triflates and trifluoroacetates?

  T Ooi; D Uraguchi; K Maruoka

  TETRAHEDRON LETTERS, 1998年10月, 査読有り

  
• First Meerwein-Ponndorf-Verley alkynylation: Nonorganometallic way for carbonyl alkylations

  T Ooi; T Miura; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998年10月, 査読有り

  
• Highly efficient, catalytic Meerwein-Ponndorf-Verley reduction with a novel bidentate aluminum catalyst

  T Ooi; T Miura; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998年09月, 査読有り

  
• Organoaluminum-promoted selective addition to fluorinated carbonyl compounds via pentacoordinate trialkylaluminum complexes

  T Ooi; N Kagoshima; D Uraguchi; K Maruoka

  TETRAHEDRON LETTERS, 1998年09月, 査読有り

  
• Highly efficient, catalytic Meerwein-Ponndorf-Verley reduction with a novel bidentate aluminum catalyst

  T Ooi; T Miura; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998年09月, 査読有り

  
• Facile and selective alkylation of 3,3,3-trifluoropropene oxide (TFPO) with organoaluminum reagents via pentacoordinate trialkylaluminum complexes

  T Ooi; M Furuya; K Maruoka

  CHEMISTRY LETTERS, 1998年08月, 査読有り

  
• Hypercoordination of boron and aluminum: Synthetic utility as chelating Lewis acids

  T Ooi; D Uraguchi; N Kagoshima; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998年06月, 査読有り

  
• Selective conjugate alkylation of alkyllithium nucleophiles to alpha,beta,gamma,delta-unsaturated aldehydes with functionalized Lewis acid receptors

  T Ooi; Y Kondo; K Kon-I; K Maruoka

  CHEMISTRY LETTERS, 1998年05月, 査読有り

  
• Dilithium 2,2 '-methylenebis(4,6-di-tert-butylphenoxide) as a bidentate Lewis acid in organic synthesis

  T Ooi; A Saito; K Maruoka

  TETRAHEDRON LETTERS, 1998年05月, 査読有り

  
• Simultaneous coordination and double activation phenomena of carbonyl and epoxy oxygens by bis-titanium reagent as a bidentate Lewis acid catalyst

  N Asao; S Kii; H Hanawa; K Maruoka

  TETRAHEDRON LETTERS, 1998年05月, 査読有り

  
• o-bis(allyldimethylsilyl)benzene as a remarkably effective allylation agent for carbonyl compounds with Bu4NF catalyst

  N Asao; A Shibato; Y Itagaki; F Jourdan; K Maruoka

  TETRAHEDRON LETTERS, 1998年05月, 査読有り

  
• High activation of carbonyl groups with bidentate Lewis acid catalysts

  T Ooi; N Asao; K Maruoka

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1998年05月, 査読有り

  
• Selective conjugate alkylation of alkyllithium nucleophiles to α, β, γ, δ-unsaturated aldehydes with functionalized Lewis acid receptors

  T. Ooi; Y. Kondo; K. Kon-i; K. Maruoka

  Chemistry Letters, 1998年05月, 査読有り

  
• Rate acceleration in nucleophilic alkylation of carbonyl compounds with a new template containing two metallic centers

  T Ooi; M Takahashi; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998年04月, 査読有り

  
• Protic solvent-promoted neutral allylation of aldehydes and ketones with 1,8-bis(allylstannyl)naphthalenes

  N Asao; N Abe; Z Tan; K Maruoka

  SYNLETT, 1998年04月, 査読有り

  
• Exceptionally bulky Lewis acidic reagent, MAD

  T Ooi; K Maruoka

  REVIEWS ON HETEROATOM CHEMISTRY, 1998年, 査読有り

  
• Remarkable Rate Acceleration of Nucleophilic Carbonyl Alkylation with a New Bimetallic Two-Center Template.

  丸岡 啓二

  Angew. Chem. Int. Ed. Engl.,37/6,835-837, 1998年, 査読有り

  
• Unprecedented encapsulation of carbonyl guest with designer Lewis acid receptor

  T Ooi; Y Kondo; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998年, 査読有り

  
• 1,8-bis(allylstannyl)naphthalene derivatives as neutral allylation agents: Rate acceleration by chelation-induced Lewis acidity

  N Asao; PL Liu; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997年12月, 査読有り

  
• Bidentate organoaluminum Lewis acid for selective activation of carbonyl over acetal functionality: Chemoselective functionalization

  T Ooi; E Tayama; M Takahashi; K Maruoka

  TETRAHEDRON LETTERS, 1997年10月, 査読有り

  
• Organoaluminum-catalyzed new alkylation of tert-alkyl fluorides: Synthetic utility of Al-F interaction

  T Ooi; D Uraguchi; N Kagoshima; K Maruoka

  TETRAHEDRON LETTERS, 1997年08月, 査読有り

  
• Regioselective Robinson annulation realized by the combined use of lithium enolates and aluminum tris(2,6-diphenylphenoxide) (ATPH)

  S Saito; Shimada, I; Y Takamori; M Tanaka; K Maruoka; H Yamamoto

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997年07月, 査読有り

  
• Fluorine-assisted selective alkylation to fluorinated epoxides and carbonyl compounds: Implication of pentacoordinate trialkylaluminum complexes

  T Ooi; N Kagoshima; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997年06月, 査読有り

  
• Remarkable template effect of a Lewis acidic receptor in intramolecular radical cyclizations

  T Ooi; Y Hokke; K Maruoka

  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997年06月, 査読有り

  
• Evaluation of several fluorinated ATPH derivatives as functionalized Lewis acid receptors for conjugate alkylation to α,β-unsaturated aldehydes with alkyllithium nucleophiles

  T. Ooi; Y. Kondo; T. Miura; K. Maruoka

  Tetrahedron Letters, 1997年06月, 査読有り

  
• Conjugate allylation to α,β-unsaturated aldehydes with the new chemzyme p-F-ATPH

  T. Ooi; Y. Kondo; K. Maruoka

  Angewandte Chemie - International Edition in English, 1997年06月, 査読有り

  
• Conjugate allylation to α,β-unsaturated aldehydes with amphiphilic alkylation system, ATPH/allylcerium reagents

  T. Ooi; T. Miura; Y. Kondo; K. Maruoka

  Tetrahedron Letters, 1997年06月, 査読有り

  
• Selective alkylation of ketones with a bulky aluminum reagent - The THF-TBSOTf system

  S Saito; M Ito; K Maruoka; H Yamamoto

  SYNLETT, 1997年04月, 査読有り

  
• Organoaluminum-promoted cyclization of olefinic epoxides. A new and stereoselective approach to cyclohexane frameworks

  N Murase; K Maruoka; T Ooi; H Yamamoto

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997年03月, 査読有り

  
• Organoaluminum-promoted rearrangement of epoxysilanes to α-silylaldehydes

  T. Ooi; T. Kiba; K. Maruoka

  Chemistry Letters, 1997年, 査読有り

  
• (2,7-dimethyl-1,8-biphenylenedioxy)bis(dimethyl-aluminum) as a bidentate Lewis acid: Its reactivity and selectivity in organic synthesis

  T Ooi; M Takahashi; K Maruoka

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996年11月, 査読有り

  
• Novel anionic oligomerization by a new, sequential generation of organolithium compounds

  K Maruoka; M Oishi; H Yamamoto

  MACROMOLECULES, 1996年04月, 査読有り

  
• The catalytic Shapiro reaction

  K Maruoka; M Oishi; H Yamamoto

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996年03月, 査読有り

  
• Exceptionally bulky Lewis acidic reagent, MAD

  T Ooi; K Maruoka

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1996年03月, 査読有り

  
• 共役アルキル化反応の新展開 (1996年の化学-2-)

  丸岡 啓二

  化学, 1996年02月, 査読有り

  
• UNPRECEDENTED NUCLEOPHILIC-ADDITION OF ORGANOLITHIUMS TO AROMATIC-ALDEHYDES AND KETONES BY COMPLEXATION WITH ALUMINUM TRIS(2,6-DIPHENYLPHENOXIDE)

  K MARUOKA; M ITO; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995年09月, 査読有り

  
• EVALUATION OF ALUMINUM TRIS(2,6-DI-TERT-BUTYL-4-METHYLPHENOXIDE) (ATD) AS A LEWIS-ACID RECEPTOR

  K MARUOKA; H IMOTO; H YAMAMOTO

  SYNLETT, 1995年07月, 査読有り

  
• ORGANOALUMINUM-PROMOTED CYCLOADDITION OF TRIALKYLSILYLKETENE WITH ALDEHYDES - A NEW, STEREOSELECTIVE APPROACH TO CIS-2-OXETANONES AND 2(Z)-ALKENOIC ACIDS

  AB CONCEPCION; K MARUOKA; H YAMAMOTO

  TETRAHEDRON, 1995年04月, 査読有り

  
• REARRANGEMENT OF TRANS-STILBENE OXIDE TO DIPHENYLACETALDEHYDE WITH CATALYTIC METHYLALUMINUM BIS(4-BROMO-2,6-DI-TERT-BUTYLPHENOXIDE) - (OXIRANE, 2,3-DIPHENYL-, TRANS- TO BENZENEACETALDEHYDE, ALPHA-PHENYL-)

  T OOI; K MARUOKA; H YAMAMOTO

  ORGANIC SYNTHESES, VOL 72, 1995年, 査読有り

  
• ALUMINUM TRIS(2,6-DIPHENYLPHENOXIDE) (ATPH) AS AN EFFICIENT AND SELECTIVE ACTIVATOR FOR INOUE POLYMERIZATION

  K MARUOKA; M AKAKURA; H YAMAMOTO

  SYNLETT, 1995年01月, 査読有り

  
• MOLECULAR DESIGN OF A CHIRAL LEWIS-ACID FOR THE ASYMMETRIC CLAISEN REARRANGEMENT

  K MARUOKA; S SAITO; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995年01月, 査読有り

  
• 新しいルイス酸型レセプターATPHを用いる選択的有機合成

  丸岡 啓二

  化学,50/3,58, 1995年, 査読有り

  
• EXO-SELECTIVE DIELS-ALDER REACTION-BASED ON A MOLECULAR RECOGNITION APPROACH

  K MARUOKA; H IMOTO; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994年12月, 査読有り

  
• ORGANOALUMINUM-PROMOTED HOMOLOGATION OF KETONES WITH DIAZOALKANES

  K MARUOKA; AB CONCEPCION; H YAMAMOTO

  JOURNAL OF ORGANIC CHEMISTRY, 1994年08月, 査読有り

  
• ASYMMETRIC DIELS-ALDER REACTION OF UNSYMMETRICAL MALEATES - A CHEMICAL ACCESS TO CHIRAL, UNSYMMETRICAL CIS-CYCLOHEXENE-1,2-DICARBOXYLATES

  K MARUOKA; M AKAKURA; S SAITO; T OOI; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994年07月, 査読有り

  
• METHYLALUMINUM BIS(4-SUBSTITUTED-2,6-DI-TERT-BUTYLPHENOXIDE) AS AN EFFICIENT NONCHELATING LEWIS-ACID - APPLICATION TO ASYMMETRIC DIELS-ALDER REACTION AND DIASTEROSELECTIVE ALKYLATION TO ALKOXY CARBONYL SUBSTRATES

  K MARUOKA; M OISHI; K SHIOHARA; H YAMAMOTO

  TETRAHEDRON, 1994年07月, 査読有り

  
• Virtually complete blocking of α,β-unsaturated aldehyde carbonyls by complexation with aluminum tris(2,6-diphenylphenoxide)

  K. Maruoka; H. Imoto; S. Saito; H. Yamamoto

  Journal of the American Chemical Society, 1994年05月, 査読有り

  
• Unprecedented stereochemical control in the intramolecular ene-reactions of δ,ε-unsaturated aldehydes using exceptionally bulky organoaluminum reagents: Elucidation of the transition state

  T. Ooi; K. Maruoka; H. Yamamoto

  Tetrahedron, 1994年05月, 査読有り

  
• LEWIS ACID-PROMOTED SELECTIVE REARRANGEMENT OF TRISUBSTITUTED EPOXIDES TO ALDEHYDES OR KETONES

  K MARUOKA; N MURASE; R BUREAU; T OOI; H YAMAMOTO

  TETRAHEDRON, 1994年03月, 査読有り

  
• REGIOSELECTIVE FISCHER INDOLE SYNTHESIS MEDIATED BY ORGANOALUMINUM AMIDES

  K MARUOKA; M OISHI; H YAMAMOTO

  JOURNAL OF ORGANIC CHEMISTRY, 1993年12月, 査読有り

  
• REGIOSELECTIVE HYDROALUMINATION OF ALLENES AND THEIR SYNTHETIC APPLICATION

  S NAGAHARA; K MARUOKA; H YAMAMOTO

  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993年12月, 査読有り

  
• STABILIZATION OF REACTIVE ALDEHYDES BY COMPLEXATION WITH METHYLALUMINUM BIS(2,6-DIPHENYLPHENOXIDE) AND THEIR SYNTHETIC APPLICATION

  K MARUOKA; AB CONCEPCION; N MURASE; M OISHI; N HIRAYAMA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993年05月, 査読有り

  
• CHIRAL HELICAL LEWIS-ACIDS FOR ASYMMETRIC DIELS-ALDER CATALYSTS

  K MARUOKA; N MURASE; H YAMAMOTO

  JOURNAL OF ORGANIC CHEMISTRY, 1993年05月, 査読有り

  
• CHEMOSELECTIVE FUNCTIONALIZATION OF MORE HINDERED ALDEHYDE CARBONYLS WITH THE METHYLALUMINUM BIS(2,6-DIPHENYLPHENOXIDE)/ALKYLLITHIUM SYSTEM

  K MARUOKA; S SAITO; AB CONCEPCION; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993年02月, 査読有り

  
• エポキシドの選択的転位を機軸とする不斉アルドール合成

  丸岡 啓二

  化学,48/3,218-9, 1993年, 査読有り

  
• Designer Lewis Acid Based on Molecular Recognition

  丸岡 啓二

  Supramolecular Chemistry,2/2-3,111-21, 1993年, 査読有り

  
• PRACTICAL ASYMMETRIC-SYNTHESIS OF BOTH ERYTHRO AND THREO ALDOLS BASED ON THE MABR-PROMOTED SELECTIVE REARRANGEMENT OF ERYTHRO AND THREO EPOXY SILYL ETHERS - UNUSUAL EFFECT OF SILYL SUBSTITUENTS

  K MARUOKA; J SATO; H YAMAMOTO

  TETRAHEDRON, 1992年05月, 査読有り

  
• MIGRATORY APTITUDE OF ALKYL SUBSTITUENTS IN THE MABR-PROMOTED EPOXIDE REARRANGEMENT

  K MARUOKA; T OOI; H YAMAMOTO

  TETRAHEDRON, 1992年04月, 査読有り

  
• Methylaluminum Bis(4-bromo-2, 6-di-┣DBtert(/)-┫DB-butylphenoxide) as a Key Reagent for Effecting α-┣DBprimary(/)-┫DB-Alkylation of Carbonyl Compounds

  丸岡 啓二

  Journal of the American Chemical Society,114/11,4422, 1992年, 査読有り

  
• Discrimination of Two Different Ester Carbonyls with MAD : Application to the Regio- and Stereocontrolled Diels-Alder Reaction of Unsymmetrical Fumarates

  丸岡 啓二

  Journal of the American Chemical Society,114/3,1089, 1992年, 査読有り

  
• A HIGHLY EFFICIENT SEPARATION OF STRUCTURALLY SIMILAR EPOXY SILYL ETHERS BY COMPLEXATION CHROMATOGRAPHY ON POLYMERIC ORGANOALUMINUM REAGENTS

  S NAGAHARA; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1992年01月, 査読有り

  
• Organoaluminum-catalyzed rearrangement of epoxides a facile route to the synthesis of optically active β-siloxy aldehydes

  K. Maruoka; T. Ooi; S. Nagahara; H. Yamamoto

  Tetrahedron, 1991年08月, 査読有り

  
• Practical Asymmetric Synthesis of Both ┣DBerythro(/)-┫DB and ┣DBthreo(/)-┫DB Aldols : Unusual Effect of Silyl Groups

  丸岡 啓二

  Journal of the American Chemical Society,113/14,5449, 1991年07月01日, 査読有り

  
• ENANTIOSELECTIVE ACTIVATION OF ETHERS BY CHIRAL ORGANOALUMINUM REAGENTS - APPLICATION TO ASYMMETRIC CLAISEN REARRANGEMENT

  K MARUOKA; H BANNO; H YAMAMOTO

  TETRAHEDRON-ASYMMETRY, 1991年, 査読有り

  
• Unprecedented stereochemical control in the organoaluminum-promoted intramolecular ene reactions of δ,ε-unsaturated aldehydes

  K. Maruoka; T. Ooi; H. Yamamoto

  Journal of the American Chemical Society, 1990年11月, 査読有り

  
• STEREOSELECTIVE AND REGIOSELECTIVE ORGANIC TRANSFORMATIONS BASED ON MAIN GROUP ORGANOMETALLIC REAGENTS - APPLICATION TO THE STEREOCONTROLLED CLAISEN REARRANGEMENTS

  H YAMAMOTO; K MARUOKA

  PURE AND APPLIED CHEMISTRY, 1990年10月, 査読有り

  
• MOLECULAR RECOGNITION OF ETHERS WITH MODIFIED ORGANOALUMINUM REAGENTS

  K MARUOKA; S NAGAHARA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990年08月, 査読有り

  
• Generation of Stable Formaldehyde-Organoaluminum Complexes and its Synthetic Utility

  丸岡 啓二

  Journal of the American Chemical Society,112/20, 1990年, 査読有り

  
• ORGANOALUMINUM-PROMOTED CLAISEN REARRANGEMENT OF ALLYL VINYL ETHERS

  K NONOSHITA; H BANNO; K MARUOKA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990年01月, 査読有り

  
• ORGANOALUMINUM-PROMOTED REARRANGEMENT OF ALLYL PHENYL ETHERS

  K MARUOKA; J SATO; H BANNO; H YAMAMOTO

  TETRAHEDRON LETTERS, 1990年, 査読有り

  
• MOLECULAR RECOGNITION OF OXYGEN-CONTAINING SUBSTRATES WITH MAD

  K MARUOKA; S NAGAHARA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1990年, 査読有り

  
• A NEW PREPARATIVE METHOD FOR VARIOUS METAL ENOLATES

  K MARUOKA; N HIRAYAMA; H YAMAMOTO

  POLYHEDRON, 1990年, 査読有り

  
• Organoaluminum-promoted rearrangement of epoxy silyl ethers to β-siloxy aldehydes

  K. Maruoka; T. Ooi; H. Yamamoto

  Journal of the American Chemical Society, 1989年08月, 査読有り

  
• LEWIS ACID CATALYST IN ORGANIC-SYNTHESIS

  H YAMAMOTO; K MARUOKA; K FURUTA

  ACID-BASE CATALYSIS, 1989年, 査読有り

  
• ORGANOALUMINUM-PROMOTED CLAISEN REARRANGEMENT OF BISALLYL VINYL ETHERS

  K MARUOKA; H BANNO; K NONOSHITA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1989年, 査読有り

  
• AN EFFICIENT, CATALYTIC PROCEDURE FOR EPOXIDE REARRANGEMENT

  K MARUOKA; S NAGAHARA; T OOI; H YAMAMOTO

  TETRAHEDRON LETTERS, 1989年, 査読有り

  
• GENERATION OF CHIRAL ORGANO-ALUMINUM REAGENT BY DISCRIMINATION OF THE RACEMATES WITH CHIRAL KETONE

  K MARUOKA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989年01月, 査読有り

  
• AMPHIPHILIC REACTIONS BY MEANS OF EXCEPTIONALLY BULKY ORGANO-ALUMINUM REAGENTS - RATIONAL APPROACH FOR OBTAINING UNUSUAL EQUATORIAL, ANTI-CRAM, AND 1,4 SELECTIVITY IN CARBONYL ALKYLATION

  K MARUOKA; T ITOH; M SAKURAI; K NONOSHITA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988年05月, 査読有り

  
• METHYLALUMINUM BIS(2,6-DI-TERT-BUTYL-4-METHYLPHENOXIDE) AS A PROTECTING GROUP FOR MULTIFUNCTIONAL MOLECULES - SYNTHETIC UTILITY IN SELECTIVE CARBONYL REDUCTIONS

  K MARUOKA; Y ARAKI; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988年04月, 査読有り

  
• ASYMMETRIC ENE REACTION CATALYZED BY CHIRAL ORGANO-ALUMINUM REAGENT

  K MARUOKA; Y HOSHINO; T SHIRASAKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1988年, 査読有り

  
• CHEMOSELECTIVE CARBONYL ALKYLATION AND REDUCTION OF ALDEHYDES OR KETONES

  K MARUOKA; Y ARAKI; H YAMAMOTO

  TETRAHEDRON LETTERS, 1988年, 査読有り

  
• ASYMMETRIC HETERO-DIELS-ALDER REACTION CATALYZED BY CHIRAL ORGANO-ALUMINUM REAGENT

  K MARUOKA; T ITOH; T SHIRASAKA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988年01月, 査読有り

  
• Tetrahedron report number 239. Organoaluminums in organic synthesis

  K. Maruoka; H. Yamamoto

  Tetrahedron, 1988年, 査読有り

  
• Unusual conjugate addition of organolithium reagent to α, β-unsaturated ketone

  K. Maruoka; K. Nonoshita; H. Yamamoto

  Tetrahedron Letters, 1987年, 査読有り

  
• ORGANOBORANE-CATALYZED HYDROALUMINATION OF OLEFINS

  K MARUOKA; H SANO; K SHINODA; S NAKAI; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986年09月, 査読有り

  
• Epoxy silyl ether rearrangements: A new, stereoselective approach to the synthesis of β-hydroxy carbonyl compounds

  K. Maruoka; M. Hasegawa; H. Yamamoto; K. Suzuki; M. Shimazaki; G.-I. Tsuchihashi

  Journal of the American Chemical Society, 1986年06月, 査読有り

  
• ASYMMETRIC DIELS-ALDER REACTION DIRECTED TOWARD CHIRAL ANTHRACYCLINE INTERMEDIATES

  K MARUOKA; M SAKURAI; J FUJIWARA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1986年, 査読有り

  
• ASYMMETRIC CYCLIZATION OF UNSATURATED ALDEHYDES CATALYZED BY A CHIRAL LEWIS ACID

  S SAKANE; K MARUOKA; H YAMAMOTO

  TETRAHEDRON, 1986年, 査読有り

  
• CHIRAL LEAVING GROUP - ASYMMETRIC-SYNTHESIS OF LIMONENE AND BISABOLENE

  S SAKANE; J FUJIWARA; K MARUOKA; H YAMAMOTO

  TETRAHEDRON, 1986年, 査読有り

  
• SELECTIVE ORGANIC-SYNTHESIS USING ORGANO-ALUMINUM REAGENTS

  K MARUOKA; H YAMAMOTO

  JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1985年, 査読有り

  
• Selective Reactions using Organoaluminum Reagents

  丸岡 啓二

  Angewandt Chemie, Int. Ed. Engl.,24/8, 1985年, 査読有り

  
• ASYMMETRIC CYCLIZATION OF UNSATURATED ALDEHYDES CATALYZED BY A CHIRAL LEWIS ACID

  S SAKANE; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1985年, 査読有り

  
• NUCLEOPHILIC CLEAVAGE OF ACETALS USING ORGANOMETALLIC REAGENTS

  A MORI; J FUJIWARA; K MARUOKA; H YAMAMOTO

  JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985年, 査読有り

  
• A NEW, STEREOCONTROLLED SYNTHESIS OF EQUATORIAL ALCOHOLS BY THE AMBIPHILIC REDUCTION OF CYCLOHEXANONES

  K MARUOKA; M SAKURAI; H YAMAMOTO

  TETRAHEDRON LETTERS, 1985年, 査読有り

  
• Trialkylaluminum-alkylidene iodide. A powerful cyclopropanation agent with unique selectivity [1]

  K. Maruoka; Y. Fukutani; H. Yamamoto

  Journal of Organic Chemistry, 1985年, 査読有り

  
• METHYLALUMINUM BIS(2,6-DI-TERT-BUTYL-4-ALKYLPHENOXIDE) - A NEW REAGENT FOR OBTAINING UNUSUAL EQUATORIAL AND ANTI-CRAM SELECTIVITY IN CARBONYL ALKYLATION

  K MARUOKA; T ITOH; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985年, 査読有り

  
• Stereoselective conjugate addition of organoaluminum reagents to chiral α,β-unsaturated ketals

  Y. Fukutani; K. Maruoka; H. Yamamoto

  Tetrahedron Letters, 1984年, 査読有り

  
• A NEW SYNTHESIS OF NITROGEN-CONTAINING HETEROCYCLES BY MEANS OF ORGANO-ALUMINUM REAGENTS

  J FUJIWARA; H SANO; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1984年, 査読有り

  
• Unprecedented regio- and stereochemical control in the addition of organoaluminum reagents to chiral α,β-unsaturated acetals

  J. Fujiwara; Y. Fukutani; M. Hasegawa; K. Maruoka; H. Yamamoto

  Journal of the American Chemical Society, 1984年, 査読有り

  
• NUCLEOPHILIC CLEAVAGES OF ACETALS USING ORGANOTITANIUM REAGENTS - A NEW SYNTHESIS OF CHIRAL ALCOHOLS

  A MORI; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1984年, 査読有り

  
• SELECTIVE REACTIONS USING ORGANO-ALUMINUM REAGENTS

  H YAMAMOTO; K MARUOKA

  PURE AND APPLIED CHEMISTRY, 1983年, 査読有り

  
• ASYMMETRIC REDUCTION OF KETONE REDUCTIVE CLEAVAGE OF CHIRAL ACETALS USING ORGANO-ALUMINUM REAGENTS

  A MORI; J FUJIWARA; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1983年, 査読有り

  
• NUCLEOPHILIC AROMATIC-SUBSTITUTION BY ORGANO-ALUMINUM REAGENTS - APPLICATION TO THE SYNTHESIS OF INDOLES

  J FUJIWARA; Y FUKUTANI; H SANO; K MARUOKA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983年, 査読有り

  
• CARBON CARBON BOND FORMATION BY SELECTIVE COUPLING OF ENOL SILYL ETHERS WITH OXIME SULFONATES

  Y MATSUMURA; J FUJIWARA; K MARUOKA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983年, 査読有り

  
• CONCENTRATION PROFILE OF CU-2+ ION NEAR A PLANE VERTICAL CATHODE IN ELECTROLYTES CONTAINING CUSO4 AND AN EXCESS OF H2SO4 AS A SUPPORTING ELECTROLYTE

  Y FUKUNAKA; K DENPO; M IWATA; K MARUOKA; Y KONDO

  JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983年, 査読有り

  
• A NEW SYNTHESIS OF IMIDOYL IODIDES VIA BECKMANN REARRANGEMENT OF OXIME SULFONATES

  Y ISHIDA; S SASATANI; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1983年, 査読有り

  
• OLEFINIC CYCLIZATION PROMOTED BY BECKMANN REARRANGEMENT OF OXIME SULFONATE SYNTHESIS OF DL-MUSCONE

  S SAKANE; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1983年, 査読有り

  
• OLEFINIC CYCLIZATIONS PROMOTED BY BECKMANN REARRANGEMENT OF OXIME SULFONATE

  S SAKANE; Y MATSUMURA; Y YAMAMURA; Y ISHIDA; K MARUOKA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983年, 査読有り

  
• DIISOBUTYLALUMINUM HYDRIDE - A NOVEL REAGENT FOR THE REDUCTION OF OXIMES

  S SASATANI; T MIYAZAKI; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1983年, 査読有り

  
• CHIRAL LEAVING GROUP - BIOGENETIC-TYPE ASYMMETRIC-SYNTHESIS OF LIMONENE AND BISABOLENES

  S SAKANE; J FUJIWARA; K MARUOKA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983年, 査読有り

  
• ORGANOALUMINUM-PROMOTED BECKMANN REARRANGEMENT OF OXIME SULFONATES

  K MARUOKA; T MIYAZAKI; M ANDO; Y MATSUMURA; S SAKANE; K HATTORI; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983年, 査読有り

  
• STEREOSELECTIVE SYNTHESES OF SOLENOPSIN-A AND SOLENOPSIN-B

  Y MATSUMURA; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1982年, 査読有り

  
• BIOMIMETIC ENTRY TO ACYCLIC TERPENE SYNTHESIS A NOVEL REARRANGEMENT OF ALLYL ETHER CATALYZED BY ORGANO-ALUMINUM REAGENTS

  Y YAMAMURA; K UMEYAMA; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1982年, 査読有り

  
• BECKMANN REARRANGEMENT OF OXIME SULFONATES BY GRIGNARD-REAGENTS

  K HATTORI; K MARUOKA; H YAMAMOTO

  TETRAHEDRON LETTERS, 1982年, 査読有り

  
• Total synthesis of (±)-celacinnine, (±)-celallocinnine, (±)-celafurine, and (±)-celabenzine

  H. Yamamoto; K. Maruoka

  Journal of the American Chemical Society, 1981年, 査読有り

  
• SUCCESSIVE BECKMANN REARRANGEMENT-ALKYLATION SEQUENCE BY ORGANO-ALUMINUM REAGENTS - A SIMPLE ROUTE TO DL-PUMILIOTOXIN-C

  K HATTORI; Y MATSUMURA; T MIYAZAKI; K MARUOKA; H YAMAMOTO

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981年, 査読有り

  
• REGIOSELECTIVE CARBONYL AMINATION USING DIISOBUTYLALUMINUM HYDRIDE

  H YAMAMOTO; K MARUOKA

  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981年, 査読有り

  
• NOVEL N-ALKYLATION OF AMINES WITH ORGANOCOPPER REAGENTS

  H YAMAMOTO; K MARUOKA

  JOURNAL OF ORGANIC CHEMISTRY, 1980年, 査読有り

  
• Intramolecular dibromo ketone-iron carbonyl reaction in terpene synthesis [5]

  R. Noyori; M. Nishizawa; F. Shimizu; Y. Hayakawa; K. Maruoka; S. Hashimoto; H. Yamamoto; H. Nozaki

  Journal of the American Chemical Society, 1979年, 査読有り

  
• A new and highly effective aldol synthesis [2]

  K. Maruoka

  Journal of the American Chemical Society, 1977年, 査読有り

  

MISC

• Stereoselective terminal functionalization of small peptides for catalytic asymmetric synthesis of unnatural peptides

  K Maruoka; E Tayama; T Ooi

  PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2004年04月, 査読有り

  
• Catalytic asymmetric synthesis of α-amino acid derivatives and peptides using chiral phase-transfer catalysts

  K. Maruoka

  Proceedings of the Japan Academy Series B: Physical and Biological Sciences, 2003年09月, 査読有り

  

講演・口頭発表等

• Design of High-Performance Organocatalysts for Green Sustainable Chemistry: A Good Harmony with Water

  The 2nd Korea Forum on Organic Chemistry-KSOS, 2012年11月23日

  
• Design of High-Performance Organocatalysts for the Efficient Synthesis of Both Enantiomeric Products

  COST ORCA Meeting, 2012年11月01日

  
• The Power of Asymmetric Phase Transfer Catalysis

  International Conference “Catalysis in Organic Synthesis”, 2012年09月15日

  
• Design of Single and Supramolecularly Assembled Organocatalysts for Green Sustainable Chemistry

  The Chinese Chemical Society Annual Meeting, 2011年12月04日

  
• New Frontier on Organocatalytic Aldol Chemistry: Development of anti- and syn-Selective Asymmetric Cross-Aldol Reaction of Two Different Aldehydes

  Tenth International Conference on Organic Reactions (10th ISOR), 2011年11月21日

  
• Design of High-Performance Phase-Transfer Catalysts as Promising Organocatalysts

  Second International Collaborative and Cooperative Chemistry Symposium (2nd ICCCS), 2011年10月31日

  
• Development of New Synthetic Methodologies of α-Diazo Carbonyl Compounds Promoted by Metal and Organocatalysts

  The 5th International Symposium: The Chemistry of Aliphatic Diazo Compounds: Advances and Outlook, 2011年06月07日

  
• Design of High-Performance Organocatalysts for the Development of Environmentally-Benign Reactions for Green Sustainable Chemistry

  12th Spring Meeting of Synthetic Chemistry, 2011年06月07日

  
• Design of High-Performance Organocatalysts for Green Sustainable Chemistry

  CATAFLU.OR Symposium, 2011年03月24日

  
• Organocatalytic Way to the Asymmetric Synthesis of Small Peptides

  PACIFICHEM2010 - Frontiers in Peptide Chemistry: Synthesis and Applications Symposium, 2010年12月18日

  
• New Discovery in Asymmetric Phase-Transfer Catalysis

  PACIFICHEM2010 - New Dimension of Green Sustainable Chemistry: Novel Reactions and Catalysts Symposium, 2010年12月15日

  
• Design of High-Performance Bifunctional Organocatalysts

  International Symposium on Organocatalysis (ISOμ 2010), 2010年07月14日

  
• Design of High-Performance Bifunctional Organocatalysts for Practical Asymmetric Synthesis

  First International Conference on Advancing the Chemical Science (1st ICACS), 2010年07月07日

  
• Surprising Discovery on Base-Free Phase-Transfer Reactions

  Eleventh International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-11), 2009年11月09日

  
• Design of High-Performance Organocatalysts for Practical Asymmetric Synthesis

  Chemistry Conference on "Frontiers in Synthesis, Catalysis and Biochemistry", 2009年09月13日

  
• Organocatalytic Way to the Asymmetric Synthesis of Useful Amino Acids and Alkaloids

  20th International Symposium on Chirality, 2008年07月06日

  
• (131) Designer Chiral Organocatalysts for Catalytic Asymmetric Synthesis

  International Workshop on Green Chemistry, 2008年04月28日

  
• Design of Binaphthyl-Modified Chiral Organocatalysts for Asymmetric Synthesis

  9 th Netherlands Catalysis and Chemistry Conference, 2008年03月03日

  
• Binaphthyl-Modified Chiral Organocatalysts for Practical Asymmetric Synthesis

  2 nd ERA-Chemistry Flash Conference on “Catalysis without Metal”, 2007年10月28日

  
• Designer Chiral Organocatalysts for Practical Asymmetric Synthesis

  Gordon Research Conference on Organic Reactions and Processes, 2007年07月15日

  
• (104) Design of Chiral Phase Transfer Catalysts for Practical Asymmetric Synthesis

  8th International Symposium on Carbanion Chemistry (ISCC-8), 2007年06月06日

  
• Practical Asymmetric Synthesis with Designer Chiral Organocatalysts

  9th International Symposium for Chinese Organic Chemists (ISCOC-9), 2006年12月17日

  
• Designer Chiral Phase Transfer Catalysts for Practical Asymmetric Synthesis

  Organocatalysis Synposium in the 232nd ACS National Meeting, 2006年09月10日

  
• Catalytic Asymmetric Synthesis with Chiral Designer Phase Transfer Catalysts

  16th IUPAC’s International Conference on Organic Synthesis (ICOS-16), 2006年06月11日

  
• Catalytic Asymmetric Synthesis with Designer Chiral Organocatalysts

  7th Tetrahedron Symposium, 2006年05月25日

  
• Design of Extremely Active Chiral Phase Transfer Catalyst for Practical Asymmetric Synthesis

  PACIFICHEM2005-Organocatalyzed Asymmetric Synthesis Symposium, 2005年12月17日

  
• Design of Powerful Chiral Phase Transfer Catalysts for Asymmetric Carbon-Carbon Bond Formation

  10th International Chemical Conference in Taipei (ICCT 10), 2005年10月28日

  
• Design of C2-Symmetric Chiral Phase-Transfer Catalysts as Chiral Organocatalysts for Practical Asymmetric Synthesis

  40th Euchem Conference on Stereochemistry, 2005年04月16日

  

書籍等出版物

• Asymmetric α-Functionalization of Carbonyl Compounds and Alkylation of Enolates

  丸岡 啓二

  Georg Thieme Verlag KG: Stuttgart, 2012年, 査読無し

  
• Asymmetric Organocatalysis: Vol. 6

  丸岡 啓二

  Georg Thieme Verlag KG: Stuttgart, 2012年, 査読無し

  
• Asymmetric Phase-Transfer Catalysis

  丸岡 啓二

  Wiley-VCH: Weinheim,, 2012年, 査読無し

  
• Comprehensive Chirality: Vol. 5

  丸岡 啓二

  Elsevier, 2012年, 査読無し

  
• Asymmetric Catalysis on Industrial Scale, Second Edition

  丸岡 啓二

  Wiley-VCH, 2010年07月, 査読無し

  
• 使える！有機合成反応241実践ガイド

  丸岡 啓二

  化学同人, 2010年04月01日, 査読無し

  京大の蔵書を調べる：

  
• Catalytic Asymmetric Synthesis, Third Edition

  丸岡 啓二

  化学同人, 2010年03月, 査読無し

  
• Handbook of Cyclization Reactions

  丸岡 啓二

  Wiley-VCH, 2009年12月, 査読無し

  
• 進化を続ける有機触媒, 丸岡啓二編

  丸岡 啓二

  化学同人, 2009年07月30日, 査読無し

  
• Asymmetric Synthesis and Application of α-Amino Acids: ACS Symposium Series

  丸岡 啓二

  American Chemical Society,Vol.1009, 2009年06月, 査読無し

  
• Handbook of Asymmetric Heterogeneous Catalysis

  丸岡 啓二

  Wiley-VCH, 2008年11月, 査読無し

  
• Asymmetric Phase Transfer Catalysis

  丸岡 啓二

  Wiley-VCH, 2008年04月, 査読無し

  
• Catalytic Asymmetric Synthesis

  丸岡 啓二

  VCH Publishers, Inc.,413-40, 1993年, 査読無し

  
• Asymmetric Reactions with Chiral Lewis Acid Catalysts

  丸岡 啓二

  VCH Publishers,, 1993年, 査読無し

  

産業財産権

• (18) 光学活性α-置換マンデル酸化合物の製造方法

  
• (17) アルジミンまたはその誘導体を用いる一置換アルキル化化合物の製造方法

  
• 軸不斉を有する光学活性アミノ酸誘導体及び該アミノ酸誘導体を不斉触媒として用いる光学活性化合物の製造方法

  
• 軸不斉を有する光学活性な４級アンモニウム塩を用いたα-アミノ酸誘導体の製造方法

  
• 光学活性４級アンモニウム塩化合物およびそれが触媒する不斉エポキシ化反応

  
• 光学活性3,5-ジヒドロ-4H-ジナフト[2,1-c:1ﾕ,2ﾕ-e]アゼピンおよびそのシュウ酸塩の製造方法

  
• キラル相間移動触媒およびそれを用いた不斉ペプチドの製造方法

  
• ビナフチル基およびビフェニル基を含むＮ-スピロ不斉相間移動触媒

  
• 軸不斉を有する光学活性な４級アンモニウム塩、その製法およびα-アミノ酸誘導体の不斉合成への応用

  
• 軸不斉を有する光学活性な４級アンモニウム塩、その製法およびα-アミノ酸誘導体の不斉合成への応用

  

受賞

• 1986年

  日本化学会, 日本化学会進歩賞
• 2001年

  井上科学振興財団, 井上学術賞
• 2002年

  新技術開発財団, 市村学術賞
• 2003年

  有機合成化学協会, 有機合成化学協会賞
• 2004年

  万有生命科学振興国際交流財団, 名古屋シルバーメダル
• 2006年

  グリーンサステイナブルケミストリーネットワーク・文部科学省, グリーン・サステイナブル・ケミストリー賞・文部科学大臣賞
• 2007年

  Molecular Chirality Research Organization, モレキュラー・キラリティー賞
• 2007年

  日本化学会, 日本化学会賞
• 2007年

  ノバルティス製薬, ノバルティス・レクチャーシップ賞
• 2010年

  中日新聞, 中日文化賞
• 2011年

  アメリカ化学会, アーサー・C・コープ・スカラー賞
• 2011年

  フンボルト財団, フンボルト研究賞
• 2011年11月

  日本政府内閣府, 紫綬褒章
• 2012年

  東レ科学振興会, 東レ科学技術賞
• 2012年

  京都新聞社, 京都新聞大賞　文化学術賞

外部資金：科学研究費補助金

• ペプチド医薬合成を指向する新規な触媒・精密合成反応の開発

  基盤研究(S)

  大区分E

  京都大学

  丸岡 啓二

  自 2021年07月05日, 至 2026年03月31日, 交付

  ペプチド医薬;金属触媒;有機触媒;ラジカル触媒;精密合成反応;ペプチド合成;かさ高いアミノ酸;超原子価ヨウ素;アミノ化合物;フッ化アシル;ペプチド開裂反応;ベンジルラジカル;カチオン性DABCO型触媒

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21H05026/
• 新規な有機ラジカル触媒の開発を指向したデザイン型N-オキシラジカルの機能創出

  挑戦的研究(萌芽)

  中区分33:有機化学およびその関連分野

  京都大学

  丸岡 啓二

  自 2020年07月30日, 至 2023年03月31日, 完了

  ラジカル反応;有機ラジカル触媒;N-オキシラジカル;N-ヒドロキシベンズイミダゾール;ベンジル位;アルデヒド;アシルラジカル;フッ化アシル;ラジカル触媒;N-ヒドロキシフタルイミド;プリビリッジド構造;炭素ラジカル

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20K21193/
• 高性能ハイブリッド触媒系を活用する高選択的ドミノ反応の開発

  新学術領域研究(研究領域提案型)

  理工系

  京都大学

  丸岡 啓二

  自 2017年06月30日, 至 2022年03月31日, 完了

  ハイブリッド触媒;ドミノ反応;精密有機合成;有機分子触媒;金属錯体触媒;ペプチド;臭化銅;セレクトフルオル;ラジカル反応;フッ化アシル;超原子価ヨウ素;アルキルシリルペルオキシド;環状アセタール;β-ヒドロキシアルデヒド;セロトニン拮抗薬;酸フッ化物;アミン触媒;不斉ベンゾイロキシ化反応;ラジカル;セミピナコール転位;アルキルシリルパーオキシド;Ｎ－ヒドロキシベンゾイミダゾール

  https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-17H06450/
• 次世代型有機分子触媒の創製と実践的精密有機合成への応用

  基盤研究(S)

  京都大学

  丸岡 啓二

  自 2014年05月30日, 至 2019年03月31日, 完了

  高性能有機触媒;精密有機合成;塩基触媒;酸触媒;酸塩基複合触媒;ラジカル触媒;環境調和型;不斉変換反応;次世代型有機触媒;有機塩基触媒;脱芳香族化反応;不斉共役付加反応;有機酸塩基触媒;有機ラジカル触媒;NHBI触媒;アシル化反応;有機触媒;脱金属触媒;次世代型触媒;ベンゾイロキシ化反応;共役付加反応;有機ラジカル;ジフルオロメチル化剤;キラル相間移動触媒;二官能性触媒;ラクトン化反応;有機分子触媒;精密有機合成反応;不斉アルドール反応;オキシインドール;アシルラジカル;有機酸職場

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26220803/
• 化学合成を指向する新方法論としてのレドックス有機触媒反応

  特別研究員奨励費

  京都大学

  丸岡 啓二

  自 2012年04月01日, 至 2015年03月31日, 完了

  軸性キラルアニリド;不斉合成;キラル相間移動触媒;エナンチオ選択性;ラジカル環化反応;アルデヒド;共役付加反応;二官能性有機アミン触媒;有機合成;有機触媒;レドックス触媒

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12F02034/
• 多機能性分子触媒の創製と合成的応用

  基盤研究(A)

  京都大学

  丸岡 啓二

  自 2009年04月01日, 至 2010年03月31日, 完了

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21245010/
• 高性能有機触媒の創製と精密有機合成化学への応用

  特別推進研究

  理工系

  京都大学

  丸岡 啓二

  自 2009年04月01日, 至 2015年03月31日, 完了

  高性能有機触媒;精密有機合成;塩基触媒;酸触媒;酸塩基複合触媒;ラジカル触媒;環境調和型;不斉変換反応;キラル相間移動触媒;不斉アルドール反応;キノンイミンケタール;不斉Diels-Alder反応;有機ラジカル;二官能性触媒;アミナール;1,3-双極子付加環化反応;触媒的不斉合成;アルキル化反応;不斉共役付加反応;マンニッヒ反応;アゲラスタチンＡ;Ugi反応;有機触媒;有機酸触媒;有機ラジカル触媒;共役付加反応;エナンチオ選択的;アゾメチンイミン;交差型アルドール反応;不斉アルキル化;イミノアザエナミン反応;遠隔不斉制御;有機二官能性触媒;不斉フッ素化反応;不斉マンニッヒ反応;交差アルドール反応;キラルジカルボン酸;双極子付加環化反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21000006/
• 二点配位型ルイス酸触媒の精密デザインと合成的応用

  基盤研究(B)

  京都大学

  丸岡 啓二

  自 2007年04月01日, 至 2009年03月31日, 完了

  触媒的不斉合成;二点配位型;ルイス酸;ブレンステッド酸;有機触媒;二点配位型触媒;不斉合成;精密有機合成化学;チタン触媒;イミノアザエナミン反応;アジリジン化反応;デザイン;1,3-双極子環状付加;シクロプロパン化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19350020/
• 精密酸塩基触媒を用いる官能基炭素分子の高度分子変換反応の開拓

  特定領域研究

  理工系

  京都大学

  丸岡 啓二

  自 2005年04月01日, 至 2009年03月31日, 完了

  炭素資源;有機酸塩基触媒;高度分子変換;プロセス有機合成化学;キラル相間移動反応;光学活性アミノ酸;二官能基性有機触媒;キラルジカルボン酸触媒;キラル相間移動触媒;キラル二官能性アミン触媒;不斉アミノ化反応;不斉マンニッヒ反応;アルドール反応;キラルジカルボン酸;イミノアザエナミン反応;炭素炭素結合形成反応;アミノ酸;不斉共役付加反応;不斉アルドール反応;不斉分子変換反応;二官能基性触媒;不斉ヒドロキシアミノ化;スピロ型アンモニウム塩;クラウンエーテル;人工アミノ酸

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17065010/
• 炭素資源の高度分子変換

  特定領域研究

  理工系

  京都大学

  丸岡 啓二

  自 2005年04月01日, 至 2010年03月31日, 完了

  炭素資源;高度分子変換;シンポジウム;成果報告書;要旨集;ポスター;計画班員;公募班員;新機能性材料;医農薬;プロセス有機合成化学;公開シンポジウム;国際会議;ニュースレター;高度分子変換反応;創設シンポジウム

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17065009/
• 二点配位型キラルチタン錯体の創製と新規不斉合成反応の案出

  特定領域研究

  理工系

  京都大学

  丸岡 啓二

  自 2003年04月01日, 至 2004年03月31日, 完了

  二点配位型キラルチタン触媒;二点配位型ルイス酸;精密有機合成;不斉アリル化;アルデヒド;アルドール体

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15036235/
• 精密酸塩基触媒の創製と精密有機合成化学への活用

  基盤研究(S)

  京都大学

  丸岡 啓二

  自 2001年04月01日, 至 2006年03月31日, 完了

  精密有機合成化学;精密酸塩基触媒;触媒的不斉合成;二点配位型ビス-チタン;二重活性化;キラル相間移動触媒;光学活性人工アミノ酸;機能性有機金属分子;精密合成反応プロセス;精密ルイス酸触媒;二点配位型ルイス酸;不斉双極子環状付加;マンザシジンA;不斉ストレッカー反応;不斉マンニッヒ反応;精密ルイス酸;カルボニル;グリシンエステル;不斉アルキル化反応;不斉アルドール反応;不斉共役付加反応;不斉アリル化;ティシュチェンコ反応;不斉ニトロアルドール反応;シリル化合物;Neber転位;精密合成;不斉合成;ルイス酸;二点配位型;キラル触媒;相間移動触媒;L-ドーバ, acid;base catalysts;bidentate Ti(IV) complex;enantioselective allylation;1, 3-dipolar cycloaddition;phase transfer catalysis;binaphthol;amino acid;Strecker reaction

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13853003/
• 環境調和を指向する有用アミノ酸類の実用的不斉合成プロセスの開発

  基盤研究(B)

  京都大学

  丸岡 啓二

  自 2001年04月01日, 至 2002年03月31日, 完了

  キラル相間移動触媒;触媒的不斉合成;有用アミノ酸;シンコナアルカロイド;ビナフトール;グリシン;不斉アルキル化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13554021/
• 半球型有機金属分子のデザインと精密有機合成化学への応用

  基盤研究(B)

  京都大学

  丸岡 啓二

  自 2001年04月01日, 至 2003年03月31日, 完了

  トリアルキルシリル;カルボン酸;半球型分子;有機ケイ素;アルキルリチウム

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13440215/
• 光学活性メタラ環状化合物の創製と不斉合成への応用

  特定領域研究(A)

  理工系

  京都大学

  丸岡 啓二

  自 2001年04月01日, 至 2002年03月31日, 完了

  メタラ環状化合物;二点配位型ルイス酸;亜鉛化合物;プロリン;不斉アルキル化;アミノアルコール;不斉合成

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13029055/
• フッ素原子による機能の創出

  基盤研究(C)

  東京薬科大学

  田口 武夫

  自 2000年04月01日, 至 2001年03月31日, 完了

  フッ素;フッ素化;トルフルオロメチル;ジフルオロメチレン;フルオロアルキル

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12895025/
• 先例のないキレート型高配位典型金属錯体の創製と精密有機合成への活用

  萌芽的研究

  京都大学

  丸岡 啓二

  自 2000年04月01日, 至 2002年03月31日, 完了

  典型金属化合物;有機アルミニウム;キレート;アルコキシケトン;ルイス酸;ボラン;トリブチルスズヒドリド;高配位典型金属;精密有機合成;アルミニウム;ホウ素;ジアステレオ選択性;アピカル型

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12874072/
• 隣接基関与を活用する新規ラジカル、アニオン発生法の案出

  基盤研究(B)

  京都大学;北海道大学

  丸岡 啓二

  自 1999年04月01日, 至 2001年03月31日, 完了

  有機合成化学;ハロゲン化アルキル;炭素ラジカル;隣接基関与;炭素アニオン種;アニオン種;ヘテロ原子;セレン;テルル;金属ハロゲン交換;炭素炭素結合形成, organic synthesis;alkyl halides;carbon-centered radicals;anchimeric effect;carbanion species

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-11440184/
• ルイス酸塩基活性種による動的立体化学制御

  特定領域研究(B)

  京都大学;北海道大学

  丸岡 啓二

  自 1998年04月01日, 至 2001年03月31日, 完了

  ルイス酸塩基活性種;5配位ホウ素錯体;二点配位型金属触媒;動的立体化学制御;アミノ酸;光学活性希土類錯体;モンモリロナイト触媒;カルボアニオン反応;不斉環化反応;不斉エポキシ化;速度論的光学分割;ルイス酸活性種;5配位ホウ素鎖体;立体化学制御;機能性ルイス酸触媒;光学活性希土類鎖体;固体触媒;5配位典型金属活性種;二点配位型有機金属分子;機能性ルイス酸;精密環化重合;希土類ルイス酸塩基触媒;カルポアニオン反応, Lewis acid;base active species;pentacoordinate boron complex;bidentate metal catalyst;dynamic stereochemical control;amino acid;chiral rare-earth metal complex;montmorillonite catalyst;carbanion reaction

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10208201/
• 動的立体化学制御

  特定領域研究(B)

  九州大学

  香月 勗

  自 1998年04月01日, 至 2001年03月31日, 完了

  立体化学;有機化学;合成化学;触媒・化学プロセス;分子認識;キラル分離;動的立体化学制御;光活性化;二点配位;不斉アリル化;エンド環化;ビニルシラン;光学活性カラム;サレン金属錯体;立体配座;電子移動型反応;カルボニルイリド;不斉識別能;不斉金属錯体触媒;立体配座制御;ルイス酸活性種;不安定活性種;電極反応制御;非安定化カルボニルイリド;不斉識別機構, stereocontrol;chiral recognition;asymmetric catalysis;Asymmetric allylation;endo-Cyclization;Vinylsilane;organic synthesis;chirality

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10208104/
• 分子間相互作用の設計ならびにルイス酸塩基活性種による動的立体化学制御

  特定領域研究(B)

  京都大学;北海道大学

  丸岡 啓二

  自 1998年04月01日, 至 2001年03月31日, 完了

  ルイス酸活性種;動的立体化学制御;5配位ホウ素;二点配位型チタン触媒;不斉触媒;触媒的不斉反応;多機能触媒;複合酸塩基金属錯体;分子間相互作用;三フッ化ホウ素;二点配位型触媒;サレン-ルテニウム錯体;不斉シクロプロパン化;光学活性ビスホスフィン;5配位典型金属;二点配位型有機金属分子, Lewis acid;base active species;dynamic stereochemical control;pentacoordinate boron;bidentate titanium catalyst;asymmetric catalyst;catalytic asymmetric synthesis;multifunctional catalyst;combined acid;base metal catalyst

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10208101/
• ダブルターゲティング能を有する人工酵素のデザインと機能開発

  特定領域研究(A)

  北海道大学

  丸岡 啓二

  自 1998年04月01日, 至 1999年03月31日, 完了

  ルイス酸型人工酵素;ATPH;カプセル分子;二官能性基質;集積型錯体;環状付加反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10145201/
• 次世代ルイス酸・反応剤の精密設計

  重点領域研究

  北海道大学

  丸岡 啓二

  自 1997年04月01日, 至 1998年03月31日, 完了

  二点配位型ルイス酸;ケトン還元;向山アルドール反応;N,N-ジメチルホルムアミド;二重活性化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-09231204/
• 特殊反応場を提供するルイス酸の触媒設計

  重点領域研究

  北海道大学

  丸岡 啓二

  自 1997年04月01日, 至 1998年03月31日, 完了

  共役アルキル化反応;機能性ルイス酸;ATPH;アンフィフィリック;p-F-ATPH;α,β,γ,δ-不飽和カルボニル

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-09218201/
• 機能性ルイス酸を活用する生理活性物質の実用的合成

  基盤研究(A)

  北海道大学

  丸岡 啓二

  自 1996年04月01日, 至 1998年03月31日, 完了

  ATPH;ラジカル反応;二点配位;アルミニウム;チタン;官能基選択性;機能性ルイス酸;二点配位型アルミニウム;二点配位型チタン;アリルトリブチルスズ;ケトン還元;テンプレート;α, β-不飽和アルデヒド, ATPH;radical reaction;conjugate alkylation;aluminum;titanium;chemoselectivity

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08555225/
• 金属型人工酵素のデザインと精密有機合成への応用

  基盤研究(A)

  北海道大学

  丸岡 啓二

  自 1996年04月01日, 至 1999年03月31日, 完了

  二点配位型ルイス酸;有機アルミニウム反応剤;二点配位型チタン触媒;向山アルドール反応;光学活性ビナフトール;光学活性チタン触媒;不斉アリル化反応;エナンチオ選択性;実用的不斉合成;カルボニル化合物;チタン;ケトン還元;アリル化;エポキシド;有機アルミニウム;N, N-ジメチルホルムアミド, bidentate Lewis acid;organoaluminum reagent;bidentate titanium catalyst;Mukaiyama aldol reaction;chiral binaphthol;chiral titaniumu catalyst;asymmetric allylation

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08404049/
• 次世代ルイス酸反応剤の精密設計

  重点領域研究

  北海道大学

  丸岡 啓二

  自 1996年04月01日, 至 1997年03月31日, 完了

  アリルトリアルキルスズ;中性有機金属化合物;キレート形成;ビス(アリル)スズ化合物;ビス(プレニル)スズ化合物;官能基選択的アリル化

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08245205/
• 実践的合成プロセスの開発

  特定領域研究(A)

  京都大学

  伊藤 嘉彦

  自 1996年04月01日, 至 1999年03月31日, 完了

  シリルホウ素化反応;不斉エポキシ化反応;分子内ディールス・アルダー反応;N-トシル-4-ビニリデン-2-オキサゾリジノン;タキソールの合成;二点配位型チタン系ルイス酸;光学活性アリルシランの合成;パラジウム(0)イソニトリル錯体;ο-アリリックヒドロキシアミンの〔2,3〕転位;ベンジル位の不斉ヒドロキシル化;メソ環状エーテルの非対称化による不斉合成;タキソ-ル不斉全合成;アリルスズとアルデヒドの分子内反応;海洋産ポリ環状エーテルの合成;キラル金属錯体触媒;触媒的不斉反応;タキソ-ル骨格の構築;アミンのα-位酸化触媒;アリル金属試薬;アリル化剤;光学活性アリルシラン;光学活性アレニルシラン

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08245104/
• 特殊反応場を提供するルイス酸の触媒設計

  重点領域研究

  北海道大学

  丸岡 啓二

  自 1996年04月01日, 至 1997年03月31日, 完了

  共役アルキル化反応;機能性ルイス酸;ATPH;α,β-不飽和カルボニル;アンフィフィリック;p-F-ATPH

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08232201/
• 2点配位型ルイス酸触媒の開発

  一般研究(C)

  北海道大学

  丸岡 啓二

  自 1995年04月01日, 至 1996年03月31日, 完了

  二点配位型ルイス酸;有機アルミニウム;エクアトリアル選択性;共役付加反応;カルボニル基

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07805081/
• 機能性有機アルミニウム反応剤の創製とその高選択的合成反応への応用

  重点領域研究

  北海道大学

  丸岡 啓二

  自 1995年04月01日, 至 1996年03月31日, 完了

  機能性有機アルミニウム;求核的芳香族置換反応;芳香族アルデヒド;芳香核ケトン;ATPH

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07216230/
• 新しい光学活性アルミニウム反応剤を用いる不斉クライゼン転位反応の開発

  重点領域研究

  北海道大学

  丸岡 啓二

  自 1995年04月01日, 至 1996年03月31日, 完了

  光学活性アルミニウム反応剤;不斉クライゼン転位;アリル ビニル エーテル;光学活性配位子;光学活性ビナフトール

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07214215/
• ルイス酸型レセプターを用いる新しい分子認識化学の開発

  基盤研究(A)

  名古屋大学

  山本 尚

  自 1994年04月01日, 至 1997年03月31日, 完了

  ルイス酸型レセプター;アルミニウム反応剤;デザイン型ルイス酸;ルイス塩基;選択的有機合成;分子認識化学;ルイス酸塩基複合体;ルイス塩基複合体;有機アルミニウム;複合体形成クロマトグラフィー, Lewis acidic receptor;Aluminum reagent;Designer Lewis acid;Lewis base;Selective organic synthesis;Molecular recognition chemistry;Lewis acid-base complex

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-06403024/
• 有機アルミニウム化合物を用いる新規ルイス酸塩基複合体形成クロマトグラフィーの開発

  一般研究(C)

  名古屋大学

  丸岡 啓二

  自 1992年04月01日, 至 1993年03月31日, 完了

  有機アルミニウム;ルイス酸型レセプター;クロマトグラフィー;エポキシド

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-04650769/
• アリル型有機金属化合物の高選択的反応の開発

  重点領域研究

  名古屋大学

  山本 尚

  自 1992年04月01日, 至 1993年03月31日, 完了

  アリル型金属化合物;高配位化合物;立体選択的発生法;アリルバリウム反応剤;α-アリル化反応;異性化温度;カルボキシル化反応;ホモアリルアルコール

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-04217211/
• 有機アルミニウム反応剤を用いる新しい分子認識化学の開発

  一般研究(B)

  名古屋大学

  山本 尚

  自 1991年04月01日, 至 1993年03月31日, 完了

  ルイス酸型レセプター;有機アルミニウム;分子認識化学;複合体形成クロマトグラフィー;ディールズ・アルダー反応;光学活性アルミニウム反応剤;ビナフトール;不斉クライゼン転位;不斉ディールズ・アルダー反応;ルイス酸型レセプタ-;複合体形成クロマトグラフィ-;ディ-ルズ・アルダ-反応, Lewis Acidic Receptor;Organoaluminums;Molecular Recognition;Complexation Chromatography;Diels-Alder Reaction;Chiral Organoaluminums;Binaphthols;Asymmetric Claisen Rearrangement

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-03453100/
• アリル型有機金属化合物の高選択的反応の開発

  重点領域研究

  名古屋大学

  山本 尚

  自 1991年04月01日, 至 1992年03月31日, 完了

  アリル型金属化合物;高配位化合物;位置制御;非対称型アリルカルボアニオン;αー選択的アリル化;アシルシラン類;立体制御;異性化温度

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-03233211/
• キラルルイス酸触媒の開発による反応の高次制御

  重点領域研究

  名古屋大学

  山本 尚

  自 1991年04月01日, 至 1992年03月31日, 完了

  光学活性アルミニウム反応剤;光学活性ホウ素反応剤;ヘテロ・ディ-ルズ・アルダ-反応;エン反応;クライゼン転位;アルド-ル反応;エナンチオ面区別反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-03215215/
• 新有機化学反応の開拓と生理活性物質の化学合成

  特別推進研究

  名古屋大学

  野依 良治

  自 1987年04月01日, 至 1991年03月31日, 完了

  新有機化学反応;有機,鉛化合物;高選択的1,4ー付加反応;パラジウム(0)錯体触媒;新脱保護法;不斉水素化;BINAP;DAIB;有機亜鉛;アルキル化;不斉クライゼン転位;アリル系保護基;超純度DNA合成;超原子価スズ化合物;分子内エン反応;アミノアルコール;有機亜鉛化合物;アシロキシボラン;不斉DielsーAlder反応;BINAP錯体;プロスタグランジン合成;DNA固相合成;不斉アルキル化;有機アルミニウム;不斉増幅;不斉触媒;O価バラジウム;2-5A;アントラサイクリン;アリルオキシカルボニル;パラジウム;イソカルバサイクリン;ルテニウム錯体;1-βメチルチエナマイシン;ナブロキャン;シトロネロール;ビタミン;プロスタグランジン, BINAL-H;TMSOTf;BINAP;BINAP-Rh;BINAP-Ru;MAD;CAB;Pd(0)Catalyzed deprotection

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-62065005/
• プロスタグランジンの工業的製法の開発

  試験研究

  名古屋大学

  山本 尚

  自 1985年04月01日, 至 1987年03月31日, 完了

  プロスタグランジン;ジアニオン;不斉DielsーAlder;アレニルアニオン;不斉シクロプロパン化;不斉Diels-Alder;不斉合成, Prostaglandin;Dianion;Asymmetric Diels-Alder;Allenyl Anion

  https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-60850154/
• 新規グリーン触媒系の創製と電子移動制御に基づく精密合成反応の開発

  学術変革領域研究(A)

  学術変革領域研究区分(Ⅱ)

  京都大学

  丸岡 啓二

  自 2023年04月01日, 至 2028年03月31日, 交付

  グリーン触媒;HAT触媒;ラジカル触媒;光照射;選択的有機合成反応;精密合成反応

  https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-23H04910/